SUBJECT : CHEMISTRY

Topic : AMINE
1. 5. How many number of isomeric 1º amines of the
KCN H2 /pt
CHCl3
−−−→ A −−−→ B −−−−→ C formula C4H11N will give positive Hinsberg
KOH reagent test ?
C is - (1) 4 (2) 3 (3) 2 (4) 0
+ −

(1) N ≡C 6.

(2) −

N ≡C
+

Reagent B can be:-

(3) CH2 − N ≡ C
− +
(1) H3PO2 (2) C2H5N2Cl
(3) CH3OH (4) SnCl2 + HCl
(4) CH2 − N ≡ C
+ −

7. Regarding the given figure,

2. NaOH
CH3CH2CONH2−−−−→ A, Aqueous solution of
Br2
A
(1) Turns blue litmus to red
(2) Turns red litmus to blue
(3) Does not affect the litmus
(4) Decolourise the litmus Which of the following statement is true?

3. Aniline can be obtained by :- (1) Intramolecular hydrogen bonding present in

primary amines
(1) Benzoyl chloride and ammonia
(2) Intermolecular hydrogen bonding present in
(2) Reduction of benzamide primary amines
(3) Phenol and ammonia in presence of ZnCl2 (3) Intramolecular hydrogen bonding present in
(4) Benzoic anhydride and ammonia secondary amines
4. What is the end product (Z) ? (4) Intermolecular hydrogen bonding present in
secondary amines
8. "DIBAL – H" can be used to prepare aldehyde
from
(1) Cyanide only
(2) Ester & isocyanides
(1) Phenolphthalein (2) Methyl red (3) Cyanide & isocyanides
(3) Methyl orange (4) Para red (4) Cyanide & ester

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9. The correct order of boiling points for 14. Find out the those reaction in which product
the following compounds is obtained gives positive isocyanide text :-
(1)

(1) c > b > a (2) c > a > b

(3) a > c > b (4) a > b > c (2)
10. Which of the following will give foul smell
when reacts with chloroform in the presence of
ethanolic KOH? (3)
(1) N – methyl ethanamine
(2) Propanamine (4)
(3) N, N-dimethylmethanamine
(4) 1-nitropropane 15. Which of the following reaction does not give
11. Intermediates formed during reaction of primary amine as a product ?
(1)
with Br2 and KOH are :
(2)
(1) RCONHBr and (2) RNHCOBr and
RNCO RNCO
(3)
(3) RNH—Br and
(4) RCONBr2
RCONHBr
12. Oxidation of (C2H5)2CHNH2 by KMnO4 gives :
(1) CH3CH2COCH2CH(2)
3 CH3CH2CH2CH2CHO (4)
(3) (C2H5)2C=NOH (4) None of these
16. Which of the following sequence of reagents
13. The reaction converts aniline into benzyl alcohol ?
(1) Ac2O/Pyridine, Br2/AlCl3, H3O+
+ N2 + (2) Sn/HCl, HNO3/273K, CuCN/HCN, H3O+
(3) conc.HNO3 + conc. H2SO4,
CuCl, is known as : Br2/AlCl3, Sn/HCl, HNO2
(1) Wurtz reaction (4) HNO2/0ºC, CuCN, H3O+, LiAlH4

(2) Sandmeyer reaction

(3) Gattermann reaction
(4) Friedel-Crafts reaction

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17. In given reaction X is: 20. Electrolytic reduction of Nitrobenzene in
presence of dil. H2SO4 gives
(1) (2)

(3) (4)
(2)
(1) 21. In the chemical reactions :

(3) the compounds ‘A” and ‘B’ respectively are

(1) nitrobenzene and fluorobenzene
(4) (2) phenol and benzene
(3) benzene diazonium chloride and phenol
(4) benzene diazonium and benzene
22.

18. What is the product obtained in the following The reagent required for the following
reaction : ....... ? conversion is :-

(1) (1) KOH/Br2, LiAlH4

(2)
(2) HNO2, (CH3CO)2O

(4) (3) KOH/Br2, CH3COCl

(3)
(4) KOH/Br2, H2/Ni
23.
19.

