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Chrome ore beneficiation challenges & opportunities – A review

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Minerals Engineering 24 (2011) 375–380

Contents lists available at ScienceDirect

Minerals Engineering
journal homepage: www.elsevier.com/locate/mineng

Chrome ore beneficiation challenges & opportunities – A review


Y. Rama Murthy a,⇑, Sunil Kumar Tripathy a, C. Raghu Kumar b
a
Research and Development Division, Iron and Ferroalloys Research Group, Tata Steel Ltd., Jamshedpur 831 001, India
b
Raw Material Technology Group, Tata Steel Ltd., Jamshedpur 831 001, India

a r t i c l e i n f o a b s t r a c t

Article history: Supply of world chromite (chrome ore) has come under severe pressure over the past year driven by
Received 23 July 2010 strong demand for ferrochrome used in ferroalloy production for making stainless steel. Many of the stra-
Accepted 5 December 2010 tegic minerals are inputs into products in fast-changing markets. This article reviews the major process
Available online 7 January 2011
flow sheets in practice for the recovery of chromite values from various types of ores and critical issues
related to chromite ore beneficiation. The comprehensive condensation of pertinent facts is intended to
Keywords: provide a single reference source rather than the reader perusing many articles. Emphasis is placed on
Chromite ore
different processes developed in identifying and solving critical plant problems.
Chromite deposits
Chromite beneficiation
Ó 2010 Elsevier Ltd. All rights reserved.
Gravity concentration techniques
Multi-gravity separator

Contents

1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 375
2. Sources of chromite . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 376
2.1. World chromite ore scenario . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 376
2.2. Indian chromite ore scenario . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 376
3. Commercial chromite ore beneficiation processes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 377
4. Chromite ore beneficiation practices . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 377
4.1. Process plant/concentrator bottlenecks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 377
5. Review of the research works . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 378
5.1. Reduction in tailing losses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 378
5.2. Beneficiation of low and sub-grade chromite ore . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 378
5.3. Recovery of ultrafine chromite particles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 378
5.4. Reprocessing of stockpiled tailings. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 379
5.5. Achievement of required grade and ratio . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 379
6. Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 379
Acknowledgements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 379
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 379

1. Introduction chrome produced (mainly high-carbon/charge grade). Chromite


varies widely in composition according to the chemical formula
Chromium is one of the modern industry’s essential element (Mg, Fe+2) (Cr, Al, Fe+3)2O4. Chromium occurs as chromium spinel,
and important raw material for the production of special steel a complex mineral containing magnesium, iron, aluminium and
and ferrochrome alloys. Around 90% of mined chromite ore is con- chromium in varying proportions depending upon the deposit. Iron
verted into different grades of ferrochrome by the metallurgical is replaced by magnesium and similarly chromium by ferric iron
industry. Stainless steel industry consumes about 80% of ferro- and aluminium. It is this replacement that improves Cr:Fe ratio
in chromite. Chromium ore occurs exclusively in ultramafic igne-
ous rocks. Commercial chromite deposits are found in two forms
⇑ Corresponding author. Tel.: +91 9204058852. stratiform seams and irregular podiform/lenticular deposits. With
E-mail address: yrama.murthy@tatasteel.com (Y.R. Murthy). the richness of silica and iron, chromite ore deposit can be

0892-6875/$ - see front matter Ó 2010 Elsevier Ltd. All rights reserved.
doi:10.1016/j.mineng.2010.12.001
Author's personal copy

