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SECTION-I (MATHEMATICS)
Multiple choice questions with only ONE option correct.
1. A curve y = f (x) passes through the point P(1,1). The normal to the curve at P is
a(y – 1) + (x – 1) = 0. If the slope of the tangent at any point on the curve is proportional to the ordinate of the
point, then the equation of the curve is
(1) y = ea(x – 1) (2) y = ea(1 – x) (3) y = e(a/2) (x – 1) (4) y = e(a/2) (x + 1)
2. If T and N be the lengths of perpendiculars from the origin on the tangent and the normal respectively to the
curve x2/3 + y2/3 = a2/3, then 4T2 + N2 =
(1) 2a2 (2) a 2 (3) 4a2 (4) none of these
3. The angle of intersection of the curve y = x2, 6y = 7 – x3 at (1, 1) is
(1) /4 (2) /3 (3) /2 (4) none of these
4. Sum of squares of intercept made on co-ordinate axes by the tangents to the curve x2/3 + y2/3 = a2/3 is
(1) a 2 (2) 2a2 (3) 3a2 (4) 4a2
5. Let f (x) = x3 + ax2 + bx + 5 sin2x be an increasing function in the set of real numbers R. Then a and b satisfy
the condition.
(1) a2 – 3b – 15 > 0 (2) a2 – 3b + 15 > 0 (3) a2 – 3b – 15 < 0 (4) a2 > 0 and b > 0
6. On which of the following intervals is he function x100 + sin x – 1 decreasing?
(1) (0, /2) (2) (0, 1) (3) (/2, ) (4) none of these
3 2
7. If f (x) = Kx – 9x + 9x + 3 is increasing on R, then
(1) K < 3 (2) K > 3 (3) K  3 (4) none of these
8. The value of b for which the function f (x) = sin x – bx + c is decreasing in the interval
(– , ) is given b y
(1) b < 1 (2) b ³ 1 (3) b > 1 (4) b  1
K sin x  2 cos x
9. If the function f (x )  sin x  cos x is increasing for all values o x, then
(1) K < 1 (2) K > 1 (3) K < 2 (4) K > 2
10. The function y = x – cot –1 x – log ( x  ( x 2  1)) is increasing on
(1) (, 0) (2) (– , 0) (3) (0, ) (4) (– , )
x 4 2
11. If f (x )  15 (3 x  10 x  15) and g (x) = cos5x where x  (0, 3) then

(1) f (x) increases as g (x) decreases (2) f (x) increases as g (x) increases
(3) f (x) decreases as g (x) decreases (4) none of these

12. If     , then cos  . cos  has a maximum value at b equal to
2
(1) /4 (2) /2 (3) /6 (4) none of these
13. The greatest value of f (x) = cos (xe[x] + 7x2 – 3x), x  [–1, ) is
(1) –1 (2) 1 (3) 0 (4) none of these

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x2 y2
14. Find the point of the hyperbola   1 which is nearest to the line 3x + 2y + 1 = 0. Compute the distance
24 18
between the point and the line
11 11 13 13
(1) 13 (2) 13
(3) (4)
11 11
15. The range of values of k for which the function f (x) = x3 – 3 (7 – k)x2 – 3 (9 – k2)x +2 ha s a point of maximum
where x > 0, is
 1 
(1) ( ,  3)   3, 4 7  (2) ( ,  3)  (3,  ) (3) (– , –3] (4) none of these

16. The abscissae of the points of the curve y = x3 in the interval [–2, 2], where the slope of the tangents can be
obtained by mean value theorem for the interval [–2, 2], are
2 3
(1)  3 (2)  3 (3)  (4) 0
2
17. The equation x log x= 3 – x has, in the interval (1, 3)
(1) exactly one root (2) atmost one root (3) atleast one root (4) no root
3 2
18. If 27 a + 9b + 3c + d = 0, then the equation 3ax + 3bx + + 2cx + d= 0 has atleast one real root in
(1) 0 and 1 (2) 1 and 3 (3) 0 and 3 (4) none of these
 
19. Consider the function f (x) = e–2x sin (2x) over the interval  0, 2  . A real number c   0,   as guaranteed by
 2
Rolle’s theorem such that f (3) = 0 is
(1) /8 (2) /6 (3) /4 (4) /3
20. A point P is given on the circumference of a circle of radius r. The chord QR is parallel to the tangent line at P.
The maximum area of the DPQR is
3 3 2 3 2 3
(1) r (2) r (3) r 2 (4) none of these
4 4 2
21. The length of the subtangent to the curve x2 + xy + y2 = 7 at (1, – 3) is p then, where [.] is g.i.f

