1

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-01

1. How many 2º and 3° hydrogens atoms are present in 6. A primary amine has amino group (–NH2) attached
the given compound respectively? to :
(1) A primary carbon atom only
(2) A secondary carbon atom only
(3) A tertiary carbon atom only
(4) A primary, secondary or tertiary carbon atom
(1) 9 & 3 (2) 18 & 4 7. The minimum number of carbon atoms in an alkyne
(3) 9 & 4 (4) 12 & 3 having one quaternary carbon atom is
(1) 5 (2) 6
2. Number of secondary carbon atoms present in the (3) 7 (4) 4
below compounds are respectively :
CH3 CH3 8. In the compound
HCC—CH2—CH=CH—CH3, total sigma bond and
and
pie bonds respectively are
CH3 (1) 5, 3 (2) 13, 3
(1) 6, 4, 5 (3) 13, 5 (4) None
(2) 4, 5, 6
(3) 5, 4, 6 9. Which of following is 1° amine ?
NH2
(4) 6, 2, 1 (1)

3. The minimum number of carbon atoms in an alkane CH3

having four primary carbon atoms is : CH3 – C – NH2
(1) 4 (2) 8 (2)
CH3
(3) 5 (4) 6
(3) CH3 – NH2
4. Number of 3º and 2º carbon atoms in the following (4) All
compound are. 10. Number of 2° alcoholic group present in
structure are_____.
OH
HO OH

OH
HO OH
(1) 7, 8 (2) 6, 9 OH
(3) 6, 8 (4) 8, 9 (1) 3 (2) 2
(3) 4 (4) 5
5. The number of primary, secondary, tertiary and
quaternary carbon atoms in iso-octane is given by the 11. Find sum of 1° Hydrogen and 1° Alcoholic group in
set the given structure
COOH
(1) 5, 0, 2, 1
(2) 5, 1, 0, 2 COOH
(3) 5, 1, 1, 1 COOH
(4) 5, 2, 0, 1 (1) 9 (2) 6
(3) 5 (4) 4
 2

12. In which of the following molecules nitrogen atom is 15. Which of the following compound contain all
sp2 hybridised ? 1°, 2°, & 3° amine
CO2H

CO2H (1)
(1) HO2C N
N NH2
HO2 C (2)
HO OH N
N H
(2) NH2

N
(3)
OH N
N
(3) N

N
N (4)
(4) N
N N
N 16. Match the column
13. Which of following is 3° amine? Column-I

(1)
(1) (2) CH3 – NH – Et

(3) CH3 – NH – CH3 (4) CH3 – NH2 (2)

14. (3)
I II

(4)

III IV
Find out the number of 1°, 2° & 3° carbon atoms in Column-II
the above compounds. (P) Even number of 1° carbon atoms
(1) I is having four 2° & four 3° carbons (Q) Even number of 2° carbon atoms
(2) II is having three 1°, six 2°, three 3° & two 4° (R) Even number of 3° carbon atoms
carbons (S) Even number of carbon atom in the w.r. of p.c.
(3) III is having four 1°, two 2°, eight 3° carbons & chain
one 4°carbon
(T) Even number of side chain
(4) IV is having three 1°, three 2° & three 3° carbons
 3

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-02

1. How many sp3 hybridised carbon atoms are there in the CH2
given anti-cancer compound (podophyllotoxin)?
OH 4. C–NH2

O
O Degree of unsaturation in the above compound is
O (1) 7
O (2) 8
(3) 9
(4) 10
MeO OMe
5. How many N atoms are sp2 hybridised in the given
OMe cation?
The anti-cancer compound podophyllotoxin. H

:
(1) 6 (2) 7 N
N
(3) 9 (4) 8 N
N
2. Which of the following is correctly matched with N
degree of unsaturation? (1) 3
CONH2 (2) 4
(1) ⎯⎯→ 4 (3) 5
(4) 6
CCH
(2) ⎯⎯→ 7 6. CC Compound has

(1) 8  bond
CCH3 (2) Degree of unsaturation is 10
COCl
(3) 3° Hydrogens are two
(3) ⎯⎯→ 8 (4) none of these
HOOC 7. How many different type of functional groups are
C present in following structure (Excluding C = C)
O NH2
CH=CH2 H3C–NH
CH2–CH2–C–CH2–NH2
(4) ⎯⎯→ 5
O
O
CN HO
O CH3
O
8. The sum of number of  bond + number of  bond +
degree of unsaturation for the compound.
3. Degree of unsaturation in is : O

N–H
(1) 6 (2) 8
(3) 7 (4) 10 O
 4

9. Find - D.B.E. of the following OH

12. H
(i) C5H10O (ii) C5H8O
(iii) C6H12 (iv) C4H8Cl2 OO
(v) C4H8Br2 (vi) C4H10O NH2 NH2
CH2 CH2
NH
(vii) (viii) O
(a) Find out the total number of 1° hydrogen.
CH2 CH2
(b) Find out the total number of 2° hydrogen.
(c) Find out the total number of 3° hydrogen.
(d) Find out the total number of 1° carbon.
10. How many compounds have double bond equivalent
= 4? (e) Find out the total number of 2° carbon.
(i) Benzene (ii) Acetic acid (f) Find out the total number of 3° carbon.
O (g) Find out the total number of 4° carbon.
(iv) (h) Find out the total number of functional groups.
(iii) Ph – Ph (i) Find out the number of degree of unsaturation.
(v) (vi) COOH
CN Comprehension Q. No. 13 to 15
CHO

