112. In the reaction, 2al(s) + 6HCI(aq) —> 2Al* (aq) + 6Cl (aq) + 3H(g) (a) 6LHCI(aq) is consumed for every 3L.H(g) produced (b) 33.6 L. H(g) is produced regardless of temperature and pressure for every mole Al that reacts (c) 6721L.11,(g) at 1 atm and 273 K is produced for every mole Al that reacts (d) 11.2 LH,(g) at 1 atm and 273 K is produced for every mole HCl(aq) consumed 113. The percentage by volume of CyH, in a gaseous mixture of CH,CH, and CO is 20. When 100 mL of the mixture is burnt in excess of 2, the volume of CO, produced is: (a) 90 mL (b) 160 mL (c) 140 mL (d) none of these 114, 40 mL gaseous mixture of CO, CH, and Ne was exploded with 15 mL of oxygen. After treatment with KOH the volume reduced by 9 mL and again on treatment with alkaline Pyrogallol, the volume further reduced by 1.5 mL. Percentage of CH, in the original mixture is: (a) 22.5 (b) 77.5 © 75 (@) 15 115. A gaseous mixture of propane and butane of volume 3 litre on complete combustion produces 11.0 litre CO, under standard conditions of temperature and pressure. The ratio of volume of butane to propane is: (a) 1:2 (b) 2:1 3:2 116. Phosphorous has the oxidation state of +1 in: (a) Orthophosphorie acid (b) Phosphorous acid (©) Hypophosphorous acid (d) Metaphosphoric acid 117. The oxidation state(s) of Cl in CaOCl, (bleaching powder) is/are: (@) 3:1 (a) +1 only (b) -1 only (©) +1 and -1 (d) none of these 118. The oxidation number of sulphur in S_,52F2, H2S and H,SO, respectively are: (a) 0,+1,-2and6 (b) +2,0,+2and6 (c) 0,+1,+2and4 (@) -2,0,+2and6 Scanned with CamScanner119. Fe shows an oxidation state of +1 in: (a) Fe(CO), (b) [Fe(H,0),NO}SO, (©) Fe,[Fe(CN).] (d) FeCl, 120. When SO , is passed into an acidified potassium dichromate solution, the oxidation numbe: of sulphur and chromium in the final products respectively are: (a) +6, +6 (b) +6, +3 (c) 0, +3 (d) +2, +3 121. The oxidation number of nitrogen atoms in NH ,NO, are: (a) +3, +3 (b) +3, -3 (c) -3,45 (d) -5,+3 122. The oxidation states of S-atoms in Caro's and Marshall's acids are: (a) +6,+6 (b) +6,+4 (©) +6,-6 (d) +4,+6 128. In which of the following the oxidation number of oxygen has been arranged in increasiny order : (a) OF, HS0, (b) 2KI + HO, —> 2KOH +1, (c) PbS + 4H,0, —> PbSO, + 4H,0 (d) Ag,0 + H,0, —> 2Ag +H,0 +0, 184. Following reaction describes the rusting of iron 4Fe +30, —> 4Fe* +607 Which one of the following statement is incorrect ? (a) This is an example of a redox reaction _(b) Metallic iron is reduced to Fe** (©) Fe* is an oxidising agent (d) Metallic iron is a reducing agent 135. Which reaction does not represent auto redox or disproportionation ? (a) Cl, +OH” —+ Cl +Cl03 +H,0 (b) 2H,0, —+ H,0 +0, (c) 2Cu* —+ Cu +Cu 136. Which of the following is redox reaction ? (a) H,SO, reacts with NaOH (b) In atmosphere, O, is formed from O, by lightning (©) Evaporation of H,0 (d) (NH,),Cr,0, —+N, +Cr,0, + 4H,0 (d) Oxides of nitrogen are formed form nitrogen & oxygen by lightning 137. Which of the following is a redox-reaction ? (a) 2Na[Ag(CN) 2] + Zn—+ Na,[Zn(CN),] + 2Ag (b) BaO, + H,S0, —> BaSO, +H,0 (©) N,0, +H,0—> 