(1)
Product (B) is (2)
(1) (2)

(4)
(3)
(3) (4)

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24. 27.

(i) NaN3 i NaOH +CHCl3

( )

−−−−−− → (A) −−−−−−−−−−−→ (B)

(ii) H3 O ⊕
(1) (2) Product B is :-
(1) (2)

(4) (3) (4)

(3)

28. Which of the following will not give coupling

reaction with benzene diazonium cloride :-
(1) (2)
25. Major product of the following reaction is :-

(3) (4)
(1) (2)

29. Which of the following amine yield alkali

(3)
(4) None of these soluble product on reaction p-toluenesulphonyl
chloride?
26. (1) Dimethyl amine
(2) Isopropyl amine
Product 'C' will be : (3) Triethyl amine
(1) (2) (4) Diphenyl amine

(4)
(3)

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30. Identify X & Y in following reactions : 32. Which of the following name reaction is not
( 1)Br2 correct:-
C6 H5 NH2 −−−−→ X
(1)

Stephen reaction
(1) (2)

X=Y=

Gattermann reaction
(2)
(3)
X= &Y=

(3) Gattermann Koch Aldehyde synthesis

(4)
X=Y=

(4)

X= &Y=

31. The reaction of p-toluidine with chloroform and Perkin's Reaction

ethanolic KOH yields :-
(2)
(1)

(3) (4)

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33. 1° amine and 2° Amine can be differentiated by 37. A given nitrogen-containing aromatic compound
:- (A) reacts with Sn/HCl, followed by HNO2 to
(1) CHCl3/Alc.KOH (2) NaNO2/HCl give an unstable compound (B). (B), on
treatment with phenol, forms a beatiful coloured
(3) PhSO2Cl then compound (C) with the molecular formula
(4) All of these
NaOH C12H10N2O. The structure of compound (A) is :-
34. Suppose the following reaction (2)
(1)

(3) (4)
The structure of Major Product will be :-
(2)
(1)
38. An aromatic compound A on treatment
with Zn/NH4Cl, and subsequent filtration in
ammonical silver nitrate solution gives a black
precipitate. Hence compound A bears the group
(3) (4) :-
(1) – COOH (2) – NO2
(3) – CHO (4) – NH2

35. 39. Ethylamine on heating with CS2 in presence of

HgCl2 forms :-
Product (A) is :- (1) C2H5CNS (2) C2H5NCS
(1) (2) (3) C2H5CNO (4) C2H5SH

(3)
(4) All of these

36. Arrange following B.D.C. in reactivity order

towards coupling reaction [Electrophilic
substitution reaction]

(1) C > B > A (2) A > B > C

(3) B > A > C (4) C > A > B

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40. Suppose the following reaction 42.

Major product A is :-
(1) (2)

The structure of product will be :- (3) (4)

(1) (2)

43.

R is :-
(1) (2)

(4)
(3) (4)

(3)
44. Which is false statement ?
(1) Carboxylic acid and phenol can be
differentiated by NaHCO3
(2) 2o Amine does not react with Hinsberg
reagent
(3) Ethyl alcohol and Acetone can be
41. differentiated by Brady's reagent
(4) 2-Alkyne does not give Tollen's reagent test
45.
NaNO2 + dil. HCl
−−−−−−−−−−−→ major product
Which is incorrect statements?
(1) A gives bromine water test but B does not Which one is correct?
(2) C does not gives freidel craft reaction (1) 3 D.U. present in major product
(3) D when reacts with CH3Cl in presence of (2) Ketone functional group present in major product.
AlCl3 gives p-methylaniline as major product (3) One time ring expension and one time (1 –
2) shifting perform in this reaction.
(4) F is floro benzene
(4) All of these
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46. Suppose the following reaction sequence

The structure of compound A will be :-

(1)

(2)

(3) CH3 – CH2 – CH2 – CH2 – NH2

(4)

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