STELLENCE PHARMSCIENCE PRIVATE LIMITED

MATERIAL SAFETY DATA SHEET

4-Hydrazinobenzoic acid hydrochloride

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifiers

Product name : 4-Hydrazinobenzoic acid hydrochloride

CAS-No. : 24589-77-3

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

1.3 Details of the supplier of the safety data sheet

Company : Stellence Pharmscience Pvt
Ltd
#456 road 3, industrial area Jigani
Bangalore South Bangalore Karnataka – 560 106
INDIA
1.4 Emergency telephone number

Emergency Phone # : +91 08110413811

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

This chemical is considered hazardous by the 2012 OSHA Hazard Communication
Standard (29 CFR 1910.1200)
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word

Warning

Hazard statement(s)
Hazard Statements
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
 STELLENCE PHARMSCIENCE PRIVATE LIMITED
MATERIAL SAFETY DATA SHEET
4-Hydrazinobenzoic acid hydrochloride

Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing
Call a POISON CENTER or doctor/physician if you feel unwell
Skin
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Storage
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
Bio accumulative or toxic (PBT), or very persistent and very bio accumulative (vPvB) at
Levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.1 Substances
Formula : C7 H8 N2 O2. HCl
Molecular weight : 188.61 /mol
CAS-No. : 24589-77-3
Component Classification Concentration

4-Hydrazinobenzoic acid hydrochloride 24589-77-3 >95

 STELLENCE PHARMSCIENCE PRIVATE LIMITED
MATERIAL SAFETY DATA SHEET
4-Hydrazinobenzoic acid hydrochloride

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

General Advice - if symptoms persist, call a physician.

Eye Contact - Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Get medical attention.
Skin Contact - Wash off immediately with plenty of water for at least 15 minutes. If skin irritation
persists, call a physician.
Inhalation - Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if
symptoms occur.
Ingestion - Clean mouth with water and drink afterwards plenty of water. Get medical attention if
symptoms occur.
Most important symptoms and effects none reasonably foreseeable.

SECTION 5: Firefighting measures

Suitable Extinguishing Media - Water spray, carbon dioxide (CO2), dry chemical,
alcohol-resistant foam. Unsuitable Extinguishing Media No information available
Flash Poin t- No information available
Method - No information available
Auto ignition Temperature - Not applicable
Explosion Limits
Upper - No data available
Lower - No data available
Sensitivity to Mechanical Impact - No information available
Sensitivity to Static Discharge - No information available
Specific Hazards Arising from the Chemical
Keep product and empty container away from heat and sources of ignition.
Hazardous Combustion Products
Carbon monoxide (CO). Carbon dioxide (CO2). Nitrogen oxides (NOx). Hydrogen chloride.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full
Protective gear.
 STELLENCE PHARMSCIENCE PRIVATE LIMITED
MATERIAL SAFETY DATA SHEET
4-Hydrazinobenzoic acid hydrochloride

NFPA

Health Flammability Instability Physical

hazards

2 1 1 N/A

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas.
Ensure adequate ventilation. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
Keep contaminated washing water and dispose of appropriately.
6.3 Methods and materials for containment and cleaning up
Pick up mechanically.
P pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in
suitable, closed
Containers for disposal.
Dispose contaminated material as waste according to item 13.
6.4 Reference to other sections
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information

SECTION 7: Handling and storage

Handling Wear personal protective equipment/face protection. Ensure adequate
ventilation. Do not
Get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store under an inert
Atmosphere. Protect from moisture.
 STELLENCE PHARMSCIENCE PRIVATE LIMITED
MATERIAL SAFETY DATA SHEET
4-Hydrazinobenzoic acid hydrochloride

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
8.2 Exposure controls
Exposure Guidelines This product does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies. Health 2 Flammability 1
Instability 1 Physical hazards N/A
Engineering Measures Ensure that eyewash stations and safety showers are close to the
workstation location. Ensure adequate ventilation, especially in confined areas.
Body Protection
Complete suit protecting against chemicals, the type of protective equipment must be selected
According to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle r (US) or type
ABEKP2
(EU EN 143) respirator cartridges. Use respirators and components tested and approved under
Appropriate government standards such as NIOSH (US) or CEN (EU).
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.
Control of environmental exposure
Do not let product enter drains.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical State Powder Solid
Appearance Tan, Light pink
Odor No information available
Odor Threshold No information available
pH No information available
Melting Point/Range 252 - 254 °C / 485.6 - 489.2 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
 STELLENCE PHARMSCIENCE PRIVATE LIMITED
MATERIAL SAFETY DATA SHEET
4-Hydrazinobenzoic acid hydrochloride

