Unique Practice Questions

Chemistry
Unique Practice Questions

(Collection of JEE Main 2019-21)
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Unique Practice Questions_Chemistry

1. Consider the following reaction:
The product ‘X’ is used
(1) In acid base titration as an indicator
(2) In protein estimation as an alternative to ninhydrin
(3) In laboratory test for phenols
(4) As food grade colourant
2. The electron gain enthalpy (in kJ/mol) of fluorine, chlorine, bromine and iodine, respectively, are :
(1) –296, –325, –333 and –349 (2) –333, –325, –349 and –296
(3) –349, –333, –325 and –296 (4) –333, –349, –325 and –296
3. The number of chiral carbons in chloramphenicol is ___________.
4. The flocculation value of HCl for arsenic sulphide sol. is 30 m mol L–1. If H2SO4 is used for the flocculation of
arsenic sulphide, the amount, in grams, of H2SO4 in 250 ml required for the above purpose is ______.
(molecular mass of H2SO4 = 98 g/mol)
5. The number of sp2 hybridised carbons present in “Aspartame” is ______.
6. As per Hardy-Schulze formulation, the flocculation values of the following for ferric hydroxide sol are in the
order
(1) AlCl3 > K3[Fe(CN)6] > K2CrO4 > KBr = KNO3 (2) K3 [Fe(CN)6] < K2CrO4 < KBr = KNO3 = AlCl3
(3) K3[Fe(CN)6] > AlCl3 > K2CrO4 > KBr > KNO3 (4) K3[Fe(CN)6] < K2CrO4 < AlCl3 < KBr < KNO3
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Unique Practice Questions Chemistry
7. The number of chiral centres in penicillin is _____________.
8. For the following Assertion and Reason, the correct option is
Assertion : For hydrogenation reactions, the catalytic activity increases from Group 5 to Group 11 metals
with maximum activity shown by Group 7-9 elements.
Reason : The reactants are most strongly adsorbed on group 7-9 elements.
(1) Both assertion and reason are true and the reason is the correct explanation for the assertion.
(2) Both assertion and reason are false.
(3) The assertion is true, but the reason is false.
(4) Both assertion and reason are true but the reason is not the correct explanation for the assertion.
9. White phosphorus on reaction with concentrated NaOH solution in an inert atmosphere of CO 2 gives phosphine
and compound (X). (X) on acidification with HCl gives compound (Y). The basicity of compound (Y) is
(1) 3 (2) 2
(3) 4 (4) 1
10. Complexes (ML5) of metals Ni and Fe have ideal square pyramidal and trigonal bipyramidal geometries,
respectively. The sum of the 90°, 120° and 180° L-M-L angles in the two complexes is __________.
11. The electronic configurations of bivalent europium and trivalent cerium are
(atomic number : Xe = 54, Ce = 58, Eu = 63)
(1) [Xe] 4f7 and [Xe] 4f1 (2) [Xe] 4f7 6s2 and [Xe] 4f2 6s2
(3) [Xe] 4f2 and [Xe] 4f7 (4) [Xe] 4f4 and [Xe] 4f9
12. A chemist has 4 samples of artificial sweetener A, B, C and D. To identify these samples, he performed certain
experiments and noted the following observations :
(i) A and D both form blue-violet colour with ninhydrin.
(ii) Lassaigne extract of C gives positive AgNO3 test and negative Fe4[Fe(CN)6]3 test.
(iii) Lassaigne extract of B and D gives positive sodium nitroprusside test.
Based on these observations which option is correct?
(1) A : Aspartame; B : Alitame;
C : Saccharin; D : Sucralose
(2) A : Saccharin; B : Alitame;
C : Sucralose; D : Aspartame
(3) A : Alitame; B : Saccharin;
C : Aspartame; D : Sucralose
(4) A : Aspartame; B : Saccharin;
C : Sucralose; D : Alitame
13. Which of these will produce the highest yield in Friedel Crafts reaction?
(1) (2)
(3) (4)
14. The mass percentage of nitrogen in histamine is _____.
15. A, B and C are three biomolecules. The results of the tests performed on them are given below
A, B and C are respectively :
(1) A = Lactose, B = Fructose, C = Alanine (2) A = Lactose, B = Glucose, C = Alanine
(3) A = Glucose, B = Fructose, C = Albumin (4) A = Lactose, B = Glucose, C = Albumin
16. Biochemical Oxygen Demand (BOD) is the amount of oxygen required (in ppm)
(1) By bacteria to break-down organic waste in a certain volume of a water sample
(2) For sustaining life in a water body
(3) By anaerobic bacteria to break down inorganic waste present in a water body
(4) For the photochemical break down of waste present in 1 m3 volume of a water body
17. On heating compound (A) gives a gas (B) which is a constituent of air. This gas when treated with H 2 in the
presence of a catalyst gives another gas (C) which is basic in nature. (A) should not be:
(1) Pb(NO3)2 (2) (NH4)2Cr2O7
(3) NH4NO2 (4) NaN3
18. While titrating dilute HCl solution with aqueous NaOH, which of the following will not be required?
(1) Pipette and distilled water (2) Clamp and phenolphthalein
(3) Burette and porcelain tile (4) Bunsen burner and measuring cylinder
19. The statement that is not true about ozone is
(1) In the stratosphere, CFCs release chlorine free radicals (Cl) which reacts with O3 to give chlorine dioxide
radicals
(2) It is a toxic gas and its reaction with NO gives NO2.
(3) In the atmosphere, it is depleted by CFCs
(4) In the stratosphere, it forms a protective shield against UV radiation
20. If you spill a chemical toilet cleaning liquid on your hand, your first aid would be
(1) aqueous NaOH (2) aqueous NaHCO3
(3) aqueous NH3 (4) vinegar
21. The correct observation in the following reactions is :
(1) Gives no colour (2) Formation of red colour
(3) Formation of violet colour (4) Formation of blue colour
22. The atomic number of the element unnilennium is
(1) 109 (2) 119
(3) 102 (4) 108
23. The antifertility drug “Novestrol” can react with
(1) Br2/water; ZnCl2/HCl; FeCl3 (2) ZnCl2/HCl; FeCl3; Alcoholic HCN
(3) Br2/water; ZnCl2/HCl; NaOCl (4) Alcoholic HCN; NaOCl; ZnCl2/HCl
24. Thermal power plants can lead to
(1) Eutrophication (2) Ozone layer depletion
(3) Blue baby syndrome (4) Acid rain
25. The incorrect statement(s) among (a) – (d) regarding acid rain is (are)
(a) It can corrode water pipes.
(b) It can damage structures made up of stone.
(c) It cannot cause respiratory ailments in animals.
(d) It is not harmful for trees.
(1) (a), (c) and (d) (2) (a), (b) and (d)
(3) (c) and (d) (4) (c) only
26. Match the following drugs with their therapeutic actions
Drug Therapeutic Action
(i) Ranitidine (a) Antidepressant
(ii) Nardil (b) Antibiotic
(Phenelzine)
(iii) Chloramphenicol (c) Antihistamine
(iv) Dimetane (d) Antacid
(Brompheniramine)
(e) Analgesic
(1) (i)-(d); (ii)-(c); (iii)-(a); (iv)-(e) (2) (i)-(d); (ii)-(a); (iii)-(b); (iv)-(c)
(3) (i)-(e); (ii)-(a); (iii)-(c); (iv)-(d) (4) (i)-(a); (ii)-(c); (iii)-(b); (iv)-(e)
27. An ionic micelle is formed on the addition of
(1) excess water to liquid
(2) excess water to liquid
(3) sodium stearate to pure toluene
(4) liquid diethyl ether to aqueous NaCl solution
28. The number of groups present in a tripeptide Asp – Glu – Lys is _______.
29. Match the following
Type of Colloid Examples
(i) Foam (a) smoke
(ii) Gel (b) cell fluid
(iii) Aerosol (c) jellies
(iv) Emulsion (d) rubber
(e) froth
(f) Milk
(1) (i)-(b), (ii)-(c), (iii)-(e), (iv)-(d) (2) (i)-(d), (ii)-(b), (iii)-(e), (iv)-(f)
(3) (i)-(d), (ii)-(b), (iii)-(a), (iv)-(e) (4) (i)-(e), (ii)-(c), (iii)-(a), (iv)-(f)
30. The intermolecular potential energy for the molecules A, B, C and D given below suggests that :
(1) A-B is the stiffest bond (2) A-D has the shortest bond length
(3) A-A has the largest bond enthalpy (4) D is more electronegative than other atoms
31. The processes of calcination and roasting in metallurgical industries, respectively, can Iead to
(1) Global warming and photochemical smog
(2) Photochemical smog and ozone layer depletion
(3) Photochemical smog and global warming
(4) Global warming and acid rain
32. The reaction in which the hybridisation of the underlined atom is affected is
420 K
(1) XeF4 + SbF5 → (2) H2 SO4 + NaCl ⎯⎯⎯⎯
→
+
Disproportionation H
(3) H3 PO2 ⎯⎯⎯⎯⎯⎯⎯⎯→ (4) NH3 ⎯⎯⎯
→
33. The mechanism of action of “Terfenadine” (Seldane) is :
(1) Activates the histamine receptor (2) Helps in the secretion of histamine
(3) Inhibits the secretion of histamine (4) Inhibits the action of histamine receptor
34. The number of chiral centres present in threonine is ________.
35. If a person is suffering from the deficiency of nor-adrenaline, what kind of drug can be suggested?
(1) Analgesic (2) Antidepressant
(3) Anti-inflammatory (4) Antihistamine
36. The number of chiral carbon(s) present in peptide, Ile-Arg-Pro, is _____.
37. The one that is NOT suitable for the removal of permanent hardness of water is
(1) Calgon’s method (2) Ion-exchange method
(3) Clark’s method (4) Treatment with sodium carbonate
38. The incorrect statement is
(1) bronze is an alloy of copper and tin
(2) cast iron is used to manufacture wrought iron
(3) german silver is an alloy of zinc, copper and nickel
(4) brass is an alloy of copper and nickel
39. Consider the following reactions
A → P1 ; B → P2 ; C → P3 ; D → P4,
The order of the above reactions are a, b, c, and d, respectively. The following graph is obtained when log[rate]
vs. log[conc.] are plotted
Among the following, the correct sequence for the order of the reactions is
(1) d>b>a>c (2) d>a>b>c
(3) a>b>c>d (4) c>a>b>d
40. Match the following compounds (Column-I) with their uses (Column-II)
(1) (I)-(B), (II)-(C), (III)-(D), (IV)-(A) (2) (I)-(B), (II)-(D), (III)-(A), (IV)-(C)
(3) (I)-(C), (II)-(D), (III)-(B), (IV)-(A) (4) (I)-(D), (II)-(A), (III)-(C), (IV)-(B)
41. Mischmetal is an alloy consisting mainly of
(1) lanthanoid and actinoid metals (2) actinoid and transition metals
(3) lanthanoid metals (4) actinoid metals
42. For Freundlich adsorption isotherm, a plot of log (x/m) (y-axis) and log p (x-axis) gives a straight line. The
intercept and slope for the line is 0.4771 and 2, respectively. The mass of gas, adsorbed per gram of adsorbent
if the initial pressure is 0.04 atm, is ______ × 10–4 g. (log 3 = 0.4771)
43. The atomic number of Unnilunium is _______.
44. Out of the following, which type of interaction is responsible for the stabilisation of a-helix structure of proteins?
(1) Covalent bonding (2) Hydrogen bonding
(3) Ionic bonding (4) vander Waals forces
45. The major components in “Gun Metal” are:
(1) Cu, Ni and Fe (2) Cu, Sn and Zn
(3) Al, Cu, Mg and Mn (4) Cu, Zn and Ni
46. The gas released during anaerobic degradation of vegetation may lead to :
(1) Acid rain (2) Corrosion of metals
(3) Ozone hole (4) Global warming and cancer
47. Match List-I with List-II.
List-I List-II
(Monomer unit) (Polymer)
(a) Caprolactum (i) Natural rubber
(b) 2-Chloro-1, 3-butadiene (ii) Buna-N
(c) Isoprene (iii) Nylon 6
(d) Acrylonitrile (iv) Neoprene
Choose the correct answer from the options given below:
(1) (a) → (iv), (b) → (iii), (c) → (ii), (d) → (i) (2) (a) → (iii), (b) → (iv), (c) → (i), (d) → (ii)
(3) (a) → (i), (b) → (ii), (c) → (iii), (d) → (iv) (4) (a) → (ii), (b) → (i), (c) → (iv), (d) → (iii)
48. Given below are two statements :
Statement-I : The value of the parameter “Biochemical Oxygen Demand (BOD)” is important for survival of
aquatic life.
Statement-II : The optimum value of BOD is 6.5 ppm.
In the light of the above statements, choose the most appropriate answer from the options given below:
(1) Both statement I and statement II are true (2) Both statement I and statement II are false
(3) Statement I is false but statement II is true (4) Statement I is true but statement II is false
49. Match List-I and List-II.
List-I List-II
(a) Valium (i) Antifertility drug
(b) Morphine (ii) Pernicious anaemia
(c) Norethindrone (iii) Analgesic
(d) Vitamin B12 (iv) Tranquilizer
(1) (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii) (2) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
(3) (a)-(ii), (b)-(iv), (c)-(iii), (d)-(i) (4) (a)-(i), (b)-(iii), (c)-(iv), (d)-(ii)
List-I (Salt) List-II (Flame colour wavelength)
(a) LiCl (i) 455.5 nm
(b) NaCl (ii) 670.8 nm
(c) RbCl (iii) 780.0 nm
(d) CsCl (iv) 589.2 nm
(1) (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii) (2) (a)-(ii), (b)-(iv), (c)-(iii), (d)-(i)
(3) (a)-(iv), (b)-(ii), (c)-(iii), (d)-(i) (4) (a)-(i), (b)-(iv), (c)-(ii), (d)-(iii)
51. Given below are two statements:
Statement-I : CeO2 can be used for oxidation of aldehyde and ketones.
Statement-II : Aqueous solution of EuSO4 is a strong reducing agent.
In the light of the above statements, choose the correct answer from the options given below:
(1) Both Statement I and Statement II are false (2) Both Statement I and Statement II are true
(3) Statement I is true but Statement II is false (4) Statement I is false but Statement II is true
52. Given below are two statements:
Statement-I : An allotrope of oxygen is an important intermediate in the formation of reducing smog.
Statement-II : Gases such as oxides of nitrogen and sulphur present in troposphere contribute to the fomation
