Cc a 2. Do BP syjgr = 0,771 V> ESiy.s = 0,141 Vinén: Pb’ +H,O0 = PbOHY + H* *f,=107™" Q Zn* + H,0 = ZnOH* + H* *f,=10%% QB) HO = OH + HY rey So sfnh (1) —> (4): *Br.C,_», >> *Bo-C,.a. >> *Bs.C,,.>> Ky > tinh pH, theo (1): Fe + H,0 = FeOH* + H’ “pf; 0,05 0.05 -x x x [H*] =x =0,0153 M > pHa = 1,82. 0” ay 1/2Fe* + HS ——> 2Fe™* + S| + 2H" 00s 1 @ . 0.05 0.05 S 21Pb + HS —-> PbS) 0,10 4/Fe* + HS K va Ks nho, ea Oren K, Vi mdi trudng axit >, Déi voi HLS, es) at = 10? nhé — kha nang phan li cla HoS trong méi axit khong difg ke, do d6 chap nhan [H'] = C,.= 0,25 M — tinh C,, theo can Ta 06: C,,>,-C, Khong téch ra. Nhu vay trong hdn hop B, ngoai S, chi c6 PbS két tiia. ig < Kswas) > ZnS khong xudt hign; C_.,,.C,. < Keres) > FeS 0,0592 mt 0,75 0.750,0592 , anim, — 9 . trong d6 [H"] duge tinh nhur sau: CH;COONH; — NH} + CHsCOO 1 1 NH} = NH; + Ht K,=10°" (5) CH;COO’ +H,O0 = CH;COOH + OH Ky=10°" (6) a 2 - e107 Do Ke= Ky v8 Coe = Coop copy PH= 7,00 > [H'] = 10 (6 thé tinh [H*] theo diéu kién proton hoac t6 hgp 2 can bang (5) vagy = 09,0592), [HP _ 0,0592,, 104 oot ie ata 2 a 2 "103 dién cue chi 1a catot, dién cuc platin 1a anot. So dé pin: @ (©) Pt(H,)| CH;COO" IM; NH} 1M || S; PbS; HS ipo? eas Fe™* 0,05M; Zn”* 0.01M [Pb (+) \ (p= 103 asm) ‘Tren catot: PbS + 2H? + 2p Pb| + HS” “Tren anot: Hy CS 2H +2. 2x Ht + Rieroo = CH.COOH i COO’ > 2CH,COOH + 2c Phan tmg trong pin: RKGSP H+ 2H" + 2CH,COO’ > Pb + ThS + 2CH,COOH = Vay:E, 0.415 V cab isin = - 0.33 V Cau 9. (2,0 diémor Halogen. a di qua 3,00 g m6t nguyén 16 A ri sau d6 lam lanh thu duoc 1,06 g mot wa rn maging B. Dun néng B trong dong khf nito r6i dn khf sinh ra qua dung dich KI. 1g dich sm mau sinh ra bing natri thiosunfat 0,120 M. Chat rin C sinh ra khi nbit phi tan vao nude réi cb bay hoi dung méi thu duoc chat rin D. Khi sinh ra duoc hia tan?Va0 150,0 mL nude due dung dich E. Chuan 46 20,0 mL dung dich E bang dung dich NaOH 0,100 M. un néng chat rin D 6 400°C thu duge 0,403 g chat rin F. Dun néng chat rn F trong dong khf hydro duge 0,300g A. a) Xée dinh céc chat tir A dén F b) Viét cde phan ting xay ra . ©) Tinh thé tich dung dich natri thiosunfat cin dé chudn 46 dung dich sim mau 4) Tinh thé tich dung dich NaOH can dé chun d6 20,0 mL dung dich E e) Tai sao phai dun néng B trong dong khi nito? C6 thé thay nito bang chat nao khic? Gia1/ Tim F: Goi cong thie Fla A,0, Mo = 0,403-0,3 = 0,103 mg => no = 6,4375 mmol => ny = 12,875/n mmol m,= 300 mg => M,=233n n 1 2 3i 4 M_| 23,3 46,6 | 69,9 | 93,2 Kim | Na . Loai|Ga | Nb loai_ | (Loai vi Na khéng tao ket (Loai vi Nb khong ¢6 hi tua D) ti4) Vay: A la Ga Tim B: Goi céng thire B 1A GaC ly, Ma = 1060-300 = 760 mg => mq = 21,408 mmol => m = 21, 408 : 12,875/3 = 5 => GaCls => B: GaCh.Cl, C-GaCl;, D - Ga(OH);, E - dung dich nuée HCI, F Sy ? 