2023 April 8

FIITJEE
Solutions to JEE(Main) -2023

Test Date: 8th April 2023 (Second Shift)
PHYSICS, CHEMISTRY & MATHEMATICS

Paper - 1
Time Allotted: 3 Hours Maximum Marks: 300
 Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
5. Section – B : Do any 5 questions out of 10 Questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (1 – 10) contains 10 Numerical based questions. The answer to each question
is rounded off to the nearest integer value. Each question carries +4 marks for correct
answer and –1 mark for wrong answer.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2023 (8th April-Second Shift)-PCM-2
PART – A (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. The waves emitted when a metal target is bombarded with high energy electrons are
(A) Infrared (B) Microwaves
(C) Radio waves (D) X-rays
Q2. For a given transistor amplifier circuit in CE configuration

VCC  1 V,RC  1k  , Rb  100k and   100. Value of R C  1k 
base current Ib is Ic
(A) Ib  1.0 A
R b  100k 
(B) Ib  0.1A
B
(C) Ib  10 A Ib E Ie
(D) Ib  100A
VBB
VCC=1V
Q3. An emf of 0.08V induced in a metal rod of length 10cm held normal to a uniform magnetic field of
0.4 T, when moves with a velocity of :
(A) 20 ms-1 (B) 3.2 ms-1
-1
(C) 2 ms (D) 0.5 ms-1
Q4. Electric potential at a point ‘P’ due to a point charge of 5  109 C is 50 V. The distance of ‘P’ form
the point charge is :
1
(Assume,  9  10  9 Nm2 C 2 )
4  0
(A) 90 cm (B) 3 cm
(C) 9 cm (D) 0.9 cm
Q5. The acceleration due to gravity at height h above the earth if h << R (Radius of earth) is given by
 2h2   h 
(A) g'  g  1  2  (B) g'  g  1  
 R   2R 2 
 h2   2h 
(C) g'  g  1   (D) g'  g  1 
 2R 2   R 
x2
Q6. The trajectory of projectile, projected from the ground is given by y  . Where x and y are
20
measured in meter. The maximum height attained by the projectile will be.
(A) 10 m (B) 200 m
(C) 10 2 m (D) 5 m
Q7. The orbital angular momentum of a satellite is L, when it is revolving in a circular orbit at height h
from earth surface. If the distance of satellite from the earth centre is increased by eight times to
its initial value, then the new angular momentum will be.
(A) 9 L (B) 3 L
(C) 8 L (D) 4 L
Q8. The temperature at which the kinetic energy of oxygen molecules becomes double than its value
at 27 C is.
(A) 627 C (B) 927 C

(C) 1227 C (D) 327 C
Q9. Given below are two statements :

Statement I : Area under velocity-time graph gives the distance travelled by the body in a given
time.
Statement II : Area under acceleration-time graph is equal to the change in velocity-in the given
time.
In the light of given statements, choose the correct answer from the options given below.
(A) Both Statement I and Statement II are true.
(B) Statement I is correct but Statement II is false.
(C) Both Statement I and Statement II are False.
(D) Statement I is incorrect but Statement II is true.
Q10. In photo electric effect

(A) The photo current is proportional to the intensity of the incident radiation.
(B) Maximum Kinetic energy with which photoelectrons are emitted depends on the intensity of
incident light.
(C) Max. K.E with which photoelectrons are emitted depends on the frequency of incident light.
(D) The emission of photoelectrons require a minimum threshold intensity of incident radiation.
(E) Max. K.E of the photoelectrons is independent of the frequency of the incident light.
Choose the correct answer from the options given below :
(A) A and C only (B) A and E only
(C) B and C only (D) A and B only
Q11. The equivalent resistance between A and C 10k

B as shown in figure is : A B
20k 20k D
(A) 5k
(B) 30k
(C) 20k
(D) 10k
Q12. Given below are two statements: one is labelled as Assertion A and the other is labelled as
Reason R
Assertion A : Electromagnets are made of soft iron.
Reason R : Soft iron has high permeability and low retentivity.
In the light of above, statements, choose the most appropriate answer from the options
given below.
(A) Both A and R are correct but R is NOT the correct explanation of A
(B) Both A and R are correct and R is the correct explanation of A
(C) A is not correct but R is correct
(D) A is correct but R is not correct
Q13. For particle P revolving round the centre O with radius of y P(t)
circular path r and angular velocity , as shown in below
P(t = 0)
figure, the projection of OP on the x-axis at time t is
T = 6s 30  x
O
    
(A) x  t   r cos  t    (B) x  t   r sin  t  
 6   6 
 
(C) x  t   r cos  t  (D) x  t   r cos  t  
 6
Q14. A radio active material is reduced to 1/8 of its original amount in 3 days. If 8  103 kg of the
material is left after 5 days the initial amount of the material is
(A) 40 g (B) 256 g
(C) 32 g (D) 64 g
Q15. The width of fringe is 2 mm on the screen in a double slits experiment for the light of wavelength
of 400nm. The width of the fringe for the light of wavelength 600 nm will be :
(A) 3 mm (B) 1.33 mm
(C) 4 mm (D) 2 mm
Q16. A hydraulic automobile lift is designed to lift vehicles of mass 5000kg. The area of cross section
of the cylinder carrying the load is 250 cm 2. The maximum pressure the smaller piston would
have to bear is [ Assume g = 10 m/s2] :
(A) 20  10 6 Pa (B) 2  10 5 Pa
6
(C) 2  10 Pa (D) 200  106 Pa
Q17. A bullet of mass 0.1kg moving horizontally with speed 400 ms-1 hits a wooden block of mass
3.9kg kept on a horizontal rough surface. The bullet gets embedded into the block and moves 20
m before coming to rest. The coefficient of friction between the block and the surface _________.
(Given g = 10 m/s2)
(A) 0.50 (B) 0.25
(C) 0.65 (D) 0.90
Q18. Work done by a Car not engine operating between temperatures 127 C and 27 C is 2 kJ.
The amount of heat transferred to the engine by the reservoir is :
(A) 4 kJ (B) 8 kJ
(C) 2.67 kJ (D) 2 kJ
Q19. The power radiated from a linear antenna of length  is proportional to

