‘Scanned with CamScanner5.1. Define average rate and instantaneous rate. How is instantaneous rate evaluated? 5.2. Define rate law and rate constant, Explain rate law with two examples. 53. Explain the term order of a reaction with examples. 5 5.4. What is pseudo-first order reaction? Give one example. 55 Define integrated rate law. Derive the expression for integrated rate law for first order reaction, A ——> products. 5.6 Define half life of a reaction. Derive the relationship between half life and rate constant for a first order reaction. q 5.7 Describe one method to determine rate law and order of a reaction. 5.8 Give the units of rate of reaction and rate constants of first and zero order reactions. 5.9. The gas-phase reaction between NO and Br, is represented by the equation. 2NO (g) + Br; (g) —> 2NOBr (g) (a) Write the expressions for the rate consumption of reactants and formation products. (b) Write the expression for the rat reaction in terms of rates of const reactants and formation of pr 5.10 equation. 2N,0; (g) ——>4NO; (a) How is the rate of fo Scanned with CamScanner5.13 The reaction H,0,(aq)+31-(aq)+2H* (aq) —> 2H,0()41; (aq) is first order in HO and I, zero order in Hs Write the rate law. ¢ 5.14. The reaction A+ B ——> products is first order in each of the reactants. (a) Write the rate lay, (b) How does the reaction rate change if the concentration of B is decreased by a factor 3 (c) What is the change in the rate if the concentration of each reactant is (d) What is the change in the rate i tration of A is doubled and that of B is he What is an elementary reaction? Wi molecularity of an elementary 5.16 Distinguish between mol reaction. What do you mean by 5.15 Scanned with CamScanner524 Write the rate law for the following reactions: A reaction that is zero order in A and second order in B. (b) A reaction that is second order in NO ade first order in Br,. Define the term activation energy. Arrhenius equation explain why reaction (a) increases with i temperature (b) increases with di activation energy. Scanned with CamScannerler the reaction 2A + B ——» 2C. Suppose a particular moment during the reaction, disappearance of A is 0.076 M/s, (a) s the rate of formation of C? (b) What is rate of consumption of B? (c) What is the ie of the reaction? {(a) 0.076 M/s (b) 0.038 M/s (c) 0.038 M/s] Consider the reaction 31(aq) + S,0§ (aq) > Ty (aq) + 280} (aq) afsox]_ Ata particular time t, are F 2.2x10? M/s. at ] What are the values of (a)- [s,0F ] as] (3) dt ((a) 3.310 M/s (c) 1.1102 M/s] Consider the reaction 2A + 2B ——>2C + D. From the following data, calculate the order and rate constant of the reaction. (b)- == at the same time? (b) 11x10? M/s 5.4 we] [A]/M [B],/M 0.488 0.160 0.244 0.160 0.244 0.320 Scanned with CamScanner Write the rate law of the reaction. [AJM [B/M 0.3 0.05 0.6 0.05 0.6 0.20 What is the rate constant andy pean stro iniger tac a * C,H,Br, + 3 —_, CoH, B = k(C,H,Bry][ I+]. The rat found to be 1.x a95.6 Consider the reaction A, + B ——> products. If the concentration of A, and B are halved, the rate of the reaction decreases by a factor of 8- If the concentration of A is increased by a factor of 2.5, the rate increases by the factor of 2.5- What is the order of the reaction? Write the rate law. [Third order, rate = Kl. 5.7 Consider the reaction C + D products. The of the reaction increases by a factor of 4 concentration of C is doubled. The rate’ reaction is tripled when concentration Of tripled. What is the order of the reé ct the rate law. ’ [Third order, rate = 5.8 The reaction F,(g) + 2ClO{g) r is first order in each of the reactan of the reaction is 4.88 x 10* 0.015M and [CIO,] = 0.025 M. rate constant of the reaction. 5,9 The reaction 2H, (g) + +N, (g) is first order NO. The rate co 5.10 Scanned with CamScanner | |