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http://dx.doi.org/10.15242/ IJRCMCE.E1113542 41
Int'l Journal of Research in Chemical, Metallurgical and Civil Engg. (IJRCMCE) Vol. 1, Issue 1(2014) ISSN 2349-1442 EISSN 2349-1450
combustion engines [10]. The oil may be used directly as a the present. One major reason for the decline is a lower
fuel, added to petroleum refinery stocks, upgraded using demand due to relatively high sulphur content compared
catalysts to a premium grade fuel or used as a chemical alternatives. On this basis, the relative price for HFO is at
feedstock [11]. The gases from tyre pyrolysis are typically $ 0.516/liter excluding transportation costs [3]. This is 60%
composed of C1–C4 hydrocarbons and hydrogen with a high cheaper than commercial diesel and can be sold at much lower
calorific value, of sufficient energy content to act as fuel to price since there is currently no regulations and levies applied
provide the heat for the pyrolysis process [12]. The solid char on this fuel.
consists of the carbon black filler and also char [13]. The Research has shown that crude tyre derived oil cannot be
liquid and gaseous fractions obtained are a valuable fuel used as an alternative fuel in diesel engines without further
source; while the solid fraction (char) has the recovery purifications [19]. Murugan et al., 2008 [10] investigated
potential of low- grade carbon black or as carbon adsorbent combustion of pure crude tyre derived fuel and its blend with
after applying an activation step [14]. The uncondensed diesel in diesel engines. It was observed that pure tyre derived
gaseous fraction has almost similar properties to synthesis gas fuel cannot be used in these engines as an alternative fuel
as described by Bajus and Olahova, 2011[15] in Table I. unless it is blended with commercial diesel up to 40% vol. The
These gases can be used as a direct fuel in commercial gas engine operates efficiently besides the high level of sulphur
burners or to run fork lift engines. Special attention has been oxides emissions reported due to the fuel quality. An average
given to the liquid fraction, highlighting its properties as of 0.23% by volume in sulphur oxide and other emissions were
alternative fuel in compression ignition engines [16]. recorded in the engine exhaust emission fuelled with diesel-
tyre derived fuel blend [10].
TABLE I This is significantly high and will pose a serious
TYPICAL TYRE PYROLYSIS GAS COMPOSITION [15]
environmental challenge if the fuel blend is used in diesel
Component Concentration (vol. %) operated vehicles. For this reason, it will be beneficial to use
CO Carbon monoxide 47.42 this fuel blend in stationary engines such as diesel generator
CH4 Methane 10.70 sets where the resulting emissions can be contained and
C3H6 Propene 7.80 chemically treated into value added products. The flue gas
C4H8 1-Butene 7.20 emissions resulting from combustion of HFO-diesel blends and
C2H6 Ethane 6.70 gas-oil in the generator set and reactor heating source are
CO2 Carbon dioxide 6.50 contained and scrubbed through a gas absorption tower using
sodium hydroxide solution [20].
C3H8 Propane 5.70
Table II shows typical flue gas composition from
C2H4 Ethylene 4.50
combustion of Heavy Fuel Oil (HFO) to prevent further air
C4H6 1,3-Butadiene 1.78
pollution carbon dioxide can be reacted with sodium
C4H10 n-Butane 1.70
hydroxide to form water and sodium carbonate as shown in
Molecular Mass(g/mol) 32.9 (1). Due to reaction kinetics favoring sodium carbonate
Latent Heat of Vaporization(kJ/kg) 348.6 formation in the presence of sulphur dioxide, sodium sulfite is
Calorific Value(kJ/m3) 37,000 formed as a final stable product (2)
Gas density (kg/m3) 1.40 TABLE II
Constant Pressure Heat capacity(kJ/kg.K) 1.3 FLUE GAS EMISSIONS FROM COMBUSTION OF WASTE TYRE DERIVED FUEL[21]
Concentration Emission level
Component (vol. %) (g/kWh)
The main options used for treating waste tyres are through
the use of tyres as fuel in cement kilns. Other energy recovery Suplher Dioxide (SO2) 0.23% 8.0
options for tyres include use in power plants and co- Carbon Dioxide (CO2) 12.5% 296
incineration [17]. A large portion of tyres are used in material Nitrogen Oxides (NOx) 0.003% 0.08
recovery options such as crumb products for the production of Hydrocarbons(HC) 0.02% 0.18
rubberised flooring in sports fields and playgrounds, paving Carbon Monoxide (CO) 0.01% 0.15
block and other rubber application. A significant proportion of
Moisture (H2O) 10.1% 98
the waste tyres are used in civil engineering applications such
as road and rail foundations and embankments [18]. Nitrogen (N2) 73.6% 1110
The total consumption of Heavy Fuel Oil (HFO) in South Oxygen (O2) 3.5% 60
Africa was 470 million litres in 2007. Recent data is no longer
published due to competition-related concerns. HFO is the 2 NaOH + CO2 → Na2CO3 + H2O 1
lowest cost liquid fuel, and prices are usually determined on a The initial combination generates sodium-bisulfite
negotiated basis. There are no price regulations for HFO. (NaHSO3), which is converted to the sulfite by reaction with