(Given,   Wavelength of wave) :
 
(A) (B) 2
 
2
2 
(C) (D)  
 
Q20. Match List I with II

LIST I LIST II
A. Torque I. ML2 T 2
B. Stress II. ML2 T 2
C. Pressure gradient III. ML1 T 1
D. Coefficient of viscosity IV.
ML1 T 2
(A) A – IV, B – II, C – III, D – I (B) A – II, B – IV, C – I, D – III
(C) A – III, B – IV, C – I, D – II (D) A – II, B – I, C – IV, D – III
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1. A series combination of resistor of resistance 100  , inductor of inductance 1H and capacitor of
capacitance 6.25 F is connected to an ac source. The quality factor of the
circuit will be __________
Q2. A 600 pF capacitor is charged by 200V supply. It is then disconnected from the supply and is
connected to another uncharged 600 pF capacitor. Electrostatic energy lost in the process is
_________ J
Q3. A guitar string of length 90cm vibrates with a fundamental frequency of 120 Hz. The length of the
string producing a fundamental frequency of 180 Hz will be _________cm.
Q4. The number density of free electrons in copper is nearly 8  1028 m3 . A copper wire has its area of
cross section  2  10 6 m2 and is carrying of 3.2 A. The drift speed of the electrons is _________
106 ms1
Q5. A body of mass 5kg is moving with a momentum of 10 kg ms 1 . Now a force of 2N acts on the
body in the direction of its motion for 5s. The increase in the kinetic energy of the body is _____J.
x
Q6. The ratio of wavelength of spectral lines H and H  in the Balmer series is . The value of
20
x is _________.
Q7. The ratio of magnetic field at the centre of a current carrying coil of radius r to the magnetic filed
at distance r from the centre of coil on its axis is x : 1. The value of x is _______
Q8. A hollow spherical ball of uniform rolls up a curved

surface with an initial velocity 3 m/s (as shown in figure).
Maximum height with respect to the initial position
covered by it will be _______cm
(take, g = 10 ms2)
m
3
s
Q9. A steel rod of length 1m and cross sectional area 10-4 m2 is heated from 0  C to 200 C without
allowed to extend or bend. The compressive tension produced in the rod is_________
104 N. (Given Young’s modulus of steel  2  1011Nm2 , coefficient of linear expansion  10 5 K 1 )
Q10. Two transparent media having refractive indices 1.0 and1.5 are separated by a spherical
refracting surface of radius of curvature 30cm. The centre of curvature of surface is towards
denser medium and a point object is placed on the principle axis in rarer medium at a distance of
15 cm from the pole of the surface. The distance of image from the pole of the surface is
________cm.
PART – B (CHEMISTRY)
SECTION - A
Q1. Henry Moseley studied characteristic X- ray spectra of elements. The graph which
represents his observation correctly is
Given v= frequency of X-ray emitted
(A) z (B) v2
v z
(C) v (D) v
z v
Q2. A compound ‘X’ when treated with phthalic anhydride in presence of concentrated H2SO4 yields
‘Y’ , “Y” is used as an acid / base indicator. ‘X’ and ‘Y’ are respectively
(A) Salicyladehyde, Phenolphthalein (B) Anisole, methyl orange
(C) Carbolic acid, Phenolphthalein (D) Toludine,Phenolphthalein
Q3. Arrange the following gases in increasing order of vander Waals constant ‘a’
A. Ar
B. CH4
C. H2O
D. C6H6
Choose the correct option from the following
(A) B, C, D and A (B) D, C, B and A
(C) C, D, B and A (D) A, B, C and D
Q4. The descending order of acidity for the following carboxylic acid is
A. CH3COOH
B. F3CCOOH
C.ClCH2COOH
D. FCH2COOH
E.BrCH2COOH
(A) B > C > D > E (B) E > D > B > A. C
(C) B > D > E > A (D) D > B > A > E > C
Q5. For a good quality cement, the ratio of lime to the total of the oxides of Si, Al and Fe should be as
close as to.
(A) 3 (B) 4
(C) 1 (D) 2
Q6. The correct order of reactivity of following haloarenes towards nucleophilic substitution with
aqueous NaOH is.
NO 2
Cl Cl Cl Cl
(A) (B)
(C) (D)
NO 2
OMe O 2N NO 2
Choose the correct answer from the options given below:
(A) D > C > B > A (B) C > A > D > B
(C) A > B > D > C (D) D > B > A > C
Q7. The correct reaction profile diagram for a positive catalyst reaction
Without
catalyst Without With
catalyst catalyst
With
(A) catalyst (B)
Energy
Energy
Reactant Product Reactant Product
Reaction Coordinate Reaction Coordinate
Without With Without Without

catalyst catalyst catalyst catalyst
(C) (D)
Energy
Energy
Product
Product
Reactant Product Reactant Product
Reaction Coordinate Reaction Coordinate
Q8. The product (P) formed from the following multistep reaction is:
NO 2 (i) Br2
(ii) H2 / Pd
(P)
H3C (iii) NaNO2, HCl, 0 °C Product
(iv) H3PO2
Br OH
(A) (B)
H3C H3C Br
Br OH
(C) (D)
H3C Br
H3C
Q9. In Hall-Heroult process, the following is used for reducing Al2O3:-

(A) Graphite (B) CaF2
(C) Na3AlF6 (D) Magnesium
Q10. Given below are two statements:

Statement I: In redox titration, the indicators used are sensitive to change in pH of the solution.
Statement II:In acid-base titration, the indicators used are sensitive to change in oxidation
potential.
In the light of the above statements, choose the most appropriate answer from the options given
below.
(A) Both Statement I and Statement II are incorrect
(B) Statement I is incorrect but Statement II is correct
(C) Statement I is correct but Statement II is incorrect
(D) Both Statement I and Statement II are correct
Q11. Given below are two statements: One is labelled as Assertion A and the other is labelled as
Reason R.
Assertion A: Sodium is about 30 times as potassium in the oceans
Reason R: Potassium is bigger in size than sodium
In the light of the above statements, choose the correct answer from the options given below:
(A) A is true but R is false
(B) A is false but R is true
(C) Both A and R are true but R is NOT the correct explanation of A
(D) Both A and R are true and R is the correct explanation of A
Q12. Which of the following can reduce decomposition of H2O2 on exposure to light
(A) Urea (B) Alkali
(C) Glass containers (D) Dust
Q13. Major product ‘P’ formed in the following reaction is:

OH Br
2
P
O NaHCO 3 Major Product
Br Br
OH (B) Br OH
(A)
O O
(C) Br (D) Br OH
O O
O
Q14. Which of these reactions is not a part of breakdown of ozone in stratosphere?

   
uv
(A) ClO(g)  O(g) 
 C l(g)  O2 (g) (B) CF2 Cl2 (g)  Cl(g)  CF2Cl(g)
   
(C) Cl(g)  O3 (g) 
 ClO(g)  O2 (g) (D) 2ClO  ClO 2 (g)  C l(g)
Q15. Given below are two statements:

Statement I: Methyl orange is a weak acid.
Statement II:The benzenoid form of methyl orange is more intense / deeply coloured than the
quionoid form.
In the light of the above statements, choose the most appropriate answer from the options given
below.
(A) Both Statement I Statement II are incorrect
(B) Both Statement I and Statement II are correct
(C) Statement I is incorrect but Statement II is correct
(D) Statement I is correct but Statement II is incorrect
Q16. Match List I with List II

List – I List - II
Coordination Complex Number of unpaired electrons
A. Cr  CN 6 
3 I. 0
B. Fe  H2 O 6 
2 II. 3
C. Co  NH3  6 
3 III. 2
D. Ni NH3 6 
2 IV. 4
Choose the correct answer from the option given below :

(A) A-II, B- I, C-IV, D-III (B) A-IV, B-III, C-II, D-I
(C) A-III, B-IV, C-I, D-II (D) A-II, B-IV, C-I, D-III
Q17. Match List I with List II

List I List II
Natural amino acid One letter code
A. Glutamic acid I. Q
B. Glutamine II. W
C. Tyrosine III. E
D. Tryptophan IV. Y
(A) A-II, B- I, C-IV, D-III (B) A-IV, B-III, C-I, D-II
(C) A-III, B-IV, C-I, D-II (D) A-III, B-I, C-IV, D-II
Q18. Which of the following have same number of significant figure?

A.0.00253
B. 1.0003
C.15.0
D. 163
Choose the correct answer from the options given below
(A) B and C only (B) A, B and C only
(C) A, C and D only (D) C and D only
Q19. The correct IUPAC nomenclature for the following compound is:
O
CH2 CH3
H3C CH2 CH
COOH
(A) 2- Formyl-5-methylhexan-6-oic acid (B) 2-Methyl-5-oxohexanoic acid
(C) 5-Formyl-2-methylhexanoic acid (D) 5-Methyl-2-oxohexan-6-oic acid
Q20. The statement/s which are true about antagonists from the following is / are:
A. They bind to the receptor site.
B. Get transferred inside the cell for their action
C. Inhibit the natural communication of the body.
D. Mimic the natural messenger.
Choose the correct answer from the options given below:
(A) A and B (B) B only
(C) A and C (D) A, C and D
SECTION - B
Q1. The number of species from the following carrying a single lone pair on central atom Xenon
is_______________.
XeF5 , XeO3 , XeO2F2 , XeF5 , XeO3F2 , XeF4
Q2. For complete combustion of ethene,

C2H4 (g)  3O2 (g)  2CO2 (g)  2H2 O(l)
The amount of heat produced as measured in bomb calorimeter is 1406 kJ mol1 at 300K. The
minimum value of TS needed to reach equilibrium is (-)______kJ (Nearest integer)
Q3. The sum of oxidation state of the metals in Fe  CO 5 VO2  and WO3
Q4. The ratio of sigma and  bonds present in pyrophosphoric acid is___________.
Q5. The number of incorrect statement from the following is____________.

A. The electrical work that a reaction can perform at constant pressure and temperature is equal
to the reaction Gibbs energy.
B. E0cell is dependent on the pressure.
dE0 cell  r S0
C. 
dT nF
D. A cell is operating reversibly if the cell potential is exactly balanced by an opposing
source of potential difference.
Q6. The solubility product of BaSO4 is 11010 at 298 K. The solubility of BaSO4 in 0.1 M K2SO4(aq)
solution is _________109 g L1(nearest integer)
Given: Molar mass of BaSO4 is 233 g mol1
Q7. The number of atomic orbitals from the following having 5 radial nodes is _______.
7s, 7p, 6s, 8p,8d
Q8. Coagulating value of the electrolytes AlCl3 and NaCl for As2S3 are 0.09 and 50.04 respectively.
The coagulating power of AlCl3 is x times the coagulating power of NaCl. The value of x is_____.
x
Q9. The observed magnetic moment of the complex Mn  NCS 6  is 6.06 BM. The numerical value
of x is__________.
Q10. If the boiling points of two solvents X and Y (having same molecular weights) are in the ratio 2:1
and their enthalpy of vaporizations are in the ratio 1:2, then the boiling point elevation constant of
X is m times the boiling points elevation constant of Y. The value of m is _____(nearest integer)
PART – C (MATHEMATICS)
SECTION - A
 1  2isin  
Q1. Let A  0   0, 2  : is purely imaginary  . Then the sum of the elements in A is
 1  i sin  
(A) 2 (B) 
(C) 4 (D) 3
n
 1 
Q2. The absolute difference of the coefficients of x10 and x 7 in the expansion of  2x 2   is equal
 2x 
to
(A) 133  13 (B) 113  11
(C) 12 3  12 (D) 103  10
Q3. If the number of words, with or without meaning, which can be made using all the letters of the
word MATHEMATICS in which C and S do not come together, is  6!  k , then k is equal to
(A) 1890 (B) 5670
(C) 2835 (D) 945
Q4. For a,b   and a  b  10 , let the angle between the plane P : ax  y  z  b and the line
 1
 : x  1  a  y  z  1 be cos 1   . If the distance of the point  6,  6, 4  from the plane P is
3
3 6 , then a 4  b2 is equal to
(A) 48 (B) 25
(C) 85 (D) 32
Q5. The area of the quadrilateral ABCD with vertices A  2, 1, 1 , B 1, 2, 5  , C  2,  3, 5  and
D 1,  6,  7  is equal to
(A) 48 (B) 8 38
(C) 9 38 (D) 54
 ˆ u  î  bjˆ  kˆ and u  c î  ˆj  kˆ be coplanar. If the vectors

