APEEJAY SCHOOL, BHUBANESWAR SET-A

HALF
Time: 3 hr
YEARLY EXAMINATION- 2023-24
Class- XII
General Instructions: - Subject: CHEMISTRY (043) MM: 70

There are 35 questions in this

SECTION Aconsists of 18 question paper with internal choice.
SECTION B
SECTION Cconsists
multiple-choice
of 7 very shot answer questions
carrying 1lmark each.
consists of 5short answer questions carrying 2 marks each.
SECTION Dconsists of 2 case-
based
questions carrying 3 marks each.
SECTION Econsists of 3 long answer questions carrying 45 marks each.
questions carrying marks each.
1.
The molarity of 900 g of Section-A
as0 M water is [1]
b)Cannot be
2.
calculated c) 55.55 M d) 5 M
Which will form maximum boiling
a)C;HsOH + H,0 b)C%H,azeotrope?
+ CoH;CH; c) HNO3 + H0
[1]
d) None of these
3.
Greater the value of KH. lower will be the
a)Pressure b) Solubility c) Concentration [1]
d) Temperature
4. For the reduction of silver ions with
copper metal the standard cell potential was found to be
25°C. The value of standard Gibbs energy, AG° +0.46V at J
a) -44.5 kJ b) -98.0kJ c) -88.78 kJwill be (F =96500C mol')
d) -81 kJ
5. The standard electrode potential for the half
cell reactions are
Zn+2e ’ Zn.E' =-0.76V [1]
Fe+2e ’ Fe. E' = -0,44V
The e.m.f. of the cell reaction Fe* + Zn ’ Zn + Fe is
a) + 0.32 V b) -0.32 V c) +1.20 V ) -1.20 V
6. Calculate the emf of the cell at 298K
Sn(s) |Sn"(0.050M) | H(0.020M) | HY(g) (l bar) | Pt(s) [ given E Sn [1]
a) 0.0654V b) 0.101 V c) 0.18 V dj0.0781V /Sn-0.14V, E'HH=01
7. The rate of the first-order reaction is 0.69 x 10 mol
Lmin and the initial concentration is 0.2mol
L'the half-life period is: [1]
a) 1200 s b600 s c) 0.33 s d) 1 s
8 If the reaction 2 A+3D ’ product is first order in Aand
have the form: rate = second order in D, then the rate law will [1]
a k[AJ|Dj b) k [A] [D]
c) k[A]2(Dj d) k[A} D]
9. Chloroform is stored in closed dark coloured bottles completely filled because it:
a)gets slowly oxidized by air in the presence of light and form a poisonous gas. [1]
b) can change its colour in the presence of light and get spoilt by the
action of light.
JOforms an extremely poisonous gas in thepresence of light.
d) gets slowly oxidized by air in the presence of light.
 lemm

5.Cle
10. What is A in the following reaction?

(H-C(H

CHH--CHC1 CHCH-(H

11. Which of the following reactions will yield phenol? [1]

i.

(0 NaNO,/HC!
(u) HOWarming)

(u NaOH. Heatg!

NaQH {ag..235k/ lat:

{L) HC

a)i, ii, iv c) i, i, ii d) i, iü, iv

alcohol by aqueous NaOH is classified as

12. The conversion of an alkyl halide into
a)a dehydrohalogenation reaction
b) asubstitution reaction
c) an addition reaction
adehydration reaction
13. Give IUPAC names of the following
compound:

C C1
w0CiH

dimethylcyclohexane b)6 - Ethoxy -6.6 - dimethylcvclohexane

a)l - Ethoxy -2.2 - dimethylcyclohexane d) 1 -Ethoxy - 6. 6 - dimethylcyclohexane
2- Ethoxy - 1. I -
 UCtiOn S using Zinc
13, d)Dow reduction reductionamalgam and conc.
olff Kishner
Clemmensen
a)Zn - reduction of a
Hg with HCI ketone is
carried out in the
HCl is called

c) LiAH4 b) H2
d)
and Pt aspresence
catalyst
of which of the following?
16.
Phenol on reduction with H, in Glycol with KOH
the presence of Ni
a)Benzene b)toluene c)eyclohexane catalyst gives
17.
Assertion (A): Increasing pressure on water d)Cyclohexanol [1]
Reason (R): The density decreases its
of water is at 273 K. freezing point.
a)Both Aand R are true and Rmaximum
is the correct
b)Both Aand R are true but R is
not the
explanation of A.
c)A is true but R is false. correct explanation of A.
d) A is false but R is true.
18. Assertion (A): Benzyl chloride ismore reactive than p-chlorotoluene towards aqueous NaOH. (1]
Reason (R): The C-Cl bond in benzyl chloride is more polar than C -Cl bond in p-chlorotoluene.
a)BothA and R are true and R is the correct explanation of A.
b)Both A andR are true but R is not the correct explanation of A.
c)A is true butR is false.
d) A is false but R is true
Section-B calculate 2]
92 g of Nat ions per kg of water,
 19, f the density of some lake Section-B
water is 1.25 g mL and contains 92 g of Na'
the molarity of Na ions in the lake. 10ns per kg of water., calculate 21
OR
The treatment of alkyl chlorides with aqueous
KOHleads to the
presence of alcoholic KOH, alkenes are major products. Explain. formation of alcohols but in the
20. What happens when
2)
i.A pressure greater than osmotic pressure is applied on the solution side separated from solvent by a
semipermeable membrane?
ii.acetone is added to pure ethanol?
21. Components of a binary mixture of two liquids Aand Bwere being separated by distillation. Afer some (2]
time separation of components stopped and composition of vapour phase became same as that of liquid
phase.Both the components started coming in the distillate. Explain why this happened.

solution at 298 K is 1500 ohm. What is

22. The resistance ofaconductivity cell containing 0.001 MKCl
at 298 K is 0.146 x 10 S cml?
the cell constant if conductivity of 0.001 M KCI solution
[21
23. For a reaction A + H0 ’ B
Rate « [A]
What is its
reaction
() molecularity (ii) Order of
conversion? But-1-ene to but-2-ene
24. How will you bring the 21

How the following conversions can be carried out?

25.
i.Butan-1-ol to Butan-2 ol
ii.Aniline to phenylisocyanide Page 3 of5
 29. 23. 21. 0.

Determine Wnte silver

unknownA Onemolarity
the
Calculate
during [Given, voltage
recharging.
involved antireeze n
the nitrate half-cell
(A
the
e chemistry concentration.
thE'znZn-0.763V of
solution?
theof
solution.
1.48V in molality
solution
order a
of measured isvoltaic
of of is
reaction recharging The cell prepared
the
other is solution.
and constructed
for
and from
the half-cell
this
also leadE'Agt/Ag= If
222.6
cell. the
determine storage Use from density
consists Section-Cg
+0.80VJ. of
this silver a ethylene
battery, of of
the information the
a
zinc wire
units solutionglvcol
n highlighting electrodedipped
f of
rate to (CH.O)is
calculate in L.072
constant. in
silver
at all 1.0 gand
a the M mL.then
the nitrate 200
materials concentration solution
g
soluion owatei:
what
ot
that Zn(NO3)2. ol shall
are 09 Y
be
 (A}
30. The
following’SOg)
SOCl2g
data were given for thermal
+Cl2g) decomposition of SO;Clh at a constant volume :
Exp. Time's Total p'atm
0.5
2 100
0.6
AG
Calculate the rate of the reaction when total pressure is
0.65 atm.

