IN

Raw Material Hardwood wt%

Cellulose 0.42152
Hemi-Cellulose 0.32572
Lignin 0.21076
water 0.042
1

Ca0(mol/m3) Rate Constant (1/sec)

suppose 100 0.5

For N=1 (-ra)(mol/m3.sec)Volume of Reactor(m3)

(-ra)=KCa 14.32523984301 3.25520833333333

wt%
Nitrogen 1
 Fast Pyrolysis
Temperature Pressure(bar)
500◦C 5

Mass Flow Rate Molar Flow Rate

(Ton/hr) (kg/hr) Molecular Weight (mol/hr) density(kg/m3)
197.5875 197587.5 162.14 1218.622795115 100
152.68125 152681.25 132 1156.676136364 100
98.79375 98793.75 1513.599 65.27075533216 100
19.6875 19687.5 18 1093.75 100
468.75 468750 3534.319686811

residence time (sec) Exp(-kt) X=1-Exp(-kt) Conversion(%) Ca(mol/m3)

2.5 0.2865047968602 0.71349520313981 71.3 28.650479686

Fa0(mol/sec)
130.208333333333
Mass Flow Rate Molar Flow Rate
(kg/hr) Molecular Weight (mol/hr) density(kg/m3)
0.075036 28 0.002679857143 1.2506
Volumetric Flow Rate
(m3/hr)
1975.875
1526.8125
987.9375
196.875
4687.5

Volumetric Flow Rate

(m3/hr)
0.06
 Fa0(mol/sec) Ca0(mol/m3) Rate Constant (1/seConversion Ca(mol/m3)
130.208333333333 100 0.5 0.713 28.7
100 0.5 0.6 40
100 0.5 0.5 50
100 0.5 0.4 60
100 0.5 0.3 70
100 0.5 0.2 80
100 0.5 0.1 90
100 0.5 0 100

suppose diameter(m) 1
area(m2) 0.785375
length of Reactor(m) 4.04481321459191 0.08

0.07

0.06

(-1/ra) 0.05

0.04

0.03

0.02

0.01

0
0 0.1 0.2 0.3 0.4
Conversion
 Trapezoidal Rule= h/2(f0+f7+2(f1+f2+
(-ra)(mol/m3.sec) (-1/ra) Trapezoidal Rule
14.35 0.0696864111 0.02439701897019 f7
20 0.05 f6
25 0.04 f5
30 0.0333333333 f4
35 0.0285714286 f3
40 0.025 f2
45 0.0222222222 f1
50 0.02 f0 Area Under The Curve=V/Fa0

Hence Voulme OF PFR=Fa0*0.02439

Volume(m3)
3.1766951784101

0.3 0.4 0.5 0.6 0.7 0.8

Conversion
idal Rule= h/2(f0+f7+2(f1+f2+f3+f4+f5+f6)

h=b-a/n
h=0.1
h/2=0.05

der The Curve=V/Fa0

oulme OF PFR=Fa0*0.02439
 Fast Pyrolysis Reactor
Input
Mass Flow Rate (kg/hrCp(KJ/kg.K) Ref Temp(K) temp.(K) Q=mcp∆T(KJ/hr)
Wood 468750 0.0062 298 773 1380468.75
Nitrogen 0.075 1.1143 298 773 39.6969375
468750.075 1380508.447

Heat of reaction(KJ/hr)
∆H at 298 K -8068.27643630308 -3782005185
Cp(KJ/kg.K) 1014696.1508025
∆H at 773K -3300024513.00661 3300024513
Heat removed by water
2807386445

Water(Q) Mass Flow Rate (kg/hrCp(KJ/kg.K) Ref Temp(K) temp.(K)

