Scribd Logo
Upload

Welcome to Scribd!

  • CSEC Chemistry 2019 Paper 02

    Uploaded by

    Naps Library
    42 views21 pages

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    42 views21 pages

    CSEC Chemistry 2019 Paper 02

    Uploaded by

    Naps Library

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 21
    906 aout resrcove 01212020 | FORM TP 2019054 SB MAY/JUNE 2019 CARIBBEAN EXAMINATIONS COUNCIL CARIBBEAN SECONDARY EDUCATION CERTIFICATE* EXAMINATION CHEMISTRY Paper 02 — General Proficiency 2 hours 30 minutes READ THE FOLLOWING INSTRUCTIONS CAREFULLY. ‘This paper consists of SIX questions in TWO sections. Answer ALL questions. Write your answers in the spaces provided in this booklet. Do NOT write in the margins. Where appropriate, ALL WORKING MUST BE SHOWN in this booklet. You may use 4 silent, non-programmable calculator to answer questions. If you need to rewrite any answer and there is not enough space to do so onthe | original page, You must use the extra lined page(s) provided at the back of this booklet. Remember to draw a line through your original answer, Ifyou use the extra page(s) you MUST write the question number clearly in the box provided at the top of the extra page(s) and, where relevant, include the question part beside the answer. Naps DO NOTTERN THIS PAGE UNTIL YOU ARE TOLD TO DO SO. Copyright © 2018 Caribbean Examinations Counei Al rights reserved LL 0121 2020/MNOSEC 2019 (A 0 r + 1 SECTION A Answer ALL questions. DO NOT spend more than 30 minutes on Question 1. (a) Michael and Jennifer were assigned a group project to investigate the effect of surface area on the rate of reaction between zine metal (Zn) and dilute sulfuric aeid (H,80,). They obtained six different grades of granulated zinc. The grades represent the average size of the radius {in microns, pm) of the granules. Six experiments were carried out using the different grades of zinc granules which were reacted with an excess of 0.5 mol dm” dilute sulfuric acid at 25 °C. The same mass, 0.55 g of zine granules was used in all experiments and the time taken to collect 100 em” of hydrogen gas was noted as shown in Table 1 on page 6. pe Nor TRRC HS REAL! Figure 1 shows the stopwatch readings of the time taken to collect 100 em* of hydrogen gas for Experiments 1-6. Experiment 4 ‘Experiment 5 Experiment 6 Figure L. Time taken to collect 100 cm’ of hydrogen gas GO ON TO THE NEXT PAGE 01212020/MNCSEC 2019 L TEAR 4 TABLE 1. DATA OBTAINED FOR EXPERIMENTS 1-6 Zine Grade (um) Time(s) Rate (s") 1 08 Th) 0.091 2 19 3 3.0 4 ad s 52 6 63 3 (From the stopwatches displayed in Figure | on page §, record the times for the hydrogen gas to be collected in Column 3 in Table 1. Tie time taken for Experiment Thus alveady been recorded fur you. (3 marks) 1 Gi) Using the formula Rate ~ == — calculate the rate of reaction for each experiment and record these values to 3 decimal places in Column 4 of Table 1, The rate of reaction for Experiment 1 has already been calculated for you. GB marks) Gili) Using the grid provided on page 7, plot graph of rate versus time for Experiments 1-6. Draw the best curve through the points. {5 marks) g = GO ON TO THE NEXT PAGE | 01212020/MJ/CSEC 2019 L r * 7 sf z save 2 6.099} | & cs 3! 0.080 } 007 2 a 0.060 | 0.050 sa 0.030] + 0.020 o.o10 Popp pt ° aS mo Time (3) GO ONTO THE NEXT PAGE 01212020/MJ/CSEC 2019 L nO | (b) @ marks) (i) Explain how the trend in the rate of reaction stated in (0) (1) retates to the surface aren of the zine granules, 8g " @ marks) i) List THREE. factors, other than Surface area, that affect the Tate of a reaction, . © a “(mark (2) Suggest ONE way in which Michael and Jennifer may have controlled the temperature during the experiments, “mark GO ON TO THE NEXT PAGE iM _! 4 in, including stats symbols, for the reaction between (© Gi) Writeabalanced chemical eq zine metal and sulfuric acid, (Q marks) Calculate the total volume of hydrogen gas that would be produced at RTP from 0.55 g of zine granules. [RAM: Zn = 65.4; | mole of a gas occupies 24 000 em? at RTP] @ marks) ‘Total 25 marks GO ON TO THE NEXT PAGE _ 01212020/MCSEC 2019 L In aon r “ 7 2 Table 2 lists the chemical symbols of elements in Period 3 of the Periodic Table and their respective stomic numbers, TABLE 2, ELEMENTS IN PERIOD 3 Chemical Symbols [ Na | Me [Al [si | P [$s | ci] ar Atomic Number uP [is Ta fis Tie [7 [is (a) Explain why these elements are all placed in Period 3 of the Periodic Table (2 marks) (b) Which element in Table 2 forms an oxide which readify dissolves in water to give a solution with a pH greater than 7? Write a balanced equatian to support your answer. Element Equation (3 marks) (©) The element sulfur, S, can exist as different aliotropes. Define the term “allotrope’ GO ON 10 THE NEXT PAGE 01212020MI SEC 2019 r -ie 77] (4) Draw a diagram to show the arrangement of electrons in sulfur. (2 marks) (©) (i)_State the type of bond