Q6. Let the vectors u  î  ˆj  ak, 2 3
  
v1   a  b  i  cj  ck, v 2  a i  b  c  j  ak and v 3  b î  bjˆ   c  a  k are also coplanar, then
ˆ ˆ ˆ ˆ ˆ ˆ
6  a  b  c  is equal to
(A) 12 (B) 4
(C) 6 (D) 0
Q7. If     0 are the roots of the equation ax 2  bx  1  0 , and

1
lim 

 1  cos x 2  bx  a  2 1  1 1 
     , then k is equal to
2
x   k 
1

2 1  ax  
(A)  (B) 2
(C) 2 (D) 
 1 5  1 2 2 2
Q8. If A    , A  A   I and     2 , then 4     is equal to :
  10 
(A) 12 (B) 19
(C) 14 (D) 10
n
Q9. Let an be the nth term of the series 5  8  14  23  35  50  ..... and Sn   ak . Then
k 1
S30  a40 is equal to

(A) 11310 (B) 11260
(C) 11290 (D) 11280
x 1 y  2 z  5
Q10. Let P be the plane passing through the line   and the point  2, 4,  3  . If the
1 3 7
image of the point  1, 3, 4  in the plane P is  , ,   then      is equal to
(A) 12 (B) 9
(C) 10 (D) 11
Q11. If the probability that the random variable X takes values x is given by
P  X  x   k  x  1 3  x , x  0, 1, 2, 3,....., where k is a constant, then P  X  2  is equal to
7 7
(A) (B)
27 18
11 20
(C) (D)
18 27
Q12. Let S be the set of all values of    ,   for which the system of linear equations
x  y  3z  0
x   tan   y  7z  0
x  y   tan   z  0
120
has non-trivial solution. Then   is equal to
 s
(A) 10 (B) 30
(C) 40 (D) 20
9
Q13. Let the mean and variance of 12 observations be and 4 respectively. Later on, it was observed
2
that two observations were considered as 9 and 10 instead of 7 and 14 respectively. If the correct
m
variance is , where m and n are coprime, then m + n is equal to
n
(A) 314 (B) 317
(C) 315 (D) 316
Q14. Let O be the origin and OP and OQ be the tangents to the circle x 2  y 2  6x  4y  8  0 at the
 1
points P and Q on it. If the circumcircle of the triangle OPQ passes through the point  ,  then
 2
a value of  is
5 3
(A) (B)
2 2
1
(C) 1 (D) 
2
Q15. Let A  0, 1, B 1, 1 and C 1, 0  be the mid-points of the sides of a triangle with incentre at the
point D. If the focus of the parabola y 2  4ax passing through D is    
2, 0 , where

 and  are rational numbers, then is equal to
2
9
(A) (B) 12
2
(C) 6 (D) 8
Q16. Let A  1, 2, 3, 4, 5, 6, 7 . Then the relation R   x,y   A  A : x  y  7 is

(A) transitive but neither symmetric nor reflexive
(B) reflexive but neither symmetric nor transitive
(C) an equivalence relation
(D) symmetric but neither reflexive nor transitive
Q17.   
The value of 36 4 cos2 90  1 4cos2 270  1 4 cos2 810  1 4 cos2 2430  1 is  
(A) 18 (B) 54
(C) 27 (D) 36
  x x  2 x 
Q18. The integral    2    x   log2 x dx is equal to
 
x x x
 x  2 x x
(A)       C (B)   log2    C
2 x 2 2
x x x
 x  2 x 2
(C)       C (D)   log2    C
2 x 2 x
Q19. The negation of  p    q      p  is equivalent to

(A) p   q    p   (B) p    q 
(C) p  q (D) p   q    p  
Q20. 25190  19190  8190  2190 is divisible by

(A) both 14 and 34 (B) 14 but not by 34
(C) 34 but not by 14 (D) neither 14 nor 34
SECTION - B
Q1. Let the area enclosed by the lines x  y  2, y  0, x  0 and the curve
 3 
f  x   min  x 2  , 1   x   where  x  denotes the greatest integer  x , be A. Then the value of
 4 
12A is………….
Q2. Let R  a, b, c, d, e and S  1, 2, 3, 4 . Total number of onto functions f : R  S such that
f  a   1, is equal to………
Q3. The ordinates of the points P and Q on the parabola with focus  3, 0  and directrix x  3 are in
the ratio 3 : 1 . If R  ,   is the point of intersection of the tangents to the parabola at P and Q,
2
then is equal to………

2.4
2
Q4. Let  t  denote the greatest function. If   x
0
 dx     2   3   5 , then        is

equal to…………
1 1 1
Q5. Let 0  z  y  x be three real numbers such that , , are in an arithmetic progression and
x y z
3 2
x, 2y, z are in a geometric progression. If xy  yz  zx  xyz , then 3  x  y  z  is equal
2
to……….
Q6. Let k and m be positive real numbers such that the function
3x 2  k x  1, 0  x  1 8f '  8 
f  x   2 2
is differentiable for all x  0 . Then is equal to……….
 mx  k , x 1 1
f ' 
8
 6x 2  5x  1  2
1  2x  3x  4 
Q7. If domain of the function loge 
2x  1 
  cos   is  ,     ,  , then
  3x  5 
 
18  2  2   2  2 is equal to………..
Q8. Let m and n be the numbers of real roots of the quadratic equations
x 2  12x   x   31  0 and x 2  5  x  2  4  0 respectively, where  x  denotes the greatest
integer  x . Then m2  mn  n 2 is equal to………

