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 XIIth NEET-2021-22
Hydrocarbans + Solution
Target Marks : 180 Date : 18/04/2021
Time : 50 min Sub. : Chemistry
01. 2hexyne gives trans2hexene on treatment
with
1) Li/NH3 (2) Pd/BaSO4 07.
3) LiAlH4 (4) Pt/H2
02. When two alkenes may be formed by
dehydrohalogenation of an alkyl halide, the 1) (2) (3) (4)
alkene which is more substituted is the major
or preferred product. This generalisation is
known as 08.
1) Markownikoff’s rule
2) AntiMarkownikoff’s rule 1)
3) Saytzeff rule
4) Hoffmann’s rule
2)
03. In the reaction
1. Hg(OAc) ,H O
2 2
CH 3CH 2 CH  CH 2   3)
2. NaBD 4

the product obtained is

4)
1) CH3CH2CHOHCH2D 2) CH3CH2CHDCH2OH
3) CH3CH2CHDCH2OH 4) CH3CH2CD2CH2OH 09. Rearrangement can occur in which of the
Lindlar's Na/NH3
04. B 
Catalyst R  C  C  R 
A following reactions ?
A and B are geometrical isomers 1) Oxymercuration-demercuration
(RCH=CHR) 2) E2 elimination
1) A is trans, B is cis 2) A and B both are cis 3) Hydroboration-Oxidation
3) A and B both are trans 4) A is cis, B is trans 4) Addition of HBr to an alkene
05. Which of the following orders is correct for the
10. What is the major product of the reaction ?
reactivity of HX in electrophilic additions on
an alkene?
1) HF > HCl > HBr > HI (2) HI > HBr > HCl > HF
3) HBr > HCl > HI > HF (4) HI > HF > HCl > HBr

06.
1) (2)

1) (2)

3) (4)
3) (4)
11. cis-2-Butene on reaction with Br2 in CCl4 produces 17. Among the following incorrect statement(s) is/are
mainly 1) In alkenes the boiling point increases with a rise in
1) 1-bromo-2-butene (2) 2, 3-dibromobutane molecular mass
3) Meso-2, 3-dibromobutane 2) Branching in an alkane decreases the boiling point
4) (±) 2, 3-dibromobutane 3) Boiling point of an odd numbered carbon atoms alkane
is lower than both of its even numbered neighbours
12. 4) Melting point of an odd numbered carbon atoms alkane
is lower than next even numbered neighbours
A is
18. Me3CMgCl on reaction with D2O produces :

1) (2) 1) Me3CD (2) Me3COD

3) (CD3)3CD (4) (CD3)3COD
19. Which of the following alkyl bromide may be used
for the synthesis of 2, 3-dimethyl butane by Wurtz
3) (4)
reaction ?

13. Which of the following reaction will lead to the

1) (2)
creation of two chiral centres in the product ?
4
1) CH3CH = CHCH3 + Br2  
CCl 3) Isobutyl bromide (4) s-butyl bromide

4 CCl
2) CH3CH2CH = CH2 + Br2  
20. Products.
3) CH3CH = CHCH3 + HBr 
4) CH3CH2CH = CH2 + HBr 
How many monobrominated products will be
14. obtained by above reaction ?
1) 6 (2) 4 (3) 5 (4) 3
Product of above reaction will be :
Peroxide
1) Racemix mixture (2) Diastereomers 21. H3C - CH = CH2 + HCl 
 Product,
3) Meso (4) Constitutional isomers the intermediate of reaction is :
 
1) CH 3  C H  CH 3 (2) CH 3  CH 2  C H 2
15.
 
3) CH 3  C H  CH 3 (4) CH 3  CH 2  C H 2

1) (2)
22.

3) (4)
1)

16.
2)

1) (2) 3)