22. In the graph of the function 3 sin x + cos x the maximum distance of a point from x-axis is

23. The minimum value of e(2 x 2

 2 x  1)
sin 2 x is

24. If the function f (x) = x3 – 6ax2 + 5x satisfies the conditions of Lagrange’s value theorem for the interval [1, 2]
7
and the tangent to the cure y = f (x) at x  is parallel to the chord that joins the points of intersection of the
4

1
curve with the ordinates x = 1 and x = 2. Then the value of   where [.] is g.i.f
a

25. If the function f (x) = ax3 + bx2 + 11 x – 6 satisfies the conditions of Rolle’s theorem for the interval [1, 3] and
 1 
f '2    0 , then the values of |a-b|
 3

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SECTION-II (PHYSICS)
Multiple choice questions with only ONE option correct.
26. At a certain place, vertical component of earth’s magnetic field is 3 times the horizontal component of earth’ss
magnetic field. If a magnetic needle is suspended freely in air then it will incline
(1) 30° below horizontal (2) 60° below horizontal
(3) 30° above horizontal (4) 45° above horizontal
27. The figure illustrates how B, the flux density, inside a sample of ferromagnetic material varies with external
magnetic field B . For the sample to be suitable for making a permanent magnet

(1) OQ should be large, OR should be small (2) OQ and OR both should be large
(3) OQ should be small and OR should be large (4) OQ and OR both should be small
28. Soft iron is used in many parts of electrical machines for
(1) Low hysteresis loss and low permeability (2) Low hysteresis loss and high permeability
(3) High hysteresis loss and low permeability (4) High hysteresis loss and high permeability
29. A magnetic needle oscillates in a horizontal plane with a period T at a place where the angle of dip is 60°. When
the same needle is made to oscillate in a vertical plane coinciding with the magnetic meridian, its period will be
T
(1) (2) T (3) 2T (4) 2T
2
30. Two different magnets are tied together and allowed to vibrate in a horizontal plane. When their like poles are
joined, time period of oscillation is 5 s and with unlike poles joined, time period of oscillation is 15 s. The ratio of
their magnetic moments is
(1) 5 : 4 (2) 1 : 3 (3) 3 : 1 (4) 2 : 5
31. The values of the apparent angles of dip in two planes at right angles to each other are 45° and 30° respectively.
The true value of angle of dip at the place is
(1) cot–1 (1) (2) cot–1 (2) (3) cot–1 (3) (4) cot–1 (4)
32. A magnet is placed horizontally on ground with its north pole towards the geographic north pole of the earth. The
neutral point is obtained
(1) Along the axis of the magnet
(2) On the east-west line through the centre of the magnet
(3) In only east side of the magnet
(4) In only west side of the magnet
33. The value of horizontal component of earth’s magnetic field at a place is 0.35 × 10–4 T. If the angle of dip is 60°,
the value of vertical component of earth’s magnetic field is nearly
(1) 0.1 × 10–4 T (2) 0.2 × 10–4 T (3) 0.4 × 10–4 T (4) 0.61 × 10–4 T
34. The period of oscillation of a magnet of a vibration magnetometer is 2.45 s at one place and 4.9 s at the other. The
ratio of the horizontal component of earth magnetic field at the two places is
(1) 1 : 4 (2) 1 : 2 (3) 2 : 1 (4) 4 : 1

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35. If declination at a place is known to be 15° E. And a compass needle points as shown, then geographic north is
represented by the direction numbered.

(1) 1 (2) 2 (3) 3 (4) 4

36. When photon of energy 3.8 eV falls on metallic surface of work function 2.8 eV, then the kinetic energy of
emitted electrons are
(1) 1 eV (2) 6.6 eV (3) 0 to 1 eV (4) 2.8 eV
37. The work function of a substance is 4eV. The longest wavelength of light that can cause the emission of
photoelectrons from this substance is approximately
(1) 540 nm (2) 400 nm (3) 310 nm (4) 220 nm
38. Wavelength of an electron accelerated through a potential difference of 1 volt is
(1) 12.27 Å (2) 1.234 Å (3) 1 micron (4) 1 fermi
39. If in a photoelectric cell, the wavelength of incident light is changed from 4000 Å to 3000 Å then change in
stopping potential will be
(1) 0.66 V (2) 1.03 V (3) 0.33 V (4) 0.49 V
40. In photoelectric effect, if a weak intensity radiation instead of strong intensity of suitable frequency is used then
(1) Photoelectric effect will get delayed (2) Photoelectric effect will not take place
(3) Maximum kinetic energy will decrease (4) Saturation current will decrease
41. The work function of tungsten is 4.50 eV. The wavelength of fastest electron emitted when light whose photon
energy is 5.50 eV falls on tungsten surface, is
(1) 12.27 Å (2) 0.286 Å (3) 12400 Å (4) 1.227 Å
42. A proton is accelerated through 225 V. Its de Broglie wavelength is
(1) 0.1 nm (2) 0.2 nm (3) 0.3 nm (4) 0.4 nm
43. For same energy, find the ratio of photon and electron (Here m is mass of electron)

