Dikki Institute

16/1 Raja Singh Colony, Shahbad Markanda

WORKSHEET 11C GOC

Class 11 - Chemistry

1. Which of the following is a property of a carbocation? [1]

a) all of these b) it is positively charged

c) it is unstable d) it has a sextet of electrons

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2. When inductive and electromeric effects operate in opposite directions, what happens? [1]

a) resonance structures are formed. b) the inductive effect predominates.

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c) inductive and electromeric effects operate d) the electomeric effect predominates.
with the same magnitude.
3. The most stable carbocation, among the following is ________. [1]
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a) CH - C H - CH - CH - CH b) CH - CH - C H - CH - CH
+ +

3 2 2 3 3 2 2 3

c) CH - CH - C H +
d) (CH ) C - C H - CH
+
S
3 2 2 33 3

4. Delocalisation of σ electrons of C - H bond of an alkyl group directly attached to an atom of unsaturated system [1]
IN

or to an atom with an unshared p orbital is called:

a) Electromeric effect b) Hyperconjugation

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c) Inductive effect d) Resonance effect

5. ________ is observed especially in conjugated systems. [1]
K

a) Inductive effect b) Electromeric effect

c) Mesomeric effect d) Polarizibility effect

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6. The reaction
[1]
P eroxide

C H3 C H = C H2 + HBr −−−−−→ C H3 C H2 C H2 Br can be explained by

a) carbanion formation b) free-radical mechanism

c) carbocation formation d) electrophilic substitution

7. In which of the following compounds the carbon marked with asterisk is expected to have greatest partial [1]
positive charge?

a) *CH3 - CH2 - Br b) *CH3 - CH2 - Cl

c) *CH3 - CH2 - I d) *CH3 - CH2 - CH3

8. A methyl carbanion has C-atom which has ________. [1]

a) four pairs of electrons b) three pairs of electrons

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 c) two pairs of electrons d) five pairs of electrons
9. Electrophilic addition reactions proceed in two steps. The first step involves the addition of an electrophile. [1]
Name the type of intermediate formed in the first step of the following addition reaction.

H3C—HC = CH2 + H+→ ?

a) 2° Carbocation b) 1° Carbocation

c) 2° Carbanion d) 1° Carbanion
10. Consider the following compounds:
[1]

Hyperconjugation occurs in ________.

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a) I and III b) II only

c) III only d) I only

11. Which of the following is an electrophile? [1]

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a) Ammonia b) Water

c) Cyanide ion TI d) Dimethyl chloride

12. CH3 - MgBr and (C2H5)2 CuLi are ________. [1]

a) electrophiles b) lewis acids

S
c) nucleophiles d) both electrophiles and nucleophiles
IN

13. Which of the following carbocation is most stable? [1]

a) (C H ⊕

)3 C
b) ⊕

(C H3 )3 C C H2
3

c) C H ⊕
d) ⊕
KI

3
C HC H2 C H3 C H3 C H2 C H2

14. Heterolysis of carbon - bromine bond gives ________. [1]

K

a) two free radicals b) one carbocation ion and one carbanion

c) two carbocations d) two carbanions

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15. Acid catalysed electrophilic addition reaction to carbon-carbon double bond proceeds in two steps. The first step [1]
involves the addition of an H+ to double bond. Name the type of intermediate formed in the first step of the
following addition reaction:

+
H3 C − HC  =  C H2 +   H →?

a) 2° Carbanion b) 1° Carbocation

c) 2° Carbocation d) 1° Carbanion
16. Which among the following is a nucleophile? [1]

a) ZnCl2 b) NH3

c) FeCl3 d) AlCl3

17. Nucleophile is a species that should have: [1]

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 a) capacity to accept electrons b) a pair of electrons to donate

c) positive charge d) electron deficiency

18. Zero inductive effect is assumed for ________. [1]

a) C - N bond b) C - Br bond

c) C - O bond d) C - H bond
19. In which bond of CH3CH2CH2Br the inductive effect is expected to be the least? [1]

a) bond between carbon-1 and hydrogen b) bond between carbon-3 and carbon-2

c) bond between carbon-1 and Br d) bond between carbon-2 and carbon-1

20. Which of the following statements is not correct for a nucleophile? [1]

a) Nucleophiles are not electron seeking. b) Nucleophiles attack low electron density

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sites.

c) Ammonia is a nucleophile. d) Nucleophile is a Lewis acid.

21. ________ are formed by the homolytic fission of C - C bond in ethane. [1]

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a) Methyl carbonium ions b) Methyl free radicals

c) Methyl carbanions d) Ethyl free radicals

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22. Ionic species are stabilized by the dispersal of charge. Which of the following carboxylate ion is the most stable? [1]

a) O

||
b) O

||
S
C H3 − C − O F − C H3 − C − O

c) d)
IN

||

C l − C H3 − C − O
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23. The bond that undergoes heterolytic cleavage most readily is: [1]

a) O - H b) C - C
K

c) C - H d) C - O
24. The CORRECT statement regarding electrophile is: [1]
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i. Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from a
nucleophile.
ii. Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from
another electrophile.
iii. Electrophiles are generally neutral species and can form a bond by accepting a pair of electrons from a
nucleophile.
iv. Electrophile can be either neutral or positively charged species and can form a bond by accepting a pair of
electrons from a nucleophile.

a) Option (iv) b) Option (ii)

c) Option (i) d) Option (iii)

25. Polarisation of σ-bond caused by the polarisation of adjacent σ-bond is termed as: [1]

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 a) Metamerism b) Hyperconjugation

c) Resonance effect d) Inductive effect

26. Assertion (A): Energy of resonance hybrid is equal to the average of energies of all canonical forms.
[1]
Reason (R): Resonance hybrid cannot be presented by a single structure.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

27. Assertion (A): Inductive effect is a permanent effect.
[1]
Reason (R): Inductive effect involve the complete transfer of electron.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

E
c) A is true but R is false. d) A is false but R is true.