of photochemical smog.
In the light of the above statements, choose the correct answer from the options given below:
(1) Statement I is true but Statement II is false (2) Both Statement I and Statement II are false
(3) Statement I is false but Statement II is true (4) Both Statement I and Statement II are true
53. Compound(s) which will liberate carbon dioxide with sodium bicarbonate solution is/are :
(1) B only (2) C only
(3) A and B only (4) B and C only
54. The major components of German Silver are:
(1) Cu, Zn and Ni (2) Zn, Ni and Ag
(3) Ge, Cu and Ag (4) Cu, Zn and Ag
55. The correct sequence of reagents used in the preparation of 4-bromo-2-nitroethyl benzene from benzene is:
(1) CH3COCl/AlCl3, Zn-Hg/HCl, Br2/AlBr3, HNO3/H2SO4
(2) HNO3/H2SO4, Br2/AlCl3, CH3COCl/AlCl3, Zn-Hg/HCl
(3) CH3COCl/AlCl3, Br2/AlBr3, HNO3/H2SO4, Zn/HCl
(4) Br2/AlBr3, CH3COCl/AlCl3, HNO3/H2SO4, Zn/HCl
List-I (Ore) List-II (Element Present)
(a) Kernite (i) Tin
(b) Cassiterite (ii) Boron
(c) Calamine (iii) Fluorine
(d) Cryolite (iv) Zinc
Choose the most appropriate answer from the options given below:
(1) (a)(ii), (b)(i), (c)(iv), d(iii) (2) (a)(iii), (b)(i), (c)(ii), d(iv)
(3) (a)(ii), (b)(iv), (c)(i), d(iii) (4) (a)(i), (b)(iii), (c)(iv), d(ii)
57. The presence of ozone in troposphere :
(1) Protects us from greenhouse effect (2) Protects us from the X-ray radiation
(3) Generates photochemical smog (4) Protects us from the UV radiation
58. Which of the following vitamin is helpful in delaying the blood clotting?
(1) Vitamin B (2) Vitamin E
(3) Vitamin K (4) Vitamin C
59. Calgon is used for water treatment. Which of the following statement is NOT true about Calgon?
(1) It is polymeric compound and is water soluble
(2) Calgon contains the 2nd most abundant element by weight in the Earth’s crust
(3) It is also known as Graham’s salt
(4) It doesnot remove Ca2+ ion by precipitation
List-I List-II
(a) Sucrose (i) -D-Galactose and -D-Glucose
(b) Lactose (ii) -D-Glucose and -D-Fructose
(c) Maltose (iii) -D-Glucose and -D-Glucose
Choose the correct answer from the options given below :
(1) (a) → (i), (b) → (iii), (c) → (ii) (2) (a) → (iii), (b) → (ii), (c) → (i)
(3) (a) → (ii), (b) → (i), (c) → (iii) (4) (a) → (iii), (b) → (i), (c) → (ii)
61. Which among the following pairs of Vitamins is stored in our body relatively for longer duration?
(1) Ascorbic acid and Vitamin D (2) Vitamin A and Vitamin D
(3) Thiamine and Ascorbic acid (4) Thiamine and Vitamin A
62. Match List-I with List-II :
List-I (Industrial process) List-II (Application)
(a) Haber’s process (i) HNO3 synthesis
(b) Ostwald’s process (ii) Aluminium extraction
(c) Contact process (iii) NH3 synthesis
(d) Hall-Heroult process (iv) H2SO4 synthesis
Choose the correct answer from the options given below.
(1) (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i) (2) (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
(3) (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii) (4) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
63. The type of pollution that gets increased during the day time and in the presence of O 3 is
(1) Reducing smog (2) Acid rain
(3) Global warming (4) Oxidising smog
64. Given below are two statement : one is labelled as Assertion A and the other is labelled as Reason R :
Assertion A : Size of Bk3+ ion is less than Np3+ ion.
Reason R : The above is a consequence of the lanthanoid contraction.
In the light of the above statements, choose the correct answer from the options given below.
(1) A is false but R is true
(2) A is true but R is false
(3) Both A and R are true but R is not the correct explanation of A
(4) Both A and R are true and R is the correct explanation of A
65. The INCORRECT statements below regarding colloidal solutions is
(1) The flocculating power of Al3+ is more than that of Na+.
(2) A colloidal solution shows Brownian motion of colloidal particles.
(3) An ordinary filter paper can stop the flow of colloidal particles.
(4) A colloidal solution shows colligative properties.
List-I List-II
Test/Reagents/ Species detected
Observation(s)
(a) Lassaigne’s Test (i) Carbon
(b) Cu(II) oxide (ii) Sulphur
(c) Silver nitrate (iii) N, S, P, and halogen
(d) The sodium fusion (iv) Halogen Specifically
extract gives black
precipitate with acetic
acid and lead acetate
The correct match is:
(1) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
(2) (a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)
(3) (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
(4) (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)
67. The green house gas/es is (are):
(A) Carbon dioxide (B) Oxygen
(C) Water vapour (D) Methane
(1) (A), (C) and (D) only (2) (A) and (B) only
(3) (A) and (C) only (4) (A) only
68. A colloidal system consisting of a gas dispersed in a solid is called a/an
(1) aerosol (2) foam
(3) solid sol (4) gel
Statement-I : Retardation factor (Rf) can be measured in meter/centimeter.
Statement-II : Rf value of a compound remains constant in all solvents.
Choose the most appropriate answer from the options given below :
(1) Statement I is true but statement II is false (2) Both statement I and statement II are true
(3) Both statement I and statement II are false (4) Statement I is false but statement II is true
70. The INCORRECT statement(s) about heavy water is (are)
(A) used as a moderator in nuclear reactor
(B) obtained as a by-product in fertilizer industry
(C) used for the study of reaction mechanism
(D) has a higher dielectric constant than water
(1) (B) and (D) only (2) (B) only
(3) (D) only (4) (C) only
71. With respect to drug-enzyme interaction, identify the wrong statement.
(1) Allosteric inhibitor competes with the enzyme’s active site
(2) Allosteric inhibitor changes the enzyme’s active site
(3) Non-Competitive inhibitor binds to the allosteric site
(4) Competitive inhibitor binds to the enzyme’s active site
Enzyme A
72. C12H22O11 + H2O ⎯⎯⎯⎯⎯
→ C6H12O6 + C6H12O6
Glucose Fructose
Enzyme B
C6H12O6 ⎯⎯⎯⎯⎯
→ 2C2H5OH + 2CO2
Glucose
In the above reactions, the enzyme A and enzyme B respectively are
(1) Amylase and Invertase (2) Invertase and Zymase
(3) Zymase and Invertase (4) Invertase and Amylase
List-I (Chemical Compound) List-II (Used as)
(a) Sucralose (i) Synthetic detergent
(b) Glyceryl ester (ii) Artificial sweetener
of stearic acid
(c) Sodium benzoate (iii) Antiseptic
(d) Bithionol (iv) Food preservative
Choose the correct match.
(1) (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii) (2) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
(3) (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii) (4) (a)-(iii), (b)-(ii), (c)-(iv), (d)-(i)
74. Which of the following statement(s) is(are) incorrect reason for eutrophication?
(A) Excess usage of fertilisers
(B) Excess usage of detergents
(C) Dense plant population in water bodies
(D) Lack of nutrients in water bodies that prevent plant growth
Choose the most appropriate answer from the options given below.
(1) (D) Only (2) (A) only
(3) (B) and (D) only (4) (C) only
List-I List-II
(a) Ca(OCl)2 (i) Antacid
1
(b) CaSO4 · H2O (ii) Cement
2
(c) CaO (iii) Bleach
(d) CaCO3 (iv) Plaster of Paris
(1) (a)-(iii), (b)-(ii), (c)-(i), (d)-(iv) (2) (a)-(iii), (b)-(ii), (c)-(iv), (d)-(i)
(3) (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i) (4) (a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)
76. Match List-I with list-II :
List-I List-II
(a) Chlorophyll (i) Ruthenium
(b) Vitamin - B12 (ii) Platinum
(c) Anticancer drug (iii) Cobalt
(d) Grubbs catalyst (iv) Magnesium
(1) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i) (2) (a)-(iv), (b)-(ii), (c)-(iii), (d)-(i)
(3) (a)-(iii), (b)-(ii), (c)-(iv), (d)-(i) (4) (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
77. Match List-I with list-II :
List-I (Class of Drug) List-II (Example)
(a) Antacid (i) Novestrol
(b) Artificial Sweetener (ii) Cimetidine
(c) Antifertility (iii) Valium
(d) Tranquilizers (iv) Alitame
Choose the most appropriate match :
(1) (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii) (2) (a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)
(3) (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii) (4) (a)-(ii), (b)-(iv), (c)-(iii), (d)-(i)
78. Match List-I and with List-II.
List-I (Process) List-II (Catalyst)
(a) Deacon's process (i) ZSM-5
(b) Contact process (ii) CuCl2
(c) Cracking of (iii) Particles 'Ni'
hydrocarbons
(d) Hydrogenation of (iv) V2O5
vegetable oils
(1) (a)-(iv), (b)-(ii), (c)-(i), (d)-(iii) (2) (a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)
(3) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii) (4) (a)-(i), (b)-(iii), (c)-(ii), (d)-(iv)
79. The chemical that is added to reduce the melting point of the reaction mixture during the extraction of
aluminium is
(1) Cryolite (2) Calamine
(3) Kaolite (4) Bauxite
Statement I : Non-biodegradable wastes are generated by the thermal power plants.
Statement II : Bio-degradable detergents leads to eutrophication.
In the light of the above statements, choose the most appropriate answer from the options given below :
(1) Both statement I and statement II are false (2) Statement I is true but statement II is false
(3) Statement I is false but statement II is true (4) Both statement I and statement II are true
81. Deficiency of vitamin K causes :
(1) Cheilosis (2) Increase in blood clotting time
(3) Increase in fragility of RBC’s (4) Decrease in blood clotting time
List-I (Class of Chemicals) List-II (Example)
(a) Antifertility drug (i) Meprobamate
(b) Antibiotic (ii) Alitame
(c) Tranquilizer (iii) Norethindrone
(d) Artificial Sweetener (iv) Salvarsan
Choose the most appropriate match :
(1) (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii) (2) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
(3) (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i) (4) (a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)
List-I List-II
(a) Mercury (i) Vapour phase refining
(b) Copper (ii) Distillation refining
(c) Silicon (iii) Electrolytic refining
(d) Nickel (iv) Zone refining
Choose the most appropriate answer from the option given below.
(1) (a)-(ii), (b)-(iv), (c)-(iii), (d)-(i) (2) (a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)
(3) (a)-(i), (b)-(iv), (c)-(ii), (d)-(iii) (4) (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)
List-I List-II
(a) Be (i) treatment of cancer
(b) Mg (ii) extraction of metals
(c) Ca (iii) incendiary bombs and signals
(d) Ra (iv) windows of X-ray tubes
(v) bearings for motor engines
Choose the most appropriate answer from the option given below.
(1) (a)-(iii), (b)-(iv), (c)-(ii), (d)-(v) (2) (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
(3) (a)-(iii), (b)-(iv), (c)-(v), (d)-(ii) (4) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
85. The conditions given below are in the context of observing Tyndall effect in colloidal solutions:
(A) The diameter of the colloidal particles is comparable to the wavelength of light used.
(B) The diameter of the colloidal particles is much smaller than the wavelength of light used.
(C) The diameter of the colloidal particles is much larger than the wavelength of light used.
(D) The refractive indices of the dispersed phase and the dispersion medium are comparable.
(E) The dispersed phase has a very different refractive index from the dispersion medium.
Choose the most appropriate conditions from the options given below.
(1) (A) and (D) only (2) (C) and (D) only
(3) (B) and (E) only (4) (A) and (E) only
86. An inorganic Compound ‘X’ on treatment with concentrated H 2SO4 produces brown fumes and gives dark
brown ring with FeSO4 in presence of concentrated H2SO4. Also Compound ‘X’ gives precipitate ‘Y’, when its
solution in dilute HCl is treated with H2S gas. The precipitate ‘Y’ on treatment with concentrated HNO 3 followed
by excess of NH4OH further gives deep blue coloured solution, Compound ‘X’ is
(1) Cu(NO3)2 (2) Pb(NO2)2
(3) Pb(NO3)2 (4) Co(NO3)2
87. Identify the incorrect statement from the following
(1) Amylose is a branched chain polymer of glucose
(2) -Glycosidic linkage makes cellulose polymer
(3) Glycogen is called as animal starch
(4) Starch is a polymer of -D glucose
88. Which one of the following statements is not true about enzymes ?
(1) The action of enzymes is temperature and pH specific
(2) Enzymes are non-specific for a reaction and substrate
(3) Enzymes work as catalysts by lowering the activation energy of a biochemical reaction
(4) Almost all enzymes are proteins
89. Two radioactive substances A and B have decay constants 5 and  respectively. At t = 0, a sample has the
2
 1
same number of the two nuclei. The time taken for the ratio of the number of nuclei to become   will be :
 e
1 1
(1) (2)
2 4
1 2
(3) (4)
 
