Professional Documents
Culture Documents
Presented by
Alvarez, Pamela
Casapao, Lalaine Avegail
Garcia, Jullia Nicole
Mabini, Jessica
Panganiban, Jasmine Mae
May 2022
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
Student Outcomes
Rationale
Methodology
Discussions
Alvarez, Pamela Material, Energy and Heat May 15, 2022
Balances
Thermodynamics Principles
Garcia, Jullia Nicole Material, Energy and Heat May 15, 2022
Balances
Discussions
Mabini, Jessica Material, Energy and Heat May 15, 2022
Balances
2. Strategy of Operation
To set a task and complete it on time, collaboration and teamwork are required.
First, the participants should begin brainstorming ideas for the assigned topic and allocate
assignments to each member. They will be given enough time to complete their own parts.
Second, each part will be compiled, and the paper will be reviewed. Because it is a
laboratory exam, substantial revisions are required to better grasp the study's data and
conclusions.
1. Discuss briefly the operation of the whole equipment, showing the flow process
and steps of operation, the material going in and out, chemical reaction involved
and individual specification and operation of the equipment involved.
growing organisms such as bacteria or yeast under controlled conditions, is needed in order to
control sudden changes in temperature and pH during the process that could potentially kill or
retard the reaction.
The apparatus's flow process is aligned with the working equations of material balancing
for batch operations, such that mass in equals mass out. Moreover, the steps involved in SSF are
placing the feed to the SSF Vessel, Gelatinization, Simultaneous Saccharification Fermentation,
and Distillation.
STEP 2. Gelatinization
Turn on the main breaker switch and the SSF vessel’s thermocouple and heating system
breaker switch consecutively. Be sure that the SSF vessel switch is turned on before switching on
the control panel. Remove the pH probe then pre-heat the SSF vessel for at least 10 liters of
distilled water at 1000℃ to sterilize it. Prepare the substrate solution according to the required
proportions. Ensure that all the materials that are used in the preparation of the solution are aseptic.
Through the sample port at the top plate, dispense the prepared solution to the SSF vessel. Then,
turn on the agitator and set the temperature to 70℃ for 1 hour to gelatinize the solution. (Note:
The agitation speed and retention period will vary depending on the consistency of the gelatinized
solution.)
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
STEP 4. Distillation
Turn off the agitation and the SSF vessel’s heating system breaker circuit. Open the valve
connecting to the distillation vessel. Ensure that the vessel is not totally filled up to prevent
overflow. Make sure that all ports and bolts are tightly closed. Then, turn on the heating system
circuit breaker of the distillation vessel. Located at the control panel, switch the thermocouple
reading to distillation. Set the temperature to 80℃. Collect the product through condensation of
the gaseous ethanol. Place the product in a closed container.
It was built in such a way that its contact with the SSF
inner vessel is maximized, and the heat supply is
SSF Heating Coil
sufficient to meet the vessel's requirement. The heating
coil was divided into 3 parts which have 3 loops.
This serves as cover and ports for all the auxiliary devices
in the SSF vessel. Its material of construction was
SSF Top Plate
stainless steel with a thickness of 5 mm and a diameter of
0.3 m.
Feed port It serves as the means of passage of the feed to the vessel.
B. Distillation Vessel
This serves as cover and ports for all the auxiliary devices
in the distillation vessel. Its material of construction was
Distillation Top Plate
stainless steel with a thickness of 5 mm and has a
diameter of 0.25 m.
C. Control Panel
D. Circuit Breakers
2. Discuss your basis and assumptions in order to complete the material, energy
and heat balances involved.
Certain quantities are determined for the balances using assumptions derived from relevant
studies due to the numerous missing data points such as the amount of the total feed and
accordingly, the amount or mass for each component, such as the diastase enzyme and
glucoamylase. These figures will be used to calculate the elemental analysis, mass balance, heat
balance, and energy balance required for the equipment. Corn starch will be mixed with water,
diastase enzyme, glucoamylase, and S. cerevisiae inoculum at their respective processes to create
the final product which is pure bioethanol. In order to improve the material's quality and efficiency,
The basis amount for the solution is 15 L which is the optimum capacity of the SSF Vessel.
