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Portland cement
Chemical composition
Although the formulas above treat C–S–H as a specific stoichiometry, with the formula
C3S2H3, it does not at all form an ordered structure of uniform composition. C–S–H is
actually an amorphous gel with a highly variable stoichiometry. The ratio of C to S, for
example, can range from 1:1 to 2:1, depending on mix design and curing conditions.
Structural properties
The strength developed by portland cement depends on its composition and the fineness
to which it is ground. The C3S is mainly responsible for the strength developed in the
first week of hardening and the C2S for the subsequent increase in strength. The alumina
and iron compounds that are present only in lesser amounts make little direct
contribution to strength.
Set cement and concrete can suffer deterioration from attack by some natural or
artificial chemical agents. The alumina compound is the most vulnerable to chemical
attack in soils containing sulfate salts or in seawater, while the iron compound and the
two calcium silicates are more resistant. Calcium hydroxide released during the
hydration of the calcium silicates is also vulnerable to attack. Because cement liberates
heat when it hydrates, concrete placed in large masses, as in dams, can cause the
temperature inside the mass to rise as much as 40 °C (70 °F) above the outside
temperature. Subsequent cooling can be a cause of cracking. The highest heat of
hydration is shown by C3A, followed in descending order by C3S, C4AF, and C2S.
Types of portland cement
Five types of portland cement are standardized in the United States by the American
Society for Testing and Materials (ASTM): ordinary (Type I), modified (Type II), high-
early-strength (Type III), low-heat (Type IV), and sulfate-resistant (Type V). In other
countries Type II is omitted, and Type III is called rapid-hardening. Type V is known in
some European countries as Ferrari cement.
There also are various other special types of portland cement. Coloured cements are
made by grinding 5 to 10 percent of suitable pigments with white or ordinary gray
portland cement. Air-entraining cements are made by the addition on grinding of a
small amount, about 0.05 percent, of an organic agent that causes the entrainment of
very fine air bubbles in a concrete. This increases the resistance of the concrete to
freeze-thaw damage in cold climates. The air-entraining agent can alternatively be
added as a separate ingredient to the mix when making the concrete.
Low-alkali cements are portland cements with a total content of alkalies not above 0.6
percent. These are used in concrete made with certain types of aggregates that contain a
form of silica that reacts with alkalies to cause an expansion that can disrupt a concrete.
Masonry cements are used primarily for mortar. They consist of a mixture of portland
cement and ground limestone or other filler together with an air-entraining agent or a
water-repellent additive. Waterproof cement is the name given to a portland cement to
which a water-repellent agent has been added. Hydrophobic cement is obtained by
grinding portland cement clinker with a film-forming substance such as oleic acid in
order to reduce the rate of deterioration when the cement is stored under unfavourable
conditions.
Oil-well cements are used for cementing work in the drilling of oil wells where they are
subject to high temperatures and pressures. They usually consist of portland or
pozzolanic cement (see below) with special organic retarders to prevent the cement from
setting too quickly.
Slag cements
The granulated slag made by the rapid chilling of suitable molten slags from blast
furnaces forms the basis of another group of constructional cements. A mixture
of portland cement and granulated slag, containing up to 65 percent slag, is known in
the English-speaking countries as portland blast-furnace (slag) cement. The
German Eisenportlandzement and Hochofenzement contain up to 40 and 85 percent
slag, respectively. Mixtures in other proportions are found in French-speaking countries
under such names as ciment portland de fer, ciment métallurgique mixte, ciment de
haut fourneau, and ciment de liatier au clinker. Properties of these slag cements are
broadly similar to those of portland cement, but they have a lower lime content and a
higher silica and alumina content. Those with the higher slag content have an increased
resistance to chemical attack.
High-alumina cement gains a high proportion of its ultimate strength within 24 hours
and has a high resistance to chemical attack. It also can be used in refractory linings for
furnaces. A white form of the cement, containing minimal proportions of iron oxide and
silica, has outstanding refractory properties.
Expanding and nonshrinking cements
Expanding and nonshrinking cements expand slightly on hydration, thus offsetting the
small contraction that occurs when fresh concrete dries for the first time. Expanding
cements were first produced in France about 1945. The American type is a mixture of
portland cement and an expansive agent made by clinkering a mix of chalk, bauxite, and
gypsum.