2Ga + SCl > 2GaCh,.Cl, ‘i GaCl-Ch $ GaCls + Cl WO GaCl; +3 H,0 “ Ga(OH); +3 HCI & t 2 Ga(OH); 5 Ga; +3 HO to S Gi,0,+3 Hy 262430 2KI+Ch—>2KCI+b 2 NarS203 + 12 > NaS4Og + 2 HCI + NaOH — NaCl + Hi Can 71,5 mL dung dich oe va 17,2 mL dung dich NaOH 48 chudn 46. Sit dung khi mang an chuyén clo vao dung dich Nal. Khf mang phai tro’ v6i tatca cae chat 66 tn ri — Ite husnh ing vat hiém gp trong tur nhién, o6 mau den pha tim va anh kim. Thinh lit gom Ag’, Tuu huynh (S~) va mot hop chat chia mot nguyén 16 méi X chua y gid. Dét chdy ho’n 1,0002 gam Acgiroodit trong khdng khf thay cé SO, i chat ran A. Chat rin A hda tan trong axit nitric thu duge dung dich C va cht rin B (B 2} mot oxit ludng tinh). Dé xdc dinh ion Ag’, ngubi ta cho vao dung dich C 100ml dung dich RSCN 0,1M, long du KSCN duge chudn 46 béi dung dich Fe3” 0,1M thay hét 9,69 ml. Khi SO; sinh ra durge hap thu hodn toin trong dung dich Ba(OH)> dur thu duge 1,156 gam két tia. a) Xc dinh nguyén t6 X va cng thitc cia Acgiroodit. b) Viét phuong tinh héa hoc khi cho B téc dung véi dung dich HCI dim dic va dung dich NaOH. a)Ag’ + SCN — > AgSCN Fe* + 3SCN’ —> Fe(SCN): Ta c6: neers = 0,1.9,69.10" (mol) 02).1.100.10 (mol) (scx) ~ 3 Nuressy = 7,093.10 (mol) SO: + Ba(OH); —> BaSO; Ta c6: n@gasos) = 5,317.10" (mol) > nis.) = Mpasos = 5,317.10 (mol) b) Trong Acgiroodit c6 chita Ag:S: Magas) = n(Ag)/2. = 3,547.10" (mol) = S6 mol S* trong hop chat cdn lai: n¢g2)= 1,770.10" (mol) > Nguyén té X phai cé s6 oxi hoa duong trong hgp chat cdn lai X,Sp Nexast) = 0,177.10" fo mol 1x2) =0,177.10%a/> mol mx = 1,0002 ~ms - may = 0,0642 (gam) © Mx =36,27 b/a (g/mol) => Hop chat X,S, 06 thé la X28, XS, X2S3, XS2, X2Ss; XS3; XaS>. Tuong tg véi ti Ié b/a lA : 0,5; 1; 1,5: 2;2,5; 3; 3.5. Ss Mxtuong img: 18,15 3 loai vi Tot e6 dé aim dign ton hom S' © GeSr > Ges7= 8,85.10% mol © Mages) : MGes2) = 4:1 © Céng thite Acgiroodit la: ©) GeO + 4HCI GeO, + 2NuOH 0.25 0,25 0945. 363. 828____HQLCAC TRUONG CHUYEN DE DE XUAT VUNG DUYEN HAI VA DONG BANG BAC BQ MON HOA HOC- KHOI10 DE DE XUAT. Cau 12 diém) 1. (probl ~ IChO 12 - Ao— 1980) Su phan li cita phén tir clo 1a m6t qué trinh thu nhiét, AH = BAY r "Su phan li c6 thé cing xay ra béi dnh sing > a. O bude s6ng bao nhiéu thi sur phan li xay ra? & Anh séng 6 thé lam xay ra qué trinh phan li khiebigu¥2o mot hon hop g6m kh clo va hidro, hidro clorua duge hinh thanh, duge chiéu véi dén thiy ngdn UV (2 Dén c6 cong suat tigu thy Id LOW. oe 2% nang long cung cip duge hap thy bai hén hgp khi ~ mo L), Trong 2,5 gidy chiéu xa, 65 mmol cita HC! dirge sinh ra. 53,6 nm). b. Higu suat lung tir ba OF 2.