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LAKSHYA JEE 2023

Alcohol, Phenol and Ethers DPP-01

1. The general molecular formula, which represent the

homologous series of alkanol is: 8. Isobutyl alcohol is a:
(1) CnH2nO (2) CnH2n+1O (1) Primary alcohol
(3) CnH2n+2O (4) CnH2nO2 (2) Secondary alcohol
(3) Tertiary alcohol
2. Which one is a primary alcoholic group? (4) None of these
(1) −CH 2 OH (2)
9. If two — OH groups are attached to
1, 3-carbon atoms, it is called:
(3) (4)
(1) α-glycol (2) β-glycol
3. Butan-2-ol is a: (3) γ-glycol (4) ∆-glycol
(1) Primary alcohol (2) Secondary alcohol
(3) Tertiary alcohol (4) Dihydric alcohol 10. Vinyl carbinol is:
(1) HO − CH 2 − CH = CH 2
4. Number of isomeric alcohols and total number of OH
(2) |
isomer with formula C4H10O is: CH3 − C = CH 2
(1) 2, 7 (2) 1, 10
(3) CH3 − CH = CH − OH
(3) 3, 7 (4) 4, 7
(4) CH3 − C ( CH 2 OH ) =
CH 2
5. An isomer of ethanol is:
(1) Methanol (2) Dimethyl ether 11. Which of the following ‘gem’ diols is stable?
(3) Acetone (4) Diethyl ether OH OH
| |
(1) CH3 − C− H (2) CBr3 − C− H
6. The IUPAC name for the following compound is: | |
OH OH
OH OH
| | OH OH
CH3 − C− CH 2 − CH − CH3 | |
| (3) CF3 − C− H (4) C6 H5 − C− C6 H5
CH3 | |
OH OH
(1) 1, 1-dimethyl-1, 3-butandiol
(2) 2-methyl-2, 4-pentandiol
(3) 4-methyl-2, 4-pentandiol
12. The IUPAC name of the compound
(4) 1,3,3-trimethlyl-1, 3-propandiol

7. The IUPAC name of (1) 3, 3-dimethyl cyclohexanol

(2) 1,1-dimethyl-3-hydroxy cyclohexane
CH3 − CH − CH 2 − CH ( OH ) − CH3
| is (3) 3,3-dimethyl-1- cyclohexane
CH 2 CH3 (4) 1,1-dimethyl-3- cyclohexane
(1) 2-ethylpentan-4-ol
(2) 4-ethylpentan-2-ol 13. CH3CH2OH is:
(3) 4-methylhexan-2-ol (1) Methyl carbinol
(4) 4-methylpentan-2-ol (2) Ethyl alcohol
(3) Drinkable alcohol
(4) All are correct
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OH 17. The product of the following reaction is

|
(i) BH /THF
14. CH3CH 2 − C − CH3 cannot be prepared by 
3
→
−
| (ii) H 2O 2 , OH
Ph (1) 2-pentanol (2) pentane
(1) CH3CH2COCH3 + PhMgX (3) pentan-2-one (4) 1-pentanol
(2) PhCOCH3 + CH3CH2MgX
(3) PhCOCH2CH3 + CH3MgX 18. Ortho-dihydroxy benzene is:
(4) HCHO + PhCH(CH3) CH2MgX (1) Carvacrol (2) Resorcinol
(3) Catechol (4) Orcinol
15. Which of the following compounds on reaction with
excess of CH3MgBr will give a tertiary alcohol? 19. Glycerin has:
(1) One primary and two secondary –OH
(1) groups
(2) One secondary and two primary –OH
(2) C2H5CO2CH3 Groups
(3) C6H5CHO (3) Three primary –OH groups
(4) Three secondary –OH groups
(4) C2H5COOH

16. Oxymercuration-demercuration reaction of

1-methylcyclohexene gives
(1) Trans-2-methyl cyclohexanol
(2) Cis-2-methylcyclohexanol
(3) 1-methylcyclohexanol
(4) Mixture of cis- and trans-2-methylcyclo-
hexanol
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Answer Key
1. (3)
2. (1)
3. (2)
4. (4)
5. (2)
6. (2)
7. (3)
8. (1)
9. (3)
10. (1)
11. (3)
12. (1)
13. (4)
14. (4)
15. (2)
16. (3)
17. (4)
18. (3)
19. (2)

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