(vii) COOH
O
H
OHC
COOMe N O
N

Me2N N N
(viii)
(ix)
Me H
COOH
13. How many different type of functional groups are
O
11. CH3 present in given compound.
CH–2 CH=CH – C – Cl (1) 6 (2) 5
(3) 4 (4) 3
N
O
CH–2 CH3 14. Degree of unsaturation of this compound is
(a) Find out the total number of 1° hydrogen. (1) 10 (2) 9
(b) Find out the total number of 2° hydrogen. (3) 8 (4) 7
(c) Find out the total number of 3° hydrogen.
(d) Find out the total number of 1° carbon.
(e) Find out the total number of 2° carbon. 15. Number of 2° nitrogens present in given compound
(f) Find out the total number of 3° carbon. are
(g) Find out the total number of 4° carbon. (1) 2 (2) 3
(h) Find out the total number of functional groups. (3) 4 (4) 5
(i) Find out the number of degree of unsaturation.
 5

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-03

1. The number of olefinic bonds in the given compound 6. Which of the following represent correct pair of
is/are : homologous?
CH2 CH C CH CH C N
(1) &
O
(1) 2 (2) 3 (2) Me–OH & MeCH2CH2OH
(3) 1 (4) 4

2. The compound which represents an unsaturated (3) &

hydrocarbon is :
(4) CH3–CH2–NH2 &
(1) CH3 – C  N (2) CH3 – CH = CH2
(3) CH3 – CH = O (4) all of these
7. Which of the following represent pair of homologue.
3. Which of the following is not a Homocyclic
compound.
COOH (1)
(1) (2) OH
(2) OH
O O
(3) (4) NH NH
(3)
N O
NH2
H H
(4) H
O
4. Which of the following homologous series has
incorrect general formula:
8. CnH2n–2 represents the homologous series of
(1) Alkyne CnH2n–2
(1) Alkyne (2) Diene
(2) Alkanol CnH2n+2O (3) Cycloalkene (4) Both 1 and 2
(3) Alkanal CnH2n+1O
(4) Carboxylic acid CnH2nO2 9. Which of the following is not triad of homologous
series
5. Which of the following is a Heterocyclic compound. (1) CH3NH2, (CH3)2NH, (CH3)3N
(2) Ph – OH, Ph – CH2 – OH, Ph – CH2 – CH2 – OH
HOOC NO2 H3C N (3) HCOOH, CH3COOH, CH3COOCH3
(1) OH (2)
(4) None of these
OH
O 10. Molecular formula C4H8O2 can have
N
(1) Carboxylic acid (2) Ester
(3) (4) (3) Diketone (4) Saturated Diol
OH
 6

11. Statement-1: Homologues are having similar 12. How many different structures of molecular formula
physical properties & different chemical properties. C3H4.
Statement-2: They are having different molecular
masses & having same functional group.
(1) Statement-1 is true, statement-2 is true and 13. How many different structures of molecular formula
statement-2 is correct explanation for statement-1. C3H8O.
(2) Statement-1 is true, statement-2 is true and
statement-2 is NOT the correct explanation for 14. How many different structures of keton of molecular
statement-1. formula C4H8O.
(3) Statement-1 is false, statement-2 is true.
(4) Statement-1 is true, statement-2 is false.
 7

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-04

1. IUPAC name of the hydrocarbon (A) is: 5. The correct structure of 2-Ethyl-3-methylhexa-1,
CH3 4-diene.
A:
C2H5 (1) (2)
(1) 2-Ethyl-5methylhexane
(2) 5-Ethyl-2methylhexane
(3) 2, 5-Dimethylheptane
(4) 5-Ethyl-2, 5-dimethylpentane (3) (4)
2. The correct structure of 6-Ethyl-2,3,5-
trimethylnonane is :
6. What is the correct IUPAC name of the following
(1) compound.
H2C = CH – CH2 – C  CH
(1) Pent-1-en-4-yne
(2) Pent-4-ene-1-yne
(2) (3) Pent-1-yn-4-ene
(4) 1-Ethenyl-prop-1-yne

7. Which of the following is the correct IUPAC name

(3)
for the following compound?

(4)

3. The correct IUPAC name of following compound is – (1) 2-(1, 1-Dimethyl ethyl)-5-(1-methyl ethyl)
CH3 heptane
–

CH3 – C – CH2 – CH2– CH– CH2– CH2– CH2– CH3 (2) 2-(1, 2-Dimethyl ethyl)-5-ethyl-6-methyl
heptane
–

CH3 CH3 – C – CH3 (3) 3-Ethyl-2, 6, 7, 7-tetramethyl octane

–

CH3 – CH – CH3 (4) 6-Ethyl-2, 2, 3, 7-tetra methyl octane

(1) 2, 3, 3, 7, 7 Pentamethyl-4- Butyloctane
(2) 4-Butyl-2, 3, 3, 7, 7 pentamethylnonane 8. Give IUPAC name
(3) 2, 2-Dimethyl-5-(1, 1, 2-trimethylpropyl)nonane
(4) 5-(1, 1, 2-Trimethylpropyl)-2, 2-dimethylnonane
(1) 3,3-Diethenyl pent-1-ene
4. The IUPAC name of the structure is :- (2) 3,3-Diethenyl pent-4-ene
(3) 3-Ethenyl-3-ethyl penta-1,4-diene
(4) 3,3,3 Triethenyl propane
9. IUPAC name of CH3–C=C=C–C  CH is :
(1) 6-Ethyl-2, 3, 5-trimethylnonane (1) 2-Hexen-4-yne
(2) 3, 4, 6-trimethyl-5-propylnonane (2) Hexa-2, 3-dien-1-yne
(3) 2, 4, 5–Triethyl–nonane (3) Hexa-3, 4-dien-1-yne
(4) 3–Ethyl–5–methyl–3–heptene (4) None of these
 8