(Question 7 — 201 national chemistry olympiad) Oxi va lu husnigigith thanh mot a, Sunfua so F, 1a rét khOng bén, chuyén thanh disunfua tetraflorua SF, trong d ic florua. nguyén ti flo 6 méi truéng khée nhau, Biéu dign 16 rang cdu tr ‘chidu phi hop héa hoc ctia disunfua tetraflorua $F, va gidi os nay khong tuong duong cho tit ca 4 nguyén tir flo nhur thé nao. unfua tetraflorua SF y(t", = -38°C) c6 nhiét d6 Qerone SF, (’, = -64°C). Giai thich tai sao sunfua tetraflorua SF, it bay hoi i cao hon sunfua hon sunfua hexaflorua SFs.Cau 2(2 diém) 1.(Ex 10.71-73 — General Chemistry - Zumdahl) Hop chat Na,O, CdS va Zrl, tat cd déu cé anion két tinh dang lap phuong tam dién cdn cation chiém héc tir dién. Ti 1é héc tr dién bi chiém trong mdi trudng hop 1a bao nhiéu? 2.(probl4 — CBIChO 42 — Nhgt - 2010) ‘Thém mét lugng nhdY;0; vio CeO; c6 cau tnic tinh thé giéng CaF, < (hinh vé) va nung néng thi tao thanh dung dich rin Ce,..¥,O2, ma tro1 Ce va Y* déng nhdt chiém vi tri cia cation va ché tring cia oxi Ahhh 6 vj tr anion. O day, héa tri ctia ion Cesi duge gia sit a hing nN a) Hay du dodn xem c6 bao nhiéu cation va anion trong mét té bao don vi cu tric CeOs. QO b) Tilé % chd trong oxi chiém vi trf nO anion trong dung dich rin tong hop dur O vi ti 1@ mol CeO, : Y,0; = 0.8 : —a__, bao mhiéu ? Oo c) Hay tinh sé chd trond) 66 trong 1.00.em? cia dung dich ran trén. 6 day, thé tich té bao don 13 1.36 x 107 1 Cau 3 (2 diém) SS 1,420.1 Oe 862- General Chemistry — EBBING) ‘natri photphat Na;PO, nang 54,5 mg chira dng vi phong xa P- 32 (cORHGI long 32,0 u). Néu 15,6% s6 nguyén tit photpho trong hgp chat -ABY(con lai 1A photpho c6 trong ty nhién), c6 bao nhiéu hat nhan P-32 phan 1a os mit gidy déi voi mau nay? P-32 ¢6 thoi gian bin phan img 1a 14,3 ngay. Cho bidt P tu nhién c6 khi 2. (probl — IchO 41 — Anh ~ 2009) Tudi cia dé thu thép duge tir mat trang trén tau va tru Apollo 16 duge xde dinh bang tilé “Rb / “Sr va ’Sr/**Sr cita cde mau khodng vat khéc nhau. Khoang *Rb/™Sr "Sr /™Sr 2 i wong nguyén tir trung binh 12 30,97 u;A (Plagioclaze) 0.004 0.699 B (Tinh chat) 0.180 0.709 a) “Rb phong xa B , hay viét phuong trinh phan img hat nhan. Thoi gian ban hay 124.8 x 10'°nam. b) Tinh tudi cia loai dé nay. Gia thiét ban dau ti 18 "Sr / "Sr trong mau A va B bang nhau va *’Sr va “Sr bén. Cau 4 2 diém) 1.(P2.9- page73— Physical Chemistry — Peter Atkins) ‘ OG Entanpi hinh thanh chuan ctia metallocene bis(benzen) crot xc do trong nhiét luong ké. Phan img : Cr(C, H,)4—> Ch, + Au? (583K) = 8,0 kJ.mol! S Tim entanpi tuong img ciia phan img nay va npi hinh thank, chudn cia hgp chat metallocene tai 583K) WO Nhiét dung mol dang 4p cia 1 J.K"' mol" & pha long va 81,67 J.K.mol' 6 pha khi. S\ 3 4 Cho : C%, (Hb,K) = 24924 60900 ‘:€°, (graphit, 1) = 8,527 J.Kmol". BK AH, 00x 49,0 cu, =30,8kJ.mol 2(Ex 3.3b- Physi Tinh AS (cia = 7/2R) chuyén Céiu 5(2,0 tric tit prob 5 IChO. 24-1992) joxit 14 mot trong s6 cdc oxit clia nit