Q9. Let the solution curve x  x  y , 0  y  , of the differential equation
2
2  1
 log  cos y  
e  
cos y dx  1  3x loge  cos y  sin y dy  0 satisfy x   
 3  2loge 2
.
Q10. Let P1 be the plane 3x  y  7z  11 and P2 be the plane passing through the points
 2,  1, 0  ,  2, 0,  1 and  5, 1, 1 . If the foot of the perpendicular drawn from the point  7, 4,  1 on
the line of intersection of the planes P1 and P2 is  , ,   , then      is equal to………….
FIITJEE
KEYS to JEE (Main)-2023
SECTION - A
1. D 2. C 3. C 4. A
5. D 6. D 7. B 8. D
9. A 10. A 11. A 12. B
13. D 14. B 15. A 16. C
17. B 18. B 19. D 20. B
SECTION – B
1. 4 2. 6 3. 60 4. 125
5. 30 6. 27 7. 8 8. 75
9. 4 10. 30
SECTION - A
1. D 2. C 3. D 4. C
5. D 6. D 7. A 8. A
9. A 10. A 11. D 12. A
13. C 14. D 15. A 16. D
17. D 18 C 19. B 20. C
SECTION - B
1. 4 2. 1411 3. 10 4. 6
5. 1 6. 233 7. 3 8. 556
9. 4 10. 8
SECTION - A
1. C 2. C 3. B 4. D
5. B 6. A 7. B 8. C
9. C 10. C 11. A 12. D
13. B 14. A 15. D 16. D
17. D 18 DROP 19. C 20. C
SECTION - B
1. 17 2. 180 3. 16 4. 6
5. 150 6. 309 7. 20 8. 9
9. 12 10. 11
FIITJEE
Solutions to JEE (Main)-2023
SECTION – A
Sol1. X-rays
Sol2. VCC  1V
RC  1k
Rb  100k
 = 100
Ic Rc  Vcc
V 1
Ic  cc  3  1mA
Rc 10
Ic I 1 103
  Ib  c   1 105 A  10 A
Ib  100
Sol3.    vB
 .08
v   2m / s
B .1 .4
kq kq 9  109  5  109
Sol4. V   r   9  108  10 9
r v 50
 90cm
 2h 
Sol5. g'  g  1 
 R 
x2
Sol6. y  x 
20
dy dy 2x
For ymax, 0   1 0
dx dx 20
 x  10
100
y max  10   5m
20
Sol7. L  mv 0 r0
GM
m . r0
r0
When r  8r0  r0  9r0 E
GM GM
Lf  m . gr0  m .3r0  3L
gr0 r0
3 3
Sol8. K  KT  K.300
2 2
3
K f  2K  k.600
2
 600  273  t
 t  600  273  327 C

Sol9. Area under v  t graph gives displacement.

Area under a  t graph gives change in velocity.
Sol10. K max  h    K max depends on frequency of light.

Greater the photon flux, greater the no. of photoelectrons emitted and so greater the
photocurrent.
Sol11.
1 1 1 1 1 C
    A B
R 20 20 10 5 20 k 20 k D 10k
R eq  5k 

D
B
A
C

A D
B
C
Sol12. Soft iron has high permeability as well as low retentivity

 both A and R are correct and R is the correct explanation of A
Sol13. at time ‘t’   


 t
P t 
6

So, projection of OP on the x-axis is – Pt  0

130 

x  t   OPcos   r cos t  
6  x
N0
Sol14. N  , Where n  no. of half lives.
2n
N N
 0  n0  n  3
8 2
If T = half life then 3T = 3 days
 T  1day
After 5 days –
N N
N  50  0  8  103 kg
2 32
 N0  32  8  103 kg
 256  10 3 kg
 256 gm.
Sol15. B1  2mm
D   600nm 6 3
As,    2  2   
d 1 1 400nm 4 2
3 3
 2  1   2mm  3mm
2 2
F 5  104 1 m = 5000kg
Sol16.  P1  P2   4
  108
A 250  10 50 P1 P2
6
 2  10 Pa
Sol17. From COLM :- u=400m/s

.1 400   3.9  0.1 V 
.1 400 m=0.1kg
v  10m / s M=3.9kg 20m
4
Loss in K = work done by friction
1
  M  m  v 2    M  m  g.x.
2
v2

2gx
100 1
 
20  20 4
T1 Q1 127  273 400 4 127  C 27  C

Sol18. As,     Q1 Q2
T2 Q2 27  273 300 3
4 T1 T2
 Q1  Q2
3
 Q1  Q2  W  2kJ W
3
 Q1  Q1  2kJ.
4
Q1
  2KJ  Q1  8KJ
4
2

Sol19. Power P   

Sol20. Torque  MLT 2  L  ML2T 2

Stress  MLT 2  L 2  ML1 T2
SECTION - B
Sol1. R  100  , L  1H, C  6.25 F
XL 1 L 1 106 1000 100
Q   
R R C 100 6.25 100 625
10
 10  4
25
C  600PF  12 8 +q 600PF

Sol2.  Q i  CV  120000  10  12  10 C
V  200 V 
Qf  6  10 8  CVf
6  10 8
Vf   100V
600  1012
Electrostatic energy lost = Ui  Uf +q 600PF
2 2

12  10 C
8

 
2 600  1012 100 
 6J.
2  600  1012 2
Sol3. f0 
v f 
 0 2  1  2 
f0  1
1
 1  90 cm
2 f0 1  2 f0  2
Sol4. n  8  1028 m3

A  2  106 m2
i  3.2 A
j i 3.2
As, j  neVd  Vd   
ne A ne 2  10  8  1028  1.6  1019
6
1
  10 3
8
 125  10 3 m / s
Sol5. Ft  P  Pf  Pi
 2  5  Pf  10
 Pf  20kg.m / s
Pf2 Pi2 1
 K     400  100   30 J.
2m 2m 10
Sol6. For H , n1  2, n2  3
For H , n1  2, n2  4
 1 1 
H  Rz2  2  2  1  1
 2 4  4 16 3 36
    
H   1 1  1 1 16 5
Rz2  2  2  
2 3  4 9
H  3  9 27 x
     x  27
H  20 20 20
Bcentre
Sol7.  x
Baxis
0 i
2r
  x
0 ir 2
3/ 2


2 r2  r2
2 3/2
1  2r 
   x
r r2
r3
 23/ 2  x  x  23/ 2
r3
 x  23  8
Sol8. From COME :-

Ei  E f
1 1 2 2 2
 mv 2  mr   mgh.
2 2 3
3m / s
1 1
 mv 2  mv 2  mgh. v
2 3
5 v  r
 mv 2  mgh
6
5v 2 59 3
h   m  75 cm
6g 6  10 4
Sol9. Are A  104 m2 .   1m