Gypsum plasters
Gypsum plasters are used for plastering, the manufacture of plaster boards and slabs,
and in one form of floor-surfacing material. These gypsum cements are mainly produced
by heating natural gypsum (calcium sulfate dihydrate, CaSO4 · 2H2O) and dehydrating it
to give calcium sulfate hemihydrate (CaSO4 · 1/2H2O) or anhydrous (water-free) calcium
sulfate. Gypsum and anhydrite obtained as by-products in chemical manufacture also
are used as raw materials.
The hemihydrate, known as plaster of Paris, sets within a few minutes on mixing with
water; for building purposes a retarding agent, normally keratin, a protein, is added.
The anhydrous calcium sulfate plasters are slower-setting, and often another sulfate salt
is added in small amounts as an accelerator. Flooring plaster, originally known by its
German title of Estrich Gips, is of the anhydrous type.
Cement testing
Various tests to which cements must conform are laid down in national cement
specifications to control the fineness, soundness, setting time, and strength of the
cement. These tests are described in turn below.
Fineness
Fineness was long controlled by sieve tests, but more sophisticated methods are now
largely used. The most common method, used both for control of the grinding process
and for testing the finished cement, measures the surface area per unit weight of the
cement by a determination of the rate of passage of air through a bed of the cement.
Other methods depend on measuring the particle size distribution by the rate of
sedimentation of the cement in kerosene or by elutriation (separation) in an airstream.
Soundness
After it has set, a cement must not undergo any appreciable expansion, which could
disrupt a mortar or concrete. This property of soundness is tested by subjecting the set
cement to boiling in water or to high-pressure steam. Unsoundness can arise from the
presence in the cement of too much free magnesia or hard-burned free lime.
Setting time
The setting and hardening of a cement is a continuous process, but two points are
distinguished for test purposes. The initial setting time is the interval between the
mixing of the cement with water and the time when the mix has lost plasticity, stiffening
to a certain degree. It marks roughly the end of the period when the wet mix can be
molded into shape. The final setting time is the point at which the set cement has
acquired a sufficient firmness to resist a certain defined pressure. Most specifications
require an initial minimum setting time at ordinary temperatures of about 45 minutes
and a final setting time no more than 10 to 12 hours.
Strength
The tests that measure the rate at which a cement develops strength are usually made on
a mortar commonly composed of one part cement to three parts sand, by weight, mixed
with a defined quantity of water. Tensile tests on briquettes, shaped like a figure eight
thickened at the centre, were formerly used but have been replaced or supplemented by
compressive tests on cubical specimens or transverse tests on prisms. The American
Society for Testing and Materials (ASTM) specification requires tensile tests on a 1:3
cement-sand mortar and compressive tests on a 1:2.75 mortar. The British Standards
Institution (BSI) gives as alternatives a compressive test on a 1:3 mortar or on
a concrete specimen. An international method issued by the International Organization
for Standardization (ISO) requires a transverse test on a 1:3 cement-sand mortar prism,
followed by a compressive test on the two halves of the prism that remain after it has
been broken in bending. Many European countries have adopted this method. In all
these tests the size grading of the sand, and usually its source, is specified.
In the testing of most cements, a minimum strength at 3 and 7 days and sometimes 28
days is specified, but for rapid-hardening portland cement a test at 1 day also is
sometimes required. For high-alumina cement, tests are required at 1 and 3 days.
Strength requirements laid down in different countries are not directly comparable
because of the differences in test methods. In actual construction, to check the strength
of a concrete, compressive tests are made on cylinders or cubes made from the concrete
being placed.
Frederick M. LeaThe Editors of Encyclopaedia Britannica
Asano Sōichirō
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Asano Sōichirō
Japanese businessman
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Asano Sōichirō, (born 1848, Etchū province, Japan—died 1930, Tokyo), Japanese
businessman who founded the giant Asano zaibatsu, or industrial combine.