duoc tim thay & trong khi {6 cé thé dime héa cho N20, (k) : 2NO,(k) = NO, iemistry ~ Peter Atkins) i 2,00 mol phan tir khi If tung ludng phan tir (c6 C, 15°C va 1,50 atm dén 135°C va 7,00 atm s 1. Tai 298K, AG® tao thanh cia N2O4(k) 1a 98,28 kJ, cdn cla NO2(k) 1a 51,84 kJ. Bat diu v6i 1,0 mol N:O, (k) tai 1,0 atm va 298K, tinh % N20, bi phan hay néu 4p suat tng khong déi tai 1,0 atm va nhiét d6 duge gitt nguyén 298K. 2. Néu AH? cia phan img W,0,(k) = 2NO,(k) 1a 58,03 kJ, tai nhiét d6 nao % N20, phan huy sé gp d6i 6 phan 1Cau 6 (2 1.( Question 4— 2016 U.S national chemistry olympiad) m) Jon axetylsalixilat (dn xuat tir aspirin va duge biéu dién 1a X trong phuong trinh duéi day bi thiiy phan khi c6 mat ciia ion OH: aovee Ba x X trong Phan img duge nghién cia 6 60°C va duge xdc dinh |i moi diéu kién. Luong X duge nghién citu theo thi gian tron; jung dich dém khdc nhau va thu duge cdc dit kién sau day: t(s) [x] (M) RS [x1 pH = 1010, (emi 2> pH = 10,60 (dém) 0 3.61.1 3.59.10" 600 F) 1,78.107 740 10 a. Vi phan tmg la terireo va nong d6 cia ion OH duge gitt cé dinh bai dung dich dém *[X]. Xéc dinh gia tricia k’ cho meade em, b. Ba n (mg 1a bao nhiéu theo ion OH”? Giai thich. ‘inh luat t6c 46 day du cho phan img va tinh hing s6 tc dé k Nae —Chemistry —Keneth W.Whitten) sw fing s6 téc d6 phan hiyy nito dioxit : 2NO: + 2NO + O» bing burc xa laze 181,70 M" phat? in tng c6 thé viét nhur sau: v ‘Tim théi gian can thiét (theo s) dé NO; 2,0M giam xuéng cdn 1,25M Cafu 7 (2,0 digm) (Ngudn chwra xc dinh 15) 1. Tron céc thé tich bing nhau cua 4 dung dich sau: CJHsCOOH 0,04M; HCOOH 0,08M; NH 0,22M; H2S 0,1M duoc dung dich A a.Cho biét thanh phan gidi han cla dung dich A? b, Khéng tinh pH, hay cho biét dung dich A cé phan tmg axit hay bazo?Vi sao? . Tinh thé tich cita dung dich HC\( hoc NaOH) 0,05M cén dé trung hda 20ml dung dich A dén pH = 10. Cho pK, cut C,HsCOOH: 4,20; HCOOH: 3,75; NH: 9,24; HS: 7,02; 12,90. 2. Tinh dé tan cita BaF2 & pH = 3,00 Cho K, = 105; #8, .,,,.= LO; Kym = 10°”, Cau 8(2 diém)trichbai 13 — chudn bi IChO 38 - Han Quoc - 2006 Céc phan img oxihod - khir cho phép do duge céc sé ligu nhiét a6 a quan trong. Cho sn céc thong tin sau: Ag"(dd) + — Agr) E? = 0,7996 V AgBr(1) + & — Ag(r) + Br (dd) B= "ey AG,°(NH3(dd)) = - 26.50 kJ.mol" S AG(Ag(NH);"(dd)) = — 17.12 kI.mols > +1441V ef 2 BrOs (dd) 5 opr _ Bri(dd) 1+ Br-(dd) 1. Tinh AG;*(Ag" (dd). 