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Durability of concrete
It is defined as its ability to resist weathering action,
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Significance of durability
Now a days pollution is increased particularly in industrially
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Significance of durability
Presently use of concrete extended and even good
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Impact of W/C ratio on durability
Volume changes in the concrete causes cracks in the
Failure
Of Cracks
Permeability
Concrete
concrete.
The dense and impermeable concrete does not mean that
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Impact of W/C ratio on durability
In the concrete with lower water cement ratio and adequate
cover can protect the steel against corrosion rather than higher
water cement ratio and then protecting the steel by epoxy
coating.
Earlier it was impossible to keep water cement ratio lower than
0.40 but now the use of super plasticizers can make the water
cement ratio lower than 0.25 and even low as 0.22. This can
produce high quality and high performance durable concrete.
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Impact of W/C ratio on durability
Cement particles hydrated in presence of water when
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Permeability
As we know water cement ratio is one of the factor for
ratio. At lower water cement ratio capillaries are small and less in
diameter.
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Permeability of cement paste
The cavities by lower water cement ratio can be filled
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Permeability of cement paste
The higher permeability of mortar or concrete in actual
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Permeability of cement paste
Drying shrinkage, thermal shrinkage and externally applied
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Factors influencing of cracks in concrete
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Factors influencing of cracks in concrete
Plastic Shrinkage Cracks
Plastic shrinkage usually occurs prior to final finishing, before curing
Due to the restraint provided by the concrete on the drying surface layer,
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Factors Contributed for cracks in Concrete
Settlement of Cracks
In plastic state of concrete it is possible to uniformly can
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Factors influencing of cracks in concrete
Bleeding
Early bleeding when the concrete mass is fully plastic, may not
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Factors influencing of cracks in concrete
Constructional Effects
Form work
Vibration
Finishing
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Factors influencing of cracks in concrete
Delayed Curing
Due to plastic shrinkage cracks are developed.
day of concreting which is make concrete very thirsty and dry up.
As during the initial stage hydration process is faster and
concrete.
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Factors influencing of cracks in concrete
Early Frost Damage
If the concrete is frozen after few hours of placement it reduces
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Factors influencing of cracks in concrete
Early Frost Damage
Inside temperature of the concrete affected by the material used
water get frozen and cause the disruption of concrete and affect
on the durability of the concrete.
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Factors influencing of cracks in concrete
Unsound Materials
If the cement and aggregate can saw the volume change in
cement can make cement unsound and also MgO and CaO can
also participating to make cement unsound.
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Factors influencing of cracks in concrete
Unsound Materials
The use of gypsum in cement to reduce the flashing time of the
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Factors influencing of cracks in concrete
Thermal Shrinkage
Thermal property of the concrete to understand the behavior of
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Factors influencing of cracks in concrete
Thermal Shrinkage
The important thermal properties are as following:
Thermal Conductivity
Thermal Diffusivity
Specific Heat
Co-efficient of thermal expansion
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Factors influencing of cracks in concrete
Thermal Conductivity :
This measures the ability of the material to conduct the heat.
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Factors influencing of cracks in concrete
Specific Heat :
It is defined as the quantity of heat required to raise the
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Factors influencing of cracks in concrete
Coefficient of Thermal Expansion :
It is defined as the change in unit length per degree change of
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Factors influencing of cracks in concrete
Coefficient of Thermal Expansion :
There is thermal incompatibility between aggregate and paste
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Factors influencing of cracks in concrete
Coefficient of Thermal Expansion :
Large quantity of heat liberated during the hydration.
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Sulphate attack
Sulphur content present in most of soil and ground water along
bacterial action.
Water used in concrete can also be a major source of the
sulphate attack.
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Sulphate attack
Solid sulphate do not attack the concrete but in solution
concrete maximum.
A characteristics whitish appearance is the indication of
sulphate attack.
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Sulphate attack
In the hydrated concrete, calcium aluminate hydrate [ C-A-
H ] can react with the sulphate salt from out side and
produce the product calcium sulpho-aluminate in the
hydrated cement paste.
Due to that the volume of the concrete paste is increased
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Sulphate attack
Example of the sodium sulphate attack on Ca(OH)2
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Sulphate attack
The concentration of the sulphate expressed as the
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Methods of controlling sulphate attack
Use of Sulphate Resisting Cement
To resist sulphate attack use the cement with lower C3A
content.
C3A content with 7% shows good and poor performance in
sulphate water.
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Methods of controlling sulphate attack
Quality Concrete
Well designed, placed and well compacted concrete which
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Methods of controlling sulphate attack
Use air-entrainment
Use of air-entrain reduce segregation, bleeding, and
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Methods of controlling sulphate attack
Use of Pozzolana
Admixing of pozzolana convert calcium hydroxide in to
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Methods of controlling sulphate attack
Use of High Alumina Cement
High alumina cement contains approximately 40%
alumina, a compound very susceptible to sulphate attack,
when in normal Portland Cement.