Born:
1848 Japan
Died:
The son of a physician, Asano chose a career in business, but his first company failed. In
1871 he became a coal merchant in Tokyo. Five years later he developed methods for
utilizing coke, until then a waste by-product of gas manufacture, in cement production,
and this enterprise prospered. His business acumen interested Shibusawa Eiichi, a
leading figure in Meiji era industrial development, who enabled Asano in 1883 to
acquire a government cement plant being transferred to private ownership free of
charge. It became the Asano Cement Company, cornerstone of the
Asano zaibatsu, which eventually included shipping and shipbuilding, mining, gas and
electricity, oil, iron and steel, and beer brewing. By 1929 it was the fifth-largest such
combine in Japan, with 17 wholly owned companies, 26 subsidiaries, 26 affiliates, and 6
associated concerns. The Allied Occupation authorities broke up the Asano zaibatsu into
separate enterprises in 1947.
portland cement
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portland cement
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portland cement, binding material in the form of a finely ground powder, usually
gray, that is manufactured by burning and grinding a mixture of limestone and clay or
limestone and shale. The inventor Joseph Aspdin, of England, patented the basic
process in 1824, naming it for the resemblance of the cement when set to portland
stone, a limestone from the Isle of Portland. When mixed with water, the anhydrous
calcium silicates and other constituents in the portland cement react chemically with the
water, combining with it (hydration) and decomposing in it (hydrolysis) and hardening
and developing strength. See concrete.
Related Topics:
clinker semidry process hydraulic cement
materials processing
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The cycle of manufacturing processes that converts materials into parts and products
starts immediately after the raw materials are either extracted from minerals or
produced from basic chemicals or natural substances. Metallic raw materials are usually
produced in two steps. First, the crude ore is processed to increase the concentration of
the desired metal; this is called beneficiation. Typical beneficiation processes include
crushing, roasting, magnetic separation, flotation, and leaching. Second, additional
processes such as smelting and alloying are used to produce the metal that is to be
fabricated into parts that are eventually assembled into a product.
In the case of ceramic materials, natural clay is mixed and blended with various silicates
to produce the raw material. Plastic resins are produced by chemical methods in
powder, pellet, putty, or liquid form. Synthetic rubber is also made by chemical
techniques, being produced, as is natural rubber, in such forms as slabs, sheeting, crepe,
and foam for fabricating into finished parts.
The processes used to convert raw materials into finished products perform one or both
of two major functions: first, they form the material into the desired shape; second, they
alter or improve the properties of the material.
Forming and shaping processes may be classified into two broad types—those
performed on the material in a liquid state and those performed on the material in a
solid or plastic condition. The processing of materials in liquid form is commonly known
as casting when it involves metals, glass, and ceramics; it is called molding when applied
to plastics and some other nonmetallic materials. Most casting and molding processes
involve four major steps: (1) making an accurate pattern of the part, (2) making
a mold from the pattern, (3) introducing the liquid into the mold, and (4) removing the
hardened part from the mold. A finishing operation is sometimes needed.
Materials in their solid state are formed into desired shapes by the application of a force
or pressure. The material to be processed can be in a relatively hard and stable condition
and in such forms as bar, sheet, pellet, or powder, or it can be in a soft, plastic, or
puttylike form. Solid materials can be shaped either hot or cold. Processing of metals in
the solid state can be divided into two major stages: first, the raw material in the form of
large ingots or billets is hot-worked, usually by rolling, forging, or extrusion, into
smaller shapes and sizes; second, these shapes are processed into final parts and
products by one or more smaller scale hot or cold forming processes.
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pozzolana
hydraulic cement
Alternate titles: pozzolan, pozzuolana, pulvis puteoli, volcanic-ash cement
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Pozzolana was first found at Puteoli (modern Pozzuoli), near Naples, where there are
still extensive beds, and also around Rome. Natural pozzolana is often composed mainly
of a fine chocolate-red volcanic earth. Industrial, artificial pozzolans are produced in
furnaces where organic materials, such as coal, are burned and the ash is reclaimed. Fly
ash is the most common form of industrial pozzolan.
architecture: Concrete
The Editors of Encyclopaedia BritannicaThis article was most recently revised and updated by Melissa
Petruzzello.
glue
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glue
adhesive
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glue
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Synthetic resin adhesives such as the epoxies are replacing glue for many uses, but glue
is still widely used as an adhesive in woodworking, in the manufacture of such abrasives
as sandpaper, and as a colloid in industrial processes—e.g., the recovery of solid
particles suspended in a liquid.
