Fluorescence

Near ultraviolet-excited blue light-emitting fluorescent powder, preparation method and

application thereof in preparing blue or white light emitting device

By: Hao, Zhendong; Zhang, Sheng; Zhang, Jiahua; Zhang, Xia; Zhang, Liangliang; Pan,
Guohui; Wu, Huajun

Assignee: Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of
Sciences, Peop. Rep. China

The title near UV-excited blue light-emitting fluorescent powder has general formula of Sr1-
3+
xMxLu2-yLnyO4:Ce m, An, wherein, Ln represents Y, La, Gd and/or Sc; A represents Li, Na, K,
Rb and/or Cs; x ≥0 and ≤0.5; y ≥0 and ≤1; m ≥0.0001 and ≤0.01; and n ≥0 and ≤0.01. The
effective excitation range of blue light emission is located at 380-450nm, and emission peak is
located at 445-480nm. The inventive blue light-emitting fluorescent powder has low cost, no
pollution, and simple prepn. method, can be used as near UV LED light conversion material
for prepg. blue light emitting device, or be used for prepg. white light emitting device along
with green fluorescent powder and red fluorescent powder.

Double-perovskite red fluorescence powder and preparation method thereof

By: Luo, Xuefang; Zhang, Tiantian; Chen, Wenjuan; Zhang, Liang; Qu, Cheng

Assignee: Jiangsu Luohua New Materials Co., Ltd., Peop. Rep. China

The title double-perovskite red fluorescence powder has compn. structure as AA'1-x-
3+ 2+
yZnMO6:xMe ,yZn (A is one of Li (lithium), Na (sodium) and K (potassium), A' is one or
more selected from Y (yttrium), La (lanthanum) and Gd (gadolinium), M is Mo (molybdenum)
and /or W (tungsten), Me is rare earth element Eu (europium) or Pr (praseodymium),
0.001≤x≤0.6, and 0.001≤y≤0.2). The double-perovskite red fluorescence powder has high
light intensity, high color purity, complete fluorescent powder particle crystal, relatively good
dispersibility, and size of 5-10 μm, and the invention has low prodn. cost, simple operation,
high yield, and controllable process.

Mn4+-activated fluorotungstate red fluorescent powder and preparation method thereof

By: Jiao, Huan; Zhou, Yang; Zhang, Shuai; He, Diping; Wang, Xiaoming; Xu, Ling

Assignee: Shaanxi Normal University, Peop. Rep. China

The title red fluorescent powder is composed of the material represented by formula AxWF6:
Mn4+y, wherein A represents Na or K in formula, when A is Na, x=1, and when A is K, x=3, Y
value is 0.01-0.1. The title method comprises: using WO3 and AHF2 as raw material, preps.
AxWF6 in H2 atm., subjecting K2MnF6 and AxWF6 to low temp. solid phase reaction in
hydrogen fluoride atm., and doping Mn4+. The present invention has simple and safe prepn.
method, relatively low temp. of reaction, no pollution, and controllable activate agent
content. The prepd. red light fluorescent powder has good light emitting performance, and
unchanged wavelength of emitting light. It is adapted to the field of higher requirement to light
emitting material such as white-light LED illumination device and backlight source.

Phosphorus-spectrum fluorescent double-tracer polycarboxylate water-reducing agent

and preparation method thereof

By: Fu, Change; Qu, Haojie; Dai, Chaoxia; Chen, Wan; Xia, Guanghui; Wu, Guoping; Yu,
Yanchun; Xiang, Qizhi; Zhou, Xin

Assignee: Jiangsu Open University, Peop. Rep. China

The invention discloses a phosphorus-spectrum fluorescent double-tracer polycarboxylate

water-reducing agent represented by the structural formula as shown, wherein R1' is -H, -M (M
is H+, K+, Na+ or NH4+) or the group as shown in the figure; R2' is -H, -M (M is H+, K+, Na+ or
NH4+) or the group as shown in the figure, * is connected to oxygen atom of P-O bond; R1 is -
H or -COOH; R2 and R3are -H or C1-C4 lower alkyl, no. m of repeating units is 0-10, no. n of
repeating units is 0-100, d.p. x is 1-500, d.p. y is 1-5000, and d.p. z is 1-5000. The polymer as
water-reducing agent has excellent dispersibility of small parameter and high fluidity, has low
solid content, thereby greatly reducing cost, and increases benefit. The synthesis raw materials
are nontoxic and harmless, so that the synthetic product does not need to sep., meets
characteristics of clean prodn., and adapts to generalization in the market.
Selective and sensitive morpholine-type rhodamine B-based colorimetric
and fluorescent chemosensor for Fe(III) and Fe(II)

