dilution of Na+ and Cl- ions are 51.12 × 10-4 S cm2/mol and 73.54 × 10-4 Scm2/mol respectively?

a) 198.20 S cm2/mol b) 175.78 S cm2/mol

c) 22.42 S cm2/mol d) 124.66 S cm2/mol

49
. In the presence of a catalyst, the activation energy of a reaction is lowered by 2 kcal at 27°C. The rate of reaction [1]
will increase by

a) 20 times b) 28 times

c) 14 times d) 2 times
50. In a chemical reaction X → Y, it is found that the rate of reaction doubles when the concentration of X is [1]
increased four times. The order of the reaction with respect to X is

a) 1

2
b) 2

c) 1 d) 0

51. The reaction 2A → B is first order in A with a rate constant of 2.8 determining 10–2s–1. How long will it take [1]
for A to decrease from 0.88 M to 0.14 M?

a) 76 s b) 44 s

c) 66 s d) 50 s
52. For the reaction A → products, at [A] = 0.4 M , t1/2 = 24 s and at [A] = 0.2 M , t1/2 = 12 s . The unit [1]
for the rate constant is

a) S-2 b) mol L-1s-1

c) L2/mol2/s d) S–1

53. Lanthanoid contraction is a caused due to: [1]

a) Poor shielding effect of 4f electron b) Effective nuclear charge

c) Size of 4f orbitals d) Atomic number

54. KMnO4 acts as an oxidising agent in alkaline medium. When alkaline KMnO4 is treated with KI, iodide ion is [1]
oxidised to:

a) IO −
3
b) IO-

c) I2 d) IO
−
4

55. Haemoglobin and chlorophyll contain: [1]

a) Fe and Mg b) Fe and Mn

c) Fe and Co d) Mg and Fe
56. Out of the following transition elements, the maximum number of oxidation states are shown by [1]

a) Mn (Z = 25) b) Sc (Z = 21)

c) Cr (Z = 24) d) Fe (Z = 26)
57. The formula of the coordination compound Tetraammineaquachloridocobalt(III) chloride is [1]

a) [Co(NH3)4(H2O)Cl]CI2 b) [Co(NH3)2(H2O)CI]CI2

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