" *"

@ jbrennerfisics ORGO NOTES

( organic chemistry 1)
Hey !
I hope these notes help a bit .

its hard to take others notes since Remember Best WAYS to learn
argo
all classes teach different
things .

I tried to create -

breathe
some sheets where it
focuses on the MOST IMPORTANT
dont just look at notes WRITE it out
'

ideas / things you need for ,

MCAT Isometimes more than once )

( red star of these
pages/ * top right
in corner
try to make with the
-

how
maps reagents and
I also
they come
together Important for synthesis)
putting random notes on
pages) -

make a sheet of notes for

your exceptions
* key after teach SM/El
they
-

SNZIEZ you jump into

alllll the different rims
its
important to keep
-

reminding yourself of a
couple things when you
do these
new rxs (like aldol, Michael
. . .

)
dsKyarself_
what base
using ? pka ?
-

we

-
what does the reactant look like ?

SNIIEI ? SN215=2 ?
-

proton transfer ?

END NOTE : OR GO is fun -

(i might be crazy but I love it I

just stay on top of it -

ask for help in DISCORD we all want to help

you ! ( Dan Jordie Ashi hi Noah )
, , ,

* if
you find a mistake
please tell me so we can fix it !

XOXO

your dextrose daddy Jackie

love All !
you good luck benzene babes
 Relativeimportanceofcontributingstructures
1. Filled Valence Shell

④ M o o
④
CH ,
-

0 =
C
-

H - CH ,
-

O -

c
-

H
° °
00

1 1
H H
Greater contribution : Lesser :

Both 0 { N have full carbon has

only
valence shells 6 valence e-

2. Maximum Number Covalent Bonds

④ M o o
④
it ,
-

0 =
C
-

H - CH ,
-

O -

c
-

H
O O
O O

l l
H H

Greater contribution :
lesser :

8 covalent bonds 7- covalent bonds

3. least separation of Unlike

charges
①
Co"
• a

: :O :

I
CH } C CH } ←
CH } C CH }
- -
- -

Greater contribution :
lesser :

no
separation of unlike
charges separation unlike
charges

4.
Negative charge on a more Electronegative Atom

:O :-O
Co : :O :⑦
↳ ,
c④ → 42 →
do
CHT
\
}/
"
CHT
\
•

CH } CH , CH CH }

Less Best should not be

drawn

BasicR
1. Avoid breaking single bonds sp
'

2. Never Exceed the octet for row 2 elements •

• -0

3.
✗
keep same framework
lone next door to
Avoid
drawing carbon with opposite charges pair a
pi system

* key
Eanes Carbon { Hydrogen *
-

/ not very reactive

Ites -

I double bond

Alkynes -

I triple bond you got alkynes of problems

1- meth
profane ↳ Hq ~
2- eth

3- prop butane Cytlio N ✗

n butane isobutane
4- but
-

5- pent
pentane Cgtha ~ Ñ ¥
6- hex
pentane isopentane neopentane
7-
kept
h c6Hl4
~ µ
µ
8- oct

9- non

to -

dec

µ
~ C6H14 CnH2n+2 Cyctoalkanes
cyclopropane cydobutane
Ñ Gotta Cntlzn A

~ Clotho Cntlzn -2
cyclopentane cyclohexane

a
( 61-112 ( 61-110
 LUPI *

Substituents -
- - -

parent chain - - - - -

suffix
2,4 -

dimethyl pentane

branching "
"""" " "" "
"""""
in

:*
+ with
principle functional
group
locating functional
group -

ane
-

ene -

yne
3-
ethylhex
-

3- ene

rgv
Alkylsvbstitvants replace suffix -

ane with -

yl

Bromo.ch/oro.Iodo,FluoroJ
CH }
Halogens
*
-

← D.N.M.NU
methyl ethyl propyl butyl pentyl

.±÷i¥
•
10

~
Y•

CH }CH2CH CHZCHCH } y y
-
-

propyl group isopropyl group isobvtyl secbutyl tert-butyl

1- methyl
ethyl

namingwithmultipledovblebonds ortho
xylene
-

in
n
3€ ' ICH }

2
meta
hexadiene
-

xylene
1,3
cyclopropane
-

:÷÷÷÷;÷e*a-÷É¥-
•
I triple
-

hexyne
 * highest priority
opposite side bond
( start from the most
configurationallsome.rs
substituted )
2
point ( E) -

Trans X }
3
121 -

Cis A

4- see
butyl -1,1 dimethyl cyclohexane
-

cis -

3- chlorocyclopentanol 11=-1121314 hexen

-
-
2- ol 4-
isopropyl phenol

ii. ii.
H
Y
-
, ÷x¥: I
Ñdoµ
-

"
"OH
/
'

OH

(E) 7- chloro -

5- ethyl -212,3 -

trim
ethyl
-

3- heptene meta -

isopropyl benzaldehyde
0
Cl

nix
it 1T¥ "

¥
.

trans -3 -

tertbutylcyclohexanol

"

¥90 (E) -3,7 dimethyl octa -2,6 dien 1-01

' -
-
-

IR ) 3,7 -

dimethyl oct -1,6 -

adien -3-01
HOWYVY
OH

%
.
"

8
 Toluene Phenol
Benzyaldehyde Benzoic Acid

É¥ ÉÉ "
EEE "

hottie

Anisole Acetophenone Aniline

Styrene
41-12
" "

Chlorobenzene 1- Bromo -
2- chlorobenzene 3- FluoroToluene

Br

1T¥
' "

EE
1- chloro -

4- nitrobenzene 2- Bromo toluene 2- Bromo phenol

OH

H" É¥→r
I
 Ethernomendature

O ' '

alkyl alkyl ether

- -
R common
R

- or X" nor
ethyl methyl ether tert-butyl methyl ether diethyl ether

"

IPAD
"

alkoxy alkane

°
-
R
larger parent END

The
10¥
'

methoxy ethane 2-
methoxy propane

3
"

EI
l

"
T.in
f
H
"
'
'

Br

12512 butane l ethoxybutane 4- ethoxy I

cyclohexane
- - -
-
-

↳#
O
CH 's

14
OH

3- I butanol
¥6 z

isopropoxy Hzc 5
-

3
-

4- hexane
ethoxy 2-
methyl t
- - -
 Unsaturation
*

SOPBAR =
l2C+2)-lH+X
2

Example =
CYH > Br 12141+212--17+11 = ,

possibles ( constitutional isomers )

✗ ✗
Br ÑBr Br

y .
µ .

y µ .

Br

'"

ftp.r
Br
 Drawings &
Right side left side

☒ ☒
☒ ☒

""

=É*É=#" .

¥¥¥É±☒÷¥¥E☒¥É☒a÷÷ 013
3
① 1
2
'
::¥÷¥
mostequitorial positions

A- 1,3 strain
µ µ
µ

z*→ "
*
" "
 E ←
EH
-899 '

"
LET ←
IIe

l i ke d

" "

Ef -
T
-899
.

'

"
II .
.
=
FI ,

ii "

¥7
'
←
x.
=