Scribd Logo
Upload

Welcome to Scribd!

  • Purification Chemistry

    Uploaded by

    vaibhav
    7 views5 pages

    Original Title

    Purification chemistry

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    7 views5 pages

    Purification Chemistry

    Uploaded by

    vaibhav

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 5
    SUMMARY FOR REVISION \fhalogen present | Nag + Conc. HNO; ——> H,S b [[HIETx > Lamergnars test] NaCN + Cone. HNO; HCN NaX + AgNO; —— Agx | +NaNO3 ppt AgX AgCl AgBr Aal White ppt Pale Yellow ppt * Yellow ppt (Soluble in NH,OH) (Sparingly soluble (Insoluble in NOH) in NHOH) If phosphorus present (NH,}:MoOg NajO> (Ammonium molybdate) (NH4)sPO4-12MoO3 Compound ro eres (Ammonium phosphomolybdate) Phosphate in HNO Canary yellow colour or ppt SUMMARY FOR REVISION (Revise byes NEET) Feso, fect fe te NacN ——> > FealFe(ON)els Prussian blue P Lead acetate pbs (CHsCOO),Pb Black ppt, NaS ‘Sodium nitroprusside Nag[Fe(CN) NOS] Violet colour Naz[Fe(CN)NO} [Rasen Fett NaSCN——> Fe(SCN)3 Sodium thiocyanate Blood red colour Na (Excess) v NaSCN————_Na,S + NaCN IMMARY (CHROMATOGRAPHY, Adsorption chromatography Partition chromatography a) Column b) Thin layer chromatography chromatography Stationary | Silica gel and alumina _| Silica gel and alumina Paper chromatography Chromatography paper contain water trapped in it Eluant which is a liquid | Liquid or a mixture of or a mixture of liquid | liquid Process | Mobile phase flow from | Mobile phase flow from top to bottom in a bottom to top over a thin Liquid or a mixture of liquid Mobile phase flow from bottom to top over column having Tayer of an adsorbent stationary phase coated on glass plate chromatography paper Type {C) Distillation under reduced pressure Conditions When liquid boils at higher temperature and it may Examples 4x Concentration of sugar juice {Vacuum distillation) decompose before BP is attained. (if Recovery of glycerol from (D) Steam distillation When the substance is immiscible with water and steam volatile, Po= P+ P, Vapour Vapour Vapour pressure pressure pressure min) of of water Organic liquid spent lye. Gif Glycerol Li-Aniline is separated from water

    You might also like