T  200
A
Y  2  1011Nm2
Steel rod
  105 k 1

Compressive tension produced = YA
0
 0 T
 YA
0
  T YA
 10 5  200  2  1011  104

 4  104 N
2 1 2  1
Sol10. Using  
v u R
O R = 30cm
1.5 1 1.5  1
  
v 15 30 15cm
1.5 1 1 3 1 2  1.5
     1  1
v 60 15 60 20
 v  1.5  20  30 cm.
SECTION – A
Sol1. z
Sol2.
OH
OH
O
O C C O
H O C C O
HO H H2SO4(c)
HO
Carbolic acid (Phenol) Phenolphthalein
Sol3. Vander waal constant depend upon entermolecular force of attraction and correct order is
C6H6 > H2O > CH4 > Ar
Sol4. -I effect of F, Cl, Br are F > Cl > Br and greater the extent of –I effect greater is the acidic
properties.
Sol5. For good quality cement ratio of CaO to total oxide of Si (SiO2), Al (Al2O3) and Fe(Fe2O3) should
be close to 2
Sol6. Chlorobenzene undergoes aromatic nucleophic substitution via carbanion intermediate so

grater the –M group at ortho and para position greater is the stability of carbanion
intermediate the faster is the rate of reaction.
Sol7. Positive catalyst decrease the activation energy
Sol8.
NO 2 NO 2 NH2 N2Cl
Br2 H2 / Pd NaNO2 / HCl

°C
Br Br Br
CH3 CH3 CH3 CH3
H3PO 2
H3PO 3 + N2 + HCl+
Br
CH3
Sol9. In Hall- Heroult process reduction of Al2O3 to Al can be done using graphite
Sol10. In redox titration indicators are sensitive to oxidation potential and in acid base titration
indicators are sensitive to change in pH.
Sol11. Due to bigger size of potassium it form more stable lattice as compared to sodium with silicates
sodium is more abundant than potassium due to more soluble nature of salt of sodium.
Sol12. H2O2 decomposes slowly as

1
H2 O2    
 H2 O     O 2  g 
2
Urea act as stabilizer.
Sol13.
Br
OH
+ Br2 OH NaHCO 3
O
O
Br
Br O O Na
O
O
hv
Sol14. CF2 Cl2  Cl   CF2 Cl
Cl   O3  ClO  O2
ClO  O   Cl  O2
Sol15. Methyl orange is weak base

Benzenoid structure  Quinonoid structure
Yellow coloured Red coloured
Sol16.
-3 +3 3
[Cr(CN)6] Cr 3d
2 3
d Sp
+2 +2 6
[Fe(H 2O)6] Fe 3d
3 2
Sp d
+3 +3 6
[Co(NH3)6] Co 3d
2 3
d Sp
+2 +2 8
[Ni(NH3) 6] Ni 3d
3 2
Sp d
Sol17. It is fact.
Sol18. Number Significant figure

0.00252 3
1.0003 5
15.0 3
163 3
Zero between no zero digit are significant
Sol19.
O
C CH2 CH3
5 3 2
H3C CH2 CH
6 4
COOH
1
2- methyl-5- oxohexanoic acid
Sol20. Drugs that bind reseptor site and inhibits it natural function are called antagonists
SECTION – B
Sol1.
F F
XeF 5 XeO 3 Xe
Xe O
F O O
F
F
F
F F O
XeO 2F 2 Xe
XeOF 4 Xe
F O F
O F
F
O H3C F
XeF 4 Xe
XeO 3F 2 Xe O
F
O HO
F
Sol2. H  U  ngRT
 2  8.3  300
 1406 
1000
 1410.98  1411 KJ
G  0 , at equilibrium
G  H  T  S
H  TS  1411 KJ
Sol3. 0  4   6 
Fe  CO 5 VO2  WO3
Sum of oxidation state = 0+4+6 =10
Sol4.
O O
H O P O P O H
O O
H H
 12
 6
 2
Sol5. E0 is defined for standard conditions

Pressure 1 bar
Concentration 1M
2
Sol6. BaSO 4  S   Ba2  SO4
S S  0.1
Ba 2  SO 42   10 10

S  .1  1010
S  109 mol / L
 233  109 gm /L
Sol7. Number of radial nodes = n   1

7S 701=6
7P 711=5
8S 801=7
8d 821=5
6S 601=5
1
Sol8. Cogulating power 
Cogulation Value
 CP AlCl 50.04
3
  566
 CP NaCl .09
Sol9.   n n  2 
6.06  n n  2 
n  5 no of unpaired electron = 5
Mn2 3d5
x  2  6
x4
RT 2  Msolvent
Sol10. Tb  Kb m Kb 
1000  Hvap
2
 Tb x  Tb x Mx Hy
 2
 
 Tb y  Tb x My Hx
2
 2   1  2 
     
 1   1  1 
8
 8
1
SECTION – A
1  2 isin  1  isin 
Sol1. z 
1  i sin  1  isin 
1  2sin2   i 3 sin 
z
1  sin2 
Re  z   0 are purely imaginary
1  2 sin2 
0
1  sin2 
1
 sin   
2
  3  3 7 
A , , , 
4 4 4 4 
 3 5 7 
    4
Sum = 4 4 4 4
r
11 r  1 
Sol2. Tr 1  11

Cr 2x 2   
 2x 
11
Tr 1  Cr 211 2r , x 22  2r r
11
 Cr 211 2r  x 22 3r
22  3r  10 22  3r  7
r4 r5
10 7
Coefficient of x …….. coefficient of x
 11C 4 23  11C5 21
 11 12  13  123  12
Sol3. Total words when C & S are together

11! 10!
   2!
2! 2! 2! 2!  2! 2!
10!
 9
2!  2! 2!
9  10  9  8  7
  6!
8
 5670  6!
k  5670
1
Sol4.   cos1
3
1 2 2
sin   1  
9 3
a  1  1 1   1  1 2 2
sin   
2
a  1 1  3 3
2