10. 3, 3-Diethenyl penta-1,4-diene is : 14. Statement-1 : IUPAC name of

H2C = CH–CH2 – C  CH is Pent-4-en-1-yne.
(1) (2) Statement-2 : Alkene is preferred over alkyne when
they are placed at same position.
(1) Statement-1 is true, statement-2 is true and
statement-2 is correct explanation for statement-1.
(3) (4) (2) Statement-1 is true, statement-2 is true and
statement-2 is NOT the correct explanation for
statement-1.
CH3– C  C – CH – CH = CH — CH – C  C – CH3
(3) Statement-1 is true, statement-2 is false.
11. (4) Statement-1 is false, statement-2 is true.
CH3 – CH = CH CH = CH – CH3
(1) Parent Carbon Chain contains three double 15. Match the Column
bonds. Column I
(2) Parent Carbon Chain contains one double bond (1) Isobutane
and two triple bonds. (2) Neohexane
(3) Parent Carbon Chain contains two double bonds (3) Isooctane
and one triple bond. (4) Isodecane
(4) Parent Carbon Chain contains two double bonds
Column II
and two triple bonds.
(P) Contains 1° carbon atoms
(Q) Contains 2° carbon atoms
12. Which IUPAC name is correct :
(R) Contains 3° carbon atoms
(1) CH3 – C = C – CH3 → 2,3–Diethylbutene
(S) Contains 4° carbon atoms
–

C2H5 C2H5 (T) Parent carbon chain contains odd number of

carbon atoms in IUPAC
(2) HC ≡ C – CH – CH2 – CH2 – CH3
–

HC = CH2 16. Write IUPAC name of the following compound

→ 3-Ethynylpenta-1,4-diene (i) (ii)

(3) HC  C– CH=CH2 → But-1-en-3-yne CH2 – CH3
(4) CH3–CH=CH–C  CH → Pent–1–yne–3–ene
|
(iii) CH3 – CH – CH2 – CH3
CH3 – CH – CH3
13. IUPAC name of the following compound is CH2 CH3
(iv)
CH3 – CH2 – CH2 – CH2 – CH2 – CH2 – CH – CH – CH3

C(CH3)3
(1) 3-(Prop-2-ynyl)hexa-1, 3, 5-triene (v) CH3CH2CHCHCH3
(2) 4-Ethenylhepta-1, 3-dien-6-yne CH(CH3)2
(3) 4-Ethenylhexa-4, 6-dien-1-yne CH3
(4) 4-(Prop-2-ynyl) hexa-1, 3, 5-triene H3C
(vi)
CH3
CH3

CH3
(vii) HC

H2C
(viii) CH3
HC
 9

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-05

1. Degree of unsaturation and s bond in the following 4. Correct IUPAC name of compound is :
compound is Br
Br

(1) 4,4-Dibromo cyclohexene

(2) 5,5-Dibromo cyclohexene
(1) 4, 36 (2) 5, 35
(3) 5, 36 (4) 4, 35 (3) 1,1-Dibromo cyclohex-3-ene
(4) 1,1-Dibromo cyclohex-4-ene
2. In which of the following compound IUPAC
numbering is correct :

5. The IUPAC name of is :-

(1)

(1) 1–Methyl–5–ethyl cyclohex–2–ene

(2) 5–Ethyl–3–methyl cyclohex–1–ene
(3) 4–Ethyl–6–methyl cyclohex–1–ene
(2) (4) 1–Ethyl–5–methyl cyclohex–3–ene

6. IUPAC name of given structure:

1 Cl
6 2
(3)
3 Br
5
4 (1) 8-bromo-5-chloro cyclooct-3-en-1-yne
(2) 5-bromo-8-chloro cyclooct-1-en-3-yne
1 (3) 1-bromo-6-chloro cyclo oct-4-en-2-yne
6 2 (4) 1-bromo-4-chloro oct-5-en-7-yne
(4)
3
5
4 7. What will be the correct IUPAC name for the
following compound.
CH=CH–CH2
CH3
3. name of the compound is
(1) 1-(But-1-enyl) cyclohexane

(1) 5-Chloro-2-ethyl-1-methyl cyclohexane (2) 1-Cyclohexyl-2-ethyl ethene

(2) 1-Chloro-4-ethyl-3-methyl cyclohexane (3) 1-Cyclohexyl but-1-ene
(3) 1-Ethyl-2-methyl-4-chloro cyclohexane (4) 1-Cyclohexyl-3-methyl prop-1-ene
(4) 4-Chloro-1-ethyl-2-methyl cyclohexane
 10

8. IUPAC name of the compound is 13. Statement-1 : 3-Nitrocyclohexene is the correct

CH3 IUPAC name.
Statement-2 : According to IUPAC rule principle
functional group is given priority over multiple bond
in numbering of parent chain.
Br (1) Statement-1 is true, statement-2 is true and
statement-2 is correct explanation for statement-1.
(2) Statement-1 is true, statement-2 is true and
(1) 3-(2-Bromo cyclopentyl)-6-methyl-cyclohex-1-ene statement-2 is NOT the correct explanation for
(2) 3-Methyl-6-(2-bromo cyclopentyl)-cyclohex-1-ene statement-1.
(3) 1-Methyl,4-(2-bromo cyclopentyl)-cyclohex-2-ene (3) Statement-1 is true, statement-2 is false.
(4) 4-Methyl-1-(2-bromo cyclopentyl)-cyclohex-2-ene (4) Statement-1 is false, statement-2 is true.
9. IUPAC name of the compound is 14. Write IUPAC name of the following compound
OH
(i)
H3C CH3
(1) 3-Ethyl-5-methyl phenol
(2) 5-Methyl-3-ethyl phenol
(3) 5-Methyl-3-ethyl cyclohexanol (ii)
(4) 3-Ethyl-5-methyl cyclohexanol
CH3
(iii)
10. H3C