4) None of these

3) (4)
23. Correct order of reactivity towards electrophilic 31. The number of iodine molecules present in 1cm3
addition reactions is : of its 0.1 M solution is
1) CH2 = CH2 > CH3 - CH = CH2 > (CH3)2C = CH2 1) 6.02 x 1023 2) 6.02 x 1022
2) CH2 = CH2 > CH3 - CH = CH2 < (CH3)2C = CH2 3) 6.02 x 1019 4) 6.02 x 1020
3) CH2 = CH2 < (CH3)2C = CH2 < CH3 - CH = CH2 32. The weight of Ca(OH)2 in 100 ml of 0.01 M
4) CH3 - CH = CH2 < CH2 = CH2 < (CH3)2C = CH2 solution will be: (At mass of Ca = 40)
24. HBr reacts with H 2 C =CH–OCH 3 under 1) 1.48 g 2) 74 g
anhydrous conditions at room temperature to 3) 14.8 g 4) 0.074 g
give : 33. Two solutions of a substance (non electrolyte)
1) CH3 CHO and CH3Br are mixed in the following manner 480 ml of
2) BrCH2 CHO and CH3OH 1.5 M first solution and 520 ml of 1.2 M second
3) BrCH2 – CH2 – OCH3 solution. What is the molarity of the final
4) H3C – CHBr – OCH3 mixture?
25. Reaction of trans – 2– phenyl –1– bromocyclopentane 1) 1.26 M 2) 1.50 M
on reaction with alcoholic KOH produces : 3) 1.344 M 4) 2.70 M

1) 4- phenyl cyclopentene 34. When 6 gm urea dissolve in 180 gm H2O. The

2) 2- phenyl cyclopentene mole fraction of urea is [Mol. wt. of urea = 60]

3) 1- phenyl cyclopentene
10 10.1
4) 3 - phenyl cyclopentene 1) 2)
10.1 10
26. What is the molarity of H2SO4 solution that has
a density of 1.84 gm/cc at 350C and contains 98% 10.1 0.1
3) 4)
by weight? 0.1 10.1
1) 4.18 M 2) 8.14 M
35. 20 g of hydrogen is present in 5 litre vessel. The
3) 18.4 M 4) 18 M
molar concentration of hydrogen is:
27. The molality of 90% H2SO4 solution is
1) 4 2) 1
[density = 1.8 gm/ml] 3) 3 4) 2
1) 1.8 2) 48.4
36. The number of moles present in 2 litres of 0.5
3) 9.18 4) 94.6 M. NaOH is
28. Density of a 2.05 M solution of acetic acid in 1) 2 2) 1 3) 0.1 4) 0.5
water is 1.02 g/mL. The molality of the solution 37. 9.8 g of H2SO4 is present in 2 litres of a solution.
is The molarity of the solution is
1) 2.28 mol kg1 2) 0.44 mol kg1 1) 0.1 M 2) 0.05 M 3) 0.2 M 4) 0.01 M
3) 1.14 mol kg 1
4) 3.28 mol kg 1
38. The weight of (COOH) 2 . 2H 2 O needed to
29. A molal solution is one that contains one mole prepare 500 dm3 of 0.1 M solution is:
of a solute in 1) 12.6 g 2) 9 g 3) 4.5 g 4) 6.3 g

1) 1000 g of solvent 2) 1000 ml of solution 39. A solution of CaCl2 is 0.5 mol/litre, then the
moles of chloride ion in 500 ml will be
3) 1 litre of the solvent 4) 22.4 litre of the solution
1) 0.25 2) 0.50 3) 0.75 4) 1.00
30. Molarity of 10.6% (w/v) Na2CO3 solution
1) 2 M 2) 0.5 M
3) 1.5 M 4) 1 M
40. The molarity of a solution obtained by mixing
750 mL of 0.5 M HCl with 250 mL of 2 M HCl
will be
1) 0.875 M 2) 1.00 M 3) 1.25 M 4) 2.5 M
41. If 100 mL of 1.0 M NaOH solution is diluted to
1.0 L, the resulting solution contains
1) 1 mol of NaOH 2) 0.1 mole of NaOH
3) 10.0 mole of NaOH 4) 0.05 mole of NaOH
42. How many grams of methanol would have to
be added to water to prepare 150 mL of solution
which is 2 M CH3OH?
1) 9.6 2) 2.4 3) 9.6 x 103 4) 4.3 x 102
43. 0.5 M of H2SO4 is diluted from 1 litre to 10 litre,
molarity of resulting solution is
1) 1 M 2) 0.05 M 3) 10 M 4) 11 M
44. Number of moles present in 6 dm3 of solution
to form centimolar solution is
1) 6 x 102 2) 6 x 103 3) 6 x 101 4) 6 x 104
45. True for solution of 0.020 M H2SO4?
1) 2 litre of the solution contains 0.20 mole of SO42
2) 2 litre of the solution contains 0.080 mole of H3O+
3) 1 litre of the solution contains 0.020 mole of H3O+
4) 1 litre of the solution contains 0.04 mole of SO42