Professional Documents
Culture Documents
.UNIT TEST - 6 A
Std : Long term (Batch - A) Max. Marks: 720
Test Date : 23.03.2023 CHEMISTRY & BOTANY Time : 3 Hrs.
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 180 x 4 = 720
1. Picric acid is X
4. C6H5 –CH =CHCHO → C6H5CH =CHCH2OH
In the above sequence X can be
1) H2/Ni 2) NaBH4
+
1) 2) 3) K2Cr2O7/H 4) Both (1) and (2)
5. In which of the following bond angles on sp3-
hybridized are not contracted due to lone pair
of electron?
1) OF2 2) H2O
3) 4) 3) CH3OCH3 4) CH3OH
6. Phenol can be converted to o-hydroxy
benzaldehyde by
2. 1-propanol and 2-propanol can be 1) Kolbe’s reaction
2) Reimer-Tiemann reaction
distinguished by
3) Wurtz reaction
1) Oxidation with alkaline KMnO4 followed
4) Cannizaro reaction
by reaction with Fehling solution
7. An organic compound ‘X’ with molecular
2) Oxidation with acidic dichromate followed
formula, C7H8O is insoluble in aqueous
by reaction with Fehling solution NaHCO3 but dissolves in NaOH. When treated
3) Oxidation by heating with copper followed with bromine water ‘X’ rapidly gives ‘Y’
by reaction with Fehling solution C7H5OBr3. The compounds ‘X ’ and ‘Y’
4) Oxidation with concentrated H2SO4 respectively, are
followed by reaction with Fehling solution 1) Benzyl alcohol and 2, 4, 6-tribromo-3-
3. Propan-1-ol (major) can be prepared from methoxy benzene
propene by 2) Benzyl alcohol and 2, 4, 6-tribromo-3-
1) H2O/H2SO4 methyl phenol
2) Hg(OAc)2/H2O followed by NaBH4 3) m-cresol and 2, 4, 6-tribromo-3-methyl
phenol
3) B2H6 followed by H2O2/OH–
4) Methoxybenzene and 2, 4, 6-tribromo-3-
4) CH3CO2H/H2SO4
methoxy benzene
2 Test ID : 831[A]
8. On treatment with anhydrous zinc chloride in 1) Predominantly 2-butyne
concentrated HCl at room temperature, an 2) Predominantly 1-butene
alcohol immediately gives turbidity. The 3) Predominantly 2-butene
alcohol can be 4) Equimolar mixture of 1 and 2-butene
1) C6H5OH 2) CH3CHOHCH3 14. Which one of the following does not give
3) (CH3)3COH 4) Any of these iodoform test?
O
9. Strength of acidity is in the order
OH OH OH OH 1) C CH3
NO2
2) CH3OH
3) CH3CH2OH
4) CH 3 − CH − CH 3
|
CH3 NO2 NO2 OH
(I) (II) (III) (IV) 15. The molecular formula of diphenyl methane is
1) II > I > III > IV 2) III > IV > I > II
3) I > IV > III > II 4) IV > III > I > II
Jones
10. CH3CH=CH−CH(OH)CH3
reagent
→? How many structural isomers are possible
Product is when one of the hydrogen is replaced by a
chlorine atom?
1) CH3CH2CH2COCH3
1) 6 2) 4
2) CH3CH=CHCOCH3
3) 8 4) 7
3) CH3CH2CH2CH(OH)CH3
16. CH3Br + Nu– → CH3 – Nu + Br–
4) CH3CH2COOH
The decreasing order of the rate of the above
11. Identify X and Y in the following sequence reaction with nucleophiles (Nu–) A to D is
X
C2H5Br Y
→ product → C3H7NH2 [Nu– = (A)PhO–, (B)AcO–, (C)HO–, (D)CH3O–]
1) X = Alcoholic KCN, Y = LiAlH4 1) D > C > A > B 2) D > C > B > A
2) X = Alcoholic KCN, Y = H3O+ 3) A > B > C > D 4) B > D > C > A
3) X = CH3Cl, Y = AlCl3/HCl 17. How many isomers (including stereo) are
4) X = CH3NH2, Y = HNO2 obtained by dichlorination of propane?
12. Which is best method of preparing pure alkyl 1) 2 2) 3
3) 4 4) 5
chloride?