2. Tinh tri sé K, ocane (ry tai 25°C. 3. Mot nguyén, en dang dién cyc hidro chudn lam anot duge xay dung sao cho, Br(l) jin xay ra phan tmg sau “+ 2 HO(I) > 2 Br (dd) + 2 HjO"(dd). thém cho dén khi AgBr két tita tai catot va [Ag*] dat Dién Ap do duge 1a 1,721 V. Tinh AE® cho nguyén t6 ganvani. (Q-4. Tinh &6 tan cia brom trong nude 48 tao thanh muse brom tai 25°C. ju 9(2 diém) t6i 1. (Question 1 ~ 2016 U.S national chemistry olympiad) M6t hop chat chua biét A chi chira C, O va Cl a. Mét miu A 3,00 g duge lm bay hoi ho’n to’n trong mot binh 1,00 L & 70,0°C va gay ra 4p sudt 0,854 atm. Khéi luong mol cia A bang bao nhiéu?1b. Mét mau A duge cho vao 100 mL nude, chuyén héa toan bé Cl trong A thanh HCI. Sau khi cho khi N; qua dung dich mét thai gian, axit HCI duge chudn 46 véi dung dich NaOH 0,200M. Su chudn dé can 30,33 mL. NaOH thém vao dé lam cho phenolphtalein di mau. Phan tram khéi lugng cia Cl trong A bang bao nhiéu? cc. Dé nghi céng thite phan tir cho A va vé cau trie Lewis hgp Ii cho n6. 4d. Viét phuong trinh (c6 cn bing) cho phan img A véi nuée (nhu m6. 6 phan b). oO 2. (Question 7.e — 2017 U.S national chemistry olympiad) Viét phuong tinh phan img xay ra khi cho hoi florua va boron trifloua due ngung tu déng thai. Du doan san Bey hu duge 6 trang Cau 10 (2 diém) S 1.(Ex 9.96 — General Chemistry - oT Sap xép nang luong ion héa cita cdc tiéu phin sau day theo thir tu tir, cao O, 02, O.', 02". Gidi thich. 2Angudn cha xde minh ro xp Hod tan hodn toan hen hg théi nao (rn, dng, khi) 6 diéu kign thudng, gom-a mol Cu,FeS, va b mol FeS, (a:b = ing dich HNO; dic néng thu duoc dung dich Y chi gdm hai mudi sunfafS Xe dinh x. y. qd yd minh ro rang) lai cé tinh sat tring? ‘phiromg phép nhén biét lugng ozon dir trong nude. 1:3; x, y nguyén duong) 3.nguén c a. Visg Qe Nguoi ra dé: Nguyén Tién Hung SDT: 0916623088,____ HQLCAC TRUONG CHUYEN DE DE XUAT VUNG DUYEN HAI VA DONG BANG BAC BQ MON HOA HOC- KHOI10 iG DAN CHAM. Cau 1(2,0 diém) 1. (probl ~ IChO 12 - Ao— 1980) Su phan li cita phén tir clo 1a m6t qué trinh thu nhiét, AH = BAY r "Su phan li c6 thé cing xay ra béi dnh sing > a. O bude s6ng bao nhiéu thi sur phan li xay ra? & Anh séng 6 thé lam xay ra qué trinh phan li khiebigu¥2o mot hon hop g6m kh clo va hidro, hidro clorua duge hinh thanh, duge chiéu véi dén thay ngan UV (2 Den 6 cOng suat tiéu thy 1 LOW. Mi oe 2% nding lugng cung cip dugc hap thy bai hén hgp khé trees mo L). Trong 2,5 gidy chiéu xa, 65 mmol cita HC! dirge sinh ra. 53,6 nm). b. Higu suat lung tir ba OF 2.(Question 7 — 201 national chemistry olympiad) Oxi va luu huynigigith thank mét s6 ede florua. a, Sunfua so F, 1a rét khOng bén, chuyén thanh disunfua tetraflorua SF, trong d nguyén ti flo 6 méi truéng khée nhau, Biéu dign 16 rang cdu tr ‘chién phi hgp héa hoc cia disunfua tetraflorua SF, va gidi nay khéng tuong duong cho tat ca 4 nguyén tir flo nhu thé nao. os a 6 junfua tetraflorua SF,(t°, = -38°C) c6 nhiét do Qerone SF, (’, = -64°C). Giai thich tai sao sunfua tetraflorua SF, it bay hoi i cao hon sunfua hon sunfua hexaflorua SFs. Dap dn: 1 a. AE = he/A suy ra} = he/AE = 6,626. 