By: Lee, Sanghyuck; Jang, Hoeun; Lee, Jisuk; Jeon, Sun Hee; Sohn, Youngku; Ra, Choon Sup

The development of chemosensor materials is crucial for the early detection of hazardous
materials, such as heavy metal ions and infectious viruses. In this study, three rhodamine B
(RhB) derivs. (referred to as Rh-OS, Rh-OO, and Rh-SO) bearing a morpholine-type 6-
membered ring as colorimetric, fluorescent sensors were synthesized,
and fluorescence responses to various metal ions (Fe3+, Fe2+, Pb2+, Cr6+, Ce2+, Mn2+, Cd2+,
Hg2+, K+, Na+, Mg2+, Li+, Ca2+, As3+, Co2+, Cu2+, Ni2+, and Zn2+) were investigated. Rh-OS,
Rh-OO, and Rh-SO exhibited high sensitivity to Fe2+ and Fe3+, with the formation of a 1:1
(ligand: metal) complex, as evidenced by the UV-vis absorption and photoluminescence
spectra. Luminescence turn-on was explained by the transfer of resonance energy from the
morpholine-type moiety to the RhB framework. In addn., the selectivity of Fe3+ and Fe2+ was
evaluated by 2D and 3D photoluminescence imaging.

Protein surface recognition with targeted fluorescent molecular sensors

By: Nissinkorn, Yael; Motiei, Leila; Margulies, David

Protein surface recognition by fluorescent mol. sensors poses an immense challenge in

supramol. recognition chem. owing to the immense difficulty of selectively targeting these
large, relatively flat, and non-contiguous domains. The fact that protein surfaces can exhibit
different charges, topologies, and posttranslational modifications that can be found in
other proteins in the mixt. is an addnl. factor that complicates targeting and
consequently, sensing specific protein surface modifications. A recent report, however, shows
that the difficulty of sensing changes that occur on the surface of specific proteins could be
circumvented by attaching a relatively non-specific synthetic receptor to a
specific proteinbinder. The latter brings the receptor near the target protein and enhances its
affinity toward its surface. Modifying the synthetic receptor with an environmentally
sensitive fluorescent reporter, along with suitable recognition elements, enables such systems
to target specific regions on protein surfaces and consequently, to track modifications that
result from conformational changes or binding interactions.

Molecular sensor and methods of use thereof

By: Margulies, David; Motiei, Leila; Unger, Linor

Assignee: Yeda Research and Development Co. Ltd., Israel

The present invention is directed to fluorescent mol. sensor based on Thiazole Orange
for protein detection. interaction of the protein target with the mol. sensors of this invention
results in a significant increase in the fluorescence emission. The generation of light output
signal enables one to detect protein biomarkers assocd. with different diseases or detecting
the protein of interest also in living cells.

Stellar cyclodextrin fluorescent sensor for rapid detection of microorganisms

By: Wan, Yi; Zhou, Teng; Ge, Jian

Assignee: Hainan University, Peop. Rep. China

The work herein aims to develop a stellar cyclodextrin fluorescent sensor for rapid detection
of microorganisms, and screen the antibiotic systems of microorganism film antibiotics. This
complex combined with SPSS can specifically recognize the pathogenic microorganism
film. The complex combines the characteristic microorganism film. The characteristic
microorganism competition makes the fluorescent protein on the surface free, and differences
in microorganism film binding intensity and in interaction force result in characteristic
response signals. Based on the above expts., this complex can be further used for the evaluation
and screening of antibiotic mechanisms. The innovation of this work is reflected in that: with
the help of stellar quaternary cyclodextrin and fluorescent protein forming a complex,
microorganism film is detected. The microorganism film does not require any pretreatment
but simple steps. The present invention provides a ref. for solving 'online', 'portable' and 'full-
automatic' problems combining mechatronics engineering and biol. concerning microorganism
detection method.