376 Y.R. Murthy et al. / Minerals Engineering 24 (2011) 375–380

classified as siliceous type (silica rich) and ferruginous type (iron its with reserves of about 140 million tonnes and resources of 1 bil-
rich). Major associated gangue minerals are talc, quartz, hematite, lion tonnes. Kazakhstan has podiform deposits in the Southern Ural
goethite, limonite, gabbro, serpentine, anorthosite, dunite, and Mountain region with reserves of 320 million tonnes. The ores vary
pyroxinite. Most of the chromite reserves in the world are concen- greatly in chromium content and in Cr:Fe ratios. India’s output is
trated in Africa and Asia followed by Europe, Australia and Brazil. from podiform bodies on the east coast of the Orissa state. Its re-
serves are put at 27 million tonnes with a further resource of
2. Sources of chromite 67 million tonnes. In Brazil, production is concentrated in Bahia
and Minas Gerais. These are mainly stratiform deposits with re-
Chromium ore occurs exclusively in rocks formed by the intru- serves of 14 million tonnes and resources of 17 million tonnes. Chi-
sion and solidification of molten lava or magma which is very rich na’s chromium resources are in podiform and stratiform deposits
in the heavy, iron containing minerals such as pyroxenes and oli- but are largely unknown in terms of possible reserves and re-
vines. The chromium spinel is a heavy mineral and it concentrates sources. In the year 2008, world chromite ore production was
through gravity separation from most of the other molten material 24 million tonnes against 22 million tonnes in the year 2007. The
in the magma during crystallization from the cooling magma. following breakdown is shown in Fig. 1a and the world chromite
Commercial chromite deposits are found mainly in two forms and ferrochrome production (2002–2008) is presented in Fig. 1b.
namely stratiform and podiform. Within the total volume of ore and concentrates produced in
2008, 95% were metallurgical grade, 2% chemical grade and the
 Stratiform seams in basin-like intrusions, often multiple seams balance of 3% were refractory and foundry grade.
through repeated igneous injections. The best known example
of a stratiform deposit is the Bushveld Igneous Complex of 2.2. Indian chromite ore scenario
South Africa. This complex contains most of the world’s chro-
mite reserves. Other stratiform deposits occur in Madagascar Chromite deposits occur in several Indian states like Tamilnadu,
and in the Orissa state of India. Goa, Karnataka, Maharashtra and Orissa in the form of discontinu-
 The podiform deposits are relatively small in comparison. They ous bands, lenses and pockets in different host rock associations.
are generally richer in chromium than the stratiform deposits Though insignificant in the context of world resources, India is en-
and have higher Cr:Fe ratios. Ore reserves in Kazakhstan are dowed with appreciable quantities of good grade chrome ores.
of the podiform type. Podiform ores were originally highly Around 90% of the chromite resources of India are concentrated
sought after, as the best source of metallurgical grade chromite in Sukinda valley of Jajpur district and Boula-Nuasahi belt of Orissa
for high-carbon ferrochromium. These ores also tend to be mas- state. The Indian deposits are typically characterized as ferruginous
sive (hard lumpy), as opposed to the softer, more friable ores and siliceous type ores. The ores of Sukinda valley are mostly high
from the stratiform deposits. grade, soft and friable in nature besides few quantities of hard lum-
 There is a third type of chromite deposit but of very limited py ore, formed in separate bands. These are mainly associated with
commercial significance. These are the eluvial deposits that laterite, altered ultramafic rock, nickeliferrous limonite, goethite
have been formed by weathering of chromite-bearing rock and talc serpentine schist. Based on physical characteristics, Orissa
and release of the chromite spinels with subsequent gravity chrome ores are broadly classified as:
concentration by flowing water.
 Lumpy and granular: This type of ore is hard, compact, medium
2.1. World chromite ore scenario to fine grained.
 Friable ore: This is soft, powdery in nature, mostly of high grade
The major chromite ore and concentrates producing countries (Cr2O3 > 50%) with very small gangue minerals and is the bulk
are South Africa, India and Kazakhstan, representing 70% of 2008 constituent of all brown ore horizons in Sukinda Belt.
world production as a whole. South Africa and Zimbabwe hold  Ferruginous ore: Considerable portion of ore bodies in the
about 90% of the world’s chromite reserves and resources, with Sukinda belt and Boula-Nuasahi complex are lateritised giving
South Africa having reserves of about 3.1 billion tonnes. Zimbabwe rise to ferruginous chrome ore where goethite and to some
is the only country to exploit both stratiform and podiform depos- extent hematite form the gangue minerals.

