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Department of Mechanical Engineering, Korea Advanced Institute of Science and Technology, ME3221, Guseong-dong, Yuseong-gu,
Daejeon-shi 305-701, Republic of Korea
Abstract
Since the EM properties of fiber reinforced polymeric composites can be tailored effectively by adjusting its composition, they are
plausible materials for fabricating the radar absorbing structure (RAS) of desired performance. In this study, the composite RAS
which has superior load bearing capacity and EM absorption characteristics has been developed by blending the conductive carbon
black with the binder matrix of the E-glass/polyester composite, and its EM absorption characteristics has been measured by the free
space method in the X-band frequency range (8.2–12.4 GHz). The composite RAS was designed so as to have the optimal perfor-
mance for the X-band centered at 10 GHz. From the investigation, it was found that the composite RAS of 2.93 mm thickness with
the conductive carbon black absorbed more than 90% of incident EM wave throughout the entire X-band frequency range.
2005 Elsevier Ltd. All rights reserved.
0263-8223/$ - see front matter 2005 Elsevier Ltd. All rights reserved.
doi:10.1016/j.compstruct.2005.07.021
458 W.S. Chin, D.G. Lee / Composite Structures 77 (2007) 457–465
principle: the absorber using the magnetic lossy and the black can be divided into two kinds; the acetylene black
dielectric lossy materials, and the corresponding materi- of needle shape and the porous conductive black.
als are identified as the magnetic absorber and the Among them, the porous conductive black of hollow
dielectric absorber, respectively. shell shape is better than the acetylene black in view of
The magnetic absorber has often been fabricated by a performance because it induces conductivity more
mixing magnetic lossy materials (ferrite, nickel, zinc, effectively with less compounding amount by increasing
and etc.) with the flexible mediums such as rubber or the net surface area. In this study, the porous conductive
polymeric resin. Since this method uses magnetic addi- carbon black (Ketjenblack EC300J; Mitsubishi Chemi-
tives of high weight, it has a critical weakness of being cal Co., Japan), liquid unsaturated polyester resin
heavy and has poor EM absorption characteristics in (PC670; Aekyung Chemical, Korea) and E-glass mat
the GHz frequency bands because the resonance fre- (T800-E06; Dong-il Industrial, Korea) were used to fab-
quency inducing magnetic losses exits in the MHz range ricate the organic/inorganic composite specimen. The
[5]. areal weight of the E-glass mat used in this study was
The dielectric absorber has been made by adding 0.854 kg/m2 and the linear density of its E-glass fiber
some conductive powders like carbon black or silver yarn was about 1116–1284 tex (g/km). General proper-
particle to the matrix resin in order to induce the dielec- ties of carbon black and polyester resin used in this
tric loss by enhancing the conductivity of the mixture. study are given in Tables 1 and 2, respectively.
Among them, the carbon black which has the weight After removing the moisture in the carbon black
about one fourteenth of ferrite is widely used due to powder by drying in a furnace at 80 C for 24 h, it was
its good absorption performance in high frequency mixed with the unsaturated polyester resin, followed
bands [5,6]. by the mechanical agitation for 1 h. Then, MEKPO
In this study, E-glass fiber reinforced polyester com- (methyl-ethyl-ketone-peroxide), the cure catalyst, was
posite was fabricated by blending the conductive carbon added to the compound with the volume ratio of polyes-
black with the binder matrix of the composite material, ter to catalyst of 100 to 2. Then, this liquid compound
and its dielectric properties (complex relative permittiv- was uniformly applied to five plies of the E-glass mat
ity) were measured by the free space method in the X- and cured at 80 C for 2 h so as to fabricate planar com-
band frequency range (military band; 8.2–12.4 GHz). posite specimens with the dimensions of 150 mm
The quantitative analysis of the measured permittivity (width) · 150 mm (length) · 4 mm (thickness). In this
was performed with respect to the content of carbon study, the composite specimens were manufactured with
black to describe the dielectric behavior of heteroge- several weight fractions (hereafter wt) of carbon black to
neous mixture, and the attenuation behavior of the polyester resin from 0 to 0.025 with 0.005 intervals
FRP composite containing conductive carbon black
was estimated with respect to the thickness and the con- Table 1
tent of carbon black. From those results, the optimal de- General properties of the carbon black (Ketjen Black EC300J)
sign solution for the composite RAS was suggested Properties Values
under the constraints of minimizing the thickness and Surface area (BETa) (m2/g) 950
maximizing the 10 dB absorbing bandwidth within Pore volume (cm3/g) 1.15
the X-band frequency range centered at 10 GHz. For Particle size (nm) 37 nm
the verification of design solution, the single-layered DBPb absorption (ml/100 g) 360
composite RAS for optimal performance was fabricated pH 9
Volatile content (%) 0.5
and its performance was tested with the free space meth- Ash content (%) 0.05
od. Finally, the composite RAS of 2.93 mm thickness, a
Method for analyzing the specific surface area of powder, which
which can absorb more than 90% of incident EM wave was developed by Brunauer, Emmett, and Teller.
