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DECOMPOSITION REACTION

A decomposition reaction can be defined as a chemical reaction in which one reactant breaks down into
two or more products.

AB A+B

EX:

1. H2O H+O
H2O H2 + O2
2H20 2H2 + O2

2. Na2Co3 Na2O + CO2

3. Decomposing of sugar using sulfuric acid as a catalyst

C12H22O11 12C + 11H2O

Three types of DECOMPOSITION REACTION

Thermolysis - Thermolysis is decomposition due to heat.

Electrolysis - Electrolysis is decomposition due to electricity.

Photolysis - Photolysis is decomposition due to light.

>Thermal Decomposition Reaction

A thermal decomposition reaction can be defined as a decomposition reaction which is activated by


thermal energy. In other words, a thermal decomposition reaction requires energy to be supplied to the
reactants in the form of heat.

EX: CaCO3 → CaO + CO2

When heated, calcium carbonate decomposes into calcium oxide and carbon dioxide. This process is
employed in the manufacturing of quick lime, which is an important substance in many industries.

>Electrolytic Decomposition Reaction

An electrolytic decomposition reaction is a type of decomposition reaction in which the activation


energy for decomposition is provided in the form of electrical energy.

EX: 2H2O→ 2H2 + O2

electrolysis of water
>Photo decomposition/Photolytic decomposition

A photodecomposition reaction is a type of decomposition reaction in which the reactant is broken


down to its constituents by absorbing energy from photons.

EX: O3 + hν → O2 + O.

decomposition into dioxygen and an oxygen radical

>Uses of Decomposition Reactions

1. Manufacture of cement or calcium oxide.

2. For metallurgical processes: Extraction of metals from their oxides, chlorides, etc.

3. The relief from acid indigestion.

4. Thermite welding.

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