Fig. 1. (a) World chromite ore production. (b) World chromite and ferrochrome production (2002–2008).
Author's personal copy

Y.R. Murthy et al. / Minerals Engineering 24 (2011) 375–380 377

 Banded ore: This type of ore is generally encountered in the comminution (for preparing the material to the subsequent unit
wall rock of chromite bands. operations) and concentration. The feed preparation unit incorpo-
 Disseminated ore: In this type of ore serpentine is distributed as rates screening of the ROM ore to 75 mm from 220 mm followed
white spots called ‘‘spotted ore’’. Both banded and disseminated by two stage crushing (primary and secondary crusher) and
ores are lower in Cr2O3. screening to produce less than 3 mm size fraction. This fraction is
further ground to less than 1 mm and then upgraded utilizing con-
3. Commercial chromite ore beneficiation processes ventional gravity techniques like spiral concentrator and shaking
table in the concentration section. Though gravity techniques are
Pure chromium is difficult to produce since it is readily contam- well established and widely accepted for the concentration of chro-
inated by many other elements. Huge quantity of raw chromite ore mite ore, such techniques become inefficient and complex while
is being mined and beneficiated in various chrome ore beneficia- treating fine size particles (less than 75 lm). Recovery is a concern
tion plants throughout the world to cater the customized needs particularly in finely disseminated ores due to its inherent com-
of various ferro alloy plants. During mining and processing opera- plexities. Each gravity separation technique delivers its maximum
tions enormous quantities of fines are generated, which are of ma- efficiency under specific operating conditions and particle size
jor concern from handling, storage and environmental point of range.
view. It was reported that more than 25% of the mineral value is Although literature on the performance of individual concentra-
lost as slimes during the processing of many ores. The importance tors are available but detailed information on the separator perfor-
of utility of these vast accumulated fines has engaged many R&D mance with respect to size and liberation of particle is scarce. A
organizations to recover chromite values from these rejected tail- comparison of the peak efficiencies cannot be made based on the
ings. In the last two decades, many processes for the recovery of effect of operating conditions alone. The research works of Pascoe
chromite values have been claimed and reported in the form of et al. (2007) shows that it is possible to make a sensible selection of
technical reports, papers and reviews (Gu and Wills, 1988; Guney, gravity separation from information on particle size and the miner-
1990; Guney et al., 1991, 1992, 1993, 1994; Guney, 1995; Atalay alogy of the ore. Recovery of ultrafine particles below 75 lm size
and Ozbayoglu, 1992; Cicek and Cocen, 2002; Ozdag, 1993; Ozdag from process tailings by flotation technique is the subject of recent
et al., 1994; Ucbas and Ozdag, 1994; Cicek et al., 1998; Sönmez and investigations. Since most chromite ores are easily beneficiated
Turgut, 1998; Gence, 1999). To economically recover these lower- with gravity concentration methods, flotation of chromite has not
grade deposits, separation circuits must be optimized. The present been widely applied or got commercial acceptance (Atalay and
article is a comprehensive review of all the research investigations Ozbayoglu, 1992). This is the most essential issue of every gravity
carried out by various researchers to form a data base for the chro- separation circuit in mineral processing plants, which causes loss
mite waste processing. This paper describes established industrial of large fraction of the valuable minerals into tailings.
processes for recovery of chromite from sources such as raw ore.
4.1. Process plant/concentrator bottlenecks
4. Chromite ore beneficiation practices
Due to inconsistent feed quality the efficiency of existing bene-
The purpose of beneficiation is to render the ore concentrate ficiation circuits are going down thereby losing a considerable
physically (granulometry) and chemically suitable for subsequent quantity of values as wastes. Further, the process circuit has to bear
treatments. Beneficiation practices depend on the mineral charac- the load of unwanted fines throughout the circuit, which not only
teristics of the ore deposits, gangue mineral assemblage and the affects the quality of the product but also results in the loss of con-
degree of dissemination of constituent minerals. In general siderable quantity of values into tailings. From the mineral conser-
chromite beneficiation flow sheet (Fig. 2) has two major sections: vation point of view it is now obligatory to use the high grade

Fig. 2. General process flow sheet for chromite ore beneficiation.


