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CHEMISTRY
AIATS-04 (CF + OYM)-Q.62 (c) Many naturally occurring aldehydes and
Topic: Physical Properties of Aldehydes and ketones are used in the blending of
perfumes.
Ketones
The correct statement(s) is/are
Consider the following statements
(1) (a) and (b) only
(a) Methanal is liquid at room temperature.
(2) (b) and (c) only
(b) The boiling point of acetone is more than
propanal. (3) (a) and (c) only
(c) The boiling points of aldehydes and ketones (4) (a), (b) and (c)
are higher than hydrocarbons and ethers of
3. Maximum boiling point among the following is of
comparable molecular masses.
(1) n-Butane
The correct statements are
(1) (a) and (b) only (2) (b) and (c) only (2) Methoxyethane
(3) (a) and (c) only (4) (a), (b) and (c) (3) Propanal
(4) Acetone
AIATS-04 (CF + OYM)-Q.82
Topic: Nitro Compounds
Nitrobenzene on reaction with zinc dust in
presence of aqueous NaOH majorly gives
(1) Azobenzene
(2) Phenyl hydroxylamine
(3) Hydrazobenzene
Practice Questions:
(4) Aniline
1. Consider the following statements
(a) Methanal is a gas at room temperature.
(b) Ethanal is a volatile liquid.
(c) Boiling point of propan-1-ol is greater than
propanal.
The correct statement(s) is/are
(1) (a) only
(2) (a) and (b) only Practice Questions:
(3) (b) and (c) only 1. Nitrobenzene on reaction with H2/Pd in ethanol
(4) (a), (b) and (c) majorly gives
2. Consider the following statements (1) Azobenzene
(a) Methanal, ethanal are immiscible with (2) Aniline
water. (3) Hydrazobenzene
(b) All aldehydes and ketones are fairly soluble (4) Phenyl hydroxylamine
in benzene.
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
3. CH3Mg-X + O=C=O 
dry ether
 (A) 
H3 O
 (B)

2. Product (B) is
(1) CH3COOH
A is (2) CH3CH2COOH
(1) Hydrazobenzene (3) CH3CH2CHO
(2) Benzene (4) CH3CHO
(3) Aniline AIATS-04 (CF + OYM)-Q.52
(4) Azoxybenzene Topic: Diazonium Salts
Given below are the two statements.
3.
Statement I: Benzene diazonium chloride is a
colourless crystalline solid.
The compound (B) is
Statement II: Benzene diazonium chloride is
(1) Phenyl hydroxylamine
insoluble in water.
(2) Aniline
(3) p-aminophenol In light of the above statements, choose the
(4) Azobenzene correct option.

AIATS-04 (CF + OYM)-Q.84 (1) Statement I is correct but statement II is

Topic: Methods of Preparation for Aldehydes and incorrect
Ketones (2) Statement I is incorrect but statement II is
Consider the following reaction sequence correct
(3) Both statement I and statement II are
correct

Major product B is (4) Both statement I and statement II are

incorrect
(1) (2)

(3) (4)

Practice Questions:
1. Given below are the two statements

Practice Questions: Statement I: Benzene diazonium chloride is a

+
colourless crystalline solid and is readily soluble
1. CH3CH2COONH4 
P2 O5

 X 
H /H2 O
Y in water.
X and Y respectively are Statement II: Benzene diazonium chloride is
(1) CH3CH2COOH, CH3CN stable in cold but reacts with warm water.
(2) CH3CH2CN, CH3CH2COOH In the light of above statements, select the
(3) CH3CH2CH2CN, CH3CH2COOH correct option.

(4) CH3COOH, CH3CH2CN (1) Statement I is correct but statement II is

incorrect
2. When Benzamide is heated with acidified water
the product obtained is (2) Statement I is incorrect but statement II is
(1) Benzoic acid correct
(2) Benzophenone (3) Both statement I and statement II are
(3) Benzaldehyde correct

(4) Acetophenone (4) Both statement I and statement II are

incorrect

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2. During coupling reaction of benzene diazonium

chloride and phenol, the pH of the reaction (2)
medium and colour of the product formed
respectively are
(3)
(1) 9-10, orange
(2) 4-5, yellow
(3) 3-4, orange
(4)
(4) 1-2, violet
3. Consider the following reaction 2. RCH2 –COOH 
(i) x 2 |Red phosphorus

(ii) H2 O

The product and name of the reaction are

(1) , Rosenmund reaction

(2) , HVZ reaction

(A) and (B) respectively are (3) , HVZ reaction

(4) , Rosenmund reaction

(1) (2)
3.

Identify Y in the given reaction

(3) (4)
(1)

AIATS-04 (CF + OYM)-Q.64

Topic: Chemical Properties of Carboxylic Acid (2)
Consider the following compounds
FCH2COOH HCOOH C6H5 COOH
(i) (ii) (iii)

NC – CH2COOH (3)
(iv)

The correct order of decreasing pKa values of

the given compounds is
(1) (iv) > (i) > (iii) > (ii) (2) (ii) > (iii) > (iv) > (i) (4)
(3) (iii) > (ii) > (i) > (iv) (4) (ii) > (iv) > (i) > (iii)
AIATS-04 (CF + OYM)-Q.71
Topic: Chemical Reactions of Aldehydes and
Ketones
The pair of compounds which can be
distinguished by iodoform test is
(1) Acetophenone and acetone
(2) Benzophenone and ethanol
Practice Questions: (3) Ethanal and butanone
1. Which among the following is most acidic? (4) Isopropanol and sec-butanol

(1)

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(2) Semicarbazone
(3) Oxime
(4) Hydrazone
3. Which of the following pairs cannot be
distinguished by Fehling’s test?

1. Which among the following will not give

iodoform test? (1)
(1) Ethanol
(2) Acetophenone
(3) 2-butanol (2)
(4) Methanol

2. (3)
The product of the reaction will be
(4) CH3CH2CHO and HCHO
(1) Imine



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CONCEPT STRENGTHENING SHEET

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Answer Key

AIATS-04 (CF + OYM)-Q.62 AIATS-04 (CF + OYM)-Q.52

Topic: Physical Properties of Aldehydes and Topic: Diazonium Salts
Ketones 1. (3)
1. (4) 2. (1)
2. (2) 3. (4)
3. (4) AIATS-04 (CF + OYM)-Q.64
AIATS-04 (CF + OYM)-Q.82 Topic: Chemical Properties of Carboxylic Acid
Topic: Nitro Compounds 1. (3)
1. (2) 2. (3)
2. (4) 3. (2)
3. (3) AIATS-04 (CF + OYM)-Q.71
AIATS-04 (CF + OYM)-Q.84 Topic: Chemical Reactions of Aldehydes and
Topic: Methods of Preparation for Aldehydes and Ketones
Ketones
1. (4)
1. (2)
2. (2)
2. (1) 3. (4)
3. (1)





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