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The refining is complete in about 20-25 minutes of
oxygen blowing and a tap to tap time of 40-60 minutes
is needed
The classical LD or the modified LD process, both
because of oxygen refining, are often used to make soft
steels for flat products.
Being very fast in refining, LD process does not find
enough time for effective sulphur removal during
refining. Any attempt to remove sulphur results in
high basicity for which extra lime has to be charged.
To remove sulphur, external desulphurisation of
molten iron in transfer ladles is done (pre treatment).
As the oxygen jet travels through
the convertor atmosphere it carries
some of the ambient medium along
with it. This is much less in
supersonic core but is substantial
in sonic portion of the jet. Supersonic Core
The high velocity jet tears off small droplets of metal from
the bath and throw them up in the vessel atmosphere. The
presence of thin slag and slag-gas matrix inside the vessel
leads to the formation of metal-slag-gas emulsion. It
increases the interfacial area of the metal-slag, metal-gas
and gas-slag systems tremendously. E.g. the actual
interfacial area in a 100t LD vessel is at least 7500m2
compared to apparent bath area being 12-14 m2 only.
The amount of emulsion formed depends on the blowing
conditions, metal composition, quality and quantity of the
slag, temp. etc.
The formation of emulsion manifests itself in the form of
sparking and sloping from the vessels. As the emulsion
level builds up to a certain extent with the progress of
refining, sloping from the LD vessel takes place uniformly
all around the vessel.
There are 2 distinct zones of refining viz. the reaction in
the emulsion and the bulk phase.
The contribution of bulk refining i.e. refining in impact
zone and at the bulk slag-metal interface, is dominant in
the beginning.
As the emulsion builds up the emulsion refining attains a
dominant role.