2807386444.50043 13432471026.3178 4.18 298 318

Q(in) Q(out)
3301405021.5 3301405021
 Output
mcp∆T(KJ/hr) Mass Flow Rate (TMass Flow Rate ( Cp(KJ/kg.K)
acetic acid 56.25 56250 2.0146
furfural 5.15625 5156.25 1.9774
furfuryl alcohol 24.375 24375 2.2073
hydroxyacetald 51.5625 51562.5 1.826
acetol 34.6875 34687.5 2.1809
levoglucosan 25.3125 25312.5 3.1398
guaiacol 5.15625 5156.25 2.1958
2-methoxy-4-m 8.90625 8906.25 2.5192
isoeugenol 33.75 33750 2.903
2,6-dimethoxyp 22.5 22500 2.5101
phenol 17.8125 17812.5 2.2334
o-cresol 2.8125 2812.5 2.349
p-cresol 2.34375 2343.75 2.343
m-cresol 1.875 1875 2.3508
2,4-dimethylph 1.40625 1406.25 2.5192
2-ethylphenol 6.09375 6093.75 2.2003
water 56.25 56250 2.15
gases 42.1875 42187.5 1.8101
char+sand 70.3125 70312.5 2.2
468.75 468750
Temp.(REF) temp. Q=mcp∆T(KJ/hr) moles
298 773 53827593.75 936.7194005
298 773 4843085.15625 53.666215654
298 773 25556395.3125 248.47094801
298 773 44722734.375 858.63085326
298 773 35933735.15625 468.75
298 773 37751189.0625 156.25
298 773 5377994.53125 41.535766071
298 773 10657396.875 64.460504031
298 773 46538718.75 205.53701493
298 773 26826693.75 145.94752376
298 773 18896657.8125 189.27319095
298 773 3138117.1875 26.010357903
298 773 2608417.96875 21.675298252
298 773 2093681.25 17.340238602
298 773 1682746.875 11.51154224
298 773 6368837.109375 49.880899759
298 773 57445312.5 3123.2648529
298 773 36272707.03125 357.52118644
298 773 73476562.5 5859.375
494018576.9531
 Conversion ∆H at 773K(KJ/hrCp(KJ/kg.KTemperature (K)Temperature(K)
0.713 3300024.51301 1014696 773 775.3188394633
0.6 3300024.51301 1014696 773 774.9513375568
0.5 3300024.51301 1014696 773 774.6261146307
0.4 3300024.51301 1014696 773 774.3008917045
0.3 3300024.51301 1014696 773 773.9756687784
0.2 3300024.51301 1014696 773 773.6504458523
0.1 3300024.51301 1014696 773 773.3252229261
0 3300024.51301 1014696 773 773

Temperature(K)
776
775.5
775
774.5
774
773.5
773
772.5
772
771.5
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Temperature (K)
900
800
700
600
500
400
300
800
700
600
500
400
300
200
100
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
 Specification Sheet

Bed Design Specification

g(m/sec2) 9.8
density of Particle(kg/m3) 1680
density of Fluid(kg/m3) 100
Dia OF Particle (m) 0.0018
Viscosity of Fluid 5.5E-05
Bed Height(m) 0.025
Void fraction of Bed(ϵ) 0.5
sand weight(kg) 2.2
Flow rate of sand(kg/sec) 200

Reactor Design Specification

Temperature (K) 773

Mass Flow Rate(kg/hr) 468750
Molar Flow Rate(mol/hr) 3534.319686811
Volumetric Flow Rate(m3/h 4687.5
Ca0(mol/m3) 100
Ca(mol/m3) 28.65047968602
Rate Constant (1/sec) 0.5
residence time (sec) 2.5
Conversion 0.713
Heating Rate(◦C/min) 300
Nitrogen Flow Rate(kg/hr) 0.075036
Terminal Velocity(m/sec) 50.6749090909091
Min Fluidized Velocity(m/sec) 0.974517482517483
Fluidized Velocity(m/sec) 1.52024727272727
Cross Sectinal Area (m2) 2.544615E-06
Pressure Drop(∆P) (N/m2) 193.55 0.0019355 bar
Flow Rate Min Fluidized Velocity(m3/sec) 2.479771803776E-06
Flow Rate Fluidized Velocity(m3/sec) 3.868444013891E-06
Flow Rate Terminal Velocity(m3/sec) 0.000128948133796

Pressure(bar) 5
(-ra)(mol/m3.sec) 14.3252398430095
Fa0(mol/sec) 130.208333333333
Area Of Reactor(m2) 0.785375
Dia OF Reactor(m) 1
Length Of Reactor(m) 4.04481321459191
Heat of reaction(KJ/hr) -3300024513.00661
Conversion(%) 71.3
Volume of Reactor(m3) 3.25520833333333