According to the thesis presented, they utilized 25% of cornstarch solution with 75% of water in
the gelatinization process. The standard DWC configurations, on the other hand, require more
energy than the conventional sequence, making them economically unappealing. This is due to the
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
fact that a large amount of water (approximately 90% of the feed stream) must be evaporated and
removed as side stream or top distillate. The lesson learned is that in order to avoid complete
evaporation, water must be produced as a bottom product. We use 2g of diastase enzyme in the
In order to calculate the mass (in kg) of glucoamylase to be used in the saccharification
process, the group assumed that the effect of glucoamylase on corn starch and cassava starch is
the same. In the fermentation process, the amount or mass (in kg) of the Saccharomyces cerevisiae
inoculum is necessary because it is vital in the fermentation of the glucose produced from the
saccharification process. Hence, certain quantities are needed in computing for the amount of
Saccharomyces cerevisiae inoculum. The necessary quantities to determine are the amount of pre-
treated corn starch solution (in mL), density of Saccharomyces cerevisiae inoculum (in g/mL), and
amount of Saccharomyces cerevisiae inoculum per 1000 mL of corn starch solution (in mL).
Utilizing these quantities will arrive on the amount or mass Saccharomyces cerevisiae inoculum.
When glucose was fermented then one mole of glucose changed into two moles of carbon dioxide
and two moles of ethanol. The mass of the carbon dioxide (CO₂) produced during fermentation as
a by-product and the mass of bioethanol solution in the fermented broth was calculated through
stoichiometric ratios and equations. The group assumed that the impurities to be filtered out are
the enzymes and catalysts remaining present in the fermented broth containing the bioethanol
solution, such as diastase enzyme, glucoamylase, and Saccharomyces cerevisiae inoculum, during
the filtering process. The final step is the distillation process. The bioethanol solution is considered
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
as the infeed, and it contains a total of 6.6579 kg in mass. There will still be water in the distilled
bioethanol since the boiling point of ethanol is 78.4 °C and the Azeotrope temperature of ethanol-
water is 78.2 °C. Water is still present in large quantities because it is not utilized in the ethanol-
The equation used by the group in computing for the heat balance of pre-treatment and SSF
is Q = mcΔT. For the distillation process, the group assumed that there is no variation in top and
bottom column temperature because there is an acceptable description in the paper. Using Perry's
thermodynamic characteristics, we calculated the latent heat of ethanol and water. In addition, the
difference in latent heat between liquid and vapor was also calculated. The formula we used is:
𝑚𝑒𝑡ℎ𝑎𝑛𝑜𝑙 𝑚𝑤𝑎𝑡𝑒𝑟
𝑄= (∆𝐻𝑒𝑡ℎ𝑎𝑛𝑜𝑙 ) + (∆𝐻𝑤𝑎𝑡𝑒𝑟 )
𝑀𝑊𝑒𝑡ℎ𝑎𝑛𝑜𝑙 𝑀𝑊𝑤𝑎𝑡𝑒𝑟
Wherein
ΔH is the difference in the latent heat between liquid and vapor of component
On the other hand, the values required in energy balance can be found in the paper. The
acquired value of heat from the heat balance was simply substituted to the energy balance formula
which is ∆U + ∆KE + ∆PE = Q - W. Since the system doesn’t accelerate and doesn’t change in
height, the system’s kinetic energy and potential energy are equal to 0.
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
∆𝑈 = 𝑄 − 𝑊
3. Provide an excel worksheet with embedded calculation within the cell to show
your calculation.
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
Fluid moving devices and heating elements are devices that transport fluid and transfer
heat between two or more fluids of varying temperatures. Transferring of heat can be done in
several ways, in the simultaneous saccharification fermentation-distillation apparatus, heat transfer
occurs through a solid separator that prevents the direct contact between the fluid and the heating
elements. In gathering the necessary values needed in the calculations, the researchers discovered
that a lot of data is not stated/ given in the paper which creates a difficult scenario in determining
the system’s required values. As a result of this, and based on the calculations performed, those
devices are underspecified, which implies there is insufficient information provided to solve all of
the unknown parameters.
5. What thermodynamic principles are applied in the equipment and how did it
help in the overall operation?