Author's personal copy

378 Y.R. Murthy et al. / Minerals Engineering 24 (2011) 375–380

resource judicially along with the high grade tailings, which were grade ore consumption. This necessitates development of high
generated and deposited in the tailing dams in due course of time. capacity processing plants with new technological unit operations.
Generation of consistent quality of product by optimizing the Rao et al. (1987), depicted that, low grade chrome ore with Cr2O3 of
existing flow sheet as well as development of new process flow about 20–30% of Sukinda region of India, can be beneficiated to a
sheet for the utilization of tailings is another big challenge for marketable grade of 45% Cr2O3 with 45% recovery, by grinding
the process engineers. The present article reviews all those re- the chrome ore (d80 passing size 260 lm) and desliming the same
search works that have been done, outlines the approaches that using hydrocyclone and by treating the under flow on sand table
have been taken and indicates the considerable success that has and the overflow on slime table. On the other hand, the same
been achieved. The discussion concentrates on the process flow ground sample after desliming followed by classification and ta-
sheets which have been developed to ease the solving of problems bling can produce a concentrate of 53% Cr2O3 with 56% recovery
in the Indian chromite ore beneficiation plants. Emphasis is placed or alternatively 45% Cr2O3 with 73% recovery and tailing loss of
on different processes developed in identifying and solving those 10% Cr2O3. (Rao et al., 1987), shows that low grade chromite ore
problems, and analysis of the data generated by the researchers. with Cr2O3 of about 20–30% of Sukinda region of India, can be up-
graded to a marketable chrome concentrate of 50% Cr2O3 with a
5. Review of the research works metal recovery of about 70% by using spirals and tables in the cir-
cuit. Research work of Tevfik Agacayk et al. on low grade chromite
The critical issues related to the chromite process plants inves- ores of abandoned mines in Turkey (average grade 20–40% Cr2O3)
tigated by various researchers have been categorized as: shows that best grades for Cr2O3 can be achieved by using shaking
table (55.65%), 57.52% by multi-gravity separator, 54.58% by Hum-
5.1. Reducing the tailing losses (9–20% Cr2O3). prey spiral test and 50.68% by jigging. All the unit operations were
5.2. Beneficiation of low and sub-grade chromite ore (10–30% operated individually rather than a flow sheet. Sub-grade chromite
Cr2O3). ore with Cr2O3 of about 38.5% of Sukinda region of India, can be up-
5.3. Recovery of unrecoverable ultrafine chrome particles. graded to a marketable chrome concentrate of 53–54% Cr2O3 with
5.4. Reprocessing of stockpiled tailings containing valuables. a recovery of about 58–60% and tailing loss of around 14–16.39% of
5.5. Concentrate with required Cr2O3 content and Cr/Fe ratio. Cr2O3, by using wet shaking tables in the circuit (Banerjee et al.,
2005). Based on the findings of experiments researchers developed
5.1. Reduction in tailing losses two process routes for beneficiating two different size fractions.
Considering the tailing disposal problems of chromite gravity
The critical area of concern in any chrome ore beneficiation plants, the research works carried out by Amer and Ibrahim
plant is the grinding circuit followed by beneficiation circuit com- (1996) on hydrometallurgical processing of low grade chromite
prising gravity units such as wet shaking tables and spirals. The ore (Barramiya, Egypt), with a new technique using mechanical
effectiveness of grinding circuit depends on the consistent feed alkaline treatment in an attritor followed by oxidative leaching
quality. Any variation in feed reduces the performance of the sub- in an autoclave reveals that even a short processing time in stirred
sequent unit operations. Such variations in feed/ore characteristics ball mill (25 min) leads to extraction P90% of chromium in the
