Scribd Logo
Upload

Welcome to Scribd!

  • Set 18 Chemical SC II (Y) J

    Uploaded by

    Aniket Kundu
    48 views24 pages
    Questions for SET West Bengal 2015_F

    Original Title

    Set 18 Chemical Sc II (y) j

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    Questions for SET West Bengal 2015_F

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    48 views24 pages

    Set 18 Chemical SC II (Y) J

    Uploaded by

    Aniket Kundu
    Questions for SET West Bengal 2015_F

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 24
    Signature of Invigilators Roll No. 1 (Write Roll Number from left side nally asin the Admit Card) a Question Booklet Series [Y] 1218 PAPER-IL Question Booklet No. ‘ (Gaentcal with, OMR Subject Code : 12 ice ON CHEMICAL SCIENCES Time : 2 Hours Maximum Marks: 200 Instructions for the Candidates 1, Write your Roll Number in the space provided on the top of this page as well as on the OMR Sheet provided. 2. At the commencement of the examination, the question booklet will be given to you. In the first 5 minutes, you are requested to open the booklet and verify it: (i) To have access to the Question Booklet, tear off the paper seal on the edge of this cover page Gi) Faulty booklet, if detected, should be got replaced immediately by a correct booklet from the invigilator within the period of 5 minutes. Afterwards, neither the Question Booklet will be replaced nor any extra time will be given. (iii). Verify whether the Question Booklet No. is identical with OMR Answer Sheet No.; if not, the full set is to be replaced. iv) After this verification is over, the Question Booklet Series and Question Booklet Number should be entered ‘on the OMR Sheet. This paper consists of One hundred (100) multiple-choice type questions. All the questions ate compulsory. Each question carries two marks 4, Each Question has four alternative responses marked: (A) (B) (C) (D). You have to darken the citcle as indicated below on the correct response against each question, Example: @® ® @ O, where © is the correct response 5. Your responses to the questions are to be indicated correctly in the OMR Sheet. If you mark your response at any place other than in the circle in the OMR Sheet, it will not be evaluated Rough work is to be done at the end of this booklet If you write your Name, Roll Number, Phone Number or put any mark on any part of the OMR Sheet, except in the space allotted for the relevant entties, which may disclose your identity, or use abusive language or employ any other unfair means, such as change of response by scratching or using white fluid, you will render yourself liable to disqualification. 8. Do not tamper or fold the OMR Sheet in any way. If you do so, your OMR Sheet will not be evaluated You have to return the Original OMR Sheet to the invigilator at the end of the examination compulsorily and must not carry it with you outside the Examination Hall. You are, however, allowed to carry question booklet and duplicate copy of OMR Sheet after completion of examination. 10, Use only Black Ball point pen. 11, Use of any calculator or mobile phone etc. is strictly prohibited. 12. There are no negative marks for incorrect answers. [ Please Turn Over ] y-3 1218- (CHEMICAL SCIENCES Paper I 1. For which of the following pairs bond angle of the first compound is greater than the second one? (A) NO, and CO, (B) NH, and NF, (©) OP, and XeF, (D) HLS and H,0 2, The major product of the following reactions is: _-£00H (rs (@ NaHco, LJ ow i 9 ML ® L y Nouns “cucu (J ° ON ©) \ 3. The formula of a metal carbonyl is Ma(CO); Mis (A) Fe B) Co (© Ma ©) Ni 4, Observe the following reaction: wt The reaction is an example of (A) 1,2-insertion and B-hydride elimination (B) alkene isomerization (C) a-hydride elimination (D) Both (A) and (B) 5, For a parallel reaction, the activation energy for the disappearance of A in terms of activation energies E, and E, of two