A segunda metodologia 

4500-Cl G. DPD Colorimetric Method, trata

da quantificação do cloro utilizando os mesmos princípios. Ao invés da
titulação com  a solução padrão de ferro amônio sulfato (FAS), o
princípio colorimétrico é empregado. Utiliza-se uma curva  padrão de
cloro na concentração 0,05 a 4 mg/L.

O uso do reagente indicador DPD, de acordo com o Standards

Methods for Examination of Water and Wastewater, pode ser
preparado tanto a partir do DPD Oxalato (N, N-dietil-p-
fenilenodiamina), quanto do DPD sulfato (Sulfato de N,N-dietil-1,4-
fenilenodiamônio), onde estes reagentes são solubilizados em uma
mistura de água livre de cloro mais ácido Sulfurico H2SO4 e EDTA.

Nós da Exodo Científica contamos com os componentes DPD para a

realização do reagente DPD, bem como todos os reagentes utilizados
para a análise de cloro. Consulte-nos para esta e mais outras opções
que possuímos!

MÉTODO DPD COLORIMÉTRICO (SM 4500-CL G. DPD COLORIMETRIC METHOD)

fONTE: https://www.nemi.gov/methods/method_summary/7431/

Aqui usa osintereferentes para o método do FAS

(A) Manganese: The most significant interfering substance likely to be encountered in water is
oxidized manganese. To correct for this, place 5 mL buffer solution and 0.5 mL sodium arsenite
solution in the titration flask. Add 100 mL sample and mix. Add 5 mL DPD indicator solution,
mix, and titrate with standard FAS titrant until red color is discharged. Subtract reading from
Reading A obtained by the normal procedure as described in this method or from the total
chlorine reading obtained in the simplified procedure given here. If the combined reagent in
powder form is used, first add KI and arsenite to the sample and mix, then add combined
buffer-indicator reagent. As an alternative to sodium arsenite use a 0.25% solution of
thioacetamide, adding 0.5 mL to 100 mL sample.

Copper: Interference by copper up to approximately 10 mg Cu/L is overcome by the EDTA

incorporated in the reagents. Chromate in excess of 2 mg/L interferes with end-point
determination. Add barium chloride to mask this interference by precipitation.

Color and Turbidity: Compensate for color and turbidity by using sample to zero photometer.

Chromate: Minimize chromate interference by using thioacetamide blank correction.

Chlorine in aqueous solution is not stable, and the chlorine content of samples or solutions,
particularly weak solutions, will decrease rapidly. Exposure to sunlight or other strong light or
agitation will accelerate the reduction of chlorine. Therefore, start chlorine determinations
immediately after sampling, avoiding excessive light and agitation. Do not store samples to be
analyzed for chlorine.