90. Thiamine and pyridoxine are also known respectively as:
(1) Vitamin E and Vitamin B2 (2) Vitamin B2 and Vitamin E
(3) Vitamin B1 and Vitamin B6 (4) Vitamin B6 and Vitamin B2
91. Match List-I and List-II:
List-I (Elements) List-II (Properties)
(a) Ba (i) Organic solvent soluble compounds
(b) Ca (ii) Outer electronic configuration 6s2
(c) Li (iii) Oxalate insoluble in water
(d) Na (iv) Formation of very strong monoacidic base
(1) (a)-(iii), (b)-(ii), (c)-(iv) and (d)-(i) (2) (a)-(ii), (b)-(iii), (c)-(i) and (d)-(iv)
(3) (a)-(i), (b)-(iv), (c)-(ii) and (d)-(iii) (4) (a)-(iv), (b)-(i), (c)-(ii) and (d)-(iii)
92. The idea of froth floatation method came from a person X and this method is related to the process Y of ores.
X and Y, respectively, are :
(1) Fisher woman and concentration (2) Washer woman and concentration
(3) Washer man and reduction (4) Fisher man and reduction
93. Which one of the following compounds of Groups-14 elements is not known?
(1) [GeCl6]2– (2) [SiF6]2–
(3) [Sn(OH)6]2– (4) [SiCl6]2–
94. Sodium stearate CH3(CH2)16COO–Na+ is an anionic surfactant which forms micelles in water. Choose the
correct statement for it from the following
(1) It forms non-spherical micelles with CH3(CH2)16 – group pointing towards the centre
(2) It forms spherical micelles with CH3(CH2)16 – group pointing outwards on the surface of sphere
(3) It forms non-spherical micelles with − COO− group pointing outwards on the surface
(4) It forms spherical micelles with CH3(CH2)16 – group pointing towards the centre of sphere
95. is a repeating unit for
(1) Acrilan (2) Novolac
(3) Buna-N (4) Neoprene
96. The water soluble protein is
(1) Albumin (2) Collagen
(3) Myosin (4) Fibrin
Statement I : Chlorofluoro carbons breakdown by radiation in the visible energy region and release chlorine
gas in the atmosphere which then reacts with stratospheric ozone.
Statement II : Atmospheric ozone reacts with nitric oxide to give nitrogen and oxygen gases, which add to the
atmosphere.
For the above statements choose the correct answer from the options given below :
(1) Statement I is incorrect but statement II is true
(2) Statement I is correct but statement II is false
(3) Both statement I and II are correct
(4) Both statement I and II are false
List-I List-II
Example Classification
of Colloids
(a) Cheese (i) Dispersion of liquid in liquid
(b) Pumice stone (ii) Dispersion of liquid in gas
(c) Hair cream (iii) Dispersion of gas in solid
(d) Cloud (iv) Dispersion of liquid in solid
(1) (a) - (iv), (b) - (iii), (c) - (i), (d) - (ii) (2) (a) - (iv), (b) - (i), (c) - (iii), (d) - (ii)
(3) (a) - (iii), (b) - (iv), (c) - (i), (d) - (ii) (4) (a) - (iv), (b) - (iii), (c) - (ii), (d) - (i)
99. Match List-I with List-II : (Both having metallurgical terms)
List-I List-II
(a) Concentration of Ag ore (i) Reverberatory furnace
(b) Blast furnace (ii) Pig iron
(c) Blister copper (iii) Leaching with dilute NaCN solution
(d) Froth floatation method (iv) Sulfide ores
(1) (a) - (iv), (b) - (iii), (c) - (ii), (d) - (i) (2) (a) - (iii), (b) - (iv), (c) - (i), (d) - (ii)
(3) (a) - (iii), (b) - (ii), (c) - (i), (d) - (iv) (4) (a) - (iv), (b) - (i), (c) - (iii), (d) - (ii)
100. A biodegradable polyamide can be made from :
(1) Glycine and isoprene (2) Glycine and aminocaproic acid
(3) Styrene and caproic acid (4) Hexamethylene diamine and adipic acid
101. Which one of the following metals forms interstitial hydride easily?
(1) Mn (2) Cr
(3) Fe (4) Co
102. Match List-I with List-II
List-I List-II
(a) NaOH (i) Acidic
(b) Be(OH)2 (ii) Basic
(c) Ca(OH)2 (iii) Amphoteric
(d) B(OH)3
(e) Al(OH)3
(1) (a)-(ii), (b)-(ii), (c)-(iii), (d)-(i), (e)-(iii) (2) (a)-(ii), (b)-(ii), (c)-(iii), (d)-(ii), (e)-(iii)
(3) (a)-(ii), (b)-(i), (c)-(ii), (d)-(iii), (e)-(iii) (4) (a)-(ii), (b)-(iii), (c)-(ii), (d)-(i), (e)-(iii)
103.
The compound ‘A’ is a complementary base of ___in DNA strands.
(1) Uracil (2) Guanine
(3) Adenine (4) Cytosine
104. Which one of the following statements is NOT correct?
(1) Eutrophication leads to increase in the oxygen level in water
(2) Eutrophication indicates that water body is polluted
(3) Eutrophication leads to anaerobic conditions
(4) The dissolved oxygen concentration below 6 ppm inhibits fish growth
105. Which one among the following chemical tests is used to distinguish monosaccharide from disaccharide?
(1) Seliwanoff’s test (2) Iodine test
(3) Tollen’s test (4) Barfoed test
List-I (Drug) List-II (Class of Drug)
(a) Furacin (i) Antibiotic
(b) Arsphenamine (ii) Tranquilizers
(c) Dimetone (iii) Antiseptic
(d) Valium (iv) Synthetic antihistamines
Choose the most appropriate match
(1) (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i) (2) (a)-(ii), (b)-(i), (c)-(iii), (d)-(iv)
(3) (a)-(i), (b)-(iii), (c)-(iv), (d)-(ii) (4) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
Statement I : Penicillin is a bacteriostatic type antibiotic.
Statement II : The general structure of Penicillin is
Choose the correct option :
(1) Statement I is incorrect but Statement II is true
(2) Statement I is correct but Statement II is false
(3) Both Statement I and Statement II are true
(4) Both Statement I and Statement II are false
108. The addition of silica during the extraction of copper from its sulphide ore
(1) Converts iron oxide into iron silicate
(2) Converts copper sulphide into copper silicate
(3) Reduces copper sulphide into metallic copper
(4) Reduces the melting point of the reaction mixture
List-I (compound) List-II (effect/affected species)
(a) Carbon monoxide (i) Carcinogenic
(b) Sulphur dioxide (ii) Metabolized by pyrus plants
(c) Polychlorinated biphenyls (iii) Haemoglobin
(d) Oxides of nitrogen (iv) Stiffness of flower buds
(1) (a) - (i), (b) - (ii), (c) - (iii), (d) - (iv) (2) (a) - (iii), (b) - (iv), (c) - (i), (d) - (ii)
(3) (a) - (iv), (b) - (i), (c) - (iii), (d) - (ii) (4) (a) - (iii), (b) - (iv), (c) - (ii), (d) - (i)
110. Which one of the following methods is most suitable for preparing deionized water?
(1) Synthetic resin method (2) Permutit method
(3) Clark’s method (4) Calgon’s method
111. The total number of negative charge in the tetrapeptide, Gly-Glu-Asp-Tyr, at pH 12.5 will be ______. (Integer
answer)
112.
The class of drug to which chlordiazepoxide with above structure belongs is :
(1) Antacid (2) Analgesic
(3) Tranquilizer (4) Antibiotic
113. Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Sucrose is a disaccharide and a non-reducing sugar.
Reason (R) : Sucrose involves glycosidic linkage between C 1 of -glucose and C2 of -fructose.
the most appropriate answer from the options given below :
(1) Both (A) and (R) are true and (R) is the true explanation of (A)
(2) (A) is true but (R) is false
(3) Both (A) and (R) are true but (R) is not the true explanation of (A).
(4) (A) is false but (R) is true
114. Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R)
Assertion (A) : Photochemical smog causes cracking of rubber.
Reason (R) : Presence of ozone, nitric oxide,