2HNO, (d) AgNO, + KI—> Agl+KNO, 188. For the redox reaction, MnOj +C,07 +H* —»Mn* +CO,+H,0 the correct coefficients of the reactants for the balanced reactioy i MnOj, C,0;,H*: mare respectively (a) 2,5, 16 () 16, 3, 12 (©) 15, 16, 12 (@) 2, 16,5 189. In a chemical reaction, K,Cr,0, + xH,S0, + ySO, —» K,S0, +Cr,(SO,), + sH20; the value of x, y and « respectively are : (a) x=1,y=3,2=1 (b) x=4,y=1,2=4 (©) x=3,y=2,2=1 () x=2,y=2,2=1 140. Balance the following equation and choose the quantity which is the sum of the coefficients of the products : C8, +. . Cla —> CCl, +......S,Cly ae ©) s © 6 @ 2 141. Balance the following equation and choose the quanti ; reactants and products; quantity which is the sum of the coefficients of ve PICly +... XOFy —+ Pty +...CIF +... Xe (a) 16 (b) 13 (© 18 (d) 12 2. It 0.1 mole HPO, 1s completely neutralised 14: 10.1 mal Hy Goad dna by 5.6 3 KOH then select the true statement. (b) x = 4 and given ucid has no P-H linkage (c) x = 2 and given acid does not form acid salt (d) all of these Scanned with CamScanner143. When potassium permanganate is titrated against ferrous ammonium sulphate in acidic medium, the equivalent mass of potassium permanganate is: a aes (oy SEkrule mee © molecular mass @ molecular mass 2 10 144. Equivalent mass of FeS; in the half reaction, FeS; —+ Fe,0, +50, is : (a) M/10 (b) M/11 (c) M/6 (d) M/1 145. The equivalent mass of HCl in the given reaction is: K,Cr,0- + 14H. —+ 2KC1+ 2CrCl, + 3€1; + 1,0 (a) 16.25 (©) 365 (©) 73 (4) 85.1 146. Equivalent mass of HPO, when it disproportionate into PH, and HPO, is: (a) M (b) M/2 (c) M/4 (d) 3M/4 147. In the following reaction, As;S; +H” +NO3; —»NO+H,0+AsO{ +SOT the equivalent mass of As_S, is related to its molecular mass by : (a) M/2 (b) M/4 (©) M/24 (a) M28 148. Sulphur forms the chlorides $,Cl, and SC1,. The equivalent mass of sulphur in SC1, is : (a) 8 g/mol (b) 16 g/mol (©) 64.8 g/mol (@) 32 g/mol 149. The equivalent mass of an element is 4. Its chloride has a vapour density 59.25. Then, the valency of the elements is : (a) 4 ) 3 (2 (4) 1 150.6» 107? mole K,Cr,0, reacts completely with 9 x 10? mole X"" to give XO; and Cr* . The value of nis : a1 ) 2 ©3 (d) None of these 151. What mass of H,C,0, -2H,0 (mol. mass = 126) should be dissolved in water to prepare 20 mL of centinormal solution which act as a reducing agent ? (a) 063 g (b) 0.1575 g (c) 0.126 g (d) 0.875 g 152. The equivalent mass of the salt, KHC,0, -H;C,0,, - 4H ,0 when it act as reducing agent is : (a) Mol-mass (p Mol.mass (c) Molimass (q) Mobmass 1 2 3 4 153. The equivalent mass of divalent metal is W. The molecular mass of its chloride is : (a) W + 35.5 () W +71 (c) W +71 (4) 2W + 35.5 184. When BrO ; ion reacts with Br” in acid medium, Br, is liberated. The equivalent mass of Br, in this reaction is: SM SM 3M (a) . ») 3 () 5 @ 4M 155. fm, gram of a metal A displaces m, gram of another metal B from its salt solution and if the equivalent mass are E , and Ey respectively then equivalent mass of A can be expressed as ma~My (a) Ey ies (b) Ey = (© Ey ome xE, (d) Ey = mon es ms A Scanned with CamScanner