reduce the efficiency of the beneficiation circuits resulting in the form of chromate in only one leaching stage.
loss of fine values into tailings. Recovery of the valuable minerals The beneficiation studies of Suresh et al. (1981), concludes that
contained in fine particles is a complex problem in mineral pro- low grade chromite ore of 16–25% Cr2O3, of Sitampundi area of In-
cessing and particularly in gravity separation. With decreasing par- dia, cannot be upgraded by using tabling and flotation techniques,
ticle size (<100 lm), the force associated with the water flow to meet the metallurgical grade due to the intimate association of
becomes dominant over that associated with gravity. With conven- iron in the lattice of chromite. But can be upgraded to meet the
tional methods depending on the liberation particle size of the ore, refractory grade of 30–40% Cr2O3, by using gravity methods.
significant amounts of fine chromites are lost to the tailings. For
this reason, all of the methods are only partly successful in the fine 5.3. Recovery of ultrafine chromite particles
particle size range (Gence, 1999). Mozley multi-gravity separator
(MGS) can be used with success for reducing fine chromite losses Large amounts of fine sized chromite tailings naturally occur
in the gravity tailings of Turkish chromite gravity plants, based during production and processing, and this causes severe environ-
on the fact that 105 lm fraction amounts to 8–46.4% of the total, mental hazards as well as source losses due to the high chromite
with a Cr2O3 content of about 10–21% Cicek et al. (1998, 2000, content. There have been numerous research studies (Guney,
2002). Typical chromite recovery values using the MGS can be 1990; Guney et al., 1991, 1992, 1993; Guney, 1994; Ozdag, 1993;
about 65–80%. Preliminary economical evaluations shows that Ozdag et al., 1994; Ucbas and Ozdag, 1994; Gui et al., 1995; Cicek
MGS chromite fines recovery units have pay back times of less than et al., 1998; Sönmez and Turgut, 1998; Gence, 1999), on the bene-
one year. Based on the results, they developed a flow sheet. The ficiation of the tailings in recent years. Generally, after crushing
grinding circuit efficiency fluctuates due to the variation in ore and grinding, spirals and shaking tables are used as the concentra-
characteristics, resulting in an inefficient separation, with a loss tors, therefore fine size chromite particles ( 0.038 lm) are re-
of fine chromite into tailing. In order to recover the same flotation moved as tailings (Guney et al., 2001). The beneficiation of the
is the only alternative method. Numerous references are listed in valuable minerals contained in fine particles is a complicated prob-
the literature to float chromite with cationic and anionic collectors lem in mineral processing and particularly in gravity separation.
(Atak, 1982; Atalay et al., 1989; Foot et al., 1986; Guney et al., The fines below 100 lm are generally discarded as gangue from
1991, 1993). Based on this fact, the research work of Sysila et al. gravity concentration processes which ultimately reports to tailing
(1996), shows that by treating slime feed in flotation the tailing through process water stream. To recover these fines, investigation
losses can be reduced to 1.2–10% Cr2O3. results of Feng and Aldrich (2004) on the Western Chromite Mines
in South Africa, shows that maximum 95.6% of chromite fines can
5.2. Beneficiation of low and sub-grade chromite ore be recovered by using column flotation with the optimum condi-
tions of parameters. Flotation recovery of many minerals decreases
From the mineral conservation point of view it is necessary to as the particle size decreases. Based on this fact, the studies of
maximize the utilization of lean grade ore and minimize the high Akdemir and Hiçyilmaz (1996), reveals that shear flocculation of
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Y.R. Murthy et al. / Minerals Engineering 24 (2011) 375–380 379