(iv)
H3C CH3
IUPAC name of this compound is:
(1) 1,2-Dimethyl cyclohex-2-ene CH2
(2) 1,2-Dimethyl cyclohex-1-ene
(3) 2,3-Dimethyl cyclohex-1-ene (v)
(4) 1,6-Dimethyl cyclohex-1-ene

11. The IUPAC name of the compound shown below is

Cl
|
CH2
H3C
Br Br
(1) 2-Bromo-6-chlorocyclohex-1-ene
CH2
(2) 6-Bromo-2-chlorocyclohexene (vi) H3C
(3) 3-Bromo-1-chlorocyclohex-1-ene
HO CH3
(4) 1-Bromo-3-chlorocyclohexene

12. The IUPAC name of

(1) 1-Cyclohexyl-3-methyl-1-pentene
(2) 3-Methyl-5-cyclohexylpentene
(3) 1-Cyclohexyl-3-ethylbut-1-ene
(4) 1-Cyclohexyl-3,4-dimethylbut-1-ene
 11

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-06

1. How many different type of functional groups are 6. Which IUPAC name is correct for the given
present in following structure. compound?
NH2 O
OCH3
O
HO
NH2 (1) 3, 7-Dimethylocta-2, 6-dienal
O O (2) 2, 6-Dimethyloct-2, 6-dienal-8
(1) 5 (2) 4 (3) 7-Formyl-2, 6-dimethylhept-2, 6-diene
(3) 6 (4) 7 (4) 7-Aldo-2,6-dimethylhept-2, 6-diene

2. The IUPAC name of HOCH2CH = C(CH3)2 7. Select option with correct IUPAC names
COOH
(1) 2-Methyl-2-buten 4-ol
(1) cyclohexanoic acid
(2) 3-Methyl-2-buten-1-ol
(3) 2-Methyl-2-butenol
(4) 3-Methyl-2-butenol. (2) 2-hexyne
(3) CN Propane nitrile
3. What is the IUPAC name of the following
compound? CH3 − CH − OMe
(4) | 2-methoxy propane
O Me
C – Cl
8. Which of the following is primary amine
(1) Cyclohexanoyl chloride (1) t-butyl amine
(2) aniline
(2) Cyclohexane carbonyl chloride
(3) sec. butylamine
(3) 1-Cyclohexyl methnoylchloride (4) N-methyl methanamine
(4) None of these
9. Column I
4. The IUPAC name of is (Compound)
O
(1) 3-Methylpent-1-en-4-al ||
(2) 3-Methylpent-4-enal (1) CH3 − CH 2 − C − CH 2 − OH
(3) 3-Methylpent-4-carbaldehyde (2) CH3 − CH2 − C  N
(4) 3-Methyl-5-oxopent-1-ene (3) CH3 − CH2 − O − CH3
(4) CH3 − CH2 − NH2
5. What is the structure of 4-Methylhex-5-en-3-ol. Column II
(Functional group present)
(1) (2) (P) 1°-amine
(Q) Ether
(R) Ketone
(3) (4) (S) Carboxylic acid
(T) Cyanide
 12

10. Statement-1 : 4-ethyl-3-bromo pentanoic acid is not 11. Write IUPAC name of the following compound
HO
the correct IUPAC name.
H3C CH3
Statement-2 : Selection of carbon chain in 3-bromo (i)
4-ethyl pentanoic acid is not according to IUPAC
rule.
(A) Statement-1 is true, statement-2 is true and H3C
(ii)
statement-2 is correct explanation for statement-1.
HO
(B) Statement-1 is true, statement-2 is true and
statement-2 is NOT the correct explanation for CH2
statement-1.
(C) Statement-1 is false, statement-2 is true. (iii) CH
|
2 — CO — CH2 — CH2 — CH2 — Cl

(D) Statement-1 is true, statement-2 is false. CH3

(iv) CH3 — CH
|
— CO — CH — CH3
|
CH3 CH3
CH3 — C = C — CH2OH
(v) | |
CH3 Br
 13

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-07

1. In IUPAC nomenclature of compounds 5. The correct IUPAC name of compound is :

O O COOH
|| || Br
(I) − C − NH2 (II) − C − OH
O O
|| ||
(III) − C − Cl (VI) − C − H NH2
(V) −C  N (1) 3-Amino-6-bromocyclohexane-1-carboxylic acid
Correct priority order of group is : (2) 2-Bromo-5-aminocyclohexane-1-carboxylic acid
(1) I > II > III > IV > V (3) 5-Amino-2-bromocyclohexane-1-carboxylic acid
(2) II > III > I > V > IV (4) 4-Bromo-5-carboxycyclohexanamine
(3) II > I > III > IV > V
(4) I > III > II > V > IV 6. IUPAC name of following compound is:
COOH
2. The IUPAC name of is COOH
COOH
(1) 3,5-Dicarboxy-2-methyl hexanoic acid
(1) 2, 3-Dihydroxybutane-1, 4-carboxylic acid (2) Hexane-2,4,5-tricarboxylic acid
(2) 2, 3-Dihydroxybutane-1, 4-dioic acid (3) Hexane-2,3,5-tricarboxylic acid
(3) 1, 2-Dihydroxyethane dicarboxylic acid (4) 2-(1-Hydroxy carbonyl)-4-methylhexane-1,6-
(4) none of these dionic acid
3. Correct IUPAC name is: 7. Select correct statement(s):
O
(1) Acetone and acetaldehyde are homologues
O
(2) is secondary amine while N is a
(1) 2-Methyl-2-pentyl propanoate Me
(2) 1-Ethoxy-2-ethyl-3-methyl-but-2-en-1-al tertiary amine
(3) Ethyl-2-ethyl-3-methylpent-2-en-1-oate (3) HO is secondary alcohol while is
(4) Ethyl-2,3-diethylbut-2-en-oate OH
a tertiary alcohol.
4. The correct structure for the compound Hept-3-en-5- O
yne -2-one is O
(4) and both have different
O
Cl Cl
=