Globally, the value of HFO has reduced from around the same sodium hydroxide or sodium carbonate [22]. The overall
cost as brent crude oil to around 70% of the brent oil price at reaction is:
http://dx.doi.org/10.15242/ IJRCMCE.E1113542 42
Int'l Journal of Research in Chemical, Metallurgical and Civil Engg. (IJRCMCE) Vol. 1, Issue 1(2014) ISSN 2349-1442 EISSN 2349-1450
http://dx.doi.org/10.15242/ IJRCMCE.E1113542 43
Int'l Journal of Research in Chemical, Metallurgical and Civil Engg. (IJRCMCE) Vol. 1, Issue 1(2014) ISSN 2349-1442 EISSN 2349-1450
TABLE IV
WASTE TYRE TREATMENT PYROLYSIS PLANT COSTING
Description Cost US $
Tyre shredder
Diesel Generator Set
Weigh Bridge
http://dx.doi.org/10.15242/ IJRCMCE.E1113542 44
Int'l Journal of Research in Chemical, Metallurgical and Civil Engg. (IJRCMCE) Vol. 1, Issue 1(2014) ISSN 2349-1442 EISSN 2349-1450
TABLE V
MATERIAL AND ENERGY BALANCE FOR THE 30TPD PLANT
Stream 1 2 3 4 5 6 7 8 9
Crude Crude
Tyres Pyrolysis- Uncondensed- Compressed Tyre Derived
Description Tyres Steel Carbon Heavy
Chips Gas Pyrolysis-Gas Pyro-Gas Fuel-Distilled
Black Fuel Oil
Mass Flow (kg/h) 1,250 125 1,125 667 458 563 97 8 375
Volumetric flow
0.9 834 1.32 0.63 69 6 0.465
(m3/h)
Input Energy (kW)
Mechanical 85 75 150 110 85
Heating/ 89 467.8 120
Evaporation
Cooling/ -68 -99
Condensation
Output
Energy(kW)
Thermal 68 99
Fuel 709.7 57.2
Stream 10 11 12 13 14 15 16 17
Refined
Heavy Process Diesel Reagent Sodium
Description Carbon Gen-Set Flue Gas
Fuel Oil Water Fuel Solution Sulphite
Black
Mass Flow
188 458 229 79 267 98 6,588 126
(kg/h)
Volumetric flow
0.22 0.23 0.09 0.31 13,065
(m3/h)
Input Energy
(kW)
Mechanical 367 15
Output
Energy(kW)
Electrical 900
Thermal 200
B. Treatment Capacity
operation will be run by compressed pyrolysis gas at an
The technology offer modular pyrolysis reactors capable of average consumption rate of 6m3/h. The required plant power
treating up to 30 tons per day. Approximately 15 tons per will be supplied by a generator set fuelled with a blend of
cycle can be processed in a reactor; this will require 1 hour of diesel-HFO produced from the plant, excess thermal heat
loading, 4 hours processing and 3 hours of cooling and rejected from this generator will be capture through heat-
cleaning. Based on an 8-hour cycle, an average of 8 tons per exchangers and used for steam generation which will be used
day can be processed; this is equivalent to 3,750 passenger car to wash and dry the tyres prior to pyrolysis. Electrical power
tyres per day. The lead time for the supply of a complete back up will be allowed for general plant lighting. There will
pyrolysis plant is 6 weeks ex factory upon confirmation of also be a consumption of sodium hydroxide (NaOH) to treat
order. Shipping by sea is approximately 6 weeks and another the flue gas from the generator set and burner flues gasses at
11 weeks for installation and commissioning. In summary it 473 kg per day and cost of $1.36/ ton. Sodium sulphite
will take approximately six months from date of order to an precipitate resulting flue gas scrubbing is 3 ton per day which
operating plant. attracts a selling fee of around $20/ton.
TABLE VI
C. Utilities ENERGY REQUIREMENTS FOR A 30 TPD WASTE TYRE PYROLYSIS PLANT
The treatment plant will require process makeup water for Heating 677.15 kW
the wet grinding of carbon black, cooling, washing and Mechanical Energy 852.17 kW
Cooling/Condensation (366.56) kW
condensation of gasses to crude heavy fuel oil. This water will Plant Energy Requirements (combined) 1,530.00 kW
be connected onsite via an allocated point to the municipal Energy Efficiency 76%
water supply or process water if available; the daily make-up Available Fuel Energy 767 kW
Generator set Output 900.0 kW
water required is approximately 11.28 m3. The pyrolysis Total Supply 1,666.8 kW
reactors will be heated using pyrolysis gas at a consumption
rate of 69m3/h. Other components such as tyre cutter,
shredder, mill drive, compressor plant, heaters, pumps, reactor
drive unit as well as control mechanisms requires electrical
power of 852.17 kW as presented in Table VI. Fork lift
http://dx.doi.org/10.15242/ IJRCMCE.E1113542 45
Int'l Journal of Research in Chemical, Metallurgical and Civil Engg. (IJRCMCE) Vol. 1, Issue 1(2014) ISSN 2349-1442 EISSN 2349-1450
http://dx.doi.org/10.15242/ IJRCMCE.E1113542 46
Int'l Journal of Research in Chemical, Metallurgical and Civil Engg. (IJRCMCE) Vol. 1, Issue 1(2014) ISSN 2349-1442 EISSN 2349-1450
TABLE X
OPERATIONAL COST ESTIMATION ON 30 TPD WASTE TYRE PYROLYSIS PLANT
Period (Years) 0 1….n=5
Fixed Cost
http://dx.doi.org/10.15242/ IJRCMCE.E1113542 47
Int'l Journal of Research in Chemical, Metallurgical and Civil Engg. (IJRCMCE) Vol. 1, Issue 1(2014) ISSN 2349-1442 EISSN 2349-1450
http://dx.doi.org/10.15242/ IJRCMCE.E1113542 48
Int'l Journal of Research in Chemical, Metallurgical and Civil Engg. (IJRCMCE) Vol. 1, Issue 1(2014) ISSN 2349-1442 EISSN 2349-1450
http://dx.doi.org/10.15242/ IJRCMCE.E1113542 49