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28. Assertion (A): Amit noted that chloroethane C-Cl is polarized in such a way that carbon 1 gains some positive [1]
charge chlorine gains a negative charge.

Reason (R): The fractional electronic charge on the 2 atoms in a polar covalent band is denoted by delta.

a) Both A and R are true and R is the correct

explanation of A. IT
b) Both A and R are true but R is not the
correct explanation of A.
ST
c) A is true but R is false. d) A is false but R is true.
29. Assertion (A): Neha noted that resonance provided by CH3NO2 be represented by the 2 lewis structures.
[1]

Reason (R): The energy of the actual structure of the molecule is higher than the conical structure.
IN

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
I

c) A is true but R is false. d) A is false but R is true.

KK

30. Assertion (A): Group of four students finds that there are two types of resonance or mesomeric effects i.e., M or [1]
R effect.

Reason (R): Aniline shows + R effect.

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a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

⊝
[1]
⊝

31. Assertion (A): C H is better nucleophile than N H .

3 2

Reason (R): Stronger base are better nucleophiles if the size of donor atoms are nearly same.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

32. Assertion (A): A free radical is paramagnetic species.
[1]
Reason (R): A free radical is formed in the homolytic fission of a covalent bond.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the

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 explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

33. Assertion (A): Cyclopentadienyl anion is much more stable than allyl anion.
[1]
Reason (R): Cyclopentadienyl anion is aromatic in character.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

34. Assertion (A): C-C bond between carbon-3 and hydrogen in CH3CH2CH2Br experiences the least inductive [1]
effect.

Reason (R): The magnitude of the inductive effect diminishes as the number of intervening bonds increases.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the

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explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

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[1]

35. Assertion (A): is more stable than .

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Reason (R): has more resonating structure than .
NS

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
II

c) A is true but R is false. d) A is false but R is true.

36. Assertion (A): In ethyl cation positively charged carbon atom has a completely filled p-orbital.
[1]
KK

Reason (R): Hyperconjugation is a permanent effect.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
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c) A is true but R is false. d) A is false but R is true.

37. Assertion (A): Electron deficient species that can accept lone pair of electrons known as an electrophile.
[1]
⊕

Reason (R): N H is an electrophile.

4

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

38. Assertion (A): Simple distillation can help in separating a mixture of propan-1-ol (boiling point 97°C) and [1]
propanone (boiling point 56°C).

Reason (R): Liquids with a difference of more than 20°C in their boiling points can be separated by simple
distillation.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the

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 explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

39. Assertion (A): Resonance occur in the conjugated system.
[1]
Reason (R): In resonance complete transfer of electron occur.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

40. Assertion (A): The resonance structure is hypothetical and individually represents any real molecules.
[1]
Reason (R): According to the resonance theory the actual structure of benzene cannot be adequately represented
by any of these structures.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the

E
explanation of A. correct explanation of A.

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c) A is true but R is false. d) A is false but R is true.
⊕ ⊕

41. Assertion (A): H is more stable than D .

[1]
3C − C H2 3C − C H2

⊕ ⊕

Reason (R): H 3C − C H2 is stabilised by hyperconjugation while D 3C − C H2 is stabilised by +I power.

a) Both A and R are true and R is the correct

explanation of A.
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b) Both A and R are true but R is not the
correct explanation of A.
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c) A is true but R is false. d) A is false but R is true.
42. In the resonance structures of CH2 = CH - CHO given below, indicate relative stability of these structures.
[1]
I IN
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a) III > I > II b) III>II>I

c) I > II> III d) II> III > I

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43. The addition of HCl to alkene proceeds in two steps. The first step is the attack of H+ ion to  the [1]
portion which can be shown as:

A.

B.

C.

D. All of these are possible

a) C b) D

c) B d) A
44. What is the correct order of decreasing stability of the following cations? [1]

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 ⊕

I. C H 3 − C H − C H3

II. C H 3 − C H − OC H3

III. C H 3 − C H − C H2 − OC H3

a) III > I > II b) II > I > III

c) I > II > III d) II > III > I

45. State True or False: [4]
(i) The displacement of electrons in a multiple bond in the presence of attacking regent is called [1]
electromeric effect.
(ii) The shape of carbocation is linear. [1]
(iii) The vital force theory about organic compounds was proposed by Berzelius. [1]

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(iv) An electrophilic reagent is electron deficient species. [1]
46. Fill in the blanks: [10]
(i) _______ is the process of electron displacement along the chain of carbon atoms due to the presence [1]

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of a polar covalent bond at one end of the chain.
(ii) ______ of a covalent bond gives free radicals. [1]
(iii) _______ is the phenomenon of movement of electrons from one atom to another in multi bonded [1]
atoms at the demand of attacking reagent.
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(iv) _______ reactions are those in which a small molecule is removed forming additional bonds between [1]
atoms.
NS

(v) _______ are negatively charged or neutral species, containing an atom having a lone pair of electrons. [1]
(vi) Free radicals, carbocation, carbanion, carbenes, are called ______. [1]
(vii) ________ carbocation has the least stability. [1]
II

(viii) _______ reactions involve replacement of an atom or group of atoms in the molecule by different [1]
atoms or group of atoms.
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(ix) Conjugation between electrons of single (H-C) bond with multiple bonds is called _______. [1]
(x) _______ are positively charged or neutral species which are deficient in electrons. [1]
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