(1) H3C – CH = CH – C ≡ C – C – CH3 functional groups.

O 8. Total number of different functional groups in
=

(2) H2C = CH – CH = CH – C – CH3 following compounds.

OH
O N OH
=

(3) H3C – HC = CH – CH = CH – C – CH3 N

N N–H
O N
=

(4) H3C – C ≡ C – CH = CH – C – CH3 NH2

SH
 14

11. Match the Column

Column-I
9.

(1)
When IUPAC name of following compound is given,
then double bond and substituent gets respectively (
x and y) number so the sum of (2)
( x + y) will be

10. Calculate the sum of pi bonds + DBE value + 3° Carbon (3)

in given compound

(4)
O
Column-II
(p) 1-Butyl-4-methyl cyclohexane
(q) 2-Bromo-1,1-dichloro cyclohexane
(r) 1-Bromo-1,2-dichloro cyclohexane
(s) Ethyl-2-formyl cyclohexane carboxylate
 15

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-08

1. The correct IUPAC name of the compound is :

5. is named as :
(1) 2, 3-Dimethylenebutanal
(2) 3-Methyl-2-methylenebut-3-enone
(3) 3-Methyl-2-methylidenebut-3-enal
(1) 3-(1-Methylethenyl)-4-hydroxypentan-2-one (4) 2, 3-Dimethylenebutanone
(2) 3-(1-Hydroxyethyl)-4-methylpent-4-en-2-one C2H5–O
(3) 3-(1-Hydroxymethyl)-4-methylenepentan-2-one 6. The IUPAC name of C = O is:
(4) 3-(1-Oxoethyl)-4-methylpent-4-en-2-ol. C2H5–CH

CH3
2. The correct IUPAC name of the compound is :
(1) Ethoxymethanone
(2) Ethyl -2-methylbutanoate
(3) Ethoxypropanone
(4) 2-Methylethoxypropanone
7. Correct IUPAC name of the compound
(1) 4-Ethyl-3-methylnonane-2, 8-diol
O
(2) 6-Ethyl-7-methylnonane-2, 8-diol
Et
(3) 5-Ethyl-1, 6, 7-trimethylheptane-1, 7-diol
(4) 4-Ethyl-2-methylnonane-2, 7-diol O
Me
3. The correct IUPAC name of compound is : O
O
(1) 2-Ethyl-3-methylbut-2-ene-1,
Cl 4-dioic anhydride
(2) 3-Ethyl_2-methylbut-2-enedioic anhydride
O (3) 2-Ethyl-3-Methyl-1, 4-diketobut-2-enoic
anhydride
(1) 1-Chloropentane-1, 4-dione
(4) 2-Ethyl-3-methylcyclopenatanoxy-1, 4- dione
(2) 4-Chlorocarbonylbutan-2-one
(3) 4-Oxopentanoyl chloride 8. The IUPAC name of the given
(4) 3-Oxobutanecarbonyl chloride CHO CONH2
| |
CH 3 − CH − CH − CH − CH − COOH
4. The correct IUPAC name of the | |
Br COCl
compound is : compound is:
(1) 2-Bromo-4-carbamoyl-5-chlorocarbonyl-
3- formylhexanoic acid
(1) 6-Ethyl-1-methyl-4-oxohept-6-ene-1-sulphonic (2) 5-Bromo-3-carbamoyl-2-chlorocarbonyl-4-
acid formylhexanoic acid
(2) 7-Ethyl-5-oxooct-7-ene-2-sulphonic acid (3) 4-Formyl-2-chlorocarbonyl-3-carbamoyl-5-
(3) 2-Ethyl-7-sulphooct-1-ene-4-one bromohexanoic acid
(4) 7-Methylene-5-oxononane-2-sulphonic acid (4) 2-Chlorocarbonyl-3-carbamoyl-4-formyl-5-
bromohexanoic acid
 16

O 13. Write IUPAC name of the following compound

O NH2
H
9. IUPAC name of is (i) H3C
H CH3

O Br
H2C
(1) Cyclobutane-1-carbaldehyde-2-carboxylate
(2) (2-Formyl cyclobutene) carboxylate
(3) (2-Formylcyclobutyl) methanoate (ii)
(4) 2-Methanoyloxy cyclobutane carbaldehyde OH
HO O
HO
O
10. The IUPAC name of is : (iii) HO
O CH3

