KEYSTONE UNIVERSE OF EDUCATION

12TH CHEM GUJCET PAPER-5

Class 12 - Chemistry
Time Allowed: 1 hour Maximum Marks: 40

41
. The depression in freezing point for 1M urea, 1 M glucose and 1 M NaCl are in the ratio of [1]

a) 1:1:2 b) 3:2:2

c) 1:1:1 d) 1:2:3
[1]
42 Which of the following colligative property is used to find the molar mass of proteins?
a) Osmotic pressure b) RLVP

c) Elevation in boiling point d) Depression in freezing point

43
. 0.1 M solution of urea, at a given temperature, is isotonic with: [1]

a) 0.1 M glucose solution b) 0.1 M BaCl2 solution

c) 0.1 M NaCl solution d) 0.02 M KCl solution

44
. Which among the following form nearly ideal solutions? [1]

a) Chloroform and benzene b) Benzene and Toluene

c) Alcohol and water d) Acetone and aniline

45
. Which of the following is correct for spontaneity of a cell? [1]

a) ΔG = +ve, Eo = -ve b) Δ G = +ve, Eo = 0

c) ΔG = -ve, Eo = +ve d) Δ G = -ve, Eo = 0

46
. Solutions of two electrolytes X and Y are diluted. Molar conductivity of X increases 25 times whereas that of Y [1]
increases 1.5 times. Which one is a stronger electrolyte?

a) X b) None of the above

c) Both X and Y d) Y
47
. Consider the following standard electrode potential values: [1]
3+ − 2+ ∘
Fe (aq)
+ e → Fe (aq)
E = +0.77 V

− + − 2+ ∘
MnO + 8H + 5e → Mn + 4H2 O(l) E = +1.51 V
4 (aq) (aq)

What is the cell potential for the redox reaction?

a) -2.28 V b) +2.28 V

c) +0.74 V d) -0.74 V
48
. What is the molar conductance at infinite dilution for sodium chloride if the molar conductance at infinite [1]

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 dilution of Na+ and Cl- ions are 51.12 × 10-4 S cm2/mol and 73.54 × 10-4 Scm2/mol respectively?

a) 198.20 S cm2/mol b) 175.78 S cm2/mol

c) 22.42 S cm2/mol d) 124.66 S cm2/mol

49
. In the presence of a catalyst, the activation energy of a reaction is lowered by 2 kcal at 27°C. The rate of reaction [1]
will increase by

a) 20 times b) 28 times

c) 14 times d) 2 times
50. In a chemical reaction X → Y, it is found that the rate of reaction doubles when the concentration of X is [1]
increased four times. The order of the reaction with respect to X is

a) 1

2
b) 2

c) 1 d) 0

51. The reaction 2A → B is first order in A with a rate constant of 2.8 determining 10–2s–1. How long will it take [1]
for A to decrease from 0.88 M to 0.14 M?

a) 76 s b) 44 s

c) 66 s d) 50 s
52. For the reaction A → products, at [A] = 0.4 M , t1/2 = 24 s and at [A] = 0.2 M , t1/2 = 12 s . The unit [1]
for the rate constant is

a) S-2 b) mol L-1s-1

c) L2/mol2/s d) S–1

53. Lanthanoid contraction is a caused due to: [1]

a) Poor shielding effect of 4f electron b) Effective nuclear charge

c) Size of 4f orbitals d) Atomic number

54. KMnO4 acts as an oxidising agent in alkaline medium. When alkaline KMnO4 is treated with KI, iodide ion is [1]
oxidised to:

a) IO −
3
b) IO-

c) I2 d) IO
−
4

55. Haemoglobin and chlorophyll contain: [1]

a) Fe and Mg b) Fe and Mn

c) Fe and Co d) Mg and Fe
56. Out of the following transition elements, the maximum number of oxidation states are shown by [1]

a) Mn (Z = 25) b) Sc (Z = 21)

c) Cr (Z = 24) d) Fe (Z = 26)
57. The formula of the coordination compound Tetraammineaquachloridocobalt(III) chloride is [1]

a) [Co(NH3)4(H2O)Cl]CI2 b) [Co(NH3)2(H2O)CI]CI2

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 c) [Co(NH3)4(H2O)Cl]Cl3 d) [Co(NH3)4(H2O)Cl]CI