chromite is possible in aqueous solution of sodium oleate to re- ing a strategy for economic and efficient process/process flow
cover the ultrafine (<10 lm) chromite particles. sheet for the recovery of chromite from the lean/sub-grade ores
and tailings. Though high quality of research works have been car-
5.4. Reprocessing of stockpiled tailings ried out by various researchers in the beneficiation of low/sub-
grade chromite ores, the focus towards the recovery of chromite
The high value of chromite in the tailings of gravity chromite values from fine, ultrafine and tailings has to be widened. The
concentration plants has been reported by many investigators. application of enhanced gravity concentrators (MGS) and floata-
During the earlier concentration of valuable minerals in many tion columns have found wide acceptance at various beneficiation
plants, large volumes of tailings were produced and these tailings plant flow sheets of Turkey for the recovery of fine and ultrafine
_
may be harmful to the environment Ozkan and Ipekoğlu (2002). chromite. For the beneficiation of Indian chrome ore these unit
Recovery of values from these tailings of gravity concentration operations yet to be established. The detailed study of chromite
plants is one of the challenging issues for the process engineers. ore beneficiation processes reveals that the opportunities still exist
A number of research investigations were carried out to determine to recover chromite values from the low/sub-grade ores and tail-
the most economic process applicable and flow sheets were devel- ings using the conventional beneficiation processes. Following con-
oped to address the same problem. clusions were drawn from the research work carried out:
The research work of Cicek et al., evidenced that the fine chro-
mite particles can be recovered from the stockpiled tailings of  By considering the aspects of conservation of mineral resources,
Turkish chromite gravity plants with a Cr2O3 of about 8–14.4%. western researchers are now using the techniques to recover
By treating the same in a new process circuit which invariably con- even the traces of ultrafine chromite particles that are reporting
sists of multi-gravity separator (MGS) as the major fine gravity to the tailing.
concentrator, chrome concentrate of around 48% of Cr2O3 with a  From the review it can be observed that the research work on
recovery of 51.6% can be achieved. Guney et al., illustrate that by tailing losses and ultrafine recovery of chrome ore need more
introducing shaking table for 1 + 0.1 mm size fraction and high- focus in the Indian context. In order to solve the major problems
intensity wet magnetic separator (HIWMS) and column flotation that are incorporated with Indian chromite ore beneficiation
for treating 0.1 mm size fraction, fine chrome particles that are plants, following aspects deserve further attention, and have
present in the gravity tailings of Turkish chromite gravity plants, been identified on the basis of the literature survey:
chrome concentrate of 45–48% Cr2O3 and a tailing loss of below  The ores invariably contains some amount of natural fines,
7% Cr2O3 with a overall plant recovery of 60–65%, can be recovered desliming the same before processing shows high tailing
with success, based on the fact that 83% of the chromite exist in loss.
0.1 mm fraction with a Cr2O3 content of about 20–22.11%.  The investigations that have been carried out by various
The research work of Bhima Rao et al., shows that tailings of researchers are highly appreciable but still the process flow
chromite gravity plants of Sukinda region of India, which invari- sheets are not completely acceptable since high tailing losses
ably contains 11.7% Cr2O3, can be beneficiated to produce a chrome are associated with the same as far as the production of
concentrate of 46% Cr2O3 content with a recovery of 38%, by using a required quality of concentrate is concerned.
combination of Bartles Mozley (BM) table and cross belt separator.  From the literature it is evident that low grade chrome ore of
Mohan Rao et al. (2006), concludes that incorporation of addi- both ferruginous and siliceous type gets complete liberation
tional circuit in the chromite gravity plant comprising of hydrocy- at the size below 212 lm and shaking tables that are being
clone for desliming and two stage multi-gravity separators can used in the chromite ore beneficiation plants are inefficient
produce marketable grade concentrate with an increased chromite in separating chrome particle below 72 lm.
recovery of 85% from the original recoveries of 70%. The tailings so  Wet shaking table and multi-gravity separator play a key
produced will analyse <12% Cr2O3. If Cr/Fe ratio required is >1.6, it role in unit operations apart from hydrocyclone and spirals
is essential to add magnetic separation to the circuit additionally. in the processing of chromite fines of Turkey.
 These unit operations are yet to be established for benefici-
ation of Indian chromite ore fines on an industrial scale.
5.5. Achievement of required grade and ratio