(1) 3-Carboxy-3-hydroxypentanedicarboxylic acid O OH

(2) 2-Hydroxypropane-1, 2, 3-tricarboxylic acid
(3) 2-Hydroxypropane-1, 2, 3-trioic acid H3C
(4) 3-Hydroxypropane-1, 2, 3-tricarboxylic acid CH3
(iv)
HC
11. Statement-1 : The general IUPAC name of esters is CH3
alkyl Alkanoate CH3
Statement-2 : The simplest ester is HCOOCH3 NH2
(1) Statement-1 is true, statement-2 is true and H3C CH3
statement-2 is correct explanation for statement-1. (v)
H2N
(2) Statement-1 is true, statement-2 is true and
CH2
statement-2 is NOT the correct explanation for
O
statement-1. (vi) H C
(3) Statement-1 is true, statement-2 is false. 3 CH3
(4) Statement-1 is false, statement-2 is true. O
O

12. The IUPAC name of the given compound is : (vii)

OH H3C O CH3
CH3
–

HOOC – CH2 – C – CH2 – C – OH O

(viii) O CH3
–

COOH O O

(1) 3–Carboxy–3–hydroxy butane dioic Acid Cl

(2) 2–Hydroxy propane–1,2,3–tri carboxylic acid CH3
(3) 3–Hydroxy butane dioic acid (ix) O O
(4) 2–Bis(carboxymethyl)–2–hydroxyethanoic acid
O
Br
O

(x) Cl NH Br
 17

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-09

CHO 5. Which of the following is correct IUPAC name:

Ph
1. Degree of unsaturation for is OH

CN
(1)
(1) 8 (2) 9
(3) 10 (4) 11 CH3
CH3
2. Which of the following is the correct structure of
3,4-Dimethylphenol.
catechol.
OH

(1) (2)
(2)
CH3
CH3
(3) (4)
4-Hydroxy-2-methyl toluene.
CH2 – CH3
3. What is correct IUPAC name of OCH3
COOH (3)
OH
1-Ethyl-2-anisole.
Br Br
(1) 4-Bromo-2-hydroxy cyclohex-5-ene-1-oic acid
(2) 4-Bromo-2-hydroxy cyclohex-5-ene-1-carboxylic
acid (4)
(3) 4-Bromo-6-hydroxy cyclohex-2-ene-1-carboxylic Br
acid
1-(2,3-Dibromopentyl) benzene.
(4) 4-Bromo-6-hydroxy cyclohex-2-ene-1-oic acid

4. The IUPAC name of the following compound is : 6. IUPAC name of the following compound is
OH

(1) 3–(Cyclohexa–1,3-dienyl)cyclohexa-1,4-diene
CN
(2) 4–(Cyclohexa–2,5-dienyl)cyclohexa-1,3-diene
Br
(3) 2–(Cyclohexa–1,3-dienyl)cyclohexa-1,3-diene
(1) 4-Bromo-3-cyanophenol
(2) 2-Bromo-5-hydroxybenzonitrile (4) 1–(Cyclohexa–2,5-dienyl)cyclohexa-1,3-diene
(3) 2-Cyano-4-hydroxybromobenzene
(4) 6-Bromo-3-hydroxybenzonitrile
 18

7. The correct IUPAC name of following compound is 11. The no. of compound with correct IUPAC name
COOH is/are :

(a)
2-Carboxyphenol
OH
CH2NH2 (b)
(1) 4-Aminomethyl-3-hydroxycyclohex-5-ene-1-
carboxylic acid
(2) 2-Aminomethyl-5-carboxycyclohex-3-en-1-ol 3-Ethyl-4-chloro-5-hydroxybenzenecarbonitrile
(3) 4-Aminomethyl-5-hydroxycyclohex-2-ene-1-
carboxylic acid
(4) 3-Hydroxy-4-aminomethylcyclohex-5-en-1-oic
acid (c)

8. O has the IUPAC name: 3-Formyl-5-nitrobenzenecarboxylic acid

COOC2H5
(d)
(1) Ethyl–2–oxo cyclopentane carboxylate
(2) 2–Cyclopentanone–1–carbethoxy
(3) 2–Ethylcarbonate cyclopentanone
1-Hydroxy-3-methoxy-4-nitrobenzene
(4) 1–Keto–2–carbethoxy cyclo Pentanone

9. The IUPAC name of the following compound is : (e)

4-Amino-1-nitrobenzene

(f)

(1) 5-Bromo-3-hydroxybenzenecarbaldehyde
3-Methylphenol
(2) 3-Bromo-5-formylphenol
(3) 3-Bromo-5-hydroxybenzaldehyde
(4) 1-Bromo-3-formyl-5-hydroxy Benzene
(g)

10. The IUPAC name of is 2,4,6-Trimethylbenzenecarbonylchloride

(1) 2–Chlorocarbonylethyl benzoate

(2) 2–Carboxyethylbenzoylchloride
(3) Ethyl–2–(chlorocarbonyl) benzoate
(4) Ethyl–1–(chlorocarbonyl) benzoate
 19

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-10

5. Vinylcarbinol is :
(1) HO - CH2 - CH = CH2
1. The IUPAC name of is : (2) CH3CH(OH) = CH2
(3) CH3 - CH = CH - OH
(1) 2-Hydroxybenzenol (4) CH3 - C(CH2OH) = CH2
(2) 1, 2-Dihydroxybenzene
(3) Benzene-1, 2-diol 6. Correct IUPAC name of given compound.
(4) 2-Hydroxyphenol HO NH2