58. Which type of isomerism is exhibited by the given complex? [1]

[Pt(NH3)2Cl2]

a) Coordination isomerism b) Geometrical isomerism

c) Ionisation isomerism d) Optical isomerism

59. Which of the following is a polydentate ligand? [1]

a) C 2 O4
2−
b) EDTA4-

c) NH3 d) H2N - CH2 - CH2 - NH2

60. Lithium tetrahydridoaluminate is represented as: [1]

a) Al2[LiH4]3 b) Li[AlH4]2

c) Al[ LiH4] d) Lithium tetrahydridoaluminate is

represented as: Li[AlH4]

61. Inversion of configuration occurs in [1]

a) SN1 as well as SN2 reaction b) SN1 reaction

c) Neither SN2 nor SN1 reaction d) SN2 reaction

62. Benzylic halides contains: [1]

a) sp3-hybridized carbon atom, next to an b) sp2-hybridized carbon atom next to an

aromatic ring bonded to a halogen. aromatic ring.

c) sp3-hybridized carbon atom next to carbon- d) a halogen atom bonded to an alkyl group.
carbon double bond.
63. When a haloalkane with β – hydrogen atom is heated with alcoholic solution of potassium hydroxide then: [1]

a) All of these b) elimination of halogen atom from α –

carbon

c) elimination of hydrogen atom from β– d) alkene is formed as a product

carbon
64. Major product formed in the following reaction [1]
CH3

CH3 − C − Br + NaOCH3 →
|

CH3

a) CH3

|
b) CH3

CH3 − C = CH2 CH3 − C − ONa

|

CH3

c) CH3

|
CH3

|
d) CH3

CH3 − C − O − C − CH3 CH3 − C − OCH3

| | |

CH3 CH3 CH3

65. Alcoholic compounds react: [1]

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 a) only as nucleophiles. b) both as nucleophiles and electrophiles.

c) only as electrophiles. d) None of these

66. The compounds that is most difficult to protonate is: [1]

a) b)

c) d)

67. In the reaction [1]

a) Phenols are acidic in nature. b) They can donate a proton to a stronger base

c) Cleavage of O - H bond d) All of these

68. Aspirin is obtained by the acetylation of which of the following compounds? [1]

a) Acetyl salicylic acid b) Salicylaldehyde

c) Salicylic acid d) Phenol

69. One mole of a symmetrical alkane on ozonolysis gives two moles of an aldehyde having a molecular mass of [1]
44u. The alkene is:

a) 1 – butene b) 2 – butene

c) Propene d) Ethene
70. Give the products of the reaction [1]
+ 2+
H3 O ,H g

P hC ≡ C M e −−−−−−−→?

a) PhCH2CH2CHO b) PhCOCH2CH3

c) PhCOCOMe d) PhCH2COCH3

71. For making a distinction between 2 – pentanone and 3 – pentanone the reagent to be employed is: [1]

a) K2Cr2O7 / H2SO4 b) SeO2

c) Zn – Hg/HCl d) Iodine/NaOH
72. Which of the following does not give Cannizaro reaction? [1]

a) (CH3)3 C - CHO b) (CH3)2 CH - CHO

c) HCHO d)

73. Which of the following reagents would not be a good choice for reducing an aryl nitro compound to an amine? [1]

a) Fe and HCl b) LiAlH4 in ether

c) Sn and HCl d) H2 (excess)/Pt

74. Reaction of nitrous acid with aliphatic primary amine in cold acidic solution gives: [1]

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 a) A diazonium salt b) A nitrite

c) A dye d) An alcohol
75. Hoffmann Bromamide Degradation reaction is given by: [1]

a) b)

c) CH3 - C ≡ N d) O

||

C H3 − C H2 − C − N H2

76. Among the following, which has the highest value of pKb? [1]

a) b)

c) d)

77. In disaccharides, if the reducing groups of monosaccharides i.e. aldehydic or ketonic groups are bonded, these [1]
are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?

a) b)

c) d)

78. Maltose is made of: [1]

a) ∝ -D-glucose b) ∝ - D-glucose and β - D -glucose

c) Glucose and fructose d) D-fructose

79. The vitamins are generally stored in the body in the [1]

a) abdomen b) muscles

c) liver and adipose tissue d) pancreas

80. In the ring structure of glucose, the anomeric carbon is: [1]

a) C-4 b) C-3

c) C-1 d) C-2

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