throughout the entire X-band frequency range, has been b
Dibutyl phthalate.
developed.
Table 2
2. Materials and dielectric measurement by the Material properties of the cured unsaturated polyester resin (P670)
free space method
Property Value
rather than the volume fraction because it is difficult not ting and receiving antennas), a specimen holder,
only to measure the exact density of carbon black but HP8510C network analyzer, and a personal computer
also to fabricate composite specimens with an exact vol- for data acquisition as shown in Fig. 1. The network
ume fraction of carbon black. When wt of carbon black analyzer was used to make precision measurements of
exceeds 0.025, the viscosity of liquid compound sharply S-parameters (scattering parameters) of the specimen
increased due to the increase of the interfacial surface in the free space, from which the electromagnetic prop-
area between the polyester resin and the carbon black, erties of materials are inversely (or backward)
which made the further mixing impossible. The mea- calculated.
sured fiber volume fraction of the fabricated specimens For the measurement of dielectric properties, only the
was about 42.5%. complex reflection scattering parameter S11 was mea-
sured by placing a perfectly conducting plate behind
2.2. Free space measurement of the dielectric property the plate of unknown material in order to reflect
all the electromagnetic wave incident on the specimen
The free space method can measure accurately the by the transmitting antenna, while the front face of the
electromagnetic properties of anisotropic and inhomo- sample was located at the focal plane of the transmitting
geneous media such as ceramics, composites, etc., with- antenna.
out excitation of higher order modes, which is seldom In the case of the normal incidence of the transverse
possible in the traditional methods [3]. electromagnetic plane wave on the specimen, the reflec-
The free space measurement system (HVS Technolo- tion scattering parameter S11 is related to the complex
gies, Pennsylvania, USA) used in this study is composed relative permittivity ½er ¼ e0r je00r ¼ e0r ð1 j tan dÞ from
of a pair of spot-focusing horn lens antennas (transmit- the transmission line theory as follows [7]:
Fig. 1. Free space measurement system for characterization of electromagnetic properties of materials: (a) schematic configuration of the free space
measurement system and (b) photographs of the free space measurement system (HVS Technologies, Pennsylvania, USA).
460 W.S. Chin, D.G. Lee / Composite Structures 77 (2007) 457–465
7
6.5
0.02
6
6 0.015
5.5 0.01 5
5 0.005
4
4.5
0
4 3
8.2 8.8 9.4 10 10.6 11.2 11.8 12.4 0 0.005 0.01 0.015 0.02 0.025 0.03
(a) Frequency (GHz) (a) Weight Fraction of CB
Imaginary Relative Permittivity
0.02 0.6
Loss Tangent
2 0.4
0.015 0.01
1
0.005 0.2
0
0
8.2 8.8 9.4 10 10.6 11.2 11.8 12.4 0
(b) Frequency (GHz) 0 0.005 0.01 0.015 0.02 0.025 0.03
(b) Weight Fraction of CB
Fig. 2. Variation of the complex relative permittivity of the E-glass/
polyester composite laminate containing conductive carbon black with Fig. 3. Variation of the dielectric properties of the E-glass/polyester
respect to wt of carbon black and the EM frequency: (a) variation of composite containing conductive carbon black with respect to wt of
the dielectric constant and (b) variation of imaginary part of the carbon black at 10 GHz frequency: (a) dielectric constant and (b) loss
complex relative permittivity. tangent.