To achieve a consistent concentrate production of 50–52% Cr2O3 Acknowledgements


content and 2.8 Cr/Fe ratio with a recovery of 38%, from a feed
grade containing 25% Cr2O3 and 0.8–1 Cr/Fe, a combination of The authors are thankful to Tata Steel management and Dr. D.
shaking table and WHIMS can be used Murthy et al., (1994). The Bhattacharjee, Director RD&T for their encouragement, support
investigations carried out by Bhima Rao et al. (1997), reveals that and permission to publish the paper. Thanks are also due to Prof.
Cr/Fe ratio of off-grade chromite samples of Orissa, India, can be T.C. Rao for his guidance and discussion.
improved to 1.85–3.0 with a recovery around 10–30%, by high-
intensity magnetic separation of the washed ores. Based on their References
result, they have developed a new process flow sheet. Magnetic
separation studies carried out by Abubakre et al. (2007) on Ankha Abubakre, O.K., Muriana, R.A., Nwokike, P.N., 2007. Characterization and
beneficiation of Anka chromite ore using magnetic separation process. Journal
chromite ore shows that the Cr2O3 content has increased to 48% of Minerals & Materials Characterization & Engineering 6 (2), 143–150.
from 36.84% with a maximum Cr:Fe ratio of 6.2:1. Akdemir, Ü., Hiçyilmaz, C., 1996. Shear flocculation of chromite fines in sodium
oleate solutions. Colloids and Surfaces A: Physicochemical and Engineering
Aspects 110 (1), 87–93.
6. Conclusion Amer, M., Ibrahim, I.A., 1996. Leaching of a low grade Egyptian chromite ore.
Hydrometallurgy 43 (1–3), 307–316.
Atak, S., 1982. Beneficiation of chromite by flotation. Doga 6, 1–6 (in Turkish).
The recovery of fine chromite values from tailings has been the Atalay, U., Ozbayoglu, G., 1992. Beneficiation and agglomeration of chromite–its
subject of recent investigations. For sustainability of high grade application in Turkey. Mineral Processing and Extractive Metallurgy Review 9,
chromite resources and to satisfy the continuous demand in the fu- 185–194.
Atalay, M.U., Ozbayoglu, G. and Dogan, M.Z., 1989. Mechanism of collector
ture needs, beneficiation of lean/sub-grade ores as well as tailings adsorption in chromite flotation. In: Aytekin, Y. (Ed.), Proceedings of II
is imperative. This challenge has given rise to the need for develop- International Mineral Processing Symposium, Izmir, Turkey, pp. 441–449.
Author's personal copy

