SUBJECT : CHEMISTRY

Topic : ALDOL & CANNIZARO REACTION

1. (1) Ca(OH )2 4. , B is :-
CH3—COOH−−−−−−−−→ P, compound P can
(2) Δ (1)
show :-
(1) Aldol condensation reaction (2)
(2) Cannizzaro's reaction
(3) Reducing property with Tollen's reagent (3)
(4) All
2. (4)
reactant (A) is :-
5. What is the major organic product of the
(1) following aldol reaction ?

(2)

(3)

(1) (i) (2) (ii)

(4) (3) (iii) (4) (iv)
6.
3. OH Θ
−−−→ Product
Δ

Product 'B' is : Product is :-

(1) (1) (2)

(2) CH3 – CH=CH – CHO

(3) CH3 – CH2 – CH2 – CHO (3) (4)
(4) CH2=CH – CH2 – CHO

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7. 10. Major product B of the given reaction sequence
Major
is
product will be :
(1) (2)
(1) (2)
(3) (4)
(3) (4)

8.
11. Aldol condensation would not occur in :
: (1) CH3COCH3 (2) CH3CH2CHO
What is X ? (3) HCHO (4) CH3CHO
(1) 12. Cannizzaro reaction is not given by

(2) Br – CH2 – COOH (1) methanal

(3) CHO — CHO (2) phenyl methanal

(4) (CH3CO)2O (3) 2, 2-dimethylbutanal

9. (4) phenyl ethanal

, 13. Statement-I : Cross aldol condensation of ethanal
and propanal gives mixture of four structural
product is :- products (excluding stereoisomers).
(1) Statement-II : Ethanal and propanal, both have
(2) α − H.
(1) Statement I is correct and Statement II is
incorrect
(3) (4) (2) Statement I is incorrect and Statement II is
correct
(3) Both Statement I and Statement II are
correct
(4) Both Statement I and Statement II are
incorrect

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14. 17. What is the end product (D) in given reaction :-
KCN SnCl2 H+ dil
CH3 – Cl −−−→A −−−→ B −−→ C −−−→ D
+ H2 O −
HCl OH−

product (A) is :- (1)

(1) (2)
(2)
(3)
+ CH3 – CH2 – OH

(4) + CH3 – CH2 – OH

(3) (4)
18. Which of the following cannot be obtained as a
product by aldol condensation of Acetaldehyde
15. and acetone ?

is the final product formed when (1) (CH3)2C=CHCOCH3

(2) (CH3)2C=CH – CHO
by which of the following is reacted with base :- (3) CH3CH=C(CH3)2
(1) (4) CH3CH=CHCHO
19. The product formed in aldol reaction is :-
(2)
(1) a, β - hydroxy acid
(3) (2) β - hydroxy aldehyde or ketone
(3) an α - hydroxy aldehyde or ketone
(4)
(4) an α , β - unsaturated ester
16. Which of the following compound does not give 20. (i) BH3 T HF dil.NaOH
CH3 − C ≡ CH −−−−−−−−Θ−→ P −−−−−−→ Q
Aldol condensation reaction ? (ii) H2 O2 ,OH Δ
(1) Acetophenone
Q is :-
(2) Propanal
(1)
(3) Cyclohexanone
(4) Benzophenone (2)

(3)

(4)

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21. Which of the following would undergo aldol 24. Match the column
condensation ? Column-I (Aldol
Column-II (Products)
Reaction)
(2)
2CH3CHO
(1) CCl3CHO (a) (p) CH3C(OH)CH3.CH2COCH3

2CH3COCH3
(b) (q) CH3CH(OH)CH2CHO
(3) CH3CH2CHO (4) HCHO
2HCHO
22. Cannizzaro's reaction is least feasible in:
(c) (r) C6H5CH2OH+HCOONa
(2)
(1) C6H5CHO+HCHO
(d) (s) CH3OH + HCOONa

(3) C6H5 – CH=O (4) (CH=O)2

(1) 1 → r;2 → s;3 → q;4 → p
23. Acetone is treated with excess of ethanol in the
presence of hydrochloric acid. The product (2) 1 → q;2 → p;3 → s;4 → r
obtained is- (3) 1 → q;2 → s;3 → r;4 → p
(1) (4) 1 → r;2 → p;3 → s;4 → p
25. Match the following structure given in column -I
with their common name given in Coumn -II and
(2)
choose the correct option from the codes given
below.
(3) Column-II
Column – I (Structure)
(Common name)
(A) HCHO (p) Valeraldehyde

(4) (B) CH3CH2CH2CH2CHO (q) Phthaldehyde

(C) H2C = CH — CHO (r) Acrolein

(D) (s) Formaldehyde

Code:

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26. The reagent which does not react with both 30. The pair of compounds which can be
acetone and benzaldehyde is distinguished by iodoform test is
(1) sodium hydrogen sulphite (1)
(2) phenyl hydrazine
(3) Fehling's solution
(2)
(4) Grignard reagent
27. Consider the following sequence of reactions.
(3)

(4)
The final product (C) is.
(1) (CH3)2C(OH)CH2COCH3 31. Statement-I: Benzaldehyde and acetophenone in
(2) (CH3)2C = CHCOCH3 presence of aqueous alkali at 293 K gives
(3) (CH3)2CHCH2CHOHCH3 benzalacetophenone as major product.
Statement-II: Acetophenone contains three
(4) (CH3)2C=CHCHOHCH3 enolizable hydrogen atoms.
28. In light of above statements, choose the correct
answer.
Which is correct in above reaction :
(1) Statement-I is correct but statement-II is
(1) A is benzyl alcohol & B is phenol
incorrect
(2) A is benzyl alcohol & B is sodium benzoate (2) Statement-I is incorrect but statement-II is
(3) A is phenol & B is sodium benzoate correct
(4) A is benzene & B is phenol (3) Both statement-I and statement-II are
29. incorrect
(4) Both statement-I and statement-II are
correct
Product of this cannizaro reaction is :
(1) DCOO – + CH2DOD
(2) HCOO – + DCOO –
(3) DCOO – + CH2DOH
(4) DCOO – + CHD2OH

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32. Which of the following react with NaHSO3 and
form precipitate :
(1)

(2)

(3)
(4)

33.

(1) A, B and C are correct(2) A & B are correct

(3) C & D are correct (4) A & C are correct
34.

End product (B) of above reaction is :-

(1) (2)

(3) (4)

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35. 38.
+ + OH ϴ —→ ?

(1) + HCOO ϴ Find out the structure of 'X':

(2) (2)
+ CH3OH (1)

(3) HCOO ϴ + CH3OH

(4) (3)
(4) None of these
+
39. HgSO4 (i) dil. NaOH
36. HC ≡ CH −−−−−−→ A −−−−−−−−→ B
dil. H2 SO4 (ii) Δ
Product B is :
Product B is :- (1) CH3 – CH2 – CH2 – CHO
(1) HO – CH2 – (2) (2) CH3 – CH=CH – CHO
COONa (3)
(3) HOOC – CH2 – (4)
COOH (4)
37. Statement I : Cannizaro reaction is a
disproportionation 40. Which of the following is best hydride donar in
Statement II : 40% solution of HCHO in water is cannizzaro reaction ?
well known as formalin (1) (2)
In the light of the above statements, choose the
most appropriate answer from the options given
below :
(1) Both statement I and statement II are
incorrect.
(3) (4)
(2) Statement I is correct but statement II is
incorrect.
(3) Statement I is incorrect but statement II is
correct.
(4) Both statements I and statements II are
correct.

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41. Match the column I with column II & mark the 43.
appropriate choice :- . 'B' will be :-

(1)
(2)

(3) (4)

44. In a cannizzaro’s reaction, the intermediate that

will be the best hydride donar is
(1)
(1) A→ (i), B → (ii), C → (iii), D → (iv)
(2) A→ (iii), B → (iv), C → (i), D → (ii)
(3) A→ (iv), B → (i), C → (ii), D → (iii)
(4) A → (ii), B → (iii), C → (iv), D → (i) (2)
42.

(3)
Which statement is not incorrect for above
reaction?
(A) It involves a dehydration reaction
(B) Intermediate carbanion is formed
(C) One of the step is Nucleophilic addition (4)
(D) One of the step is Electrophilic addition
(1) A, B, (2) only (3) only
(4) All
C A, D B, C

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45. Number of compounds which will undergo 48. conc. NaOH
−−−−−−−−→ Product
cannizzaro reaction :- Δ
(1) (2)

(3) (4)

49.
OH Θ
−−−→ (A)
Δ
(B) ; (B) will be : –
(1)

(1) 5 (2) 6 (3) 7 (4) 4

46. Δ
(2)
A −→ B
OH Θ (3)
−−−→ C
Δ
compound B and C are :-
(1) (4)

(2)
50. product (C) will be :-
Al2 O3 /Cr2 O3 O3 NaOH
n Hexane −−−−−−∘−−→ A −−−−−→ B −−−−→ C
(3) 500−600 C H2 O/Zn

(1)
(4) None of these (2)
47.
(3)
(4)
(R) and (S) is :-
(1) Both Ph – COOH
(2) Both Ph – CH2OH
(3) Ph – COONa & Ph – CH2OH
(4) Ph – CH2OH & Ph – CHO

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