Dikki Institute

16/1 Raja Singh Colony, Shahbad Markanda

TEST 11C FULL SYLLABUS LATEST PATTERN TEST

Class 11 - Chemistry
Time Allowed: 3 hours Maximum Marks: 70

General Instructions:

1. There are 33 questions in this question paper with internal choice.

2. SECTION A consists of 16 multiple-choice questions carrying 1 mark each.

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3. SECTION B consists of 5 very short answer questions carrying 2 marks each.

4. SECTION C consists of 7 short answer questions carrying 3 marks each.

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5. SECTION D consists of 2 case-based questions carrying 4 marks each.

6. SECTION E consists of 3 long answer questions carrying 5 marks each.

7. All questions are compulsory.

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8. The use of log tables and calculators is not allowed

Section A
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1. Molecular formula represents: [1]
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a) ratio of masses of various atoms present in a b) whole number ratio of different types of
compound atoms present in a molecule of a compound

c) average fractionall ratio of various atoms d) the exact number of different types of atoms
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present in a compound present in a molecule of a compound

2. In chromatography, the process of extraction of the adsorbed components from the adsorbent by increasing the [1]
polarity of the solvents is called ________.
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a) differential extraction b) elution

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c) partition d) adsorption
3. For an isolated system, ΔU = 0, what will be ΔS? [1]

a) ΔS > 0 b) ΔS will increase for some time and then

reduce

c) ΔS < 0 d) ΔS =0
4. Mendeleev’s left the gap under aluminum and a gap under silicon having atomic weights 68 and 72 respectively. [1]
These elements respectively are

a) Aluminium and silicon b) Eka-germanium and Eka-silicon

c) Eka-aluminium and Eka-silicon d) Eka-aluminium and Eka-germanium

5. The enthalpy of combustion of methane, graphite and dihydrogen at 298 K are, -890.3 kJ mol-1, -393.5 kJ mol-1 [1]

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 and -285.8 kJ mol-1 respectively. Enthalpy of formation of CH4 (g) will be

a) +74.8 kJ mol-1 b) +52.26 kJ mol-1

c) -74.8 kJ mol-1 d) -52.27 kJ mol-1

6. The de Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10 metres per second is [1]
approximately:

a) 10-33m b) 10-31m

c) 10-23m d) 10-43m

7. 6I
−
(aq) + 2M nO
−

4
(aq) + 4H2 O(I ) ⟶ 3I2 (s) + 2M nO(s) + 8OH
−
(aq) [1]
The above balanced ionic equation represents a redox reaction where one of the following takes place.

a) permanganate ion in basic solution oxidizes b) in basic solution oxidizes I- to

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−
M nO
4

water produce I2

c) permanganate (VII) ion in basic solution d) iodide ion in basic solution oxidizes

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reduces iodide ion to produce molecular permanganate ion
iodine
8. Glycine is a functional isomer of ________. [1]
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a) ethylamine b) nitromethane

c) nitroethane d) ethanamide
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9. The IUPAC name of CH 2 = C − CH3 is [1]
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CH3

a) 2-methylbutene b) 2-methylbut-2-ene

c) 2-methylprop-1-ene d) 1-methylpropene
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10. Change in hybridisation affects the carbon’s and the organic compound’s: [1]

a) bond strength b) bond enthalpy

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c) bond length d) electronegativity

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11. For the reaction at 298 K, 2A + B → C, ΔH = 400 kJ mol-1 and ΔS = 0.2 kJ K-1mol-1. At what temperature will [1]
the reaction become spontaneous considering ΔH and ΔS to be constant over the temperature range.

a) 3500 K b) 2000 K

c) 1500 K d) 2500 K
12. Which of the following compounds is not aromatic? [1]

a) b)

c) d)

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13. Assertion (A): Resonance occur in the conjugated system. [1]
Reason (R): In resonance complete transfer of electron occur.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

14. Assertion (A): 1-hexyne is converted to cis-1-hexene by Lindlar’s catalyst. [1]
Reason (R): 1-hexyne is converted to n-hexene by the reduction with hydrogen gas in the presence of Pd

Ni
.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

15. Assertion (A): Thomson's atomic model is known as the raisin pudding model. [1]

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Reason (R): The atom is visualized as a pudding of positive charge with electrons (raisins) embedded in it.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

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c) A is true but R is false. d) A is false but R is true.
16. Assertion (A): Law of conservation of mass hold good for nuclear reaction. [1]
Reason (R): Law states that mass can be neither created nor destroyed in a chemical reaction.
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a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.
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c) A is true but R is false. d) A is false but R is true.
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Section B
17. PCl5, PCl3 and Cl2 are at equilibrium at 500 K in a closed container and their concentrations are 0.8 × 10-3 mol [2]
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L-1, 1.2 × 10-3 mol L-1 and 1.2 × 10-3 mol L-1, respectively. Calculate the value of Kc for the reaction

PCI5(g) ⇌ PCl3(g) + Cl2 (g) will be

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18. Why is an organic compound fused with sodium in Lassaigne's test? [2]
19. Define solubility product [2]
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20. Explain the diamagnetic behaviour of F2 molecule on the basis of molecular orbital theory. [2]

OR
Explain the shape of BrF5.

21. Name a suitable technique of separation of the components from a mixture of calcium sulphate and camphor. [2]
Section C
22. Account for the following: [3]
a. Gabriel phthalimide synthesis is not preferred for preparing aromatic primary amines.
b. On reaction with benzene sulphonyl chloride, primary amine yields product soluble in alkali whereas
secondary amine yields product insoluble in alkali.
23. Answer: [3]
(a) Nickel atom can lose two electrons form Ni2+ ion. The atomic number of Ni is 28. From which orbital [1]
will nickel lose two electrons?