acrolein, formaldehyde and peroxyacetyl nitrate in photochemical smog makes it oxidizing
(1) Both (A) and (R) are true and (R) is the true explanation of (A)
(2) (A) is true but (R) is false
(3) (A) is false but (R) is true
(4) Both (A) and (R) are true but (R) is not the true explanation of (A).
115. Match items of List - I with those of List - II :
List – I (Property) List – II (Example)
(a) Diamagnetism (i) MnO
(b) Ferrimagnetism (ii) O2
(c) Paramagnetism (iii) NaCl
(d) Antiferromagnetism (iv) Fe3O4
(1) (a)-(iv), (b)-(ii), (c)-(i), (d)-(iii) (2) (a)-(i), (b)-(iii), (c)-(iv), (d)-(ii)
(3) (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i) (4) (a)-(ii), (b)-(i), (c)-(iii), (d)-(iv)
116.
The correct statement about (A), (B), (C) and (D) is :
(1) (B), (C) and (D) are tranquilizers (2) (B) and (C) are tranquilizers
(3) (A) and (D) are tranquilizers (4) (A), (B) and (C) are narcotic analgesics
117. Which one of the following tests used for the identification of functional groups in organic compounds does not
use copper based reagent?
(1) Seliwanoff’s test (2) Barfoed’s test
(3) Benedict’s test (4) Biuret test for peptide bond
118. Lyophilic sols are more stable than lyophobic sols because,
(1) The colloidal particles are solvated
(2) The colloidal particles have positive charge
(3) The colloidal particles have no charge
(4) There is a strong electrostatic repulsion between the negatively charged colloidal particles
119. The denticity of an organic ligand, biuret is :
(1) 3 (2) 2
(3) 4 (4) 6
Statement I : The process of producing syn-gas is called gasification of coal.
Statement II : The composition of syn-gas is CO + CO2 + H2 (1 : 1 : 1).
In the light of the above statements, choose the most appropriate answer from the options given below :
(1) Statement I is true but Statement II is false (2) Both Statement I and Statement II are true
(3) Both Statement I and Statement II are false (4) Statement I is false but Statement II is true
121. Which of the following is NOT an example of fibrous protein?
(1) Albumin (2) Collagen
(3) Myosin (4) Keratin
122. The deposition of X and Y on ground surfaces is referred as wet and dry depositions, respectively. X and Y
are
(1) X = SO2, Y = Ammonium salts (2) X = CO2, Y = SO2
(3) X = Ammonium salts, Y = SO2 (4) X = Ammonium salts, Y = CO2
123. Water sample is called cleanest on the basis of which one of the BOD values given below :
(1) 3 ppm (2) 21 ppm
(3) 15 ppm (4) 11 ppm
List-I (Colloid Preparation Method) List-II (Chemical Reaction)
(a) Hydrolysis (i) 2AuCl3 + 3HCHO + 3H2O → 2Au(sol) + 3HCOOH +
6HCl
(b) Reduction (ii) As2O3 + 3H2S → As2S3(sol) + 3H2O
(c) Oxidation (iii) SO2 + 2H2S → 3S(sol) + 2H2O
(d) Double Decomposition (iv) FeCl3 + 3H2O → Fe(OH)3(sol) + 3HCl
Choose the most appropriate answer from the options given below
(1) (a)-(iv), (b)-(ii), (c)-(iii), (d)-(i) (2) (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)
(3) (a)-(i), (b)-(iii), (c)-(ii), (d)-(iv) (4) (a)-(iv), (b)-(i), (c)-(iii), (d)-(ii)
125. The correct match between Item-I and Item-II is

