MATRIX SCIENCE ACADEMY

Chemistry MHT CET L2 2022-23

Time : 60 Min Chem : Groupwise Paper Marks : 50
Hints and Solutions

01) Ans: D) both (a) and (b) therefore, it is paramagnetic in nature.

Sol: Carbinol is CH3OH. Hence, ethanol
CH3  CH2  OH is called methyl carbinol

02) Ans: D)  7
Sol: Since the solution is acidic, pH < 7. This is 2
For the complex ion Ni  CN4  , In the complex
because [H ] from H2O [107 ] cannot be
2
neglected in comparison to 1012 M. ion Ni  CN4  , there are four CN ligands
which are strong field ligands.
03) Ans: A) C2O24 Ni is in + 2 oxidation state.
Sol: C2O24 Ni28  4s2 3d8  Ni2  3d8 .
The hybridisation involved is dsp3 and the
04) Ans: A) Ammoniacal silver nitrate complex ion is square planar with no unpaired
electrons therefore it is diamagnetic in nature.
05) Ans: A) neutral Figure
06) Ans: D) one secondary and two primary OH 12) Ans: C) CsOH
groups. Sol: C5OH is strong base undergoes complete
CH2  OH
ionization.
|
Sol: C H  OH
| 13) Ans: A) Current
CH2  OH Sol: Current has no effect the degree of ionization.
i.e. one secondary and two primary alcoholic
14) Ans: C) C2H5OH
groups.
Sol: C2H5OH
07) Ans: B) salicylic acid.
15) Ans: D) anomeric carbon
2
 c
08) Ans: C) K a  16) Ans: B) 1.0 m
1 
Sol: This is the mathematical form of Ostwald's [salt]
Sol: pOH  pKa  log
dilution law. [Acid]
[Salt] [salt]
09) Ans: B) acetic acid. 5.5  4.5  log  log  5.5  4.5  1
K Cr O 0.1 0.1
Sol: CH3CH2OH 
2 2 7
 CH3COOH
[salt]
i.e.  antilog 1  10  [salt]  1
0.1
10) Ans: B) B2H6 and alkaline H2O2
Sol: Hydroboration oxidation i.e. industrial 17) Ans: C) primary alcohol.
preparation of alcohol is as Sol:
1 Dry
3CH3CH  CH2  B2H6   (CH3CH2CH3 )3 B
2 ether
HO
(CH3CH2CH3 )3 B 
2 2
 3CH3CH2CH2  OH

11) Ans: B) 2,0

Sol: In the complex ion NiCl4 
2
, the oxidation 18) Ans: C) 4
state of Ni is + 2.
19) Ans: B) amminepentachloroplatinate (IV) ion
Ni28  4s2 3d8  Ni2  3d8
The hybridisation involved is sp3 and the complex 20) Ans: A) Water
ion is tetrahedral. It has two unpaired electrons,

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Sol: H2O  H  OH 34) Ans: D) K4 Ni  CN2 (Ox)2 

Acid
[Acid because of donation of proton] Sol: K4 Ni  CN2 (Ox)2  by IUPAC rule.
H2O H  H3O
Base
35) Ans: B) glucosidic linkage
[Basic because of gaining of proton]
36) Ans: C) sp3
21) Ans: C) sp3d2
Sol: sp3
Sol: [CoF6 ]3 is an outer complex containing
sp3d2 hybridisation. 37) Ans: D) 4  105
Sol: c = 0.1,   0.02
22) Ans: D) CH3CHOHCH3
Kb  2.c  0.1  4  104  4  105
Sol: CH3CHOHCH3


38) Ans: B) 8  103
23) Ans: B) H2SO4 , HSO4
Sol: HgSO4 of Ksp  S2  S  Ksp

Sol: Here, H2SO4 H  HSO4
i.e. S  6.4  105  8  103 m/l
24) Ans: A) dyes.
Sol: 
39) Ans: B)  Ag  CN2 
Sol: EAN rule states that for a stable complex the
EAN - atomic number of noble gas. If not so, the
complex does not follow EAN rule. The EAN values
for the given four complex ions are as follows.
4
(a) Fe  CN6  : Fe26 ,Fe2  24 electrons, 6CN
25) Ans: A) triammine diaquachloro cobalt (III)
chloride. ligands contributing 6  2  12 electrons
Sol: From IUPAC rule.  EAN = 24 + 12 = 36 (At. No. of Kr).

(b)  Ag  CN2  : Ag 47 , Ag   46 electrons. 2CN
26) Ans: B) basic   a mino acid
Sol: Out of two lone pairs of electrons on two ligands contributing 2  2  4 electrons
nitrogen atoms, one is involved in Resonance and  EAN = 46 + 4 = 50 (Not At. No. of any noble gas).
the other is available for protonation therefore  Does not follow EAN rule
Histidine is a basic   a mino acid. 3
(c) Co  NH3 6  : Co27 ,Co3  24 electrons 6NH3

27) Ans: B) 6.3  103 ligands contributing 6  2  12 electrons

 EAN = 24 + 12 36 (At. No. of Kr
Sol: Here, Ksp  4s3 2
(d) ). PtCl6  : Pt78 ,Pt4  74 electrons. 6Cl
Ksp 6
1.0  10
S  3 3  S  6.3  103 ligands contributing 6  2  12 electrons.
4 4  EAN = 74 + 12 = 86 (At. No. of Rn).
28) Ans: D) 13 40) Ans: B) Secondary alcohol
Sol: [OH ]  101M , so pOH  1
3
We know, pH  pOH  14  p H  1 4 1 1 3 41) Ans: C) CO  H2O6 
3 3
29) Ans: D) quinol Sol: Fe  CN6  and Co  NH3 6  are low-spin

30) Ans: B) cellulose complexes involving d2sp3 hybridisation, while

3

31) Ans: D) NO3 

 Co  H O 
2 6
 is a high-spin complex involving

Sol: Those compounds which accept H are sp3d2 hybridisation (outer orbital complex).
known as Bronsted base, NO3 accepts H and
form HNO3 . So it is a base. 42) Ans: D) BF3
Sol: BF3
32) Ans: D) lysine
43) Ans: D) 1, 4
33) Ans: C) aldehydic and alcoholic.
44) Ans: B) intra-molecular hydrogen bonding

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Sol:

45) Ans: D) sp3 to dsp2

Sol: In the complex ion NiCl4 
2
, the
3
hybridisation involved is sp and the molecular
geometry is tetrahedral. When the weak-field
ligands Cl , change to strong-field ligands CN ,
2
the complex ion formed is Ni  CN 4  which

involves dsp2 hybridisation and the molecular

geometry is square planar.

46) Ans: D) B2H6 .H2O2  NaOH

Sol: In this reaction addition of H2O has taken
place according to Anti-Markownikoff rule; hence,
the reaction must be B2H6 reaction.

47) Ans: C) coordination number

48) Ans: B) 3.0

Sol: Here, [H ]  103 M,  pH   log[103 ] i.e. pH  3

49) Ans: B) Cr  H2O4 Cl2  Cl

Sol: Cr  H2O4 Cl2  Cl

50) Ans: A) Myoglobin

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