that forms when sulfur reacts with chlorine, mark) Gi) Explain why the type of bond stated in (¢) (i) is formed. " @ marks) (0 Write the formula ofa compound which is formed when sulfur reats with chlorine, " “( mmark) (@) Draw dorand oross diagram to show the bonding inthe compound stated in (D. @ marks) “Total 15 marks GO OW TO THE NEXT PAGE O1212020MH/CSHC 2019 L ‘Opa | r 7 3. (@) Polymerization is an important industrial process used in the manufacturing of many useful materials, ¢ )) Define the term ‘polymer’ Te Saag ae GAEDE eed ee “Gmark) Gay (ii) Distinguish between ‘addition polymerization’ and “eondensation polymerization” TataT E 2 marks) ance me GO ON TO THE NEXT PAGE 01212020 MCSEC 2019 L -13- rc (b) Figure 2 illustrates the formation of a polymer. ° ° ° Ss, a I crac” +n N—w—NH—> to—R— +2110 on Figure 2. Formation of a polymer (i) State the type of polymerization represented in Figure 2. (ii) — Give an explanation for your choice in (b) (i). mr) (©) Identify ONE use of EACH of the following types of polymers. (Polyester ene mark) (ii) Polyalkene .. (1 mark) GO ON TO TIE NEXT PAGE, | 01212020/MYCSEC 2019 L ow r -14- “| (6) Figure 3 shows the fully displayed structural formulae for Compounds A and B. na HoH oo It Iola u—C—C—On Wee IT | | So-n HoH HOH ‘Compound A Compound B Figure 3. Structural formulae Gi) State the homologous series to which Compounds A and B belong, Compound A 1 mark) Compound B “ (mark) (ii) State the name of Compound A. (1 mark) Compounds A and B react to form Compound ©, Skeich the FULLY DISPLAYED. structural formula for Compound C. Structure of Compound C (2 marks) GO ON TO THE NEXT PAGE. 01212020/Ms/CSEC 2019 LL ene _l PEIN Tens pOWOF Ree | ‘DOING WRITE IN THIS. “DONOT WRITEIN THISAREA T a1s- (iv} Identify the homologous series of Compound C. (¥) State TWO other types of reactions that Compound A can undergo. ) ¢ Total 15 marks GO ON TO THE NEXT PAGE, 01212020/MICSEC 2019 cL RIE a -l6- | SECTION B Answer ALL questions. (a) You are provided with two identical samples of white powdery substances labelled D and B. wo iy ii) One sample is finely ground sodium chloride and the other sample is finely ground diamond, Describe ONE simple test, including the observations, which could be used to distinguish between D and E. ‘@ marks) Sketch a unit cell of sodium chloride. (3 marks) State the type of bonding that occurs in sodium chloride. GO ON TO THE NEXT PAGE, 01212020/-M.UCSEC 2019 L pONGr wren pins iRG r w 1 () Figure 4 shows a part of the Periodic Table with some known elements and an unknown ‘element, X 12 Boi is 6 748 ti o Na [Mg sla Ca x Figure 4. Part of the Periodie Table Mg, Ca and the unknown element X react with water (i) Discuss the relative reactivity of Mg, Ca and X with water. “@ marks) Gi) Write a balanced chemical equation for the reaction between water and the unknown element (X). @ marks) GO ON TO THE NEXT PAGE ivan | 01212020/MACSEC 2019 PL ug 908 A008 rc =18- 7] (©) Element X ceacts with oxygen to form a stable eompound (i) Suggest a formula for this compound. “(1 mark) State whether an aqueous solution of this compound would be acidic o7 basic ancl give ONE reason for your answer. “@ marks) (iil) State ONE test to determine if an aqueous solution of this compound is acidic or basic. (mark) Total 15 marks GO ON TO THE NEXT PAGE. 01212020/MJ/CSEC 2019 LAER EE YN THIS ARPA TS RESP TEEE dire iN Was AREA. WANA pot r 1 5. (a) Methane is the first member of the alkane homologous series. (i) List THREE general characteristics of ¢ homologous series. (3 marks) Gi) Write the molecular formulae of the second and third members of the alkane homologous series. “@ marks) ii) Derive the general formula of the alkane homologous series. GOON TO THE NEXT PAGE gE _| 01212020/MICSEC 2019 r ™- 1 (by }-Butene belongs to the alkene homologous series and exhibits structural isomerism. BS a (i) Define the term “structural isomerism’ E * 8 8 : ses 3 mark) p Gi) Draw a FULLY DISPLAYED structural formula of |-Butene and its nwo isomers. : g cS 4 3 5 Titers - Fe q a 3 a 8 Tamer ! Tomer? (8 marks) GO ON TO THE NEXT PAGE E 01212020/MCSFE 2019 I L |e ug / _] r = 1 (©) 1-Butene, like all alkenes, are described as unsaturated compounds and undergo hydrogens tion reactions to become saturated. (Define the term ‘unsaturated’, (Gi) State what is meant by a hydrogenation reaction (mark) Gi) —_Draw the FULLY DISPLAYED structural formula for the hydrogenation product of 1-Butene, . (2 marks) ‘Total 15 marks GO ON TO THE NEXT PAGE 01212020/MJCSEC 2019 L r = 7 6 (2) Metal alloys are often used in place of metals because of their enhanced properties. (i) Define the term ‘alloy’ (mark Gi) Name ONE alloy of aluminium amd state its use based on one of its enhanced properties. Alloy Enhanced property 06 Use of alloy “@ marks) {b)_Astudemt conducted an experiment to investigate the reactivity each of the follossing metals;

    You might also like