 3 a  2  
 24 a2  2 

 3 a2  4a  4  8a 2  16 
2
 5a  12a  4  0
 5a2  10a  2a  4  0
2
a  2, ,az
5
a  2
Distance of
 6,  6,4 
2x  y  z  b  0 is 3 6
12  6  4  b
3 6
4  1 1
 b  22  18
 b  40,  4
a  b  10
b  4
a 4  b4  32
1   1   D C

Sol5. Area =  AB  AC   AC  AD
2 2
1   

2

AB  AD  AC 
1
 
  8ˆj  12kˆ   4  î  ˆj  kˆ
2
  A B
î ˆj kˆ
1
 0 8 12
2
1 1 1

  2  20iˆ  12ˆj  8kˆ 

 8 5iˆ  3ˆj  2kˆ 
Area = 8 25  9  4  8 38
  
u1 u 2 u3   0
Sol6.
1 1 a
1 b 1 0
c 1 1
b  1  c  1  a 1  bc   0
 abc  a  b  c  2
  
 V1 V2 V3   0
 
ab c c
a bc a 0
b b ca
 
 2a ac  bc  c 2  2c a2  ab  ac  0  
 2a2 c  2abc  2ac 2  2a2 c  2abc  2ac 2  0
 4abc  0  abc  0
a  b  c  2  6  a  b  c   12
Sol7. ax 2  bx  1  a  x    x   
1
 
a
 x 2  bx  a  a 1  x 1  x 
1/2
 lim 

 1  cos x 2  bx  a
  

1
x  2  1  x  

1/2
 1  cos 1  x 1  x
     a2 1  x 2 
 lim  2  
1

x   2 a  1   x 1   x 
2  
1/2
2
1 1 2   1 1    1 1 1 
   a 1       1     2
 2 2     2      2    
1 1 1
     k  2
2    
Sol8. A  XI  0
1 x 5
 0
 10  x
 x 2  11x  10  5  0
 10  5  A 1   A  II I
1 11
 , 
10  5 10  5
    2
3
1 11
  ,P 
5 5
4 121
4 2   2   2    3 2  14
25 25
Sol9. Sn  5  8  14  23  35  50  ....  an
Sn  0  5  8  14  23  .....  an
0  5  3  6  9  12  15  ........an

a n  5  3  6  9  .....  n  1 term 
2
3n  3n  10
an 
2
2
3  40   3  40   10
a 40   2345
2
30 30 30
S30  3 n2  3 n  10 1
n 1 n 1 n 1
3  30  31 61 3  30  31
  10  30
 6 2
2
S30  13635
S30  a40  11290
Sol10. Equation of plane

x 1 y  2 z  5
1 2 2 0
1 3 7
4x  y  z  7
  1   3   4 2  4  3  4  7 
   2
4 1 1 16  1  1
  7 ,   1,   2
      10

Sol11.  p x  x  1
x0
 
k 1  2  31  3  32  4  3 3  .......  1
2 3 4
S  1
   .......
3 32 33
S 1 2 3
   2  3  .......
3 3 3 3
2S 1 1 1
 1   2  3  ......
3 3 3 3
2S 1 3
 
3 1 2
1
3
9
S
4
P  x  2   1  P  x  0   P  x  1
4 2 7
 1  1  
9 3  27
Sol12. For Non trivial solution:-

D=0
1 1 3
1 tan  7 0
1 1 tan
tan2    
3 1  3  0
tan   3,  1
  2  3 
 , , , 
3 3 4 4 
120 120 
    20
  6
x 9
Sol13. 
12 2
x  54
2
x 2  9 
   4
12  2 
x2  291
xnew  54   9  10   7  14  56
2
xnew  291   81  100   49  196  355
2
2 335  56 
new   
12  12 
2 281 m
new  
36 n
m  n  317
Sol14. Circumcircle of DPQ P

 x  0  x  3   y  0  y  2  0
 1
Passes through  ,  (3, -2)
 2
1 (0, 0)
 2   3  1  0
4
Q
5
  2  3   0
4
2
 4  12  5  0
 4 2  10  2  5  0
 2  1 2  5  0
1 5
 ,
2 2
Sol15. a = OP = z P(0, 2)
b = OQ = z
c = PQ = 2 2
Incenter
 4 4 
D ,  A(0, 1) B(1, 1)
222 2 222 2 
 2 2 
D , 
2 2 2 2 
2
 2   2  O(0, 0) C(1, 0) (2, 0)
y 2  4ax     4a  
2 2  2 2 
2
4a 
2 2
1 2 2
a 
2 2
1
a
4

2 2 
1 1
  , 
2 4

8
2
 
Sol16. R  1, 6  ,  2, 5 ,  3, 4  ,  4, 3  , 5, 2 ,  6, 1 symmetric but neither reflexive nor transitive.

Sol17. 4cos2   1  4 1  sin2   1 
 3  4 sin2 
sin3

sin 
so given expression can be written as

sin270 sin810 sin2430 sin7290
36    
sin90 sin270 sin810 sin 2430
sin7290
 36   36
sin90
  x x  2 x 
Sol18. I          log2 x dx
 2   x  
 
 n  x x 2
n 
x


 e 2
e x  log2 x dx
 
 
x   nx  n2 x n2 nx 
 e  e  log2 x  dx
Sol19.  p    q    p  
   p  q  p
  p  p   q  p
 c   q  p
pq
Sol20. 25190  8190 is divisible by 25  8  17

19190  2190 is divisible by 19  2  17
25190  19190 is divisible by 25  19  6
8190  2190 is divisible by 8  2  6
 divisible by 34 but not by 14.
SECTION – B
1
2 (0, 2)
 2 3 1 3 1
Sol1.   x   dx       1
0 4 2 2 2
1
 x3 3x  2
   1 (0, 1)
3 4 0
1 3  3
A  1  0, 4 
24 8  
1 36 1 (1, 0) (2, 0)
 12A    12
2 8 2
A = 17
Sol2. Total number of onto function

5!
 4!  240
3! 21
f a  1
when
4!
4!  3!  24  36  60
2!2!
required number of function = 180
Sol3. y 2  12x

