Van Laar Equation

P1(sat)= 134.02 mmHg

P2(sat) 182.78 mmHg

Coefic. De Act 1 Coefic. De Act 2

P(mmHg) x1 y1 x2 y2 γ1(exp) γ2(exp)
208.4 0.02 0.145 0.98 0.855 11.273690493956 0.994738851882
239.8 0.095 0.28 0.905 0.72 5.2736826396689 1.043769069358
249.1 0.204 0.332 0.796 0.668 3.0249070229495 1.143690330413
252.3 0.378 0.362 0.622 0.638 1.8028699815 1.4158553023
248.8 0.49 0.384 0.51 0.616 1.4548422562578 1.644115179719
245.7 0.592 0.405 0.408 0.595 1.2542059575618 1.960348506401
237.3 0.702 0.44 0.298 0.56 1.1097973640878 2.439724728669
219.4 0.802 0.507 0.198 0.493 1.034905275239 2.98875062033
196.3 0.88 0.605 0.12 0.395 1.0069858976272 3.535146989094
169.5 0.943 0.747 0.057 0.253 1.0018645228399 4.116107370955
145.6 0.987 0.912 0.013 0.088 1.0038514416711 5.392274865959
0.8

0.7

0.6 f(x) = 0.185717173024979 x

R² = 0.590707853797811
0.5

0.4

0.3

0.2

0.1

0
0 0.2 0.4
 x1*ln(γ1(exp)) x2*ln(γ2(exp)) G(E(/RT RTx1x2/G(E( x1 γ1(cal) γ2(cal)
0.0484494347 -0.005169536 0.0432799 0.45286612398 0.02 7.889732598 1.00121021833111
0.1579592466 0.0387686317 0.19672788 0.43702499486 0.095 5.257989162 1.02604610088651
0.2258035924 0.1068710922 0.33267468 0.48811649192 0.204 3.258387686 1.11524579511221
0.2227855755 0.2162904251 0.439076 0.53547905076 0.378 1.888217368 1.39102139724409
0.1836997651 0.253573201 0.43727297 0.5714965694 0.49 1.485184436 1.67084461583819
0.1340895802 0.2746338849 0.40872347 0.59095212451 0.592 1.266841332 2.01394776164099
0.0731325655 0.2657817946 0.33891436 0.6172532787 0.702 1.124753424 2.50230762840033
0.0275165406 0.2167813786 0.24429792 0.65000962974 0.802 1.04997946 3.08004841525167
0.0061262162 0.1515305855 0.1576568 0.66980935071 0.88 1.017234701 3.63987709357215
0.0017566079 0.0806497505 0.08240636 0.65226762851 0.943 1.003721075 4.1753205491521
0.0037940713 0.0219045755 0.02569865 0.49928698922 0.987 1.000188318 4.59973961617059
0.8

0.7 1/A12=
A12=
0.6 f(x) = 0.185717173024979 x + 0.457544317915232
R² = 0.590707853797811
(A12-A21)/(A21*A12)=
0.5
A21=
0.4

0.3 300

0.2
250
0.1
200
0
0 0.2 0.4 0.6 0.8 1 1.2
150

100

50

0
0 0.1 0.2 0.3 0.4 0.5
 P(cal) x1(cal) y1(cal)
200.488819 0.02749326 0.10548039
236.668531 0.09403927 0.28286056
251.344903 0.19108905 0.35443162
253.800315 0.3630606 0.37689575
253.284224 0.48864039 0.38506846
250.699612 0.59802157 0.40092199
242.11589 0.70672268 0.43705969
224.324342 0.8082281 0.50309313
199.805828 0.88669191 0.60043404
170.351543 0.94598449 0.74464329
143.232276 0.9745056 0.923693

0.4575
2.18579235

0.1857
1.55472637

x1
y1
x1(cal)
y1(cal)

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1