2. The second member of the homologous series of

ethyl ketone has the structure:- CHO
(1) CH 3CH 2 – C – CH 2 CH 3 (1) 3-Amino-5-hydroxy benzaldehyde
|| (2) 3-Amino-5-formyl benzenol
O (3) 1-Amino-3-formyl-3-hydroxy benzene
(2) CH3 – CH – C – CH3 (4) 3-Formyl-5-hydroxy aniline
| ||
CH3 O 7. Number of –COOH groups present in Picric acid is /
(3) CH 3 – C – CH 2 CH 3 are
|| (1) 1 (2) 2
O (3) 0 (4) 3
(4) CH 3 – C – CH 3
|| O
O
C–O–Et
3. The gas leaked from a storage tank of the Union 8. IUPAC name of following
Cl—C
Carbide plant in Bhopal gas tragedy was:
O
(1) Phosgene (2) Methylisocynate compound is:
(3) Methylamine (4) Ammonia (1) 4-ethoxycarbonyl benzoyl chloride
(2) Ethyl 4-chlorocarbonyl benzene carbonate
4. Structural formula of isopropyl methanoate is: (3) Ethyl 4-chloroformyl phenyl methanoate
(1) CH 3 − C − O − CH − CH 3 (4) Ethyl 4-chlorocarbonyl benzoate
|| |
O CH 3
NH2
(2) H – C – O – CH – CH2 – CH3
––

9. For the compound select the incorrect

O CH3

(3) CH 3 − C − O − CH 2 − CH 2 statement
|| | (1) Compound is Homocyclic hydrocarbon
O CH 3
(2) Number of  bonds are 8
(4) H − C − O − CH − CH 3 (3) Degree of unsaturation of the compound is 3
|| |
O CH 3 (4) It is a heterocyclic compound.
 20

11. Degree of unsaturation for following structure is 'x'

then
CN
10. The IUPAC name of is :
CHO
(1) 2-Carboxyphenol
(2) 2-Hydroxybenzoic acid
(3) 1-Carboxy-2-hydroxybenzene COOH
(4) 2-Carboxy-1-hydroxybenzene
 x−2
Find  ?
 2 
 21

PRAYAS JEE-2024
Nomenclature (BTS SPECIAL) Practice sheet-11

6. Correct IUPAC name of given compound

COOH
1. The name of the compound is

(1) Bicyclo [2.2.1] octane

(2) Bicyclo [1.1.1] octane
(3) 1, 4-Bismethylenecyclohexane
(4) Bicyclo [2.2.2] octane (1) 3,5-Dimethyl Bicyclo [2, 2, 1] hept-2-ene-7-
carboxylic acid
2. Which of the following structures represents bicyclo (2) 3,7-Dimethyl Bicyclo [2, 2, 1] hept-3-ene-1-
[3.2.0] heptane carboxylic acid
(3) 2,6-Dimethyl Bicyclo [2, 2, 1] hept-2-ene-7-
carboxylic acid
(1) (2) (4) 3,7-Dimethyl Bicyclo [2, 2, 1] hept-6-ene-1-
carboxylic acid
(3) (4)

7. The IUPAC name of is

(1) bicyclo [3.2.0] hexan-2-ol
3. The IUPAC name of compound is (2) spiro [3.2] hexan-1-ol
(3) spiro [3.2] hexan-4-ol
(1) Bicyclo [2.2.1] hept-2-ene (4) spiro [2.3] hexan-4-ol
(2) Bicyclo [2.2.1] hept-5-ene
(3) Bicyclo [2.1.2] hept-2-ene
(4) Bicyclo [1.2.2] hept-2-ene 8. The IUPAC name of camphor is

(1) 6-Oxo-1,2,2- trimethyl bicyclo [2,2,1] heptane

4. The IUPAC name of compound is (2) 1,7,7-Trimethyl bicyclo [2,2,1] heptan-2-one
(3) 1,5,5-Trimethyl bicyclo [2,1,1] hexan-2-one
(1) Spiro [5.3] nonane (4) 1,7,7-Trimethyl bicyclo [2,1,2] heptan-2-one
(2) Spiro [3.5] nonane
(3) Spiro [5.4] nonane 9. Select incorrect IUPAC name(s).
(4) Spiro [4.5] nonane (1) 1-amino pentane-1,4-dione
(2) 3-chloro cyclohexanoic acid
5. What is the correct IUPAC name for the following (3) Propane-1,3-dicarboxylic acid
compound. (4) 2,3-dimethyl cyclohex-1-ene
OH
HO CN
Cl 10.

COOH
Select correct statement.
(1) 7-Chloro-2-methyl bicyclo [3,2,1] octan-1-ol (1) It is a homocyclic compound
(2) 7-Chloro-2-methyl bicyclo [3,2,1] octan-8-ol (2) It is having–COOH as the principal functional group
(3) 2-Chloro-7-methyl bicyclo [3,2,1] octan-8-ol (3) It is having isocyanide as one of the functional
(4) 2-Chloro-7-methyl bicyclo [3,2,1] octane-1-ol group
(4) It is having ethyl at 2nd position
 22

11. Which of the following is /are incorrect IUPAC 15. Column-I Column-II
name.
(1) 4-Chloro-3-methyl cyclopentanol-1
(2) 1-Amino-3-bromo hexan-1-one (1) (P) Homocyclic compound
(3) 4-Chloro-3-methyl cyclohexane carboxylic acid
(4) 3-Bromo-1-methyl hexan-1-ol
(2) (Q) Closed chain hydrocarbon
12. Which of the following is / are not the correct IUPAC
name?
(1) 2-Ethyl-3-methyl pentane (3) (R) Bicyclobridge heads are present
(2) 4-Formyl pentan-2-ol
(3) 3-Carboxy pentanoic acid
(4) Cyclohexanoic acid

13. Which of the following IUPAC name(s) is/are correct (4) (S) Spiro carbon is present
(1) 2,2,3-Trimethyl hexane
(2) 3-[l,2-Dimethyl Propyl]-5-Propyl Decane
(3) 3,4 Dimethyl-7-(2-methyl propyl) Undecane
(4) 3-Ethyl-2, 6-Dimethyl heptane

