ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT – JEE - 2022 TW TEST MARKS :100

TIME: 1HR CHEMISTRY DATE:19/07/20

SECTION-I (SINGLE ANSWER CORRECT TYPE)

This section contains 20 Multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out which ONLY ONE is correct. (+4, –1)

26. Schematic diagram of an electrolytic-cell is

– – – –
e e e e
+ – + – + –
–
e
–
e
+ + +
cations cations cations
– – –
anions anions anions
Anode Cathode Anode Cathode Anode Cathode
(a) (b) (c) (d) None is correct presentation

27. The density of copper is 8.94 g mL–1. Find the charge needed to plate an area of 10×10 cm2 to
thickness of 10–2 cm using a CuSO 4 solution as electrolyte (atomic weight of Cu = 63.6)
(a) 2.7 104 C (b) 8.8  10 4 C (c) 18.3  104 C (d) 1.7 104 C

28. For electrosynthesis of a substance

(a) G   ve and Ecell =–ve (b) G   ve and Ecell =+ve
(c) G   ve and Ecell =–ve (d) G   ve and Ecell =+ve

29. Match the following combinations of electrical unit with their terms as single unit
Electrical units Single units
I: Joule /volt A : Ohm
II : Joule/second B : Ampere
2
III : Joule/Ampere second C : Coulomb
IV : Coulomb/second D : Watt

I II III IV
(a) A B C D
(b) C D A B
(c) D C B A
(d) C D B A
30. Number of electrons lost during electrolysis of 0.355 g of Cl– is
0.01
(a) 0.01 (b) 0.01 N0 (c) 0.02 N0 (d)
2N0

31. A steady current of 30.0 A for 70.2 min corresponds to a passage of

(a) 1.26×105 electron (b) 1.31 C (c) 1.26×105 Faraday (d) 1.31 F

32. A current of 5.00 A, flowing for 30.00 min deposits 3.048 g of zinc at the cathode. Hence,
equivalent weight of zinc is
(a) 65.4 (b) 130.8 (c) 32.7 (d) 16.85

33. Electrochemical equivalent of Cu in the reaction, Cu2++2e–  Cu is

63.5 63.5 63.5  2 96500
(a) (b) (c) (d)
96.500 96500  2 96500 63.5  2

34. Silver is removed electrically from 200 ml of a 0.1 N solution of AgNO3 by a current of
0.1 Ampere. How long will it take to remove half of the silver from the solution
(a) 16 sec (b) 96.5 sec (c) 100 sec (d) 10 sec

35. When an electric current is passed through acidified water. 112 ml of hydrogen gas at NTP is
collected at the cathode in 965 seconds. The current passed in Amperes, is
(a) 1.0 (b) 0.5 (c) 0.1 (d) 2.0

36. Which of the following is arranged in increasing order of ionic mobility

(a) I   Br   Cl   F  (b) F   Cl   Br   I 
(c) F   I   Cl   Br  (d) F   Cl   I   Br 

37. A graph was plotted between the equivalent conductance of various electrolytes (CH 3 COOH , NiSO4

and HCl) and their concentrations in equivalents per litre. 150 –

Which of the followings represents the correct setting I
120 –
Equivalent conductance

(a) I ( NiSO4 ), II (CH 3COOH ), III ( HCl )

90 –
II
(b) I ( HCl ), II ( NiSO4 ), III (CH 3COOH )
60 –
(c) I (CH 3COOH ), II ( HCl ), III ( NiSO4 )
(d) I ( HCl ), II (CH 3COOH ), III ( NiSO4 ) 30 –
III

0.01 0.02 0.05 0.1

Conc (eq/l)
38. The specific conductance of a 0.1 N KCl solution at 23o C is 0.012 ohm1 cm 1 . The resistance of
cell containing the solution at the same temperature was found to be 55 Ohm. The cell constant will
be
(a) 0.142 cm 1 (b) 0.66 cm 1 (c) 0.918cm 1 (d) 1.12 cm1