380 Y.R. Murthy et al. / Minerals Engineering 24 (2011) 375–380

Banerjee, T.H., Sengupta, A.K., Gundewar, Amanullah, C.S., 2005. Proposed modified China, http://www.icdachromium.com/chromium-mining.php-international.
process flow-sheet for augmenting the throughput capacity of Chrome ore chromitedevelopmentassociation.
beneficiation plant of M/s TISCO, Sukinda, Orissa. In: International Conference Guney, A., Onal, G., Dogan, M.Z. and Çelik, M.S., 1993. Mechanism of anionic
on Mineral Processing Technology MPT-2005. Bombay, pp. 623–631. collector adsorption in chromite flotation. In: Proceedings of XVIII International
Cicek, T., Cocen, I., 2002. Applicability of Mozley gravity separator (MGS) to fine Mineral Congress, vol. 4. Sydney, Australia, pp. 937–940.
chromite tailings of Turkish chromite concentrating plants. Minerals Guney, A., Onal, G., Atmaca, T., 2001. New aspect of chromite gravity tailings re-
Engineering 15, 91–93. processing. Minerals Engineering 14, 1527–1530.
Cicek, T., Cocen, I., Birlik, M., 2000. Applicability of multi-gravity separation to kop Mohan Rao, S., Chandrakala, K., Gajanan, K., Nath, G., Rao, N.D., 2006. Recovery of
chromite concentration plant. In: Mineral Processing on the Verge of the 21th Chromite Values from Chrome Ore Beneficiation Plant Tailings. Tata Search,
Century, Balkema, Rotterdam. Proceedings of 8th International Mineral Tata Steel Limited, pp. 59–64.
Processing Symposium, Antalya, pp. 87–92. Murthy, Ch.V.G.K., Sripriya, R., Rao, P.V.T., 1994. Enrichment of Cr/Fe ratio in
Cicek, T., Cocen, I., Samani, S., 1998. Gravimetric concentration of fine chromite chromite concentrate produced in chromite beneficiation plant at Tata Steel.
tailings. In: Innovations in Mineral and Coal Processing, Balkema, Rotterdam. Transactions of the Indian Institute of Metals 47 (6), 413–416.
Proceedings of 7th International Mineral Processing Symposium, Istanbul, pp. Ozdag, H., et al., 1993. Enrichment of chromite ore by means of multi-gravity
731–736. separator, Yerbilimleri Dergisi (Geosound), No: 23. Çukurova University, Adana,
Feng, D., Aldrich, C., 2004. Recovery of chromite fines from wastewater streams by Turkey.
column flotation. Hydrometallurgy 72 (3–4), 319–325. Ozdag, H., Ucbas, Y., Koca, S., 1994. Recovery of chromite from slime and table
Foot, D.G., MacKay, J.D., Huiatt, J.L., 1986. Column flotation of chromite and fluorite tailings by multi gravity seperator. In: Innovations in Mineral Processing.
ores. Canadian Metallurgical Quarterly 25, 15–21. Sudbury, Canada, pp. 267.
Gence, N., 1999. Beneficiation of elazig-kefdag chromite by multi-gravity separator, _
Özkan, S., Ipekoğlu, B., 2002. Investigation of environmental impacts of tailings
Tr. Journal of Engineering and Environmental Sciences 23, 473–475. dams. Enviromental Management and Health 13, 242–248.
Gu, F., Wills, B.A., 1988. Chromite–mineralogy and processing. Minerals Engineering Pascoe, R.D., Power, M.R., Simpson, B., 2007. QEMSCAN analysis as a tool for
1 (3), 235–240. improved understanding of gravity separator performance. Minerals
Güi, A., Yüce, E., Güney, A., Gürkan, V., Arslan, F., Önal, G., 1995. Evaluation of low Engineering 20, 487–49520.
grade chromite ores from Adana-Karsanti region. In: The 14th Turkish Mining Rao, R.B., Reddy, P.S.R., Prakash, S., Ansari, M.I., 1987. Recovery of chromite values
Congress, Chamber of Mining Engineers of Turkey. from chromite ore beneficiation plant tailings. Transactions of the IIM 40 (3),
Guney, A., 1990. Concentration of fine sized chromite from the wastes of Etibank 203–206.
Uckopru chromite concentration plant. Ph.D. Thesis, Istanbul Technical Sönmez, E., Turgut, B., 1998. Enrichment of low-grade Karaburhan chromite ores by
University, Istanbul, Turkey. gravitational methods. In: Atak, S., Onal, G., Celik, T. (Eds.), Innovation in
Guney, A. et al., 1994. Flotation of fine chromite tailings using novel techniques. In: Mineral and Coal Processing. Balkema, Rotterdam, The Netherlands, pp. 723–
Demirel, H., Ersayin, S. (Eds.), Progress in Mineral Processing Technology. 726.
Balkema, Rotterdam, The Netherlands, pp. 473–477. Suresh et al., 1981. Unpublished report on chromite beneficiation.
Guney, A., Dogan, M.Z., Onal, G., 1991. Beneficiation of Etibank UqkpriJ chromite Sysila, S., Laapas, H., Heiskanen, K., Ruokonen, E., 1996. The effect of surface
tailings by column flotation. In: Proceedings of Column Flotation Symposium. potential on the flotation of chromite. Minerals Engineering 9 (5), 519–525.
Sudbury, Canada, pp. 211–219. Ucbas, V., Ozdag, H. 1994. Relationships between shake frequency and amplitude in
Guney, A., et al., 1992. Concentration of chromite gravity tailings by free jet type the concentration of chromite fines by multi-gravity separator. In: Demirel, H.,
and column flotation system. In: Proceedings of the First International Ersayin, S. (Eds.), Progress in Mineral Processing Technology. Balkema,
Conference on Modem Process Mineralogy and Mineral Processing. Beijing, Rotterdam, The Netherlands, pp. 71–76.

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