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 (b) Neutrons can be found in all atomic nuclei except in one case. Which is this atomic nucleus and what [1]
does it consist of?
(c) An electron beam on hitting a ZnS screen produces a scintillation on it. What do you conclude? [1]
24. Give reason for the following: [3]
i. Neither q nor w is a state function but q + w is a state function.
ii. A real crystal has more entropy than an ideal crystal.

25. i. Predict the maximum and minimum oxidation states for [3]

a. Cl
b. Ti
ii. The electrode reduction potentials of four metallic elements A, B, C, and D are respectively +0.79, - 0.74,
1.08 and -0.31 V. Arrange these in order of decreasing electropositivity character.
iii. Out of aluminium and silver vessel which one will be more suitable to store 1 M HCI solution and why?

E
EoAI3+ |A| = -1.66 V, Eo Ag+|Ag = + 0.80 V

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26. What are electrophiles and nucleophiles? Explain with examples. [3]
27. Justify the following statements. [3]
i. Reaction with negative Gibb's energy always has an equilibrium constant greater than 1.

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ii. Many thermodynamically feasible reactions do not occur under ordinary conditions.
iii. At low temperatures, enthalpy change dominates the ΔG expression and at high temperatures, it is the
ST
entropy that dominates the value of ΔG .
28. Point out the difference between ionic product and solubility product. [3]
Section D
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29. Read the text carefully and answer the questions: [4]
Adolf von Baeyer suggested that, since carbon prefers to have tetrahedral geometry with bond angles of

approximately 109o, ring sizes other than five and six may be too strained to exist. Baeyer based his hypothesis
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on the geometrical notion that a three-membered ring (cyclopropane) should be an equilateral triangle with bond
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angles to 60o, a four-membered ring (cyclobutane) should be a square with bond angles of 90o and so on.

According to Baeyer's analysis, cyclopropane, with a bond angle compression of 109o - 60o = 49o, should have a
large amount of angle strain and must, therefore, be highly reactive. Cyclohexane becomes puckered to release
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its strain. The angular deviation of cycloalkane is (-11o). Greater is the angular deviation more is the torsional
strain.

(a) Which of the following is the most reactive cycloalkane?

Cyclopropane, Cyclobutane, Cyclopentane, Cyclohexane
OR
If the angular deviation is higher then what would be the effect on the torsional strain?
(b) Out of Cyclopropane, Cyclobutane and Cyclopentane are the most strained cycloalkane?

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 (c) Write the tendency of Cyclopropane (I), Cyclobutane (II) and Cyclopentane (III) to form additional
compounds in descending order.
30. Read the text carefully and answer the questions: [4]
In 1830, Michael Faraday showed that if electricity is passed through a solution of an electrolyte, chemical
reactions occurred at the electrodes, which resulted in the liberation and deposition of matter at the electrodes. In
the mid-1850s Faraday began to study electrical discharge in partially evacuated tubes, known as cathode ray
discharge tubes. When sufficiently high voltage is applied across the electrodes, current starts flowing through a
stream of particles moving in the tube from the negative electrode to the positive electrode. These were called
cathode rays or cathode ray particles. J.J. Thomson measured the ratio of electrical charge (e) to the mass of the
electron (me) by using a cathode ray tube and applying electrical and magnetic fields perpendicular to each other

as well as to the path of electrons. Positively charged particle was characterised in 1919. Later, a need was felt
for the presence of electrically neutral particles as one of the constituents of the atom.

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(a) What is the value of charge to mass ratio (e/m) of electrons?
(b) How is it concluded that electrons are a universal constituent of all matter?
(c) Which fundamental property of an atom is not understood if we assume that an atom consists of a nucleus

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containing protons only and an extranuclear part containing an equal number of electrons?
OR
Calculate the total no. of electrons present in one mole of methane.
Section E
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31. Attempt any five of the following: [5]
(a) Draw the structure of SO 2−
. [1]
NS
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(b) Why are bonding molecular orbitals more stable than antibonding molecular orbitals? [1]
(c) Why are axial bonds in PCl5 are longer than the equatorial bonds? [1]
(d) HCl is a covalent compound but it ionises in solution. Explain. [1]
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(e) How many σ - and π- bonds are there in CH2 = CH-CH = CH2 ? [1]

(f) Given is the electron dot structure for carbon suboxide, C3O2. Write its structural formula. [1]
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(g) Write the significance of plus and minus sign in representing the orbitals. [1]
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32. Elements A, B, C and D have atomic numbers 12, 19, 29, and 36 respectively. On the basis of electronic [5]
configuration. Write to which group of the periodic table each element belongs.
OR
Define electron gain enthalpy. What is its unit ? Discuss the factors which influence the electron gain enthalpy.
33. Calcium carbonate reacts with aqueous HCI to give CaCI2 and CO2 according to the reaction, [5]

C aC o3 + 2HC I (aq) → C aC I2 (aq) + C O2 (g) + H2 O(I )

What mass of CaCO3 is required to react completely with 25 mL of 0.75 M HCI?

OR
A mixture of oxalic acid and formic acid is heated with concentrated H2SO4. The gas evolved is collected and on

treatment with KOH solution, the volume of solution decreases by 1/6th. Calculate the molar ratios of two acids in
the original mixture.

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