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
There are several principles applied in the SSF apparatus such as the first law, the second
law, and the zeroth law of thermodynamics. The first law of thermodynamics defines the internal
energy (E) as equal to the difference of the heat transfer (Q) into a system and the work (W) done
by the system (Hall, 2021). This can be linked to the Law of Conservation which states that energy
can neither be created nor destroyed and can only converted from one form of energy to another
(Boechler et al, 2021). For the SSF apparatus, the first law of thermodynamics is shown through
the material balance wherein the amount of input is equal to the amount of output.
The SSF process also applies an irreversible process which is connected to the second law
of thermodynamics. This law states that the change in entropy delta S is equal to the heat transfer
delta Q divided by the temperature T. An example of an irreversible process is the temperature
problem discussed in the second paragraph. Once a hot object is put in contact with a cold object,
eventually, they would both achieve the same equilibrium temperature. If we then separate the
objects, they remain at the equilibrium temperature and do not naturally return to their original
temperatures. The process of bringing them to the same temperature is irreversible (Hall, 2021).
These principles help a lot in maintaining an optimal temperature for the production of
bioethanol. Also, through the help of these principles, the corn starch input was not put into waste
and the production of bioethanol is maximized.
The equipment was built magnificently but there are some parts and aspects of it that can
be improved.
1. A sight glass might be placed to better monitor the amount of broth within the
prototype.
A sight glass is a transparent tube that is used to check the level of liquid in a tank or boiler.
A simple sight glass can be a plastic or glass tube attached to the tank's bottom at one end and the
tank's top at the other. Sight glasses act as a window for operators to observe operations inside
tanks, pipes, reactors, and vessels once they are installed. Due to their robustness, soda lime or
borosilicate glass are utilized in the manufacture of sight glasses.
SOURCE: How Does A Sight Glass Work? | Types Of Sight Glass (bmengineering.co.uk)
2. Replacement of the prototype's insulating material for both the SSF and
Distillation vessels.
The insulating material used for both the SSF and Distillation vessels is the fiberglass.
Fiberglass insulation works by restricting air flow in the area it is installed. Warmer air naturally
migrates to a cooler environment. The air trapped between the fibrous strands in fiberglass does
not move, resulting in still air, thereby reducing convection and conduction and effectively
insulating the space. So, another type of insulation must be considered as a replacement for
fiberglass insulation which will bring out more efficient products.
4. The adoption of a submersible pump for the cooling system was strongly
advised.
A submersible pump, sometimes known as an electric submersible pump, is one that can
be submerged completely in water. The motor is hermetically sealed and tightly connected to the
pump's body. A submersible pump converts rotary energy into kinetic energy and then into
pressure energy to push water to the surface. A submersible pump has the benefit of never needing
to be primed because it is already submerged in the fluid. Submersible pumps are also incredibly
energy efficient since they do not have to use much energy transporting water into the pump. Water
pressure forces water into a submersible pump, reducing the pump's energy consumption.
Submersible pumps must be operated with caution and must be fully immersed. The water around
a submersible pump actually aids in the cooling of the motor.
SOURCE: How Submersible Pumps Work: Advantages and Disadvantages of Submersible Pumps
- Pump Solutions Australasia
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
References
Hwang, C., Heldman, D., Chao, R. R., & Taylor, T. (1999, January 1). Changes in Specific
Heat of Corn Starch Due to Gelatinization: Semantic scholar. undefined. Retrieved
April 17, 2022, from
https://www.semanticscholar.org/paper/Changes-in-Specific-Heat-of-Corn-
Starch-Due-to-Hwang-Heldman/62b61d407209a9e63f694edcc04f02b694ed322a
Republic of the Philippines
BATANGAS STATE UNIVERSITY
BATSTATEU ALANGILAN
Alangilan, Batangas City
College of Engineering, Architecture and Fine Arts
https://batstate-u.edu.ph/ Tel. No. (043) 425-0139 loc. 118/2121
Wang, X., Liao, B., Li, Z., Liu, G., Diao, L., Qian, F., Yang, J., Jiang, Y., Zhao, S., Li, Y.,
& Yang, S. (2021, February 25). Reducing glucoamylase usage for commercial-
scale ethanol production from starch using glucoamylase expressing
saccharomyces cerevisiae - bioresources and bioprocessing. SpringerOpen.
Retrieved April 17, 2022, from
https://bioresourcesbioprocessing.springeropen.com/articles/10.1186/s40643-021-
00375-5