Chemistry AIIMS _ 10.05.

2019 Class Test

1. Which of the following is the most stable
conformer of cyclohexane –1, 4 – diol

5.
(1) (2)

(3) (4) Product (B) is

2. How many dichloroproduct wil be found on (1)

photochl orination of foll owing (including
stereoisomers)
(2)

(3)

(4)
(1) 4 (2) 5
6. Which of the following will not give haloform
(3) 6 (4) 2
reaction

3. (1) (2)

Product (D) is (3) (4)

7. + major

(1) (2)
Alkene
Product (P) is

(1) (2)

(3) (4)
(3) (4)
4. In which of the following first one is more
reactive towards electrophilic substitution 8. Campare the enol content in the following
than second one

(a) (b) (c)

(1) , (2) ,

(1) a > b > c (2) b > a > c

(3) c > a > b (4) c > b > a
(3) , (4) ,

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 Chemistry AIIMS _ 10.05.2019 Class Test

9.
(3) (4)
Procuct (C) is

(1) (2)

14. ‘P’, Proudct ‘P’ is

(3) (4) None

10. Which of the following will give aldol

condensation reaction
(1) (2)
(1) (2)

(3) (4)
(3) (4)

15.  – D – glucopyranose and  – D –

11. B
(Major ) glucopyranose are :
(1) anomers (2) epimers
(3) enantiomers (4) tautomers

A and B are :
16.
(1) Both A and B are (CH3)3C – OCH2CH3
(2) Both A and B are (CH3)2C = CH2
(3) A is (CH3)3 C –– OCH2CH3 and B is (CH3)2C = Product :
CH2
(4) A is (CH3)2C = CH2 and
B is (CH3)3C –OCH2CH3
12. Order of rate of reaction of following compound (1) (2)
with phenyl magnesium bromide is :

(1) I > II > III (2) I > III > II

(3) III > I > II (4) II > I > III (3) (4)

13. D
17. P

Find out the S will be :

structure of ‘A’ :

(1) (2)
(1) (2)

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Chemistry AIIMS _ 10.05.2019 Class Test
(1) I > II > III > IV (2) I > III > II > IV
(3) IV > III > II > I (4) IV > III > I > II
(3) (4)
24. Number of moles of HI consumed per mole of

18. Product, find followed by heating is

structure of product : (1) 2 (2) 1

(3) 3 (4) 4
25. The final major product obtained in the
reaction is
(1) (2)

(3) (4)

19. Nylong – 66 is made by using :

(1) phenol (2) benzaldehyde
(3) adipic acid (4) succinic acid
20. Drug which helps to reduce anxiety and brings
about calmness is : (1) (2)
(1) tranquilizer (2) diuretic
(3) analgesic (4) antihistamine
21. For the preparation of 1 – phenylethanol and 2
– phenylethanol by using phenylmagnesium
bromide followed by mild acidicfication on
reactant respectively is (3) (4) None of these
(1) HCHO and CH3CHO

(2) and CH3CHO 26. Which of the following is not an ore of lead ?
(1) Cerussite (2) Anglesite
(3) Cassiterite (4) Galena
(3) CH3CHO and 27. Which of the following is commonly known as
Indian salt peter ?
(1) NaNO3 (2) KNO3
(4) CH3COOCH3 and (3) AgNO3 (4) Sr(NO3)2
28. Which of the following statements is correct
22. If 120 gm of propanol reacts with 23 gm of Na, for elements of 15th group ?
then what will be the weight of released gas ? (1) Nitrogen can show maximum covalency 5
(1) 2 gm (2) 60 gm (2) BiCl5 is quite stable at room temperature
(3) 1 gm (4) 1. 5 gm (3) P(C2H5)3 cannot form d–d bond with
23. What will be the order of reactivity of the transition metals
following alcohols towards concentrated HCl ? (4) Stability of MH3 decreases from N to Bi
29. Which of the following is not the correct set of
chemicals for the preparation of the oxide of
(I) (II) nitrogen shown ?
(1) NH4NO2 NO2
(2) NaNO2 + H2SO4 + FeSO4 NO
(III) (IV) (3) Pb(NO3)2 NO2
(4) HNO3 + P2O5 N 2O 3
30. Industrially, dioxygen is obtained from :
(1) Heating Ag2O or HgO
(2) heating Pb3O4 or PbO2
(3) heating H 2O2 with MnO2
(4) distillation of liquid air at 77.2 K