W.S. Chin, D.G. Lee / Composite Structures 77 (2007) 457–465 461
and tan d show the tendencies of linear increment with e0r ðf ; wtÞ ¼ aðf Þ wt þ e0r;0 ðf Þ ð5Þ
respect to the carbon black loading. tan dðf ; wtÞ ¼ bðf Þ wt þ tan d0 ðf Þ ð6Þ
From the linear regression analysis of the experimen-
tal results shown in Fig. 3, the dielectric properties of the Then, the imaginary part of the complex relative per-
composite were obtained with respect to wt as the fol- mittivity of the composite e00r could be obtained from the
lowing first-order equation: following relation:
e0r ¼ a wt þ e0r;0 ð3Þ e00r ¼ tan d e0r ð7Þ
tan d ¼ b wt þ tan d0 ð4Þ Since the parameters a and b in Eqs. (5) and (6) con-
tain the information not only about the dielectric char-
where e0r and tan d designate the dielectric constant and
acteristics of carbon black but also about the
loss tangent of the E-glass/polyester composite contain-
interactions between carbon black and matrix polymer,
ing carbon black with an arbitrary wt of carbon black,
it is possible to describe the dielectric behavior of the
and e0r;0 and tan d0 designate those of the E-glass/polyes-
composite by the suggested method without the knowl-
ter composite with no carbon black, respectively. The
edge of the permittivity of carbon black. Therefore, if
constants in Eqs. (3) and (4) are functions of a frequency
e0r;0 ðf Þ and tan d0f of any fiber reinforced polymeric com-
f. The parameters a and b indicate the linear increment
posite and the parameters a and b with respect to fre-
of the dielectric constant and loss tangent with respect
quency are given, the estimation of the complex
wt of carbon black, respectively.
relative permittivity of the composite laminate might
The parameters a and b in Eqs. (3) and (4) for the E-
be possible with respect to the content of carbon black.
glass/polyester composite with carbon black changed
according to the frequency variation as shown in
Fig. 4, from which they were expressed as functions of
a frequency f (GHz) as follows: 3. Numerical analysis for obtaining optimal design
solutions
a ( f ) = -9.7801f + 180.51
2
formula for describing the complex relative permittivity
R = 0.9972
40 of the composite of an arbitrary carbon black content
was derived. When a conducting metal plate is placed
20 behind the RAS, its EM absorption characteristics can
0 be evaluated in terms of the reflection loss RS or atten-
8.2 8.8 9.4 10 10.6 11.2 11.8 12.4 uation value, which is defined in the following equation:
(a) Frequency (GHz)
RS ðdBÞ ¼ 20 log jS 11 j ð8Þ
Parameter b w.r.t. Frequency Using Eqs. (1) and (8), and the derived formula for
25
the complex permittivity, the reflection loss of the sin-
gle-layered composite laminate was simulated with re-
20
spect to wt of carbon black and laminate thickness at
15
b ( f ) = -1.5599f + 34.783 10 GHz frequency. Since this study is mainly concerned
2
R = 0.9532 with the absorption of the X-band frequency range, the
b
carbon black with respect to the laminate thickness. As tics. However, as wt of carbon black increased, the
shown in Fig. 5, in the case of the composite laminate thickness for matching decreased and the maximum
with no carbon black (wt = 0), the resonance or match- reflection loss increased as shown in Figs. 6–10. Except
ing for sufficient EM absorption did not occur, even
with increased thickness due to its low-loss characteris-
Reflection Loss w.r.t. Thickness at 10 GHz
0
Reflection Loss w.r.t. Thickness at 10 GHz
0
-5
-4
-6 -10
-8
-10 -15
0 10 20 30 40 50
-12
0 20 40 60 80 100 Thickness (mm)
Thickness (mm)
Fig. 8. Variation of the reflection loss of the E-glass/polyester
Fig. 5. Variation of the reflection loss of the E-glass/polyester composite (wt = 0.015) with respect to the laminate thickness at
composite (wt = 0) with respect to the laminate thickness at 10 GHz. 10 GHz.
