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Lakshya JEE (2024)

Haloalkanes and Haloarenes DPP-09

→( A )
1. Which of the following is not reasonable for an NaNH
5. Ph − CH2 − CH− CH2 − CH3 ⎯⎯⎯⎯
2
elimination reaction? |
Br
NaOH
⎯⎯⎯⎯
HO → Total number of elimination product is (includes
(1) 2

NaOEt stereoisomer):
⎯⎯⎯⎯
EtOH → (1) 2
(2)
NaOEt (2) 4
⎯⎯⎯⎯⎯
H O/ EtOH → (3) 6
(3) 2

NaI (4) 8
(4) ⎯⎯⎯ →
6. For the reaction, williamson's synthesis
2. What is the major product of the following reaction? E2 − 

+CH3CH2 O N a ⎯⎯ →
t −BuOK
⎯⎯⎯⎯⎯
t −BuOH → The major product is formed by
(1) SN1 reaction
(2) SN2 reaction
(1) (2)
(3) E1 reaction
(4) E2 reaction

(3) (4) 7. Debromination of meso-dibromobutane gives

mainly:
3. Which of the following dibromides would yield 2- (1) n-butane
butyne upon elimination? (2) 1-butene
(3) cis-2butene
I. II. (4) trans-2-butene

8. The reagent(s) for the following conversion,

III. IV.
(1) Alcoholic KOH
(1) III (2) II and III (2) Alcoholic KOH followed by NaNH2
(3) II and IV (4) I (3) Aqueous KOH followed by NaNH2
(4) Zn/CH3OH
4. Which alkyl bromide will yield only one alkene upon
E2 elimination? 9. n-Propyl bromide on treatment with ethanolic
potassium hydroxide produces
(1) Propane
(1) (2)
(2) Propene
(3) Propyne
(3) (4) (4) Propanol
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10. In the reaction

CH3CHCH3 (3)
| ⎯⎯⎯⎯
alc. KOH
→X ⎯⎯⎯⎯
HBr
→Y
Br Peroxide

⎯⎯⎯⎯
NaI
→Z;
Acetone Z is
(4)
(1) CH3CH2CH2I
(2) CH3 CH– CH3
|
I
Cl
(3) CH3C = CHI |
| 14. CH3 — CH — CH — CH3
I |
(4) CH3CHCH2 I CH3 ⎯⎯⎯⎯
t-BuOH

→
| Major product is
I
(1) CH3 — C = CH — CH3
11. Which one of the following compound undergoes E1 |
CH3
reaction most readily?
CH3 (2) CH3 — CH — CH = CH2
| |
(1) CH3 — C — CH2 — CH3 CH3
| (3) CH2 = C — CH2 — CH3
Br |
(2) CH3—CH2—CH2—Br CH3
(3) CH3—CH2—CH2—I
CH3
CH3 |
| (4) CH3 — CH — CH — CH3
(4) CH3 — C — CH2 — CH3 |
| CH3
I

12. 2-Chlorobutane on treatment with alcoholic KOH/Δ 15. X and Y are respectively are
gives mainly
(1) 2-Butene (2) 1-Butene
(3) 2-Butanol (4) 1-Butyne

13. Select the formula representing the major product of

the following reaction (1)
⎯⎯⎯⎯⎯⎯⎯⎯
→
CH3CH2OK/CH3CH2OH

(2)

(3)
(1)

(4)
(2)
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Br
|
( X) NaNH2 − 
16. Ph − CH− CH2 ⎯⎯⎯⎯⎯ → Ph − C  C Na
|
Br
(X = No. of moles of NaNH2) Value of X is:
(1) 1 (2) 2
(3) 3 (4) 4
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (4) 9. (2)
2. (2) 10. (1)
3. (2) 11. (4)
4. (2) 12. (1)
5. (2) 13. (3)
6. (4) 14. (3)
7. (4) 15. (1)
8. (2) 16. (3)

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