parts is, given by 2218- 6. The major products [P] and [Q] in the following reaction sequence are: Mess © McOCHLCl $uCle py cl (i) HO, HOAc ba fy gations A) Pl= © a Meo. HOG 1 oo [= \ c @) Pl= C an ¢ 7 © Pa Lome | wos 4 Los w CO 1 2 8 w= & Y4 7. The major product formed in the following transformation is: ° . A cRCOOH Meo’ 8. For the reaction, +P +2Q—>R+S, AH =~ 25keal.mol and AS = 90 cal deg! mol? at 27°C. ‘Among the following, the correct statement is: (A) The reaction is not feasible at 27°C. (B) The reaction is irreversible at 27°C. (C) The reaction is at equilibrium state at 27°C. (D) The reaction can occur only at temperatures higher than 27°C. 9. The Vapour pressure of solid and. liquid ammonia near the triple point are given by: 1630K i Joel p! {vorr)=846— 330K Peand log(p! /torr) =846-8 What is the value of the ratio of slope of the solid-gas, curve and liquid-gas curve at the triple point? (A) 0-815 B) 1815 (©) 0225 (Dy 1.225 tel or) =100~ ss30K 10. Which of the following is correct wavefunction for helium atom? (A) 1s(1) 2s(2) (oB2- Bia.) (B) [1s(1) 28(2) - 28(1) 1s(2)] (4B —- Bio) (C) 18(1)28(2) aif. — 28(1)18(2) Biart As(1) 2s (2) Bro2— 28(1) 1s(2) oB2 (D) [1s(1)2s(2) - 2s(1)1s(2)] (a4sB2— Bicte) 11. Which ofthe following co-ordination compounds! ions should be achiral? (A) [CEDTAYT (B) [Ru(bipyridy),]" (©) trans-[CrCl,(0x), ©) cis-[CrC1,(0x),]" 1218- 12, The low detection limits obtained in stripping methods are a result of (A) faster measurements, which increase flux of, the analyte to the electrode surface. (B) preconcentration ofthe analyte atthe working electrode. (©) lower charging current compared to Pulse Polarography. (D) increased concentration of analyte in the bulk solution, 13. Which one of the following reactions does not occur? (A) XeF, + 3H,0 — XeO, + 6HF (B) Xe + Pu, > XeF, +Pt (© Xek, + SbF, > [XeF} (SbF,|- (D) (CoH),B + XeF,91CHsXe]" (CoH), BET 14, Which one of the following should possess maximum effective nuclear charge (Z,9) for an outer most electron? (A) F B® Li OB (D) Na 2218- 15, Themajorproductof the following photochemical reaction is: a 3 ty Tenzophenone ‘ery crs L CF; « | ®) | | Crs os or © || cr, oF, @) CF, Y6 16, Identify the major product of the following reaction: coon m—l—n cus ° Pan A “ ry ‘Sy A manic © ® S wero ° mm SS © A phic ° Ph o pa 17. ‘The major products [P] and [(Q] formed in the following reaction sequence ae: diglyme Tec Y-7 1218- 18, Following are the electronic transitions of a diatomic molecule: @ Dy w ‘Y's @',—'; w 'n,—>'S! The allowed transitions are (A) @ and Gi) only (B) Gi) and (iv) only (© @, Gi) and Gii) only (D) (i), Gi) and (iv) only 19. Organic molecules X and Y give coloured solutions while Z give colourless solution in water. In a photochemical experiment, X and Y are found to give well defined Ame, at 550 nm and 710 nm, respectively, and Z at 240 nm. Which of the following orders refers, to the life times of the corresponding excited states? (A) X>Y>Z (B) Y>X>Z (© X>Z>¥ () Z>Y>X Mi 20, X+¥“Z_ js amillisecond reaction, Which of the following expressions corresponds to the time of relaxation + [suffix ¢ refers to equilibrium]? (B) [=k ([Xle+1V]e) +k LL r 1 © oak [Xe +k Le ©) tai (4xdelv +x) 2218- 21. The correct structural types of the following compounds BH,,, BeHy; and B,Hy are (A) nido, arachano and closo, respectively (B) closo, arachano and nido, respectively (©) closo, nido and arachano, respectively (D) arachano, closo and nido, respectively 22. The coordination compounds, [Ni(CN),]* and [PtQNH,),]”* are expected to possess (A) square planar geometry. (B) square planar and tetrahedral geometry, respectively. (©) tetrahedral geometry (D) tetrahedral and square planar geometry, respectively. 