Item-I (drug) Item-II (test)
A. Chloroxylenol P. Carbylamine test
B. Norethindrone Q. Sodium hydrogen Carbonate test
C. Sulphapyridine R. Ferric chloride test
D. Penicillin S. Bayer's test
(1) A → Q, B → P, C → S, D → R (2) A → R, B → S, C → P, D → Q
(3) A → Q, B → S, C → P, D → R (4) A → R, B → P, C → S, D → Q
126. The alkaline earth metal nitrate that does not crystallise with water molecules, is
(1) Ba(NO3)2 (2) Ca(NO3)2
(3) Mg(NO3)2 (4) Sr(NO3)2
127.
The correct match between Item-I and Item-II is :
Item-I Item-II
(A) Benzaldehyde (P) Mobile phase
(B) Alumina (Q) Adsorbent
(C) Acetonitrile (R) Adsorbate
(1) (A) → (Q), (B) → (R), (C) → (P) (2) (A) → (Q), (B) → (P), (C) → (R)
(3) (A) → (P), (B) → (R), (C) → (Q) (4) (A) → (R), (B) → (Q), (C) → (P)
128. The correct sequnce of amino acids present in the tripeptide given below is :
The given tripeptide contains.
(1) Leu - Ser - Thr (2) Thr - Ser - Val

(3) Val - Ser - Thr (4) Thr - Ser – Leu
129. If dichloromethane (DCM) and water (H2O) are used for differential extraction, which one of the following
statements is correct?
(1) DCM and H2O will make turbid/colloidal mixture
(2) DCM and H2O will be miscible clearly
(3) DCM and H2O would stay as upper and lower layer respectively in the separating funnel (S.F.)
(4) DCM and H2O would stay as lower and upper layer respectively in the S.F.
130. The correct structure of product ‘P’ in the following reaction is
NEt
Asn − Ser + (CH3CO)2 O ⎯⎯⎯
3
→P
(excess)
(1) (2)
(3) (4)
131. The correct match between item ‘I’ and item ‘II’ is :
Item ‘I’ Item ‘II’
(compound) (reagent)
(A) Lysine (P) 1-naphthol
(B) Furfural (Q) ninhydrin
(C) Benzyl alcohol (R) KMnO4
(D) Styrene (S) Ceric ammonium nitrate
(1) (A) → (R); (B) → (P); (C) → (Q); (D) → (S) (2) (A) → (Q); (B) → (P); (C) → (S); (D) → (R)
(3) (A) → (Q); (B) → (R); (C) → (S); (D) → (P) (4) (A) → (Q); (B) → (P); (C) → (R); (D) → (S)
132. The major product obtained in the following reaction is:
(1) (2)
(3) (4)
133. The major porduct of the following reaction is :
(1) (2)
(3) (4)
134. Match the metals (column I) with the coordination compound(s)/enzyme(s) (column II)
(Column I) (Column II)
Metals Coordination compound(s)/ enzyme(s)
(A) Co (i) Wilkinson catalyst
(B) Zn (ii) Chlorophyll
(C) Rh (iii) Vitamin B12
(D) Mg (iv) Carbonic anhydrase

(1) (A) - (iv), (B) - (iii), (C) - (i), (D) - (ii) (2) (A) - (i), (B) - (ii), (C) - (iii), (D) - (iv)
(3) (A) - (ii), (B) - (i), (C) - (iv), (D) - (iii) (4) (A) - (iii), (B) - (iv), (C) - (i), (D) - (ii)
135. The correct match between Item-I and Item-II is:
Item-I Item-II
(A) Ester test (P) Tyr
(B) Carbylamine test (Q) AsP
(C) Phthalein dye test (R) Ser
(S) Lys
(1) (A) → (Q); (B) → (S); (C) → (P) (2) (A) → (R); (B) → (Q); (C) → (P)
(3) (A) → (Q); (B) → (S); (C) → (R) (4) (A) → (R); (B) → (S); (C) → (Q)
136. The correct match between Item-I and Item-II is:

Item-I Item-II
(A) Allosteric effect (P) Molecule binding to the active site of enzyme
(B) Competitive (Q) Molecule crucial for inhibitor communication in the
body
(C) Receptor (R) Molecule binding to a site other than the active site
of enzyme
(D) Poison (S) Molecule binding to the enzyme covalently
(1) (A) → (P); (B) → (R); (C) → (S); (D) → (Q) (2) (A) → (R); (B) → (P); (C) → (Q); (D) → (S)
(3) (A) → (P); (B) → (R); (C) → (Q); (D) → (S) (4) (A) → (R); (B) → (P); (C) → (S); (D) → (Q)
137. Which of the following compounds reacts with ethylmagnesium bromide and also decolourizes bromine water
solution?
(1) (2)
(3) (4)
138. The standard electrode potential and its temperature coefficientfor a cell are 2 V and – 5 × 10–4 VK–1
at 300 K respectively. The cell reaction is

Zn(s) + Cu2+(aq) → Zn2+ (aq) + Cu(s)
The standard reaction enthalpy (r) at 300 K in kJ mol–1 is,
[Use R = 8 JK–1 mol–1 and F = 96,000 C mol–1]

(1) 206.4 (2) –384.0
(3) –412.8 (4) 192.0
139. The correct statement(s) among I to III with respect to potassium ions that are abundant within the cell fluids
is/are
I. They activate many enzymes
II. They participate in the oxidation of glucose to produce ATP
III. Along with sodium ions, they are responsible for the transmission of nerve signals
(1) I and III only (2) I, II and III
(3) III only (4) I and II only
140. The correct structure of histidine in a strongly acidic solution (pH = 2) is
(1) (2)
(3) (4)
141. The major product of the following reaction is
(1) (2)
(3) (4)
142. Polysubstitution is a major drawback in :

(1) Reimer Tiemann reaction (2) Acetylation of aniline
(3) Friedel Craft’s acylation (4) Friedel Craft’s alkylation
143. Fructose and glucose can be distinguished by:
(1) Fehling’s test (2) Seliwanoff’s test
(3) Barfoed’s test (4) Benedict’s test
144. The major product of the following reaction is
(1) (2)
(3) (4)
145. The peptide that gives positive ceric ammonium nitrate and carbylamine tests is
(1) Ser - Lys (2) Lys - Asp
(3) Gln - Asp (4) Asp – Gln
146. Consider the given plot of enthalpy of the following reaction between A and B.
A +B → C+D
Identify the incorrect statement.
(1) Activation enthalpy to form C is 5 kJ mol–1 less than that to form D

(2) D is kinetically stable product
(3) Formation of A and B from C has highest enthalpy of activation
(4) C is the thermodynamically stable product
147. The amorphous form of silica is
(1) Quartz (2) Tridymite
(3) Kieselguhr (4) Cristobalite
148. The principle of column chromatography is :
(1) Differential adsorption of the substances on the solid phase.
(2) Gravitational force.
(3) Differential absorption of the substances on the solid phase.
(4) Capillary action.
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Unique Practice Questions_Chemistry
Answers
1. (1) 26. (2) 51. (2)
2. (4) 27. (1) 52. (2)
3. (02.00) 28. (5) 53. (4)
4. (0.37) 29. (4) 54. (1)
5. (9) 30. (1) 55. (1)
6. (2) 31. (4) 56. (1)
7. (3.00) 32. (1) 57. (3)
8. (3) 33. (4) 58. (3)
9. (4) 34. (02.00) 59. (2)
10. (20.00) 35. (2) 60. (3)
11. (1) 36. (4) 61. (2)
12. (4) 37. (3) 62. (4)
13. (4) 38. (4) 63. (4)
14. (37.84) 39. (1) 64. (2)
15. (4) 40. (2) 65. (3)
16. (1) 41. (3) 66. (1)
17. (1) 42. (48) 67. (1)
18. (4) 43. (101) 68. (2)
19. (1) 44. (2) 69. (3)
20. (2) 45. (2) 70. (3)
21. (2) 46. (4) 71. (1)
22. (1) 47. (2) 72. (2)
23. (1) 48. (4) 73. (3)
24. (4) 49. (1) 74. (1)
25. (3) 50. (2) 75. (3)
76. (1) 101. (2) 126. (1)

77. (2) 102. (4) 127. (4)
78. (2) 103. (3) 128. (3)
79. (1) 104. (1) 129. (4)
80. (4) 105. (4) 130. (4)
81. (2) 106. (4) 131. (2)
82. (1) 107. (1) 132. (4)
83. (4) 108. (1) 133. (4)
84. (4) 109. (2) 134. (4)
85. (4) 110. (4) 135. (1)
86. (1) 111. (1) 136. (2)
87. (1) 112. (3) 137. (2)
88. (2) 113. (2) 138. (3)
89. (1) 114. (1) 139. (2)
90. (3) 115. (3) 140. (4)
91. (2) 116. (2) 141. (3)
92. (2) 117. (1) 142. (4)
93. (4) 118. (1) 143. (2)
94. (4) 119. (2) 144. (2)
95. (2) 120. (1) 145. (1)
96. (1) 121. (1) 146. (1)
97. (4) 122. (3) 147. (3)
98. (1) 123. (1) 148. (1)
99. (3) 124. (4)
100. (2) 125. (1)
Solution
1. Answer (1) 30
for 250 ml, m mol of H2SO4 is required
42
 Weight of H2SO4 required =

30
 10−3  98 g
42
= 0.3675 g
 0.37 g
Formed product is methyl orange and it is used 5. Answer (9)

as an indicator in acid base titrations.
2. Answer (4)
Electron gain enthalpy is most negative for
chlorine followed by fluorine and bromine and
least negative for iodine among given elements.
So, F(–333 kJ mol–1)
Number of sp2 hybridized carbon are ‘9’.
Cl(–349 kJ mol–1)
6. Answer (2)
Br(–325 kJ mol–1) Fe(OH)3 is a positive sol. Its coagulation will be
I(–296 kJ mol–1) caused by the anion of the electrolyte.
3. Answer (02.00) The flocculation value is inversely proportional
The structure of chloramphenicol is to coagulation power or valency of the anion.
The correct order of flocculation value is
K3 [Fe(CN)6] < K2CrO4 < KBr = KNO3 = AlCl3
7. Answer (3.00)
General structure of pencillin is
It contains 2 chiral centres.

