SOAL 1

Diketahui: Dit: dH saat T =150 C

H2Osolid m =1kg = 1000 g
P = 1 atm T1 =
T = -20 C MR = 18 T2 =
Informasi: Cp s = 0.435 cal/g.C T3 =
Cp l = 1.006 cal/g.C T4 =
Cp v = 7.36 +2.64 x 10^-3 cal/gmol.K T5 =
dH fus = 1436.3 cal/gmol T6 =
dH vap = 9717 cal/gmol

Jawab :
dH1 =
=
=

n H2O =

dH2 =
=
=

dH3 = m. Cp l. dT dH4 = n dHfvap

= 1000g x 1.006 x (100-0) = 55.5 mol X 9717 cal/gmol
= 100600 cal = 539833.33333

dH5 = n. Cp l. dT Int Cpv = 7.36T + 1.32 x 10^-3 T^2

= 23363.11111 cal 3349.46628
2928.93028
= 420.536

dHtot = dH1 + dH2 + dH3 + dH4 +dH5 = 752290.88889 cal

SOAL 3
Diketahui:
a + bT + cT2 +dT3 m =300kg/jam
Cp
Gas Bm a b c d x
H2 2.016 6.946 -0.000196 0.6
N2 28.02 6.547 0.001389 0.25
O2 32 6.117 0.003167 0.15

laju panas -32525.01037 kcal/jam

integral Cpmix dt -1411
T1 573
T2 373
23.07692308
saat T =150 C

-20 C
0C
0C
100 C
100 C = 373 k
150 C = 423 k

m .Cp s. dT
1000g x 0.435 x (0-(-20))
8700 cal

55.55555555556 gmol

n dHfus
55.5 mol X 1436.3 cal/gmol
79794.44444444 cal

5 mol X 9717 cal/gmol

cal

6T + 1.32 x 10^-3 T^2

Cpmix
a b c d Bm mix
4.1676 -0.0001176 0 0 1.2096
1.63675 0.00034725 0 0 7.005
0.91755 0.00047505 0 0 4.8
6.7219 0.0007047 13.0146

573 373
t2 0.00035235 115.68672315 49.02210315
t1 6.7219 3851.6487 2507.2687
3967.3354232 2556.290803 -1411.045
 Cp Cp mix
Gas Bm x Bm mix
a b a b
H2 2.016 0.6 6.946 -0.000196 4.1676 -0.000118 1.2096
N2 28.02 0.25 6.547 0.001389 1.63675 0.000347 7.005
O2 32 0.15 6.117 0.003167 0.91755 0.000475 4.8
6.7219 0.000705 13.0146

Gas Bm x Bm mix

H2 2.016 0.6 1.2096

N2 28.02 0.25 7.005
O2 32 0.15 4.8
13.0146