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Chemistry AIIMS _ 10.05.2019 Class Test
?
31. Which of the following statements is not (1) [Ni(H2O)6] Cl2 (2) [Ni(en)3]Cl2
correct ? (3) [Ni(en)2(H2O)2]Cl2 (4) [Ni(en)(H2O)4]Cl2
(1) SO2 reacts with chlorine in the presence of 41. Identify the correct statement w.r.t the
charcoal catalyst to produce SO2Cl2 following reaction 2K 2MnO4 + Cl2 2KCl +
(2) SO2Cl2 is named as sulphonyl chloride 2KMnO4 :
(3) SO2Cl2 has tetrahedral shape and geometry (1) orxidation of potassium manganate is
both taking place
(4) SO2Cl2 is liquid at room temperature (2) reduction of potassium maganate is taking
32. Which of the following is the ever first place
compount of noble gases to have been prepared (3) Oxidation of Cl2 is taking place
? (4) Cl2acts as reducting agent in the reaction
(1) XeF2 (2) XeO3 42. Name the gas that can readily decolourise
(3) XePtF6 (4) XeOF4 acidic KMnO4 solution.
33. Which of the following is incorrect w.r.t. (1) SO2 (2) NO2
ionisation energies as discussed ? (3) P2O5 (4) CO2.
(1) The 1st ionisation energy of Cr is less than 43. Heavy water is used as a :
that of Mn (1) fuel in engine
(2) The 2nd ionisation energy of Mn is less (2) semiconductor
than that of Cr (3) moderator in nuclear reactor
(3) The 3rd ionisation energy of Cr is less than (4) insulator in steam engine
that of Mn 44. The ionic mobility of alkali metal ions in
(4) The 4th ionisation energy of Cr is less than aqueous solution is maximum for :
that of Mn (1) K+ (2) Rb+
+
34. 7g of N2occupies 8.4L at 20°C. What is the (3) Li (4) Na+
pressure of the gas under these conditions ? 45. The products obtained on heating LiNO 3 will be
(1) 0.72 atm (2) 3.50 atm :
(3) 0.445 atm (4) 77.1 atm (1) Li2O + NO + O2 (2) LiNO2 + O2
35. Which of the following will show fac and mer (3) Li3N + O2. (4) Li2O + NO2 + O2
geometrical isomerism ?
(1) [Co(NH3)3(NO2)3] (2) [CoCl2(en)2]+
3+
(3) [Co(en)3] (4) [CoCl6]3–
36. The following two compounds (A) and (B) are
related to each other as :
(A) : [Co(NH3)6][Cr(CN)6]
(B) : [Cr(NH3)6][Co(NH3)6]
(1) ligand exchange isomers
(2) metal exchange isomers
(3) polymerisation isomers
(4) coordination isomers
37. Which of the following is paramagnetic ?
(1) [NiCl4]2– (2) [Ni(CO)4]
(3) [Ni(CN)4]2– (4) All of these
38. In strong field octahedral crystal field splitting
the value of energy in terms of 0 for d4 system
will be :
(1) + 1.6 0 (2) – 1.6 0
(3) – 0.6 0 (4) + 0.6 0.
39. Which of the following is correct according to
VBT ?
(1) [Fe(H2O)6]3+ is highly paramagnetic
(2) [Fe(CN)6]3– has EAN of Fe = 36
(3) [Co(NH3)6]3+ is outer orbital complex
(4) [Ni(NH3)6]2+ is inner orbital complex
40. Aqueous solutions of the following complexes
have pale blue, violet, blue or green colour,
which one do you expect will have green colour

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Chemistry AIIMS _ 10.05.2019 Class Test

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 Chemistry AIIMS _ 10.05.2019 Class Test
6. Ans (3)
1. Ans (3)
due to H – bond
2. Ans (2) (1) CHx3 +

(2)

+ CHX3

(3) + CH3OH

3. Ans (3)

(4) + CH3 –

CH2 –
(A) (B)
OH

7. Ans (2)

+ + CH3COOH
(C) (D)

4. Ans (3)
8. 

5. Ans (2)


Ph – OH +

(aldol

condensation)


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 Chemistry AIIMS _ 10.05.2019 Class Test
9. Ans(2)

Br2 /h
13.  

I–

O3

Zn/H2O


14.

15. Both are non-mirror image stereoisomers and

cyclic epimers, which are anomers.
10. Ans

16.
(1) do not have  – H

(2) +

(3)

(4)


Et  O Na  17.
11.  E2



EtOH

E1


18.

12. Order of SN AE

19. Theory based

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Chemistry AIIMS _ 10.05.2019 Class Test
20. Theory based 33. Ans (4)
21. Cr Mn
Atom 3d5 4s1 3d5 4s2 IE 1 : Cr < Mn
M+ 3d5 3d54s1 IE 2 : Mn < Cr
2+
M 3d4 3d5 IE 3 : Cr < Mn
111
M 3+ 3d3 3d4 IE 4 : Cr ( t2g ) > Mn
34. Ans (1)

35. Ans (1)

36. An (3)
 1 37. Ans (1)
22. Na  CH3CH2OH  CH3CH2 O Na   H2 (g)
1mole 2mole 2
In [NiCl4]2–, Ni2+ is 3d8
1
for each 1 mole of Na mole of H2 is released
2 In [NiCO4],Ni0 is 3d10
1
 weight of H2 (g)  2  2g  1g
In[NiCN]42–,Ni2+ is 3d8
23. Reactivity  stability of carbocation
38. Ans (2)
For strong field octahedral system

24.

0 = 4 × (–0.40) = – 1.60
39. Ans (1)
In [Fe(H2O)6]3+, Fe3+ has 3d5, 5 unpaired
25.
electrons.
In [Fe(CN)6]3–,Fe3+ has EAN = 26 –3 +12=35
[Co(NH3)6]3+,Co3+ has 3d6 is inner orbital
complex becomes NH3 is a strong ligand
[Ni(NH3)6]2+,Ni2+ has 3d8 Through NH3 is a
strong ligand , pairing of electrons will vacate
26. Ans (3) only one orbital of 3d– subshell. Hence
Cerussite is PbCO3, Anglesite is PbSO4, hybridisation will be sp 3d2 outer orbital system.
Cassiterite is SnO2, Galena is PbS. 40. Ans (1)
27. Ans (2) Lesser the chelation, lighter is the colour.
28. Ans (4) 41. Ans (1)
Down the group M–H bond length increases K 2MnO4 KMnO4
and strength of the bond decreases. +2+x–8=0 +1+y–8=7
29. Ans (4) x=+6 y=+7
N2O3 is condensing NO and N2O4 at 250 K. 42. Ans (1)
2NO(g) + N2O4(l) N2 O 3
Blue solid

30. Ans (4) 43. Ans (3)

31. Ans (2) 44. Ans (3)
SO2Cl2 is named as sulphuryl chloride Li+ is smallest in size and most heavily
32. Ans (3) hydrated.
45. Ans (4)