4. Answer (0.37)
Arsenic sulphide sol is negatively charged, so H+
brings about precipitation The number of chiral centres in pencillin is 3.
8. Answer (3)
for 1 L, 30 m mol of HCl is required
The assertion is true, but the reason is false
30
for 250 ml, m mol of HCl is required Refer : [NCERT Page No. 132]
4
Reactants must not get adsorbed so strongly • Saccharin also contains sulphur
that they are immobilised and other reactants • Sucralose contains chloro group thats why
are left with no space on the catalyst’s surface its Lassaigne extract gives white ppt with
for adsorption. AgNO3.
9. Answer (4)
 A = Aspartame, B = Saccharin
C = Sucralose, D = Alitame.
13. Answer (4)
Aniline and phenol form complex with Lewis
acid.
 Highest yield in Friedel Craft reaction among
Basicity of H3PO2 = 1
(Y)
10. Answer (20.00)
given species is for chlorobenzene i.e.

14. Answer (37.84)
Histamine :
120° = 3, 90° = 6,  180° = 1 Total = 10
Chemical formulae : C5H9N3
 % by mas of N
3  14
=  100
(5  12 + 1 9 + 3  14)
90° = 8, 180° = 2  Total = 10 42  100

= = 37.84%
111
Total number of 180°, 90° and 120° L-M-L bond
15. Answer (4)
angles = 10 + 10 = 20
All carbohydrates give, Molisch’s test
11. Answer (1)
- Barfoed test is specific for monosaccharide
Ce3+ (Z = 58) − [Xe]4f 1
- Biuret test is used for detecting the presence
Eu2+ (Z = 63) − [Xe]4f 7 of peptide bonds
12. Answer (4) 16. Answer (1)
• Ninhydrin test is specific for amino acids. BOD is the amount of oxygen required by
• Both aspartame and alitame contains amino bacteria to break down the organic matter
acids. present in a certain volume of sample of water.
• Alitame is sulphur containing compound 17. Answer (1)


thats why gives sodium nitroprusside test 2Pb(NO3 )2 ⎯⎯
→ 2PbO + 4NO2 + O2

(NH4 )2 Cr2O7 ⎯⎯
→N2 + 4H2O + Cr2O3

NH4NO2 ⎯⎯
→N2 + 2H2O

2NaN3 ⎯⎯
→ 2Na + 3N2
18. Answer (4)
Bunsen Burner and measuring cylinder is not
required for titration.
It can react with Br2/water, ZnCl2/HCl and FeCl3.
19. Answer (1)
24. Answer (4)
UV
CF2Cl2 (g) ⎯⎯⎯
→ Cl(g) + CF2Cl(g) … (i) From the thermal power plant CO2 is released
which causes acid rain.
Cl(g) + O3 (g) ⎯⎯
→ ClO(g) + O2 (g) 25. Answer (3)
Chlorine
monoxide Respiratory ailments in animals may be due
… (ii) to viral infections or bacterial pneumonia
etc; which can due to acid rain which
ClO(g) + O(g) ⎯⎯
→ Cl(g) + O2 (g) … (iii)
contains harmful chemicals acid rain is also
nd
Here, chlorine monoxide is formed in 2 harmless for trees.
step so, statement (1) is not true. 26. Answer (2)
20. Answer (2) Drug Therapeutic action
Aqueous NaHCO3 is used as the first aid. (i) Ranitidine Antacid
NaHCO3 is basic and not harmful. (ii) Nardil Antidepressant
21. Answer (2) (Phenelzine)
(iii) Chloramphenicol Antibiotic
(iv) Dimetane Antihistamine
27. Answer (1)
An ionic micelle consists of an aggregate of
Ketose with seliwanoff’s reagent gives red soap or detergents having a hydrophobic
colour. It is a specific test for ketose. part and a hydrophilic part. This aggregate
22. Answer (1) form a spherical shape with their
For Unnilennium hydrocarbon chain pointing towards the
IUPAC symbol – Une centre of sphere.

28. Answer (5)
Atomic No. – 109
The amino acids present in the given
23. Answer (1)
tripeptide Asp – Glu – Lys are
and XeF4 + SbF5 → [XeF3 ]+ [SbF6 ]–

3 2 3
sp d sp d
Disproportionation
H3PO2 ⎯⎯⎯⎯⎯⎯⎯⎯→ H3PO4 + PH3
3 3 3
sp sp sp
H+ +
NH3 ⎯⎯⎯
→ NH4
3 3
sp sp
33. Answer (4)

 Number of carbonyl groups present in
Seldane is an anti-histamine drug that has
tripeptide = 2 + 2 + 1 = 5
inhibitory action on histamine receptor.
29. Answer (4)
34. Answer (02.00)
The structure of threonine is
30. Answer (1)

No. of chiral centres present in it = 2
The bond which has greater potential energy
35. Answer (2)
(more negative) is considered more stable as it
Noradrenaline is an organic chemical that
requires more energy to dissociate.
functions in brain and body as hormone and
 A–B bond has most negative potential neurotransmitter.
energy hence it is strongest bond and has Antidepressant drugs can be suggested for the
maximum bond enthalpy. deficiency of noradrenaline.
A–D is longest bond. 36. Answer (4)
31. Answer (4) The amino acids present in the given tripeptide
Calcination : Heating of concentrated ore in the Ile–Arg–Pro are isoleucine, arginine and proline
absence (or limited supply of air). Mainly used
for carbonate ores.
Metal carbonate metal oxide + CO2
(causes Global
warming)
Roasting : Heating of concentrated ore in a

regular supply of air. Mainly used for sulphide
ores.
Metal sulphide + O2 ⎯→ Metal oxide + SO2
(causes acid rain)
32. Answer (1)
Number of chiral carbons present in the given 1

= 2 and log K = 0.4771
tripeptide is 4. n
37. Answer (3) = log 3
Clark’s method is used to remove temporary  K=3
hardness of water.
x
38. Answer (4) = 3· p2
m
Bronze contains 88 – 96% Cu and 4 – 12% Sn
mass of gas adsorbed per gram of adsorbent
Cast iron is used to make wraugut iron
= 3 × (0.04)2
German silver contains 50% Cu, 30% Zn and
= 48 × 10–4
20% Ni
43. Answer (101)
Brass contains 70% Cu and 30% Zn.
Unnilunium
39. Answer (1)
IUPAC symbol = Unu
Rate = k[A]n
Atomic no. (Z) = 101
log[Rate] = log k + n log [A]
44. Answer (2)
slope = n [n is order of the reaction]
“-Helix is one of the most common ways in
 Correct sequence for the order of the
which a polypeptide chain forms all possible
reaction is
hydrogen bonds by twisting into a right handed
d>b>a>c screw (helix) with the –NH group of each amino
40. Answer (2)
acid residue hydrogen bonded to the
Ca(OH)2 – Used in white wash
of an adjacent turn of the helix”
NaCl – Used for the preparation of
45. Answer (2)
washing soda (Na2CO3)
Gun metal has composition of Cu, Zn, Sn
1
CaSO4  H2 O – Used for making casts of Cu – 87%
2
statues Zn – 3 %
CaCO3 – Used as an antacid Sn – 10%
Misch metal is an alloy consisting mainly of During anaerobic degradation of vegetation CO2
lanthanoid metals. and CH4 are released which may lead to cause
42. Answer (48) global warming and cancer.
Freundlich adsorption isotherm: 47. Answer (2)

Monomer Polymer
x
= Kp1/n Isoprene Natural rubber
m
2-Chloro-1, 3-butadiene Neoprene
x 1
 log = log K + log p
m n Caprolactum Nylon 6
Acrylonitrile Buna-N
48. Answer (4)

The amount of BOD in the water is a measure of
the amount of organic material in the water, in
terms of how much oxygen will be required to
break it down biologically. Clean water would
have BOD value of less than 5 ppm, whereas
highly polluted water would have a BOD value of enough to liberate CO2 with NaHCO3 solution.
17 ppm or more. Answer (4)
Statement I is true and statement II is false. 54. Answer (1)
49. Answer (1) German silver contains Cu (50%), Zn (30%),
Valium Tranquilizer Ni (20%) respectively.
Morphine Analgesic 55. Answer (1)
Norethindrone Antifertility drug
Vitamin B12 Pernicious anaemia
(a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
50. Answer (2)
51. Answer (2)

Ce and Eu have stable oxidation state of +3. So,
Ce+4 acts as oxidizing agent to get reduced to +3 56. Answer (1)
and Eu2+ acts as reducing agent to get oxidized Kernite : Na2B4O7 . 4H2O (Boron)
to +3.
Cassiterite : SnO2 (Tin)
52. Answer (2)
Calamine : ZnCO3 (Zinc)
Reducing smog is a mixture of smoke, fog and
Cryolite : Na3AlF6 (Fluorine)
sulphur dioxide. It does not involve O3 (allotrope
of oxygen) during its formation. (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)
57. Answer (3)
The main component of the photochemical
Ozone in stratosphere (not in troposphere)
smog result from the action of sunlight on
protects us from U.V. radiation.
unsaturated hydrocarbons and nitrogen oxides.
No involvement of oxides of S. Ozone in troposphere generates photochemical
So, the answer should be, both statements false. smog.

Vitamin K is helpful in delaying the blood clotting.