39. The equivalent conductance of an acetic acid solution of concentration 0.01 M is 1.65 m S m2 mol 1 at
2 1
298 K. The dissociation constant of acetic acid at this temperature is (given,  0  39.0 m S m mol )
(a) 1.8 104 (b) 4.0  10 10 (c) 1.8 10 5 (d) 1.8 10 6

40. Which of the following statements about the spontaneous reaction occurring in a Galvanic cell is
always true
0
(a) Ecell  0, G 0  0, and Q  K eq 0
(b) Ecell  0, G 0  0, and Q  Keq
0
(c) Ecell  0, G 0  0, and Q  K eq (d) Ecell  0, G  0, and Q  K eq

41. Which of the following reactions occurs at the cathode during the charging of a lead storage battery
(a) Pb 2   2e   Pb (b) Pb 2  SO42  PbSO4
(c) Pb  Pb 2   2e  (d) PbSO4  2 H 2O  2 PbO2  4SO42  2e

42. Which one among the following is the strongest reducing agent
Fe 2  2e  Fe(0.44V )
Ni 2  2e  Ni (0.25V )
Sn2  2e  Sn (0.14V )
Fe3  e   Fe 2 (0.77V )
(a) Fe (b) Fe 2 (c) Ni (d) Sn

43. A gas X at 1 atm is bubbled through a solution containing a mixture of 1M Y  and 1M Z  at

25o C . If the order of reduction potential of Z > Y > X

(a) Y will oxidize X and not Z (b) Y will oxidize Z and not X
(c) Y will oxidize X as well as Z (d) Y will reduce as well as X and Z

44. The emf of a Daniel cell at 298 K is E1Zn | ZnSO4 || CuSO4 | Cu . When the concentration of ZnSO4 is
(0.01M ) (1.0 M )

1.0 M and that of CuSO4 is 0.01 M, the emf changed to E2 . What is the relationship between E
and E2
(a) E2  0  E1 (b) E1  E2 (c) E1  E2 (d) E1  E2
45. The Solubility of a gas in water depends on
(a) Nature of the gas (b) Temperature (c) Pressure of the gas (d) All of the above

SECTION-II : (NUMERICAL ANSWER TYPE)

This section contains 05 questions. The answer to each question is a NUMERICAL VALUE. For each question,
enter the correct numerical value (in decimal notation, truncated/rounded-off to the second decimal place; e.g.
6.25, 7.00, 0.33, 30.27, 127.30) (+4, 0)

46. A current 2.0 A is passed for 5 hours through a molten metal salt deposits 22 g of metal (At. wt. =
177). The oxidation state of the metal in the metal salt is

47. The temperature coefficient of cell whose operation is based on the reaction
Pb ( s )  HgCl2 (aq)  PbCl2 (aq)  Hg (l ) is

 E  4 1
   1.5 10 V K
 T  p
The amount of heat released during the operation is (KJMole-1)

48. For the half-cell OH O

⇌ 2 H   2e  E 0  1.30V
OH O

At pH = 2, electrode potential is

49. The vapour pressure of a pure liquid A is 70 torr at 27°C. It forms an ideal solution with another
liquid B. The mole fraction of B is 0.2 and total vapour pressure of the solution is 84 torr at 27°C.
The vapour pressure of pure liquid B at 27°C

50. V.P. of pure A PA0  100 mm Hg , V.P. of pure B PB0  150 mm Hg

Distillate of vapours of a solution containing 2 mol of A and 3 mol of B will have total vapour
pressure, approximately, on condensation
 ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT – JEE - 2021 XII - TW TEST MARKS :100

TIME: 1HR CHEMISTRY DATE:19/07/20

ANSWER KEY
26. (B) 27. (A) 28. (A) 29. (B) 30. (B)

31. (D) 32. (C) 33. (B) 34. (B) 35. (B)

36. (D) 37. (B) 38. (B) 39. (A) 40. (D)

41. (D) 42. (A) 43. (A) 44. (B) 45. (D)

46. ( 3) 47. (6.5) 48. (1.42) 49. (140) 50. (130)