31. i. Calculate AG Section-D U

for the reaction
Zns) + Cu(a0)
Cu+,
Zna0) Cus)
t+
(aq)
Given: E° for Zn/Zn Vand E° for Cu*/Cu =+0.34 VR=8314 JK1
F=96500 Cmol'. =-7.6
mol
ii. Given two
advantages of fuel cells.
OR
seady Current of 2 amperes was passed through two electrolytic cells Xand Yconnected in series
Containing electrolytes FeSO4 and ZnSO4 until 2.8 gof Fe deposited at the cathode of cell X. How long
did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y.
(Molar mass : Fe= 56 g mol' Zn =65.3 g mol', IF =96500C mol')
b. In the plotof molar conductivity (Am) vs square root of concentration(c), following curves aYe
obtained for two electrolvtes Aand B:

Answer the following:

What happens on extrapolation of (Am ) to concentration approaching zerofor electrolvtes A and B?
i.
electrolvtes A and B.
ii. Predict the nature of
Page 4 of 5
C) m
make
the
fo
Ihe decomposition ofA intoproduct has value of kas 4.5 x 10's atlo'C and energy of activation
60 kJ mol!.At what temperature would kbe 1.5 x 10s?
OR
(i.The rate constant for a first order reaction is 60s!. How much time will it take to reduce theinitial
concentration of the reactant to its 102h yalue?
ii. Write two factors that affect the rate of a chemical reaction.
ii. Write two conditions for the collisions to be effective collisions.

33. (a) Draw the structure of the following :

(i) p-Methylbenzaldehyde (ii) 4-Methylpent-3-en-2-one
(b)Give chemical tests to distinguish between the following pairs of compounds :
(i) Benzoic acid and Ethvl benzoate. (ii) Benzaldehyde and Acetophenone.
(iii) Phenol and Benzoic acid.
OR
Cannizzaro reaction.
(a) Write the chemical equation for the reaction involved in
ethanal.
(b)Draw the structure of the acetal of
of CICH COOH?
(c) Why pkaof F-CH-COOH is lower than that
reaction:
(d)Write the product in the following
()DIBAL-H
CH,-CH = CH-CH,CN (i) H,0
(e) How can you distinguish between
propanal and propanone?

Section-E pickle.Wilted (4]

concentrated saltsolution loses water via osmosis and shrivel into
34. A raw mango placed in water.A carrot that has become limp because of water loss into the
flowers revive when placed in fresh firm once again. Water willmove
making it
into its cells through
atmosphere can be placed into the water mass/yolume) salt. blood cells sweil due to
 pha
ofF-CH-COOH
(d) Write the product in the is lower than that of
following reaction: CICH) COOH? a?)
(
CH,-CH =CH-CH,CN (a DIBAL-H,
(e) How can you (i)HO
distinguish between propanal and propanone?
34. A raw mango placed in Section-E
concentrated
flowers revive when placed salt solution loses water via osmosis and
shrivel into
has become limp because of waterpickle. Wilted 4J
in fresh water. A carrot that
atmosphere can be placed into the water making it firm once again. Water will move into its loss into the
osmosis. When placed in water containing less than 0.9% (mass/volume) salt. cells through
flow of water in them by osmosis. blood cells swell due to
(i)People taking a lot of salt or salty food suffer from
this? puffiness or edema. What is the reason behind
(i1)The preservation of meat by salting and of fruits by adding sugar
How? protects against bacterial action.
(111) Whythe direction of osmosis gets reversed ifa pressure larger than the osmoticpressure is applied
to the solution side? Write its one application.
(iv)What care is generally taken during intravenous injections and why?

35. The substitution reaction of alkyl halides occurs in SN' and SN mechanism, whatever mechanism alkyl [4]
halide follow for substitution reaction to occur, the polarity of the carbon halogen bond is responsible
for the substitution reaction.
reactions steric factor
The rate of SN' reactions are governed by stability of carbocation whereas for SN
an inverted product
is adeciding factor. If the starting material is a chiral compound, we may end up with
or racemic miXture
depending upon the type of mechanism followed by alkyl halide. which willfollow SNI mechanism?
1. Among 1-bromo propne and 2-methyl-2-bromo propane,occur on reaction with aq. alkali:
ii. In which of the following inversion of configuration will
1-bromopropane or 2-methyl-2-bromo propane?
iii. What is the role of polar protic solvent in SN reaction?atom.
iv. Write example of an alkyl halide having chiral carbon

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