Flammability (solid,gas) No information available

Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Auto ignition Temperature Not applicable
Decomposition Temperature 260 °C
Viscosity Not applicable
Molecular Formula C7 H8 N2 O2. H Cl
Molecular Weight 188.61

SECTION 10 : Stability and reactivity

Reactive Hazard None known, based on information available

Stability Hygroscopic.
Conditions to Avoid Incompatible products. Excess heat. Avoid dust formation. Protect from
Water. Exposure to moist air or water.
Incompatible Materials Strong oxidizing agents
Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Nitrogen oxides
(NOx), Hydrogen chloride
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing

SECTION 11: Toxicological information

Acute Toxicity
Product Information No acute toxicity information is available for this product
Component Information
Toxicologically Synergistic
Products No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any
Ingredient as a
carcinogen.
Component CAS-No IARC NTP ACGIH OSHA Mexico
Not listed Not listed Not listed Not listed
4-Hydrazinobenzoic acid 24589-77-3 Not listed
 STELLENCE PHARMSCIENCE PRIVATE LIMITED
MATERIAL SAFETY DATA SHEET
4-Hydrazinobenzoic acid hydrochloride

hydrochloride

Mutagenic Effects No information available

Reproductive Effects
Developmental Effects
Teratogenicity
STOT - single exposure
STOT - repeated exposure
Aspiration hazard
Symptoms / effects,both acute and
Delayed
Endocrine Disruptor Information
Other Adverse Effects
No information available.
No information Available.
No information available.
Respiratory system
none known
No information available
No information available
No information available
The toxicological properties have not been fully investigated

SECTION 12: Ecological information

Eco toxicity do not empty into drains.
Persistence and Degradability Soluble in water Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation No information available.
Mobility Will likely be mobile in the environment due to its water solubility.

SECTION 13: Disposal considerations

Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous
waste. Chemical waste generators must also consult local, regional, and national hazardous waste
regulations to ensure complete and accurate classification.

SECTION 14: Transport information

1) UN-Number
ADR, ADN, IMDG, IATA : No data available
2) UN proper shipping name
ADR, ADN, IMDG, IATA : No data available
3) Transport hazard class(es)
ADR, ADN, IMDG, IATA : No data available
Class Void
4) Packing group
ADR, IMDG, IATA : No data available
 STELLENCE PHARMSCIENCE PRIVATE LIMITED
MATERIAL SAFETY DATA SHEET
4-Hydrazinobenzoic acid hydrochloride

5) Environmental hazards : Not applicable.

6) Special precautions for user not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
7) Transport/Additional information : Not dangerous according to the above specifications.
UN "Model Regulation" : --

SECTION 15: Regulatory information

United States of America Inventory

TSCA Inventory
TSCA - EPA
Component CAS-No TSCA notification -
Regulatory Flags
Active/Inactive
4- 24589-77-3 X INACTIVE -
Hydrazinobenzoic
acid
hydrochloride

Legend:
TSCA - Toxic Substances Control Act, (40 CFR Part 710)
X - Listed
'-' - Not Listed

TSCA 12(b) - Notices of Export Not applicable

International Inventories
Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Philippines (PICCS), Japan (ENCS), Australia
(AICS), China (IECSC), Korea (ECL) .

CAS- DSL NDSL EINECS PICCS ENCS AICS IECSC KECL

Component
No
4- 24589- - X 246- - - - - -
Hydrazinobenzoic 77-3 330-0
acid
hydrochloride

U.S. Federal Regulations

SARA 313 Not applicable
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
Clean Air Act Not applicable
OSHA - Occupational Safety and
Health Administration Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65
 STELLENCE PHARMSCIENCE PRIVATE LIMITED
MATERIAL SAFETY DATA SHEET
4-Hydrazinobenzoic acid hydrochloride

chemicals.
U.S. State Right-to-Know
Regulations Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N

U.S. Department of Homeland

Security This product does not contain any DHS chemicals.
Other International Regulations

Mexico - Grade No No information available

SECTION 16: Other information

Prepared By Regulatory Affairs
Stellence Pharmscience Pvt Ltd
Welcome to Stellence Pharmscience Pvt Ltd
Creation Date 07-Dec-2021
Revision Date 06-Dec-2023
Print Date 07-Dec-2021
Revision Summary This document has been updated to comply with the US OSHA Haz.Com 2012
Standard Replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
REFERENCE:
www.sigma-aldrich.com/msds/propyphenazone
The above information is believed to be correct but does not purport to be all inclusive and shall be
Used only as a guide. The information in this document is based on the present state of our knowledge
And is applicable to the product with regard to appropriate safety precautions. It does not represent any
Guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be
held
Liable for any damage resulting from handling or from contact with the above product. See
www.sigmaaldrich.com and/or the reverse side of invoice or packing slip for additional terms and
conditions of sale.