Let Q 3t 2 , 6t 

P 27t 2 , 18t 

R  ,    at1  t 2 , a  t1  t 2  
 3t  3t, 3  t  3t 

R  ,    9t 2 , 12t 
2
2 12t  144
   16
 9t 2 9
1 2 3 2 5 2.5
Sol4.  0 dx   1 dx   2 dx   3dx   4dx   5dx
0 1 2 3 2 5
9 2  3  5
        9  1 1 1  6
2 1 1
Sol5.  
y x z
2y 2  xz
2 xz xz
 
y xz 2y 2
x  z  4y
3
xy  zy  zx  xyz
2
3
y  x  z   zx  xzy
2
3
4y 2  2y2   y  2y2
2
6y2  3 2y 3
y 2
x  y  z  5y  5 2
2
3  x  y  z   3  50  150
.
Sol6. function is differentiable  x  0

 
f 1  f 1
3  2k  m  k 2
As function is differentiable  x  0
k
2mx x 1  6x 
2 x  1 x 1
k
2m  6 
2 2
k
m3
4 2
k
k2  3   3  2k
4 2
7
k
4 2
103
m
32
103
8f ' 8 8  2  8  32
  309
 1 16
f ' 
 8  12
6x 2  5x  1 - + - +
Sol7. 0
2x  1 1 1 1
 
 3x  1 2x  1
0 2 3 2
2x  1
 1 1   1 
x   ,    , 
 2 3 2 
2x2  3x  4
1  1
Again, 3x  5
 1 1   5  5
x ,    ,  x
 2 2  3  & 3
 Domain of function
 1 1   1 1 
x ,  , 
 2 3 2 2 
So,
 
18  2  2   2   2  20
Sol8. x 2  12x   x   31  0
x  x 2  11x  31
0  x 2  11x  31  1
 x 2  11x  30  0
x   5, 6 
 x   5
x 2  12x  5  31  0
x 2  12x  36  0
x  6 but x   5, 6 
x 
m=0
x2  5 x  2  4  0
x  2 x  2
x 2  5x  14  0 x 2  5x  6  0
 x  7  x  2  0  x  3 x  2  0
x  7,  2 x  3,  2
x  7,  2,  3
n3
m2  mn  n2  9
Sol9. cos y  log2 cos y dx  1  3x n cos y  sin y dy

dx  3x 1 
 tan y   2 
dy  n cos y n cos y 
dx  3 tan y  tan y
 x  2
dy  ncos y  n cos y
3 tan y
  n cos y dy
I.F = e
ncos y  t
3
 t dt
I.F = e
 e3 nt
 t 3  n3 cos y
sin y
 x  n3 cosy    ncos y dy  c
cos y
 n2 cos y
x  n3 cosy  c
2
 1
x  
 3  2n2
c=0

y
6
1 1
x 
4 n4  n3
n
3
m  n  12
x  5 y 1 z 1
Sol10. P2 is given by 3 2 1 0
3 1 2
xyz 3
DR of line intersecting of P1 & P2
i j k
1 1 1
3 1 7
6iˆ  4ˆj  2kˆ
xy 3
Let z = 0
3x  y  11
2x  8
X = 4, y = 1
x  4 y 1 z  0
  r
6 4 2
 ,,     6r  4, 4r  1, 2r 
6    7   4    4   2    1  0
6  42  4  16  2  2  0
36r  24  16r  4  4r  56  0
56r  28
1
r
2
      12r  5  6  5  11

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FIITJEE

Solutions to JEE(Main) -2023

PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours Maximum Marks: 300

5. Section – B : Do any 5 questions out of 10 Questions.

Q2. For a given transistor amplifier circuit in CE configuration

Q9. Given below are two statements :

Q10. In photo electric effect

Q11. The equivalent resistance between A and C 10k

Q19. The power radiated from a linear antenna of length  is proportional to

Q20. Match List I with II

Q8. A hollow spherical ball of uniform rolls up a curved

Reaction Coordinate Reaction Coordinate

Without With Without Without

Reaction Coordinate Reaction Coordinate

Q9. In Hall-Heroult process, the following is used for reducing Al2O3:-

Q10. Given below are two statements:

Q13. Major product ‘P’ formed in the following reaction is:

Q14. Which of these reactions is not a part of breakdown of ozone in stratosphere?

Q15. Given below are two statements:

Q16. Match List I with List II

Choose the correct answer from the option given below :

Q17. Match List I with List II

Q18. Which of the following have same number of significant figure?

Q2. For complete combustion of ethene,

Q5. The number of incorrect statement from the following is____________.

 ˆ u  ˆi  bjˆ  kˆ and u  c ˆi  ˆj  kˆ be coplanar. If the vectors

Q7. If     0 are the roots of the equation ax 2  bx  1  0 , and

S30  a40 is equal to

Q16. Let A  1, 2, 3, 4, 5, 6, 7 . Then the relation R   x,y   A  A : x  y  7 is

Q19. The negation of  p    q      p  is equivalent to

Q20. 25190  19190  8190  2190 is divisible by

Sol10. K max  h    K max depends on frequency of light.

Sol12. Soft iron has high permeability as well as low retentivity

Sol13. at time ‘t’   

Sol17. From COLM :- u=400m/s

T1 Q1 127  273 400 4 127  C 27  C

Sol20. Torque  MLT 2  L  ML2T 2

C  600PF  12 8 +q 600PF

Sol4. n  8  1028 m3

Sol8. From COME :-

Sol9. Are A  104 m2 .   1m

 10 5  200  2  1011  104

Sol6. Chlorobenzene undergoes aromatic nucleophic substitution via carbanion intermediate so

Sol7. Positive catalyst decrease the activation energy

Br2 H2 / Pd NaNO2 / HCl

CH3 CH3 CH3 CH3

Sol12. H2O2 decomposes slowly as

Sol15. Methyl orange is weak base

Sol18. Number Significant figure

Sol5. E0 is defined for standard conditions

Ba 2  SO 42   10 10

Sol7. Number of radial nodes = n   1

Sol3. Total words when C & S are together

1   1   D C

Sol10. Equation of plane

Sol12. For Non trivial solution:-

Sol14. Circumcircle of DPQ P

so given expression can be written as

Sol20. 25190  8190 is divisible by 25  8  17

Sol2. Total number of onto function

required number of function = 180

Sol6. function is differentiable  x  0