The Editors of Encyclopaedia BritannicaThis article was most recently revised and updated by Adam
Augustyn.
mortar
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mortar
building material
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BY The Editors of Encyclopaedia Britannica | View Edit History
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Mortar hardens into a stonelike mass and, properly applied, distributes the load of the
structure uniformly over the bonding surfaces and provides a weathertight joint.
Henry J. Kaiser
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Henry J. Kaiser
American industrialist
Alternate titles: Henry John Kaiser
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FAST FACTS
Quotes
Henry J. Kaiser, in full Henry John Kaiser, (born May 9, 1882, Sprout Brook, N.Y.,
U.S.—died Aug. 24, 1967, Honolulu, Hawaii), American industrialist and founder of
more than 100 companies including Kaiser Aluminum, Kaiser Steel, and Kaiser Cement
and Gypsum.
Born:
May 9, 1882 New York
Died:
In 1913 Kaiser was working for a gravel and cement dealer in Washington when one of
his clients, a Canadian road-building company, went out of business. He got a loan to
take over the company’s project and finished it with a profit. From 1914 to 1930, he
built California dams, Mississippi River levees, and highways, including 200 miles of
road and 500 bridges in Cuba, while establishing sand and gravel plants to supply his
own materials. Between 1931 and 1945, he helped organize combinations of construction
companies to build the Hoover, Bonneville, and Grand Coulee dams, as well as other
large projects. To supply the more than 6,000,000 barrels of cement needed for
the Shasta Dam, he erected a cement plant in Permanente, Calif., and a nine-mile
conveyor belt across a mountain to the dam site in 1939.
During World War II he ran seven shipyards that used assembly-line production to
build ships in as little as 4 1/2 days. By the end of the war, his yards had produced 1,490
ships for the U.S. maritime commission. In 1941–42, he built the
only integrated steel mill on the west coast of the United States, to make steel for his
shipyards. He established Kaiser Gypsum in 1944. He bought up aluminum plants from
Alcoa to supply his Kaiser-Frazer automobile business; but, because of
an industry slump, Kaiser stopped making cars in 1953. By then Kaiser Aluminum &
Chemical Corporation had become profitable. From 1954 to 1960, he directed
construction of the Hawaiian Village resort centre, which was sold in 1961 to the Hilton
chain for more than $21,000,000.
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gum
adhesive
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gum arabic
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A gum is produced by making an incision in the bark of the tree and collecting the
exudate repeatedly throughout the season. Gums so obtained consist of small lumps,
usually transparent and light yellow. Trees produce gums by a process called gummosis,
possibly as a protective mechanism, either after mechanical damage to the bark or after
a bacterial, insect, or fungal attack upon it. The Acacia senegal tree yields the greatest
amount of gum acacia when it is in an unhealthy condition, and good culture methods
reduce the yield.
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Substances known as natural gums, which are extracted from their natural sources, also...
Gum arabic is the most widely used of the water-soluble gums. True gum arabic is gum
acacia; that is, it is produced by species of Acacia. Examples of true gum arabic are gum
sudan and gum kordofan, both of which originate in Sudan, and gum senegal, which
comes from Senegal. Gum arabic is also collected in northern Nigeria, Libya, Tunisia,
and Tanzania. The name gum arabic is sometimes also applied to substitutes for gum
acacia, including gum gatti, collected in India.
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putty
adhesive
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putty, cementing material made of whiting (finely powdered calcium carbonate) and
boiled linseed oil. It is beaten or kneaded to the consistency of dough and is used to
secure sheets of glass in sashes, to stop crevices in woodwork, and to fill nail
holes. Whiting putty of a high grade consists of 85 to 90 percent whiting blended with 10
to 15 percent boiled linseed oil. White-lead whiting putty has an admixture of 10
percent white lead, reducing the amount of whiting proportionately. Prepared putty
should roll freely in the hands without exuding oil. Synthetic glazing and
filling compounds have supplanted putty in many applications.
The name putty is also applied to substances resembling putty, such as iron putty, a
mixture of ferric oxide and linseed oil; and red-lead putty, a mixture of red and white
lead and linseed oil. Certain doughlike plastics are also called putty. Putty powder (tin
oxide) is used in polishing glass, granite, and metal.
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