14. Which of the following names are correctly written

against them?
(1) CH2
NH2
Hexa-1,4-dien-3-amine

(2)

1-Carbamoyl ethane
H3C CH3
(3)
O Cl O
2,4-Dimethyl-5-oxopentanoyl chloride
O NH2
(4) H N
2
OH
1,5-Diamino-4-hydroxy hex-2-en-1-one
 23

Answer Key
Practice sheet-01
1. (2) 2. (1) 3. (3) 4. (4) 5. (3) 6. (4)
7. (2) 8. (2) 9. (4) 10. (3) 11. (2) 12. (3)
13. (1) 14. (1, 2, 3, 4) 15. (2, 3)
16. [(1) P,R, T (2) P,R T ; (3) P, Q,R, S, T ; (4) P, R, S, T)]

Practice sheet-02
1. (3) 2. (2) 3. (2) 4. (3) 5. (3) 6. (1, 2)
7. (5) 8. (29) 9. [((i)-1, (ii)-2, (iii)-1, (iv)-0, (v)-0, (vi)-0, (vii)-7, (viii)-17)]
10. (5) 11. [(a-9, b-12, c-1, d-5, e-9, f-1, g-1, h-4, i-6)]
12. [(a-9, b-11, c-3, d-5, e-9, f-3, g-0, h-7, i-5)]
13. (1) 14. (1) 15. (1)

Practice sheet-03
1. (1) 2. (2) 3. (2) 4. (3) 5. (2) 6. (2, 3)
7. (3, 4) 8. (1, 2, 3) 9. (1, 2) 10. (1, 2) 11. (3) 12. (3)
13. (3) 14. (1)

Practice sheet-04
1. (3) 2. (1) 3. (3) 4. (2) 5. (3) 6. (1)
7. (4) 8. (3) 9. (3) 10. (2) 11. (1) 12. (3)
13. (2) 14. (4) 15. [(1)-PRT, (2)-PQS, (3)-PQRST, (4)-PQRT)]
16. (i)- 2, 2-dimethylpropane
(ii)- 3,3,5,5-tetramethylheptane
(iii)- 3-methylpentane
(iv)- 4-isopropyl-2-methyldecane or 2-methyl-4-(1-methylethyl)decane
(v)- 3-ethyl-2,2,4,5-tetramethylhexane
(vi)- 3-Ethyl-6-methylheptane
(vii)- oct-5-en-1-yne
(viii)- 3-ethylhex-1-en-5-yne

Practice sheet-05
1. (3) 2. (3) 3. (2) 4. (1) 5. (2) 6. (2)
7. (3) 8. (1) 9. (4) 10. (4) 11. (3) 12. (1)
13. (2)
14. (i)- cyclopenta-1,3-diene
(ii)- 5-(1-methylethyl)cyclopenta-1,3-diene
(iii)- 1,3-dimethylcyclobutene
(iv)- 1,4-dimethylcyclobutene
(v)- 1-ethenyl-3-(prop-2-enyl)cyclohexene
(vi)- 3-methylcyclopropene
 24

Practice sheet-06
1. (1) 2. (2) 3. (2) 4. (2) 5. (2) 6. (1)
7. (2, 4) 8. (1, 2, 3) 9. ([(1) R (2) T (3) Q (4) P]) 10. (2)
11. (i)- 6-cyclopropylhept-4-en-3-ol (ii)- hexa-1,4-dien-3-ol
(iii)- 6-Chlorohexan-3-one (iv)- 2, 4-dimethylpentan-3-one
(v)- 2-Bromo-3-methyl-but-2-en-1-ol.

Practice sheet-07
1. (2) 2. (2) 3. (3) 4. (4) 5. (3) 6. (3)
7. (2, 3, 4) 8. (6) 9. (10) 10. (9) 11. (1 - q; 2 - p; 3 - s; 4 - r)

Practice sheet-08

1. (2) 2. (1) 3. (3) 4. (2) 5. (3) 6. (2)

7. (1) 8. (2) 9. (3) 10. (2) 11. (2) 12. (2)
13. (i)- 3,5-dibromohexan-2-amine
(ii)- 6-hydroxy non-8-enoic acid
(iii)- 6-cyclohexyl-5-hydroxy-6-methoxyhexanoic acid
(iv)- 6-amino-3,5-dimethyl-4-(1-methylethyl)oct-7-ynoic acid
(v)- 6-methyloct-7-en-2-amine
(vi)- ethyl ethanoate
(vii)- methyl propanoate
(viii)- butanoic ethanoic anhydride
(ix)- 2-bromoethanoic 2-chloropropanoic anhydride
(x)- 2-bromo-N-chloroethanamide

Practice sheet-09
1. (2) 2. (2) 3. (3) 4. (2) 5. (1) 6. (4)
7. (3) 8. (1) 9. (3) 10. (3) 11. (2)

Practice sheet-10
1. (3) 2. (1) 3. (2) 4. (4) 5. (1) 6. (1)
7. (3) 8. (4) 9. (1, 2, 3, 4) 10. (2) 11. (6)

Practice sheet-11
1. (4) 2. (3) 3. (1) 4. (2) 5. (2) 6. (3)
7. (4) 8. (2) 9. (1, 2, 3, 4) 10. (1, 2) 11. (1, 2, 4) 12. (1, 2, 3, 4)
13. (1, 3, 4) 14. (1, 3) 15. [(A) P, Q; (B) P,Q,R; (C) P,Q,S; (D) P,Q,R,S)]

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