2m 1 2m 1 2m 1 2m
(1) c (2) (3) (4)
E c E c2 E c E2
44. What should be the velocity of an electron so that its momentum becomes equal to that of a photon of wavelength
5200 Å?
(1) 700 m/s (2) 1000 m/s (3) 1400 m/s (4) 2800 m/s
45. Figure shows four situations in which an electron is moving in electric / magnetic field. In which case the de
Broglie wavelength of electron is increasing?

(1) (2) (3) (4)

46. The time period of a freely suspended magnet is 4 s. If it is broken in length into two equal parts and one part is
suspended in the same way, then find its time period in sec.
47. The magnetic moments of two bar magnets of same size are in the ratio 1 : 2. When they are placed one over the
other with their similar poles together, then their period of oscillation in a magnetic field is 3s. If one of the
magnets is reversed, then the period of oscillation in the same field will be m 3 sec. Then find the value of m.
48. The work done in turning a magnet of magnetic moment M by an angle of 90° from the magnetic meridian is n
times the corresponding work done to turn it through an angle of 60°. The value of n is

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49. If the number of electrons emitted per second by a 24 W source of monochromatic light of wavelength 6600 Å,
assuming 3% efficiency for photoelectric effect (take h = 6.6 × 10–34 Js) is 3n × 1017. Then find the value of n.
50. A photosensitive metallic surface is illuminated alternately with lights of wavelength 3100 Å and 6200 Å. It is
observed that maximum speeds of the photoelectrons in two cases are in ratio 2 : 1. The work function of the
n
metal is (hc = 12400 eVÅ) eV . Then find the value of ‘n’.
3

SECTION-III (CHEMISTRY)
Multiple choice questions with only ONE option correct.
51. The product (3) of the following sequence of reactions is :
(i) AlCl3 Cl2 (limited) aq. NaOH
+ CH2=CH2    A 
(ii) H O h
 B   C
2

(1) (2) (3) (4)

52. (i) chlorobenzene is mono-nitrated to M

(ii) nitrobenzene is mono-chlorinated to N
(iii) anisole is mono-nitrated to P
(iv) 2-nitrochlorobenzene is mono-nitrated to Q
Out of M, N, P and Q the compound that undergoes reaction with aq. NaOH fastest is
(1) M (2) N (3) P (4) Q
53. The appropriate sequence of reactions for obtaining 2-phenylbutanoic acid from benzene is
(1) (i) 1-chlorobutane/AICI3 (ii) limited Cl2, light (iii) aq NaCN (iv) H+, H2O, heat
(2) (i) 2-chlorobutane/AICI3 (ii) K2Cr2O7/H2SO4
(3) (i) propanoyl chloride/AlCl3 (ii) Zn-Hg/HCl (iii) limited Cl(g), light (iv) aq. NaCN (v) H+, H2O, heat
(4) (i) butanoyl chloride/AICI3 (ii) NaBH4 (iii) CuCN (iv) H+, H2O, heat

54. SOCl 2
  Product

In the above reaction which phenomenon will take place :

(1) Retention (2) Inversion (3) Racemisation (4) Partial racemisation

55. A, Product (1) is

(1) (2) (3) (4)

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56. Na C H Br (1)
 2 
 5


Product (A) in above reaction is

(1) , (inversion) (2) , (retention)

(3) , (racemic) (4) Ph–CH=CH–CH3

– 
EtO K
57.   A
EtOH

The product A is :

(1) (2)

(3) (4)

