MUMBAI / AKOLA / DELHI / KOLKATA / GHAZIABAD / NASHIK / GOA / BOKARO / PUNE

IIT – JEE: 2021 ASSIGNMENT (ADV) DATE: / / 21

TIME: 1 Hr. ALDEHYDES & KETONES MARKS: 00

MULTIPLE CORRECT ANSWER TYPE

This section contains 15 multiple choice questions. Each question has 4 options (A), (B), (C) and
(D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

1. The product

(A) (B)

(C) (D)

2.

In the above sequence the final products of the reaction is/are

(A) (B)

(C) (D)

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3.

Correct option is

(A)

(B)

(C)

(D)

4.

In the above reaction, (A) and (B) will respectively be

(A) (B)

(C) (D)

5. Which of the following pairs will form the same product with phenyl hydrazine / H  ?
(A) CH 2OH  CO  CH 3 and CHO  CHOH  CH 3
(B) Glucose and mannose
(C) Glucose and fructose
(D) Glucose and sucrose

6. Which is/are untrue statement(s)?

(A) Protonation increases electrophilic nature of carbonyl group
(B) CF3SO3 is a better leaving group than CH 3SO 3
(C) Benzyl carbonium ion is stabilized by resonance

(D) is unstable

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7. Identify the product in the following reaction

A ana d B are

(A) CHBr3 (B)

(C) (D)

8. In the following reaction

Product A and B are

(A) (B)

(C) (D)

9.

Product (C) is/are

(A) (B)

(C) (D)

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10.

Correct statements about [X] are

(A) The polymer is bakelite
(B) The polymer is Nylon–6
(C) The polymer contains six carbon atoms in the repeating units
(D) It is condensation polymer(s)

11.

(A) (B)

(C) (D) None of these

12. Select the correct reactions

(A)

(B)

(C)

(D)

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13. Choose the alkene(s) that would give the two products of the following ozonolysis reaction.

(A) i (B) ii (C) ii and iii (D) iii and iv

14. Choose the major product of the following reaction

(A) (B)

(C) (D)

15. Which of the following is correct for the final product of the given sequence of reaction

(A) Compound P3 on oxidation with  CrO3  H 2SO4  gives a compound which gives 2, 4 DNP test
(B) Compound P3 on reaction with I2  NaOH gives yellow ppt
(C) Compound P3 on reaction with ceric ammonium nitrate gives red colouration
(D) Compound P3 on reaction with MnO 2 gives carboxylic acid

NUMERICAL VALUE TYPE

This section contains 06 questions. Each question is numerical value type. For each question,
enter the correct numerical value (in decimal notation, truncated/rounded-off to second
decimal place. (e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.

16. How many products are possible when ethanal and phenyl ethanal (mixture) is treated with dil.
NaOH at about 10o C .

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17. For the given sequence of reaction

How many products are obtained finally?

18. Identify the total number of compounds that give positive test with Tollen’s reagent

19. Identify the total number of compounds that give positive iodoform test

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20. Identify the total number of compounds that give diastereomeric product on reaction with MeMgCl

21. Identify that compounds that give Cannizaro reaction

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