10°*.3.10°.6,022.10" /243,6.10° (1,0) | = 4,914.107 m= 491,40 nm. 0sb. Cong suat cia dén 1a 10W = 101.8". Luong ning luong hap thu = ,2.253,6.10°/6,626.10.3.108 = 2,552.10" photon tuong tng véi 4.2378.10* mmol.s 0s Js tuong img voi sé photon N = $6 mol HCI sin ra trong Is 12: 65/2,5 = 26 mmol.s” vay higu suat luong tir= 26/4,2378.10* 6,135.10" 2 |a. Cau tric ciia S3F,: Phin tr cé cau trie gin gidng bap bénh. O nguyén (1,0) | tir S c6 h6a tri 4, nguyén tir F lién két bién khéc véi hai F lién két trucC0,5 va khdc voi nguyen tir F 6 $ héa tri 2. Hai nguyén tir F lign két tn hor wong duong vi lién két S — F & S héa tri 2 huéng vé antupuyen tir va hudng ra xa nguyén tir cdn lai & sis For S Cr,, ft AU? (583K) = 8,0 kl.mof". Tim entanpi tuong tng ciia phan tig nay (@)inn entanpi hinh thanh chuan ciia hop chat metallocene tai el ‘ Nhiét dung mol dang 4p cia ber 1 J.K.mol'! 6 pha long va 81,67 1.Kmot" 6 pl Cho : C®, (Hs,k) = 28! Tac, 358K:AH ayn =aspina 2.(Ex 3.3b- Physical Chemistry ~ Peter Atkins) Tinh AS (ihe) khi 2,00 mol phan tk = 7/2R) chuyés D Dap R ag ‘» (graphit, r) = 8,527 J.K".mol™ AHS, fh cu, =30,8kI.mol™ tung ludng phan tir (c6 C, 1 frGng dan: Tir dit kign dau bai, lap chu trinh nhur sau: 6C(eaphit298K) + 31itk 298K) 700 cane 298K) 6x8,527(583-298)) }3x28,824(583-298) 6C (graphit 583K) + 3H:(k,583K) 136,1298-358)) | 0,25 aE srerssssaay CaHlo(k, 583K) —® CoHi(k, 358K) cul, 358K) Theo chu tinh ta c6:49000 = 6.8,527(583 — 298) +3.28,824.(583 — 298) + AH?((CeH, 583K) + 81,67.(358 — 583) + (-30800) + 136,1.(298 - 358) Suy ra: AH?(CcHg, 983K) = 49000 — 14581,17 - 24644,52 + 18375,75 + 30800 + 8166 = 67116,06 Jmol" = 67,116 (kI.mol 4, 0,25 CHC, A )ojnp —9 Oh +2C Hyg, AU® (583K) = 8,0 kJ.mol'. << Ta c6: AH®,, (583K) = AU? (583K) + AnRT = 8,0.10° + tO 2.8,314.583 = 17694,124 (J.mot'). Vay ta c6: AH®,y (583K) =2. AH*(CoHs, ek 0,25 AH? ((Metallocene, 583K) Suy ra: AH? (Metallocene, 583K) AH?,, (583K) 67,116 — 17,694 = 116, Hucng din: Gid sir di qua hai giai do, -/ Giai doan 1; nén thuan =< én 7,00 atm, -/ doan 2 : dun nén, eA ding dp 6 7,00 atm tir 25°C dén 135°C We 0.25 Voi gal doan 4G: AS, = — irs ASyg = AS: + AS2 = - 25,614 + 18,284 = -7,33 LK". 5 oy, a 408 0,25 enn Lee aks F “doan 2 : AS, =nC, In: p25 $3148 18,284.K* Cau 5(2,0 diém)(trich tir prob 5 — IChO 24 - 1992) Nito dioxit 18 mot trong s6 céc oxit cita nito duoc tim thay 6 trong kh quyén. N6 06 thé dime héa cho NzO, (k) : 2NO,(k) = N,0,(K) 1. Tai 298K, AG° tao thanh ctia N5O,(k) 1a 98,28 kJ, con cia NO»(k) 1a 51,84 kJ. Bat dau vai 1,0 mol N20, (k) tai 1,0 atm va 298K, tinh % N30, bi 6 0,25 it G.25°C tir 1,50 atm | 0,25 0,25phan huy néu 4p swat tng khOng ddi tai 1,0 atm va nhiét d0 duoc gitt nguyén 298K. 2. Néu AH? ciia phan img ,0,(k) = 2N0,(k) 1a 58,03 KJ, tai nhigt d6 nao % N24 phan hiy sé gap d6i 6 phan 1. Dap an 1 [2N0,)=N,0,0) 10 | Tacé: N,(k) +20,(k) > N,O,(k) AG°=98, 28k N,(k)+20,(K) > 2NO,(k) AG? =2.51,84= 103, 68K suy ra: N,0,(k)>2NO,(k) AG?