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ARJUNA JEE 2023

GOC-Isomerism DPP-03

1. Which of the following is known as Baker-Nathan 8. The correct order for the stability of given
effect? carbocation is
(1) Mesomeric effect
(2) Inductive effect
(3) Hyperconjugation
(4) Electromeric effect

2. Hyperconjugation involves the delocalisation of___

(1) I > II > III (2) III > II > I
(1) σ bond orbital
(3) II > I > III (4) II > III > I
(2) π bond orbital
(3) Both σ and π bond orbital
9. Number of alpha hydrogens in
(4) None of the mentioned
2, 2, 5, 5-tetramethylhex-3-ene.
(1) 12 (2) 6
3. Number of hyperconjugation structures in isopropyl
(3) 2 (4) zero
carbocation is __________
(1) 3 (2) 6
10. The most stable carbocation is
(3) 9 (4) 12

4. On increasing the number of α-hydrogens, the (1) (2)

number of hyperconjugation structures will ______
(1) Decrease
(2) Increase
(3) Remains same
(4) None of the mentioned (3) (4)

5. Larger the number of hyperconjugation structures, 11. Hyperconjugation is most useful for stabilizing
the stability of free carbocation will __________ which of the following carbocations?
(1) Increase (1) Neo-pentyl (2) tert-Butyl
(2) Decrease (3) Iso-propyl (4) Ethyl
(3) Remains same
(4) None of the mentioned 12. The hyperconjugative stabilities of tert-butyl cation
and 2-butene, respectively, are due to
6. The most stable carbocation is
(1)  →  (empty) and  → * electron
(1) (CH3)3C (2) (CH3)2C delocalisations
 
(3) CH3CH2 (4) CH3 (2)  → * and  →  electron delocalisations
(3)  →  (filled) and  →  electron delocalisations
7. The correct order for the stability of given alkenes (4)  (filled) → * and  → * electron
is delocalisations

13. Which of the following -bonds participate in

hyperconjugation?
I V
H3C – CH = CH2 H
(III) H CH3
(1) III > II > I
II
(2) II > III > I H IV
(3) I > II > III III
(4) I > III > II (1) I and II (2) I and V
(3) II and V (4) III and IV
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14. The stability of 2, 3-dimethyl but-2-ene is more than 17. Hyperconjugation involves delocalization of
2-butene. This can be explained in terms of (1) -electron
(1) Resonance
(2) -electron
(2) Hyperconjugation
(3) Electromeric effect (3) Both  and  -electron
(4) Inductive effect (4) Proton

15. Who pointed out the concept of hyperconjugation? 18. Hyperconjugation is also known as
(1) Nathan & Baker (2) Mulliken (1) Baker-Nathan effect
(3) Kekule (4) Kolbe (2) No bond resonance
(3) Anchimeric effect
16. Hyperconjugation is (4) All of these
(1) - conjugation
(2)Delocalization of  and  bonds
(3) No bond resonance
(4) All of the above
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (3) 10. (2)
2. (1) 11. (2)
3. (2) 12. (1)
4. (2) 13. (2)
5. (1) 14. (2)
6. (1) 15. (1)
7. (3) 16. (4)
8. (2) 17. (1)
9. (4) 18. (1)

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