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Methods of controlling sulphate attack
Use of High Alumina Cement
But this percentage of alumina present in high alumina cement
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Chloride attack
Chloride attack cause corrosion in reinforcement.
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Chloride attack
Chloride can enter in to concrete from cement, aggregate,
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Chloride attack
The amount of chloride to initiating the corrosion depend
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Corrosion of steel
Corrosion of steel in concrete is an electrochemical
process.
In the steel, one part becomes anode and other part
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Corrosion of steel
++
The positively charged ferrous ions Fe at the anode pass into
solution while the negatively charged free electrons e- pass
through the steel into cathode where they are absorbed by the
constituents of the electrolyte and combine with water and
oxygen to form hydroxyl ions (OH)-
These travel through the electrolyte and combine with ferrous
Anodic Reactions:
Fe Fe++ + 2e- Corrosion Mechanism
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Corrosion of steel
Product of corrosion can occupy six time volume than the original
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Corrosion of steel
Increase of rust thrust the concrete
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Corrosion of steel
Use lower water cement ratio and make concrete dense.
blast furnace slag (GGBS), silica fume etc. make concrete dense
and impermeable so it reduce the corrosion of the steel.
The improvement of the microstructure of hydrated cement paste
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Methods for controlling corrosion
Metallurgical methods
Different methods such as rapid quenching of the hot bars by
series of water jets, or by keeping the hot steel bars for a short
lime in a water bath, and by such other process the mechanical
properties and corrosion resistance property of steel can be
improved.
There are many situations where stainless steel reinforcements
initiate corrosion when the chloride ions reach the steel. The
nitrite ions present in the corrosion inhibiting admixture will
oxidize the ferrous oxide to ferric oxide, thus stabilizing the
passivating layer even in the presence of chlorides.
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Methods for controlling corrosion
Corrosion Inhibitors
Calcium nitrite in a liquid from containing about 30 per cent
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Methods for controlling corrosion
Coating to reinforcement
Coating of steel can prevent from the chloride.
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Methods for controlling corrosion
Coating to reinforcement
De-Rusting
The reinforcements are cleaned with a de-rusting solution. This
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Methods for controlling corrosion
Coating to reinforcement
Phosphating
Phosphate jelly is applied to the bars with fine brush. The jelly is
left for 45-60 minutes and then removed by wet cloth. An inhibitor
solution is then brushed over the phosphated surface.
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Methods for controlling corrosion
Coating to reinforcement
Cement Coating
Slurry is made by mixing the inhibitor solution with Portland
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Methods for controlling corrosion
Coating to reinforcement
Sealing
Two coats of sealing solution are applied to the bars in order to
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Methods for controlling corrosion
Coating to reinforcement
Fusion Bonded Epoxy Coating
The fusion bonded epoxy coaling is a specialized job carried out
process.
Initially the bar is shot blasted to remove all mill scale and to give
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Methods for controlling corrosion
Coating to Reinforcement
Cathodic Protection:
The cathodic protection comprises of application of impressed
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Methods for controlling corrosion
Coating to Reinforcement
Cathodic Protection:
In this process the negative chloride ions which are responsible
for the damage of the passivating film, are drawn away from the
vicinity of steel towards the anode where they are oxidized to
form chlorine gas.
The environment around the steel reinforcement reverts back to
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Methods for controlling corrosion
Coating to Reinforcement
Coating to Concrete:
The moisture trapped inside the concrete can do untold harm to
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Methods for controlling corrosion
Coating to Reinforcement
Coating to Concrete:
Instead, the protective coating should be based on acrylics which
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Methods for controlling corrosion
Coating to Reinforcement
Coating to Concrete:
Epoxy based coating material is not resistant to ultra violet rays
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Methods for controlling corrosion
Coating to Reinforcement
Designing and Detailing:
In case of column the cover should not less than 40 mm or the
diameter of the bar. For footing it should not less than 50 mm.
There is always an increase of paste and less of aggregate in
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Surface treatments of concrete
There are large varieties of materials, which are applied to
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Surface treatments of concrete
Some of the materials used for surface treatments are listed
below :
(a) Aqueous solution of sodium silicate
(b) Magnesium or zinc silico fluoride
(c) Drying oils such as linseed or tung oil
(d) Chlorinated rubber paints
(e) Neoprene paints
(f ) Epoxy paints or coal tar epoxy paints
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Surface treatments of concrete
The surface of the hardened and air-dry concrete may be treated
against insects and borers. Some plastic materials, rubber, latex glass
fiber coatings, PVC linings have also been given to concrete in certain
situations for increasing durability.
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Surface treatments of concrete
One of the important surface treatment adopted to increase the
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Fig. 1
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