=5,4kd Tac : AG°=-RT INK, > Ky =e * Se Goi x s6 mol N,O, phan hiy. Ta c6 : S 0,25 N,O,(k) = — 2NO,(k), Ban dau 1 0,25 0,25 2 {d6 phiin hy NsO, gdp doi = 2. 0,166 = 0,332 mol ; cn bing 4 05 N30, : 1 = 0,332 = 0,668 mol ; va NO»: 2.0,332 = 0,664 mol; ting s6 mol khi = 0,668+0,664=1,332 mol 0,25 = 0,496 1,332.0,6680,25 ‘Cau 6 (2,0 diem) 1.(Question 4 — 2016 U.S national chemistry olympiad) Ton axetylsalixilat (dn xudt tir aspirin va duoc biéu dién 1a X trong phuong trinh duéi day bi thiy phan khi c6 mat cia ion OH: oO awh, i, s CO —- CS ee ie | theo X trong Phan img duoc nghién cir 6 60°C va duoc x; moi diéu kién. Luong X duge nghiém earurtheo-théjgtan trong hai dung dich dém khéc nhau va thu duge ede dirkién t(s) 4 [x] (MW) pH = 10,60 (48m) 0 359.107 600 178.107 740 eS 2.75.10" st aVi OS Ia bie I theo X va néng dé cia ion OH due gitt e6 dinh béi dun; 1c d6 phan tng e6 thé viét nhu sau: v = K'[X]. Xac dinh gid trict 10 méi tht nghiém. sw Bac cla phan img 1a bao nhiéu theo ion OH"? Giai thich. . Cho biét dinh luat téc 46 day di cho phan img va tinh hing s6 téc 46 k 2.(E 16.32 ~Chemistry ~Keneth W.Whitten) Hing sé t6c d6 phan hiiy nite dioxit : 2NO, + 2NO + O» bing bite xa laze I 1,70 M" phi ‘Tim théi gian cdn thiét (theo s) dé NO, 2,0M gidm xuéng con 1,25M.| Dui digu kign gid be 1 ta 06: In(XVIXTo= tas Tai pH = 10,10 ta c6: In({2,75.10°/[3,61.107] 1,5 | suy rak’ = 3,68.10" s* 0,25 Tai pH = 10,60 ta c6: In({1,78.107)/[3,59.107) suy rak’ = 1,17.10° s* b. Tai pH = 10,10, [OH] = 1,26.10" M va pH = 10,60, [OH] = 3,98.10M Gitta hai gid wi, [OH'] tang 3,16 va hang sé t6c d6 k’ cita phan gid bac 1 tng 3,18. Do dé, k’ tile thudn véi [OH]: v= W'IXLA* k{OH]"[X] trong dé m la bac phan tg cia ion OH, m eS ©. Téc 46 v = KOH IX] 1 7 a 0,25 Do k[OH] =k’; ta c6: k = (3,68.10°)/(1,26.10 s Néu sir dung dir kién thi nghiém thir hai ta 294 M's" 0,25 Bac ciia pha Tabac 2 2 cia eS . y 0,25 (dua vao don vi cia hang s6 tc dé, 2 14M" phi") ,0882 phuit hay 5,29 | 0,25 05 | Sirdung déng hoe tich phan taco 6: S Cau 7 (2,0 diém) (Ngudn cl ic dinh r5) 1. Tron céc thé tie ‘nhau clia 4 dung dich sau: CcHsCOOH 0,04M; HCOOH 0,08M; a.Cho bi dn gidi han cua dung dich A? b. Khong ti hay cho biét dung dich A 6 phan img axit hay bazo? Vi sao? > g. 0. -HsCOOH: 4,20; HCOOH: 3.75; NH: 9,24: H>S: 7,02; 12,90. ‘inh d6 tan ciia BaF, & pH = 3,00 ex K,= 10°"; +6 = 108; Kyau = 10°". Tinh lai ndng d6 cia cae chat sau Khi tron: 1 | C,HsCOOH: 0,01M; NH: 0,055M; HCOOH: 0,02M; HS: 0,025M Sau khi trdn, xay ra cdc phan tmg sau: 15 NH; + HCOOH > NH; + HCOO” K=10°" 0,055 0,02 0.035 - 002 0,02 NH, + C NH; + C,HsCOO K= 10°" 9