Reflection Loss w.r.t. Thickness at 10 GHz Reflection Loss w.r.t. Thickness at 10 GHz
0 0
Reflection Loss (dB)
-5
Reflection Loss (dB)
-5
-10
-10
-15
-15
-20
-25 -20
0 20 40 60 80 100 0 5 10 15 20 25 30
Thickness (mm) Thickness (mm)
Fig. 6. Variation of the reflection loss of the E-glass/polyester Fig. 9. Variation of the reflection loss of the E-glass/polyester
composite (wt = 0.005) with respect to the laminate thickness at composite (wt = 0.02) with respect to the laminate thickness at
10 GHz. 10 GHz.
Reflection Loss w.r.t. Thickness at 10 GHz Reflection Loss w.r.t. Thickness at 10 GHz
0
0
Reflection Loss (dB)
-10
Reflection Loss (dB)
-10
-20
-20
-30
-30 -40
-50
-40
0 10 20 30 40 50 60 0 5 10 15 20 25 30
Thickness (mm) Thickness (mm)
Fig. 7. Variation of the reflection loss of the E-glass/polyester Fig. 10. Variation of the reflection loss of the E-glass/polyester
composite (wt = 0.01) with respect to the laminate thickness at composite (wt = 0.025) with respect to the laminate thickness at
10 GHz. 10 GHz.
W.S. Chin, D.G. Lee / Composite Structures 77 (2007) 457–465 463
for the specimen with no carbon black, the reflection almost close to the optimal design solution that this
loss converged on a certain value as the thickness in- study aimed to achieve.
creased because the reflected wave from the back surface
was not enough to destruct the surface reflection wave. 3.2. Optimal design solution for the single-layered
In the cases of the composite laminates with wt = 0.02 composite RAS
and wt = 0.025, matching of 20 dB, or more loss, oc-
curred below 5 mm thickness, which is a very appropri- From the previous experiments and simulation re-
ate thicknesses and absorption performance. Therefore, sults, the design specification of the single-layered com-
it was concluded that the optimal design solution of the posite RAS for optimal performance was suggested.
content of carbon black for the single-layered composite Since that design solution was derived from the dielec-
RAS might exist within the range of 0.02 6 wt 6 0.025. tric properties of the composite laminate composed of
In order to verify the above results, the reflection loss five plies of the E-glass mat (T800-E06), the results ob-
of the composite laminates with wt = 0.02 and tained so far are valid to the laminate whose fiber vol-
wt = 0.025 were simulated with respect to the frequency ume fraction is about 42.5%. In order to fabricate the
and the thickness simultaneously as shown in Fig. 11. composite laminate about 3 mm thickness, four plies
From the result of Fig. 11(b), it was found that the com- of the E-glass mat was required, and this would alter
posite laminate of 3 mm thickness with wt = 0.025 was the final fiber volume fraction of laminate due to the
predetermined areal weight and the restricted thickness
of the E-glass mat. Actually, the composite laminate
composed of four plies of the E-glass mat had the thick-
ness about 3 mm and the fiber volume fraction about
46%, respectively. Since it is known that the dielectric
properties of FRP composite are affected by its fiber vol-
ume fraction [8], the previous design solution should be
modified considering the change in the fiber volume
fraction of the composite RAS.
