MATRIX ACADEMY

MHT-CET-XII - New Syllabus (MH) 2022-23

Time : 60 Min Chem : Groupwise Paper Marks : 50

01) Choose the correct option: During an adiabatic 1

process SO2  O2  SO3  y kcal
2
A) gas is isothermally expanded
Find out the heat of formation of SO2 .
B) pressure is maintained constant
C) there is perfect heat insulation A) 2x / y
D) the system changes heat with surroundings B) x  y
C) 2x  y
02) Conversion of oxygen to ozone represented by
D) 2x  y
the equation 3O2  2O3 is an endothermic
reaction. Enthalpy change H accompanying the
08) When a current of 3 A is passed through an
reaction
aqueous solution of a palladium salt, the mass of
A) is positive.
Pd metal deposited in 1 hour is 2.98 g. If the
B) is negative.
C) is zero. metal's atomic mass is 106.4, what is the the
D) depends on temperature. valency of palladium?
A) 4
03) The logarithm of the equilibrium constant of B) 5
the cell reaction corresponding to the cell C) 2
D) 3
Xs  |X2aq  ||Y aq  |Ys  with standard cell
potential E0cell  1.2 V is ..... 09) For an elementary reaction, 2 A + B  C +D the
A) 21.5 molecularity is
B) 12.5 A) three.
C) 40.6 B) two.
D) 47.2 C) one.
D) zero.
04) The rate of the reaction
10) Which of the following curves represents a first
CCl3CHO  NO   CHCl3  NO  CO is given order reaction?
by Rate  K[CCl3CHO][NO] . If concentration is
expressed in moles/litre, the unit of K is
A) litre mole1 s 1
B) litre2 mole2 s 1
C) mole litre1 s 1 A)
1
D) s

05) 2C  O2  2CO; H   220 kJ , which of the

following statement is correct for this reaction?
A) Reaction needs no initiation.
B) Heat of combustion of carbon is 110 kJ. B)
C) Reaction is exothermic.
D) All of these are correct.

06) Partial pressure of solvent in solution of

non-volatile solute is given by
A) p1  x1p C)
B) p1  xp
C) p  x1p1
D) p  x 2p1

3 D)
07) S  O2  SO3  2x kcal
2
11) The reason for almost doubling the rate of
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reaction on increasing the temperature of the 19) A solution is obtained by mixing 300 g of a
reaction system by 10 C is 25% solution and 400 g of a 40% solution by mass.
A) activation energy decreases. Estimate the mass percentage of solute in the
B) the fraction of the molecule having energy equal resulting solution.
to threshold energy or more increases. A) 33.57
C) collision frequency increases. B) 19.24
D) the value of threshold energy increases. C) 87.23
D) 66.43
12) Which one has pH 12?
A) 1 N Ca (OH2) ml 20) The temperature at which the vapour pressure
B) 1 N NaOH ml of a liquid becomes equal to the atmospheric
pressure is .......
C) 1 N KOH ml A) freezing point
D) 0.01 M KOH B) boiling point
C) 1000 C
13) The vapour pressure lowering caused by the D) absolute zero
addition of 100 g of sucrose (molecular mass =342)
to 1000 g of water, if the vapour pressure of pure 21) The standard emf of the Daniel cell is 1.10 V.
water at 25o C is 23.8 mm Hg The maximum electrical work obtained from the
A) 0.12 mm Hg Dabiel cell is .......
B) 0.125 mm Hg A) 212.3 kJ
C) 1.15 mm Hg B) 175.4 kJ
D) 1.25 mm Hg C) 53 kJ
D) 106.1 kJ
14) The most important buffer in the blood
consists of 22) The heat evolved during the combination of 24
A) HCl and HCO3 g C and 128 g S following the change is
C  S2  CS2 ; H  22.0 kcal
B) H2CO3 and Cl
A) 11 kcal
C) H2CO3 and HCO3 B) 22 kcal
D) HCl and Cl C) 32 kcal
D) 44 kcal
15) pH of 0.005 M H2SO4 solution will be
23) Identify which of the following is not a
A) 0.005 characteristic of the crystalline solids.
B) 0.01 A) They have a regular geometry
C) 1 B) They have sharp melting points
D) 2 C) They are isotropic
D) They undergo a clean cleavage
16) In the crystals of which of the following ionic
compounds would you expect maximum distance 24) In a hydrogen - oxygen fuel cell, combustion of
between centers of cations and anions? hydrogen occurs to
A) LiI A) produce high purity water.
B) CsI B) create potential difference between the two
C) CsF electrodes.
D) LiF C) generate heat.
D) remove adsorbed oxygen from electrode
17) At infinite dilution, the percent ionization for surfaces.
both strong and weak electrolyte is .......
A) 20% 25) In the complete combustion of butanol
B) 100% C4H9OH(l) , if H is enthalpy of combustion and
C) 1%
D) 50% U is the heat of combustion at constant volume,
then
A) H  U
18) The standard heats of formation in kcal mol1
B) H  U
of NO2 (g) and N2O4 are 8.0 and 2.0 respectively. C) H  U
The heat of dimerization of NO2 in kcal is D) H, U relation cannot be predicted.
2NO2 (g)  N2O4 (g)
A) - 14.0 26) The pH of 108 molar aqueous solution of HCl
B) - 12.0 is
C) - 6.0 A) 8
D) 10.0 B) 8
C) 6 > 7 (Between 6 and 7)

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D) 7 > 8 (Between 7 and 8) B) x is more stable than y.

