1

GYANA VIKASH ACADEMY

Amines and Diazonium Salts DPP-02

1. The presence of 1° amines can be confirmed by 4. Which of the following is most basic?
(1) Reaction with HNO2
(2) Reaction with CHCl3 and alc. KOH (1)
(3) Reaction with Grignard reagent
(4) Reaction with acetyl chloride
(2)
2. Which of the following is an incorrect match?
(3)

(1) ⎯⎯⎯⎯ ⎯
NaNO 2 / HCl
→ Product
(4)

(Diazotization reaction)
5. Hinsberg’s reagent is
(1) C6H5COCl (2) CH3COCl
(2) ⎯⎯⎯⎯⎯
CHCl3 /KOH
→ Product (3) C6H5CH2Cl (4) C6H5SO2Cl

(Carbylamine reaction) 6. Nitrobenzene is subjected to reduction with zinc dust

and ammonium chloride. The main product formed
will be-
(1) Benzenamine
(3) ⎯⎯⎯⎯→
CuCN/ HCN
Product (2) Aniline
(3) N–phenyldroxylamine
(Gatterman reaction) (4) None of these

7. Ethanamine is treated with nitrous acid at ordinary

temperature, the product will be
(4) ⎯⎯⎯⎯
(i) HBF4
(ii) Δ
→ Product (1) Ethanol only
(2) Ethanol, acetic acid, N2 & H2O
(Balz Schiemann reaction) (3) Acetic acid, ethane and H2O
(4) Ethanol, N2 and HCl
3. CH3CH2NH2 ⎯⎯⎯⎯⎯
(CH COO) O
Δ
3
→ A + B.
2

8. Methyl cyanide on treatment with methyl magnesium

(A) and (B) are bromide followed by subsequent hydrolysis gives.
(1) CH3CH2NHCOCH3 + CH2CH2NC (1) Propanone
(2) CH3CH2NO2 + CH3COOH (2) Ethanone
(3) CH3CH2NHCOCH3 + CH3COOH (3) Ethanal
(4) CH3CH2NO2 + CH3CH2NHCOCH3 (4) Propanal
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9. A primary nitro alkane is treated with nitrous acid, O

which of the following will be the main product? ||
16. The CH3 − C − NH 2 ⎯⎯⎯
KOBr
→(A);
(1) Pseudonitrol (2) Nitrolic acid
(3) A primary amine (4) Primary alcohol O
||
CH3 − C − NH 2 ⎯⎯⎯
LAH
→(B)
10. Which of the following statement is correct?
Relation between (A) and (B) is:
(1) Methyl amine is slightly acidic
(1) Chain isomer
(2) Methyl amine is less basic than ammonia
(2) Homologues
(3) Methyl amine is less basic than dimethyl amine
(3) Functional isomer
(4) Methyl amine is less basic than aniline
(4) Identical

11. Which is more basic?

17. An isocyanide on reduction with hydrogen in the
(1) Benzylamine (2) Aniline presence of platinum gives.
(3) Acetamide (4) o-methylaniline (1) Amide (2) Primary amine
(3) Secondary amine (4) Alcohol
12. Which one is most volatile?
(1) CH3CH2CH2NH2 18. Which of the following compounds has localized
(2) (CH3)3N lone pair of electrons?
CH3
(3) NH
CH3 (1)
(4) CH3OH

13. 2, 4, 6-tribromoaniline is a product of

(1) Electrophilic addition on C6H5NH2
(2) Electrophilic substitution on C6H5NH2 (2)
(3) Nucleophilic addition on C6H5NH2
(4) Nucleophilic substitution on C6H5NH2

14. CH3CH2NH2 is more basic than CH3CONH2 because

(1) Acetamide is amphoteric in character. (3)
(2) In CH3CH2NH2 the electron pair on N is
delocalized by resonance.
(3) In CH3CH2NH2 there is no resonance, while in
acetamide the lone pair of electrons on N-atom is (4)
delocalized and therefore less available for
protonation.
(4) Acetamide is derivative of acid. 19. Consider ammonia (I) and water (II). Which of the
following statements is true?
15. Tautomerism is shown by H3 N•• H 2 O••
(1) CH3 – O – NO I II
(2) CH3 – CH2 – NO2
(1) I is more basic and more nucleophilic than II
(3) CH3 – CH2 – CN
(2) I is less basic and less nucleophilic than II
(4) CH3 − CH − OH (3) I is more basic but less nucleophilic than II
|
CH3 (4) I is less basic but more nucleophilic than II
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20. Which of the following compounds has the most H O Br2 + KOH
24. Ph – C  N ⎯⎯⎯⎯⎯⎯ 3
(Partial hydrolysis)
→(A) ⎯⎯⎯⎯ →(B);
basic nitrogen?
O Product (B) is:
(1) Ph – CH2 –NH2 (2) Ph – OH
a. b. (3) Ph – NH2 (4) Ph – CH3
N N
H H
O 25. CH3 − CH − CH 2 − NH 2 ⎯⎯⎯
HNO2
→(A)
O |
CH3
c. d. Major product (A) is :
N
(1)
H OH
(1) a (2) b
(3) c (4) d (2)
OH
21. Which one among the following is the least basic? OH
(1) CH3NH2 (2) NH3 (3)
(3) C2H5NH2 (4) PhNH2
(4)
22. (A) ⎯⎯⎯
KOH
CHCl
→(B) ⎯⎯⎯→
LiAlH4
H
CH3CH2NHCH3.
3

Identify compound A:
O NH2
||
(1) CH3 − CH 2 − C − OH HO CH3
NaNO2
O 26. (A) (B)
HCl(0 – 5°C) mild-basic
||
(2) CH3 − CH 2 − C − NH 2 Product (B) is:
O OH
||
(3) CH3 − CH 2 − C − Cl
(4) CH3 – CH2 – NH2 (1)
O
CH3
Cl OH
23. ⎯⎯⎯
NH3

→(A) ⎯⎯⎯
Br2
KOH
→(B)

(2)
⎯⎯⎯
CHCl3
KOH
→(C) ; Product (C) is:
N N Ph
N C
(1) CH3
OH
N N Ph
NH CH3
(2) (3)

CH2 NH2 CH3

(3)
OH

NH2 PH
(4)
CHO
(4)
CH3
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Answer Key
1. (2) 14. (3)
2. (3) 15. (2, 3)
3. (3) 16. (2)
4. (1) 17. (3)
5. (4) 18. (2)
6. (3) 19. (1)
7. (4) 20. (1)
8. (1) 21. (4)
9. (2) 22. (4)
10. (3) 23. (1)
11. (1) 24. (3)
12. (2) 25. (3)
13. (2) 26. (3