For this purpose, the E-glass/polyester composite
laminates with wt = 0 and wt = 0.025 of carbon black
were fabricated using four plies of the E-glass mat,
and their complex permittivities were measured by the
free space method in the X-band frequency range. On
the assumption that the dielectric constant and loss tan-
gent of the composite laminates will follow the previ-
ously observed linear increment tendencies, the
parameters a and b was obtained by the linear fitting
of measured data, and finally Eqs. (5)–(7) for the fiber
volume fraction of 46% were constructed. As shown in
Fig. 12, the complex relative permittivity increased as
the fiber volume fraction increased. This tendency was
irrespective of the frequency.
Through the similar numerical analysis on the reflec-
tion loss with respect to wt of carbon black and the
thickness, the modified design solution of the composite
RAS for the X-band was suggested, where wt = 0.0195
and 2.93 mm thickness were chosen as the optimum car-
bon black loading and the thickness, respectively.
Fig. 13 shows the predicted reflection loss of the sin-
gle-layered composite RAS for the suggested design
solution in the X-band frequency range.
Amplitude (dB)
(EC300J) were used. The thickness and the fiber volume
fraction of fabricated composite RAS were 2.93 mm and -20
46%, respectively.
Figs. 14 and 15 show the measured reflection loss of -30
each composite RAS by the free space method in the Optimal Design Solution
-40
X-band frequency rangae, where the comparisons with
the predicted results are also depicted. As shown in Figs. -50
14 and 15, good agreements between the measured and 8.2 8.8 9.4 10 10.6 11.2 11.8 12.4
the predicted reflection loss were observed, which con- Frequency (GHz)
firms the validity of the design method for the composite Fig. 13. Reflection loss of the single-layered composite RAS of
RAS suggested in this study. 2.93 mm thickness at wt = 0.0195 (optimal design solution) with
In order to evaluate the performance of the single- respect to the frequency (X-band: 8.2–2.4 GHz).
layered composite RAS, 10 dB (absorb 90% of inci-
dent EM wave) and 20 dB (absorb 99% of incident
EM wave) absorbing bandwidth were considered as Reflection Loss w.r.t. Frequency
0
the measure of performance. As shown in Fig. 14, the 8.2 8.8 9.4 10 10.6 11.2 11.8 12.4
-5
composite RAS with wt = 0.019 has 10 dB absorbing
Reflection Loss (dB)
bandwidth of 3.6 GHz (8.5–12.1 GHz), 20 dB absorb- -10
ing bandwidth of 1.0 GHz (9.6–10.6 GHz), and the max- -15
imum reflection loss of 33 dB, while the composite
RAS with wt = 0.02 has those of 3.7 GHz (8.6– -20
12.3 GHz), 1.13 GHz (9.65–10.78 GHz), and 55 dB, -25
Measured Result
-30 Predicted Result
5
Fiber Volume Fraction = 42.5%
Reflection Loss w.r.t. Frequency
4 0
Fiber Volume Fraction = 46%
8.2 8.8 9.4 10 10.6 11.2 11.8 12.4
3
-10
Reflection Loss (dB)
0.6
-60
Frequency (GHz)
0.4
Fig. 15. Comparison of the measured reflection loss of the single-
0.2 layered composite RAS of 2.93 mm thickness at wt = 0.02 with the
prediction result by the method suggested in this study.
0
0 0.005 0.01 0.015 0.02 0.025 0.03
(b) Weight Fraction of CB respectively, as shown in Fig. 15. From the investiga-
tion, it was found that the single-layered composite
Fig. 12. Variation of the dielectric properties of the E-glass/polyester
RAS with wt = 0.02 could absorb more than 90% of
composite with respect to wt of carbon black and the fiber volume
fraction at 10 GHz frequency: (a) dielectric constant and (b) loss incident EM wave throughout the entire X-band fre-
tangent. quency range.
W.S. Chin, D.G. Lee / Composite Structures 77 (2007) 457–465 465