58. Replacement of chlorine from chlorobenzene to give phenol requires drastic conditions but chlorine of 2, 4-
dinitrochlorobenzene is readily replaced because
(1) NO2 makes the ring electron rich at ortho- and para-positions.
(2) NO2 withdraws electrons at meta position.
(3) NO2 donates electrons at meta position.
(4) NO2 withdraws electrons from ortho and para positions.
59. Which of the following statement is correct.
(1) Nucleophiles have an unshared electron pair and can make use of this to react with an electron rich
species.
(2) AgNO3 increases the rate of solvolysis in SN1 reaction of alkyl halide.
(3) Inversion of configuration occurs at the carbon undergoing SN1 reaction.
(4) Aryl halides are more reactive towards nucleophilc substitution reaction as compared to alkyl halide.
H Br
Ag
60.  Rearranged Carbocation + AgBr

Rearranged carbocation is :
+
CH3
(1) (2) (3) (4) +

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61.

The product X and Y are respectively :

(1) & (2) &

(3) & (4) &

62. The major product(Y) of the following reaction is –

O O
CH3MgI (excess) 3 CrO


 X    Y
H3 O , Heat

O O O
(1) (2) (3) (4)
O

63. Rate of Bimolecular elimination (E2) reaction for the following :

H
H
Base Base
(i) Cl (equitorial) (ii) H
E2 E2

Cl (axial)

(1) Same for both conformers (2) i > ii

(3) ii > i (4) Can’t say anything about rate of E-2 reaction
64. Which is incorrect about alkyl bromide having molecular formula C5H11Br
(1) One isomeric alkyl bromide undergoes E1 elimination at the fastest rate
(2) Only one is incapable of reacting by the E2 mechanism
(3) Only one isomer gives a single alkene on E2 elimination
(4) 2-Bromopentane gives the most complex mixture of alkenes on E2 elimination
65. The compound 'X' is
O
||
H SO HIO4
24  [X]  

O

OH

(1) (2) (3) (4)

OH OH
OH OH OH

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66. When the all-cis isomer of C6H6Cl6 (1, 2, 3, 4, 5, 6-Hexachlorocyclohexane) is heated with alc. KOH, the most
probable product is :

(1) (2) (3) (4)

CHD 2MgI Conc.H2SO 4

67. CH2O   
 X      Y
H3 O 
In the above reaction compound X & Y respectively will be
OH
|
(1) CHD  CH2  OH , CHO – CHO (2) CHD2 – CH2 – OH , CHO – CHO

(3) CHD2 – CH2 – OH , CD2 = CH2 (4) CHD  CH2  OH , CD2 = CH2
|
OH
68. Major product of the given reaction is :

(1) (2) (3) (4)

69. .The product is :

(1) (2) (3) (4)

70. Which one of the following hexachlorocyclohexane is least reactive and which one is most reactive for E2
reactions with a strong base for dehydrohalogenation.

(1) I least & II most (2) II least & I most (3) III least & I most (4) III least & II most

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71. Number of compounds which slowly racemises on addition of SbCl5.

(i) (ii) (iii) (iv)

(v) (vi) CH2 = CH – Cl (vii) (viii)

H O / Acetone
72. C2H5 — C  CH — CH2 — Br 2  
|
CH3
(E)

How many total substitution products are formed including stereoisomers in the above reaction?
73. The order of following reaction is :

74. The number of products (stereoisomers) formed in the following reaction is (consider only major product)

75. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic
KOH is

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OYP Engg
ANSWER KEY
CODE: OYP/Engg. /JEE-MAIN/KS_09012022

Mathematics
1. (1) 2. (2) 3. (3) 4. (1) 5. (3)

6. (4) 7. (2) 8. (3) 9. (4) 10. (4)

11. (1) 12. (1) 13. (2) 14. (2) 15. (1)

16. (1) 17. (3) 18. (3) 19. (1) 20. (1)

21. (8) 22. (2) 23. (1) 24. (1) 25. (7)

Physics
26. (2) 27. (2) 28. (2) 29. (1) 30. (1)

31. (2) 32. (2) 33. (4) 34. (4) 35. (2)

36. (3) 37. (3) 38. (1) 39. (2) 40. (4)

41. (3) 42. (2) 43. (1) 44. (3) 45. (2)

46. (2) 47. (3) 48. (2) 49. (8) 50. (4)

Chemistry
51. (4) 52. (4) 53. (3) 54. (1) 55. (2)

56. (2) 57. (1) 58. (4) 59. (2) 60. (2)

61. (1) 62. (1) 63. (3) 64. (3) 65. (3)

66. (2) 67. (3) 68. (3) 69. (1) 70. (2)

71. (3) 72. (4) 73. (1) 74. (1) 75. (5)

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