Calgon is sodium hexametaphosphate, a Size of Bk3+ is 98 pm
polymeric compound also called as Graham’s Size of Np3+ is 101 pm
salt.
So size of Np3+ is more than Bk3+ ion.
Silicon is the 2nd most abundant element which
there is a gradual decrease in the size of M3+
is absent in calgon.
ions across the series. This may be referred to
60. Answer (3)
as the actinoid contraction.
65. Answer (3)
Ordinary filter paper cannot stop the flow
colloidal particles.
An ultra - filter paper is required.
66. Answer (1)
Lassaigne’s test is used in qualitative detection
of N, S, P and halogens.
(a) → (ii), (b) → (i), (c) → (iii)
(a) (iii)
61. Answer (2)
Cu(II) oxide is used for the estimation of carbon.
Vitamins which are soluble in fat and oils but
insoluble in water are fat soluble vitamins, which (b) (i)
are stored in our body relatively for longer time. Silver nitrate is used for detecting halogens in
e.g. Vitamin A and Vitamin D organic compounds (Carius Method)
Thiamine (Vit B1) and Ascorbic acid (Vit C) are (c) (iv)
water soluble. Sodium fusion extract when treated with acetic

62. Answer (4) acid and lead acetate gives black precipitate if
Process Application sulphur is present.
Haber’s process NH3 synthesis S2– + Pb 2 + → PbS

( black )
Ostwald’s process HNO3 synthesis

(d) (ii)
Contact process H2SO4 synthesis 67. Answer (1)
Hall Heroults process Aluminium Carbon dioxide, water vapour, methane are
extraction greenhouse gases.

68. Answer (2)
(a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
A colloidal system consisting of a gas dispersed
63. Answer (4)
in a solid is called a ‘foam’.
Photochemical smog occurs in warm, dry and
69. Answer (3)
sunny climate. It is also called oxidising smog.
Retardation factor (Rf) is the ratio of distance
The main components of photochemical smog
moved by the substance from the base line to
are ozone, nitric oxide, acrolein, formaldehyde
the distance moved by the solvent from the base
and PAN
line. So, it is dimensionless. The distance moved Nutrient enriched water bodies supports dense
by the substance is due to adsorption of the plant population. This is because of the excess
substance on the stationary phase. It does not usage of fertilisers and detergents. This process
depend on the nature of solvent. But the is known as eutrophication.
distance moved by the solvent will change with 75. Answer (3)
the nature of solvent. Therefore, Rf will vary with 1
CaSO4 H2O - Plaster of Paris
the change in solvent. 2
So, both the statements are false. Ca(OCl)2 - Bleaching agent

70. Answer (3) CaO is used in cement
Heavy water (D2O) is obtained as a by-product CaCO3 is used as an Antacid
in fertilizer industry. It is used as a moderator in 76. Answer (1)
nuclear reactor and for the study of reaction Chlorophyll - Mg
mechanism. Its dielectric constant is lower than
Vitamin - B12 - Co
that of H2O.
Anticancer drug - Pt
71. Answer (1)
77. Answer (2)
Allosteric inhibitor changes the enzymes active
Antacid - Cimetidine
site and they do not compete with the enzymes
Artificial Sweetener - Alitame
active site. They bind to the allosteric site.
Antifertility - Novestrol
Competitive inhibitor binds to the enzymes
active site. Tranquilizers - Valium

Invertase (a) Deacon's process - CuCl2
C12H22O11 + H2O ⎯⎯⎯⎯→ C6H12O6 + C6H12O6
Sucrose Glucose Fructose (b) Contact process - V2O5
Zymase
C6H12O6 ⎯⎯⎯⎯→ 2C2H5OH + 2CO2 (c) Cracking of - ZSM-5
Glucose
hydrocarbons
 Enzyme A is Invertase
(d) Hydrogenation of - Particles 'Ni'
Enzyme B is Zymase
vegetable oils
73. Answer (3)
79. Answer (1)
(a) Sucralose → (ii) Artificial sweetener
Cryolite is used to lower M.P. of Alumina.
(b) Glyceryl ester of stearic acid → (i) Synthetic 80. Answer (4)
NCERT, Page No. – 415, 417 – Part-II, Class-XI
detergent 81. Answer (2)
(c) Sodium benzoate → (iv) food preservative Deficiency of vitamin K causes increase in blood
clotting time.
(d) Bithionol → (iii) Antiseptic
82. Answer (1)
74. Answer (1)
(a) Antifertility drug — Norethindrone
(b) Antibiotic — Salvarsan 87. Answer (1)

(c) Tranquilizer — Meprobamate Amylose is a unbranched chain with 200–1000
(d) Artificial Sweetener — Alitame -D-(+)-glucose units held together by C1-C4
(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii) glycosidic linkage.
Element Refining method Enzymes are mostly proteins. They function as
(a) Mercury Distillation refining catalysts in biochemical reactions by lowering
(b) Copper Electrolytic refining the energy of activation. They are highly specific
(c) Silicon Zone refining w.r.t. temperature and pH in their action.
(d) Nickel Vapour phase refining 89. Answer (1)

Nx(at t) = N0e–5t
So, (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i).
84. Answer (4) Ny(at t) = N0e–t
Be – used in making windows of X-ray tube Nx 1
= = e –4 t
Mg – incendiary bombs and signals Ny e2
Ca – extraction of metals  4t = 2
Ra – treatment of cancer
2  1
 t= = 
85. Answer (4) 4   2 
The diameter of the dispersed particles is not
90. Answer (3)
much smaller than the wavelength of the light
Vitamin B1 — Thiamine
used; and
Vitamin B6 — Pyridoxine
The refractive indices of the dispersed phase
91. Answer (2)
and the dispersion medium differ greatly in
magnitude. Ba — [Xe]6s2
86. Answer (1) Ca — Calcium oxalate is insoluble (sparingly

soluble) in water
Li — LiCl is soluble in organic solvents like
pyridine
Na — NaOH is a very strong monoacidic base
92. Answer (2)
Froth floatation is a method of concentration and
it was discovered by a washer women.
93. Answer (4)
[SiCl6]2– is not known. The main reasons are (i)
six large chloride ion cannot be accommodated
around Si4+ due to limitation of its size and (ii)
interaction between lone pair of chloride ion and
Si4+ is not very strong.

Surfactant form micelles by pointing the Glycine and aminocaproic acid undergo
hydrophobic part towards the centre of sphere. condensation polymerisation to form Nylon-2-
95. Answer (2) nylon-6, a biodegradable polymer.
Given polymer is novolac H2N – CH2 – COOH + H2N – (CH2 )5 – COOH →
96. Answer (1)
[HN – CH2 – CO – NH – (CH2 )5 – CO] n
Globular proteins are usually soluble in water. Nylon − 2 − nylon − 6
Insulin and albumin are the common examples
101. Answer (2)
of globular proteins.
Cr has tendency to form hydride easily
97. Answer (4)
Elements of group – 7 and 8 do not form
Chlorofluoro carbons breakdown by radiation in
hydrides
the UV region and not in the visible region to give
102. Answer (4)
chlorine free radical which reacts with
NaOH – Basic
stratospheric ozone.
Ca(OH)2 – Basic
Be(OH)2 – Amphoteric
Atmospheric ozone reacts with NO to give NO2
Al(OH)3 – Amphoteric
and O2 and not N2 and O2
B(OH)3 – Acidic
103. Answer (3)
Both the given statements are false. The given compound (A) is Thymine. It always
98. Answer (1) bind with adenine in DNA.
Cheese – Liquid dispersed in solid
Pumice stone – Gas dispersed in solid
Hair cream – Liquid dispersed in liquid
Cloud – Liquid dispersed in gas
 Correct answer is
(a) - (iv), (b) - (iii), (c) - (i), (d) - (ii)

99. Answer (3)
Concentration of Ag ore – Leaching with 104. Answer (1)
dil. NaCN solution The lack of oxygen kills all other forms of aquatic
Blast furnace – Pig iron life such as fish and plants. Fertilizers contain
phosphates as additives. The addition of
Blister copper – Reverberatory
phosphates in water enhances algae growth.
furnace
Such profuse growth of algae, covers the water
Froth floatation method – Sulphide ores
surface and reduces the oxygen concentration
 Correct match is
in water. This leads to anaerobic conditions,
(a) - (iii), (b) - (ii), (c) - (i), (d) - (iv) commonly with accumulation of abnoxious
decay and animal death. Thus, bloom-infested exchangers. This method is more efficient than
water inhibits the growth of other living zeolite process. Cation exchange resins contain
organisms in the water body. This process in large organic molecule with - SO3H group and
which nutrient enriched water bodies support a are water insoluble. Ion exchange resin
dense plant population, which kills animal life by (RSO3H) is changed to RNa by treating it with
depriving it of oxygen and results in subsequent NaCl. The resin exchanges Na+ ions with Ca2+
loss of biodiversity is known as Eutrophication. and Mg2+ ions present in hard water to make the
105. Answer (4) water soft. Here R is resin anion.
Barfoed’s is a chemical test used to detect 2RNa(s) + M2+(aq) → R2M(s) + 2Na+(aq)
presence of monosaccharides from
The resin can be regenerated by adding
disaccharides.
aqueous NaCl solution.
106. Answer (4)
Pure de-mineralised (de-ionized) water free
Correct match are
from all soluble mineral salts is obtained by
(a) Furacin – Antiseptic
passing water successively through a cation
(b) Arsphenamine – Antibiotic exchange (in the H+ form) and an anion -
(c) Dimetone – Synthetic exchange (in the OH– form) resins:
antihistamine
2RH(s) + M2+ (aq) MR2 (s) + 2H+ (aq)
(d) Valium – Tranquilizers
In this cation exchange process, H+ exchanges
107. Answer (1)
for Na+, Ca2+, Mg2+ and other cations present in
Penicillin is a bactericidal antibiotics.
water. This process results in proton release and
108. Answer (1)
thus makes the water acidic.
Silica converts iron oxide into iron silicate.
111. Answer (4)
FeO + SiO2 ⎯⎯
→ FeSiO3 Gly-Glu-Asp-Tyr
109. Answer (2)
(a) CO ......... (iii) Haemoglobin
(b) SO2 ......... (iv) Stiffness to flower buds
(c) Polychlorinated ...(i) Carcinogenic
biphenyls
(d) Oxides of nitrogen ...(ii) Metabolized At pH = 12.5
by pyrus plants —COOH, and phenol will lose its proton
110. Answer (1)
Synthetic resin method is most suitable for
preparing deionize water.
Synthetic resins method: Nowadays hard
water is softened by using synthetic cation
112. Answer (3)
Given compound is an example of tranquilizer.