C) Both x and y are unstable.
27) The first order rate constant for the D) x and y are endothermic compounds.
decomposition of N2O5 is 6.2  104 s 1 . The half
35) Identify wrong statements.
life period for this decomposition in seconds is
A) Greater the oxidation potential of a metal, more
A) 111.7
active is the metal.
B) 160.9
C) 223.4 B) The electrode potential of pt, H21 atm |H (1 M)
D) 1117.7 is taken as zero
C) It is used as a secondary reference electrode.
28) The two third of a first order reaction having D) The electrode potential is called standard
k  5.48  1014 s 1 is electrode potential if the electrode is set up in 1 M
A) 2.01  1011 s solution at 298 K.

B) 2.01  1013 s 36) Entropy is maximum in case of

C) 16.04  10 11
s A) ice.
13 B) water at 4o C .
D) 8.08  10 s
C) water at 0o C .
29) Which is a Lewis base? D) steam.
A) NH3
B) AlH3 37) n-type semiconductor is formed when trace
C) LiAlH4 amount of impurity is added to silicon. What
must be the number of electrons in the impurity
D) B2H6 atom?
A) 3
30) The activation energy of a reaction is zero. The B) 5
rate constant of this reaction C) 2
A) is independent of temperature. D) 1
B) decreases with decrease of temperature.
C) decreases with an increase of temperature.
38) Vapour pressure of a solution of 5 g of
D) increases with increase of temperature.
non-electrolyte in 100 g of water at a particular
31) For cubic coordination, the value of radius temperature is 2985 N / m2 . The vapour pressure
ratio is
of pure water is 3000 N / m2 . The molecular
A) 0.414  0.732
B) 0.000  0.225 weight of the solute is
A) 380
C) 0.225  0.414
B) 180
D) 0.732  1.000 C) 120
D) 60
32) Solid NaCl is a bad conductor of electricity
because .... 39) Some salts although containing two different
A) it is a non-polar compound metallic elements give test for only one of them in
B) it does not contain any ions solution. Such salts are
C) the ions of Na  and Cl are not free to move A) basic salts.
D) it does not contain mobile electrons B) complex salts.
C) normal salts.
33) Identify true statement for solution of D) double salts.
0.020 M H2SO4 .
A) 2 litre of the solution contains 0.20 mole of 40) KMnO4 acts as an oxidizing agent in the
SO24 neutral medium and gets reduced to MnO2 . The
B) 2 litre of the solution contains 0.080 mole of equivalent weight of KMnO4 in neutral medium
H3O A) mol. wt/7
C) 1 litre of the solution contains 0.04 mole of B) mol. wt/4
C) mol. wt/3
SO24 D) mol. wt/2
D) 1 litre of the solution contains 0.020 mole of
H3O 41) Tetragonal crystal system has the following
unit cell dimensions
34) Enthalpy of formation of two compounds x and A) a  b  c and     90o ,   120o
y are - 84 kJ and - 156 kJ respectively. Which of B) a  b  c and       90o
the following statements is correct?
A) x is less stable than y. C) a  b  c and       90o

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D) a  b  c and       90o 49) Molecularity of reaction of inversion of sugar is

A) 0
B) 1
42) In dry cell the reaction which takes place at the
C) 2
zinc anode is
D) 3
A) Mn(s)  Mn  e  1.5 V
B) Mn2  2e  Mn(s) 50) Aqueous solution of HCl has the pH = 4. Its
molarity would be
C) Zn(s)  Zn2  2e
A) 0.0001 M
D) Zn2  2e  Zn(s) B) 0.4 M
C) 4 M
43) The osmotic pressure of a 5% solution of cane D) 10 M
sugar at 150o C is
(mol. wt. of cane sugar = 342)
A) 2.45 atm
B) 3.4 atm
C) 4 atm
D) 5.07 atm

44) Estimate how many number of atoms are there

in a cube based unit cell having one atom on each
corner and two atoms on each body diagonal of
cube.
A) 4
B) 6
C) 8
D) 9

45) Expression representing the cell potential

(Ecell ) is
A) Eleft - Eright
B) Ecathode - Eanode
C) Eanode - Ecathode
D) Ecathode + Eanode

46) On passing H2S gas through a solution of

Cu and Zn2 ions, CuS is precipitated first
because
A) solubility product of CuS is greater than the
solubility product of ZnS.
B) solubility product of CuS is lower than the
solubility product of ZnS.
C) solubility product of CuS is equal to the
solubility product of ZnS.
D) solubility product of CuS is equal to the ionic
product of ZnS.

47) It the distance between Na  and Cl  ions in

sodium chloride crystal is X pm, the length of the
edge of the unit cell is
A) X/2 pm
B) 2X pm
C) X/4 pm
D) 4X pm

48) Identify a first order reaction.

Pt
A) 2H2O2aq  
 2H2O  O2 g 
B) 2HI  H2  I2
C) 2NO2  2NO  O2
D) 2NO  O2  2NO2

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