23. The oxidant “X” used in the following reactionis: Tso Le aN ox aw NR ON NAN fi fi (A) Cros (B) 050, © Nalo, (D) mCPBA/NaOH 24, The degree of degeneracy for an energy level 1th? gqur Of ® Particle in a cubical box of side ‘L’ is ays @B) 3 o4 @2 28, ‘The partition function for a two-level system for which lower state (at energy 0) being non-degenerate and the upper state (at an energy ) triply degenerate is (A) wet (B) 3e/KT © 14 20°/KT @) 143e°#/KT 26. Pick the correct relation between vibrational temperature (0,3) and rotational temperature (0,..) from the following: vibrational frequency (A) So =“Fotational Constant * vibrational frequency (B) vy = yotational Constant“ 9" rotational Constant (©) vor = Fibrational frequency jy ——Potational Constant @) Pv vibrational frequency 27. The energy transfer efficiency between a donor (D) and an acceptor (A) molecule decreases when the (A) distance between the donor (D) and the acceptor (A) decreases. (B) distance between the donor (D) and the acceptor (A) increases. (©) the emission spectrum of the donor (D) strongly overlaps with the absorption spectrum of the acceptor (A), (D) fluorescence quantum yield of donor (D) becomes equal to that of the acceptor (A). 28, Identify the products P and Q in the following reactions: ° 1. Ph—cn,—C—en, ct —24_> p ‘workup ° 8, 2. Ph—cH—C—c, OH workap (A) P=PhCH, cH, coon Q= Ph-cH-CooH cH (B) P= Ph-cH-cooH om Q= PhCH, CH COO (©) P= PaCH,CH, coor Q= PhCH. CH, COOH (D) P= Phcit-cooH cH Qe» Ph f" ‘COOH cH, 1218- 29, Predict the major product of the following reaction. OC pHs © Lattin THE nos OCHS ° Ph (A) B) Ho! Ph © © Ho” Ph 30, ‘The number of isomeric structures possible for disubstituted borazine (B,N,H,X,) would be (A) One (B) Two (© Three (D) Four 31. An isotope !X undergoes a series of n alpha (at) and m beta (B) disintegration to form a stable isotope a-0¥?. What are the values of n and m? (A) 8,6 B) 6,8 (© 5,8 @) 8,8 2218- 32, The major product formed in the following reaction is: cooEt O COOEL SiMe, 33, A system undergoes change from macrostate Ito macrostate II, where six distinguishable particles are distributed in three different energy levels (0, ¢ and 2) energy 0 ec 26 Macrostatel 3 3 0 Macrostatel 2 2 2 ‘The change in entropy would be (A) RT Ind “ 5 @) Kings 3 Kind © King ©) 0 y10 34, What fraction of the volume of the unit cell is ‘occupied by a Copper atom? Assume each atom has a hard-sphere in contact with its neighbour and Copper crystallizes in a face-centred cubic lattice (A) 0-140 (B) 0340 (© 0540 () 0.740 35. Predict the number of spectral lines resulted as a splitting up of an energy level in a weak magnetic field for 3=5 (A) Five B) Six (© Seven (D) Eight 36. Which of the following molecules would generate triplet excited state upon irradiation by 532nm laser source during transient absorption experiment? (A) Calix [4] pyrrole (B) Tetracyanoethylene © Co () Allene Yl 37. The major product of the following reaction is - Me 38. Among the following the strongest conjugate base is (A) Noy 8) CHO Gi) Methyl vinylketone (ii), NaOAc, ACOH, H,0, heat () C,H,coo- 39. ‘The major product formed in the following reaction is: Z ~ oO om ] 7 Ny 1218- 40. Figure out the correct IUPAC name of given coordination compound; (Pt Br(NO,) (NH,),] [PtCh] (A) Bromonitrotetrammineplatinum(IV) tetrachloroplatinate (11) (B) Tetramminebromonitroplatinum(IV) tetrachloroplatinate (1) (©) Bromonitro-N tetrammineplatinum(IV) tetrachloroplatinate (II) (D) Tetramminebromonitro-N platinum(IV) tetrachloroplatinate (11) 41. For which of the following metal ions, strongest Jahn-Teller effectis observedin an octahedral complex? Ti B) v" (©) Mn” (high-spin) () Co* (high-spin) 42. Mossbauer spectra of Fes(Co);2 indicate that (A) environment around all three Fe-atoms are the same (B) environment around all three Fe-atoms are different (©) environment around two Fe-atoms are the same and that of the other Fe-atom is different (D) environment of the Fe-atoms is in dynamic equilibrium, hence indistinguishable. #. OH NaBH, Tropropanol ‘00H rons Suggest the structure of the product in the above reaction from the following spectral data: IR : 1725 em! PMR : 8 (ppm) 1-02(6H, s), 1-66 (2H, t, J= (QH, t, J = THz) and 3-9 2H, 8). “ cr ® >? ° A, NSN o-7| O VU >< 2218- 44, The cryptocyanine dye molecule, adisans of 4-637 A between two nitrogen atoms. The electronic spectra of cryptocyanine follow the model of a particle in one dimensional box. At which wavelength does it expected to absorb? (Given 8me/h = 3297). (A) 707 nm (B) 840 nm (© 727 om (D) 2706 nm 45, The major product formed in the following reaction is: yA nc Bu,SnH, AIBN(cst.) Patt eflux “~ Serb ° - NONE “™ oo SePh a N B) 9 xo © 2 ya 46. y, and yp are normalized and are mutually orthogonal to each other. The normalization constant for the function y, +3 y, is B ay @ 1 © ©) Rie wis 47. A normalized trial function for a particle in a ‘one-dimensional box of length ‘L’ is y = Nx (L— where Nis normalization constant. The upper bound to the ground state energy of the system Na ml? “w ® Nn 8ml? Nev © Gn NPL? ® a y3 . The major product of the following reaction is: a onc. no on le BFy-O8t, (i) Bur Gil) Pe me (iv) Raney Ni “ O 8) O CY OO aN (C) (D) OL ©) Ho 7 on Ww 49, If heat flows from a colder body to a hotter body (without any other change), the entropy of the system, will be (A) unchanged (B) decreased (©) incteased (D) decreased initially then increased passing through a minimum 50. Which one of the following elements is used as photoreceptor in Xeroxing? (A) Selenium (B) Titanium (©) Germanium (D) Magnesium 1218- 51. Which of the following species possess a lone pair, four bonded pairs and see-saw shaped geometry? XeF,, SF,, CIF;, CIF.” (A) SF, and CIE; (B) SF, and CIE,” (©) XeF, (D) SF, and XeF, 52, The IUPAC name of the following compound is ° “coos (A) ethyl (S)-2-methyl-4-oxocyclohex- 2-enecarboxylate (B) ethyl (R)-2-methyl-4-oxocyclohex- 2-enecarboxylate (©) (R)-4-ethoxycarbonyl-3-methyleyclohex- 2-enone (D) (5)-4-ethoxycarbonyl-3-methyleyclohex- 2-enone 53. Characters of a few symmetry operations are given below. Identify the characters of the irreducible representation Ey, EG ¢ i So 9 @ bora toro at ® 2 - 0 2 aA 0 © boro. aa - @ 2 - 0 2 1 0 2218- 54, The strongest infrared band of "C “0 occurs at 2143cm"’. Find the force constant of “C"*O if the reduced mass of °C '°O is given as 1/1385 x 10°°g. (A) 1855. Nim (B) 1855 Nim (© 1050. Nim (D) 105 Nim ‘The major product of the following reaction is: 56. ‘The CFSE (Ao) of d-orbital for the given metal ions in an octahedral field increases in the order: (A) Co® < Co =Rh® B) Co* I> I> IV (B) M>D>IV>1 (© Iv>MI>I>0 () IV>>M>1 68, ‘The major product ofthe following reaction is: ON AUB ] Pa (OAc): (cat) SAY EN, DMF y On (ON AL Sy q Opn B) OW. a ft Ss N q on 7 1 Ss N H (©) ow. Bn (D) on. | TY on 69. Predict the product of the following reaction: on work-up CHOMe), oN \ @ @) Aone NOMI ome AL © © YT 70. Identify the major product in the following reaction: rx } 140°C Se » LO “J N. NZ , ~ S 71. In a conductivity experiment, sodium hydroxide solution is titrated with oxalic acid solution. Select the correct graph for K Vs. concentration of oxalic acid plot, (K = specific conductance) w / ® c c © @) 1218- 72. The molar volume of Isobutane at 300-0K and ‘one bar is 24:31 dm*mol', What is the value of 2n4 virial co-efficient at 300-0K? (A) Oem’. mol! (B) 630 cm’-mol™ (©) -630 emo!" @) - 63.0 cm’-mol 73. An organic compound CsHyoO exhibited the following spectral data: IR = 1680 cm™ 'H-NMR = 7:8 QH, d, J = 7-5Hz), 7-2 QH, d, J =7-5H2), 2-7 (3H, s) and 24 GH, s) Identify the compound: coon, 9 l wey ®) cH VY CHO. "© O) [7 YX Me 74, Which one of the following comes within determinate error? (A) Instrument error (B) Method error (©) Personal error (D) Allof the above 78. Thecorrect ‘bond order’ forthe following species is (A) Nz>0,>NO* (B) N:>O7>NO* (©) N:>NO > 0, () Of >NO*>N, 2218- y. 76. The decreasing order of acidity of the following species is Wey a S (A) I> MI> > IV @®) W>I>IV>mr (© I>M> ven () I>U>IV>m1 71. The major