113. Answer (2)
Sucrose is a disaccharides and a non-reducing
sugar because it does not contain free
hemiacetal linkage. 120. Answer (1)
Sucrose involves glycosidic linkage between C 1 • The process of producing syn - gas is called
of –D–glucose and C2 of –D– fructose. ‘coal gasification’ — statement 1 is true
114. Answer (1) • Composition of syn - gas is CO : H2 as 1 : 1
Photochemical smog causes cracking of rubber. 121. Answer (1)
It contains ozone, nitric oxide, acrolein, When the polypeptide chains run parallel and
formaldehyde and peroxyacetyl nitrate. It are held together by hydrogen and disulphide
contains high concentration of oxidizing agents bonds, then fibre-like structure is formed. Such
and is, therefore, called as oxidizing smog. proteins are generally insoluble in water. Some
115. Answer (3) common examples are keratin (present in hair,
(a) Diamagnetism — (iii) NaCl wool, silk) and myosin (present in muscles), etc.
(b) Ferrimagnetism — (iv) Fe3O4 This structure results when the chains of
(c) Paramagnetism — (ii) O2 polypeptides coil around to give a spherical
(d) Antiferromagnetism — (i) MnO shape. These are usually soluble in water.
116. Answer (2) Insulin and albumins are the common examples
Compound (B) is Valium and compound (C) is of globular proteins.
serotonin. They are used as tranquilizers. 122. Answer (3)
117. Answer (1) Ammonium salts are also formed and can be
Seliwanoff’s test → Resorcinol dissolved in conc seen as an atmospheric haze (aerosol of fine
particles). Aerosol particles of oxides or
HCl.
ammonium salts in rain drops result in wet-
All other test use copper based reagent.
deposition. SO2 is also absorbed directly on both
118. Answer (1)
solid and liquid ground surfaces and is thus
Lyophilic sols are more stable because they are
deposited as dry-deposition.
solvated in solution. They are also called as 123. Answer (1)
solvent loving. Lesser the value of BOD, cleaner will be the
119. Answer (2) water sample
Biuret ligand is 124. Answer (4)
In reaction (i), Au (sol) is formed by reduction of
AuCl3, so the chemical method of preparation is
“Reduction”.
It forms complexes like In reaction (ii), As2S3 (sol) is formed by double

decomposition, so the chemical method of
preparation is “Double decomposition”.
In reaction (iii), S (sol) is formed by oxidation of Alumina is an adsorbent (stationary phase)

H2S, so the chemical method of preparation is Benzaldehyde is adsorbate.
“Oxidation”. Acetonitrile is mobile phase.
In reaction (iv), Fe(OH)3(sol) is formed by 128. Answer (3)
hydrolysis of FeCl3 so the chemical method of
preparation is “Hydrolysis”.
125. Answer (2)
• Chloroxylenol is dettol contain phenolic
group so give FeCl3 test
• Norethindrone has double bond so will give 129. Answer (4)
Baeyer's reagent test
Density of dichloromethane is greater than
• Sulphapyridine has – NH2 group it give
water. So, DCM would be the lower layer and
carbyl amine test water will form the upper layer in the separating
• Penicillin has – COOH group so will respond funnel.
to NaHCO3 test 130. Answer (4)
Asn 
Ser 
Asn – Ser
126. Answer (1)

Down the group as the charge density
decreases so chances of formation of hydrate 131. Answer (2)
decreases. Lysine (amino - acid) reacts with ninhydrin to

give a coloured product (blue purple)
So, Ba(NO3)2 does not crystallise with water
– In furfural test (to distinguish between glucose
molecules.
and fructose) dilute sugar solution is added to 1-
127. Answer (4) naphthol (in alcohol) and conc. HCl.
– Benzyl alcohol is oxidised to aldedydes using (R) Ser – –CH2–OH – Ester test (A)
ceric ammonium nitrate (S) Lys – –(CH2)4–NH2 – Carbylamine test (B)
Styrene is converted to
136. Answer (2)
Allosteric effect: Molecule bind to a site other
than the active site of enzyme
using KMnO4 Competitive
132. Answer (4) inhibitor: Molecule bind to the acitve
site
Receptor: Molecule crucial for

communication in the body.
Poison: Molecule binding to the

enzyme covalently
137. Answer (2)
Phenol or unsaturated hydrocarbon (alkene or
alkyne) decolourised bromine water solution.
C2H5MgBr will react with carbonyl carbon or
133. Answer (4)
acidic hydrogen.
reacts with C2H5MgBr and
also decolourized bromine water solution
134. Answer (4) 138. Answer (3)

Wilkinson catalyst is [Rh(PPh)3Cl] dE
r H = −nFE + nFT
dT
Chlorophyll contains Mg.
139. Answer (2)
Vitamin B12 contains Co.
K+ ions act as carriers for nerve signals, are
Carbonic anhydrase contains Zn.
activators for many enzymes and participate in
135. Answer (1)
the oxidation of glucose to form ATP.
140. Answer (4)
Histidine (in strongly acidic solution)
(P)
(Q) AsP – –CH2–COOH – Ester test (A)
More stable product due to conjugation .

145. Answer (1)
Ceric ammonium nitrate test is given by alcohol.
Only serine(ser) contain –OH group.
141. Answer (3) 146. Answer (1)

Activation enthalpy to form C is 5 kJ more than
that to form D.
147. Answer (3)
Quartz, tridymite and cristobalite are crystalline
forms of silica.
Kieselguhr is an amorphous form of silica.
148. Answer (1)
142. Answer (4)
In column chromatograph a solid adsorbent is
Polysubstitution is a major drawback in Friedel
packed in a column and a solution containing
Craft’s alkylation
number of solute particles is allowed to flow
143. Answer (2)
down the column. The solute molecules get
Seliwanoff’s test is used to distinguish aldose
adsorbed on the surface of adsorbent. So, it is
and ketose
differential adsorption of the substances on the
144. Answer (2)
solid phase.
❑ ❑ ❑

Unique Practice Questions - Chemistry

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Unique Practice Questions - Chemistry

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Chemistry

Unique Practice Questions_Chemistry

The product ‘X’ is used

(1) In acid base titration as an indicator

(2) In protein estimation as an alternative to ninhydrin

(3) In laboratory test for phenols

(4) As food grade colourant

3. The number of chiral carbons in chloramphenicol is ___________.

(molecular mass of H2SO4 = 98 g/mol)

5. The number of sp2 hybridised carbons present in “Aspartame” is ______.

7. The number of chiral centres in penicillin is _____________.

8. For the following Assertion and Reason, the correct option is

(2) Both assertion and reason are false.

(3) The assertion is true, but the reason is false.

(atomic number : Xe = 54, Ce = 58, Eu = 63)

(i) A and D both form blue-violet colour with ninhydrin.

(iii) Lassaigne extract of B and D gives positive sodium nitroprusside test.

Based on these observations which option is correct?

(1) A : Aspartame; B : Alitame;

(2) A : Saccharin; B : Alitame;

(3) A : Alitame; B : Saccharin;

(4) A : Aspartame; B : Saccharin;

14. The mass percentage of nitrogen in histamine is _____.

A, B and C are respectively :

(1) A = Lactose, B = Fructose, C = Alanine (2) A = Lactose, B = Glucose, C = Alanine

(3) A = Glucose, B = Fructose, C = Albumin (4) A = Lactose, B = Glucose, C = Albumin

(1) By bacteria to break-down organic waste in a certain volume of a water sample

(2) For sustaining life in a water body

(1) Pb(NO3)2 (2) (NH4)2Cr2O7

(3) NH4NO2 (4) NaN3

(1) Pipette and distilled water (2) Clamp and phenolphthalein

19. The statement that is not true about ozone is

(2) It is a toxic gas and its reaction with NO gives NO2.

(3) In the atmosphere, it is depleted by CFCs

(4) In the stratosphere, it forms a protective shield against UV radiation

(1) aqueous NaOH (2) aqueous NaHCO3

(3) aqueous NH3 (4) vinegar

21. The correct observation in the following reactions is :

(1) Gives no colour (2) Formation of red colour

(3) Formation of violet colour (4) Formation of blue colour

22. The atomic number of the element unnilennium is

(1) 109 (2) 119

(3) 102 (4) 108

23. The antifertility drug “Novestrol” can react with

(1) Br2/water; ZnCl2/HCl; FeCl3 (2) ZnCl2/HCl; FeCl3; Alcoholic HCN

(3) Br2/water; ZnCl2/HCl; NaOCl (4) Alcoholic HCN; NaOCl; ZnCl2/HCl

24. Thermal power plants can lead to

(1) Eutrophication (2) Ozone layer depletion

(3) Blue baby syndrome (4) Acid rain

(a) It can corrode water pipes.

(b) It can damage structures made up of stone.

(c) It cannot cause respiratory ailments in animals.

(d) It is not harmful for trees.

(3) (c) and (d) (4) (c) only

26. Match the following drugs with their therapeutic actions

Drug Therapeutic Action

(i) Ranitidine (a) Antidepressant

(ii) Nardil (b) Antibiotic

(iii) Chloramphenicol (c) Antihistamine

(iv) Dimetane (d) Antacid

27. An ionic micelle is formed on the addition of

(1) excess water to liquid