product photochemical reaction is: o-No of the following tou we 2 Za on “ S ye AN on Nom ®) . “ -CN on nowt © ” oo" ~ CN © ws" AN 78. The ClO; molecule (C,,) is trapped in a solid. Its ground state is known to be B;. Light polarised parallel, to the y axis (parallel to 00 separation) excites this, molecule to a upper state, What is the symmetry of that, state? Character Table Cy | BE G@ o«% oa Ali. T 1 [Zz Ali o1 1 1] R, B) 1 - 1 1] xR, B| 1-1 1 1_| yk. (A) Ay because Ay xB, x B)= Aj (B) A, because A x A, (©) B, because A, x B, = B, (D) B, because A, xB; 79. exp (-ax’) is an eigenfunction of ote provided 1 (A @=5 ®) a=1 1 © eR @) a=2 80. A polydisperse protein has 10% of molecules having molecular weight 10,000, 80% of 20,000 and 10% of 40,000, Calculate the mass-average molecular weight of the protein sample. (A) 23,333 (B) 21,000 (©) 23,300 () 20,000 yas 81. A particle of mass ‘m’ moving in one-dimension between x=aand x= bis described by a wavefunction y= where N is normalization constant, The average value of x is b ay 2 Ag ®) en abo a cn © boa" » Tinb- ina] @) 2. The number of isomers for [Mayb,c] is: (a2 @) 3 @4 ©) 6 3. The compounds, MgP, CaF, ZnO and NaClare arranged in order of their increasing lattice energy. Select the correct order. (A) NaCl < CaF, = MgF, < ZnO (B) ZnO < CaF) < MgF, < NaCl (©) CaP, Meo SY 2218- 87. The most suitable reagent for the following conversion is A (A) mCPBA (B) H,OyAcOH (©) -BuOOH/HC! ©) H,0/N0H 88, Match Column A with Column B Column A. (a) CdSeS/ZnS Column B (i) Surface Plasmon Resonance (b) Zine-Phthalocyanine (ii) Forbidden Singlet- Singlet transition ii) Electronic transition between conduction and valence band (@) Fallerene Cp (iv) Appearence of Soret and Q absorption bands A) @>@, ©) > Gi), © > Gi), @ > Gv) B) @ > Gi), ©) > @, © > GW), @ > Gi) © @ > Gi), &) > @), OO, @ > GH ©) @ >, ) > Git), > G), > @ (©) Gold nanoparticles 89. In simultaneous static and dynamic quenching reaction the ratio of fluorescence intensity of uncomplexed fluorophore to that of complexed fluorophore Vs. concentration of quencher should give rise (A) a straight line passing through origin, (B) an upward curvature (©) downward curvature (D) parabolic shape y-20 90. The degeneracy of the most probable energy level for an atom of mass ‘m’ of one mole of an ideal gas at TK and pressure P atm, assuming that the atom, can be treated as a particle in a three-dimensional cubical box is 1 Rr) w aVimkT ( RTs nh Pe) 2LV3mKT B) i 1 N3mKT (RT \2 h UP ) aL vmKT h © ©) 91. ‘The major product of the following reaction is Cally po Hays Oe Pah, Phy) m9) HON, HOH ects te nC oH “ ~*~, H Ff =( en Hoy “ \_/ nC a ®B) { Ye vo act oH © -~_ H “ Br Ph acl oH 2 92, The compound(s) possessing C,-axis of symmetry is/are I 2 f a 1 (A) Tand IV (B) I. Wand IV (©) WandIV ©) only 93. pair ‘The electronegativity differences highest forthe (A) Na, F ®) Lic (KF (D) KBr 94, The major product of the following reaction is: on OT, O~ ‘SiMe O~ base oracid (A) SiMe; @) © (D) 1218- 95. ‘The major product formed in the following reaction sequence is: 08, TSO, AA sO NMED Ha(OCOCF) arxao, NH on (A) 1380, HO” B) 1150,,, 0b © 0, 1 ot To on @ Tm, Lo So we a 2218- Y2 96. ‘The character table of Cy, point group is given as follows: Cw Let us consider the reducible representation (T}) of the Cs, point group as follows Cy | EB 2c, Th} 4 1 ‘The sum of the irreducible representation is (A) 2A, +A, +E (B) A, +2A, +E (© Ait A, +2E (D) A FAFE 97. The ground state terms for Ce**is A By ®) *¥, © as, ©) 0 , 98, ‘The major product ofthe following reaction is (@ PbLi @ HO — “ SS A @) VA wt © | 4 Ph out @) R Ph 99. Aiiger electron spectroscopy is useful only for elements having atomic number (A) above 100 (B) above 50 (©) below 30 (D) below 50 100. Arrange the following chair conformations of 1,2,4,5-tetramethylcyclohexane according to their increasing enthalpy value: . LD rk Ade Z ~2~L © a am a@ wy () @

    You might also like