18. Which statement is correct?
1) ROH + SOCl2 →
1) C2H5Br reacts with alcoholic KOH to form
2) ROH + PCl5 →
C2H5OH
3) ROH + PCl3 → 2) C2H5Br when treated with metallic sodium
Anhy.ZnCl
2→
4) ROH + HCl gives ethane
13. Dehydrohalogenation of 2-bromobutane 3) C2H5Br when treated with sodium ethoxide
results in the formation of forms diethyl ether
4) C2H5Br with AgCN forms ethyl cyanide
3 Test ID : 831[A]
o
19. Which one is most reactive towards SN1 26. At 40 C, the vapour pressure (in torr) of
reactions? methyl alcohol (A) and ethyl alcohol (B)
1) C6H5CH(C6H5)Br solution is represented by
2) C6H5CH(CH3)Br P = 120 XA + 138 ; where XA is mole fraction
3) C6H5C(CH3)(C6H5)Br of methyl alcohol. The value of
4) C6H5CH2Br PBo po
20. Which one is a colligative property? limit X A → 0, and limit X B → 0, A are:
xB XA
1) Boiling point 2) Vapour pressure 1) 138, 258 2) 258, 138
3) Osmotic pressure 4) Freezing point 3) 120, 138 4) 138, 125
21. 6 g urea is dissolved in 90 g water. The 27. The amount of ice that will separate out on
relative lowering of vapour pressure is equal cooling a solution containing 50 g of ethylene
to glycol in 200 g water to –9.3oC is :
1) 0.0196 2) 0.06 (K’f = 1.86 K molality–1)
3) 1.10 4) 0.0202
1) 38.71 g 2) 38.71 mg
22. Which one of the following is not correct for 3) 42 g 4) 42 mg
the formation of an ideal solution?
28. Percentage of free space in a body-centred
1) It must obey Raoult’s law cubic unit cell is
2) ∆H = 0
1) 32% 2) 34%
3) ∆V = 0
3) 28% 4) 30%
4) ∆G = 0
29. In a compound, atoms of element form ccp
23. In a 0.2 molal aqueous solution of a weak acid
lattice and those of element X occupy 2/3rd of
HX, the degree of ionisation is 0.3. Taking kf
tetrahedral voids. The formula of the
for water as 1.86, the freezing point of the
compound will be
solution will be nearest to
1) X4Y3 2) X2Y3
1) –0.483oC 2) –0.360oC
3) X2Y 4) X3Y4
3) –0.260oC 4) +0.480oC
30. The cubic unit cell of Al (molar mass 27 g
24. A solution containing 10 g per dm3 of urea
mol–1) has an edge length of 405 pm. Its
(mol. mass = 60) is isotonic with a 5% (wt.by
density is 2.7 g cm–3. The cubic unit cell is
vol.) solution of a non-volatile solute. The
molecular mass (in g mol–1) of non-volatile 1) Face centred 2) Body centred
solute is : 3) Primitive 4) Edge centred
1) 350 2) 200 31. How many number of atoms are there in a
3) 250 4) 300 cube based unit cell having one atom on each
25. The values of observed and calculated corner and two atoms on each body diagonal
molecular weights of calcium nitrate are of cube
respectively 65.6 and 164. The degree of 1) 8 2) 6
dissociation of calcium nitrate will be : 3) 4 4) 9
1) 25% 2) 50% 32. Which arrangement of electrons leads to anti-
3) 75% 4) 60% ferromagnetism?
4 Test ID : 831[A]
1) ↑ ↑ ↑ ↑ 2) ↑ ↓ ↑ ↓ 39. Statement I : Fluorine forms one oxoacid.
3) Both (1) and (2) 4) ↑ ↑ ↑ ↓ ↑ ↑ ↓ Statement II : Fluorine has the smallest size
33. The unit cell with dimensions α = β = γ = 90o, amongst all halogens and is highly
electronegative.
a = b ≠ c is
1) Both statements I and II are correct
1) Cubic 2) Triclinic 2) Both statements I and II are wrong
3) Hexagonal 4) Tetragonal 3) Statement I is correct, II is wrong
34. If ‘a’ stands for the edge length of the cubic 4) Statement I is wrong, II is correct
systems : simple cubic, body-centred cubic 40. Bleaching powder contains a salt of an
and face-centered, then the ratio of radii of the oxoacid as one of its components. The
spheres in these systems will be respectively, anhydride of that oxoacid is
1 1 1) Cl2O 2) Cl2O7
1) a: 3a: a 3) ClO2 4) Cl2O6
2 2
41. Which one has the highest boiling point?
1 3 2
2) a : a: a 1) Kr 2) Xe
2 2 2
3) He 4) Ne
1
3) a : 3 a : 2 a 42. The shape of XeO2F2 molecule is
2
1) trigonal bipyramidal
1 3 1 2) square planar
4) a: a: a
2 4 2 2 3) tetrahedral
35. The number of non-ionisable hydrogen atoms 4) see-saw
present in the final product obtained from the 43. Match the catalysts (Column-I) with products
hydrolysis of PCl5 is (Column-II)
1) 0 2) 2 Column – I Column – II
3) 1 4) 3 (Catalyst) (Product)
36. Blue solid which is obtained on reacting A) V2O5 i) Polyethylene
equimolar amount of two gaseous oxides of B) TiCl4/Al(Me)3 ii) Ethanal
nitrogen is C) PdCl2 iii) H2SO4
1) NO2 2) N2O3 D) Iron oxide iv) NH3
3) N2O4 4) N2O5 1) A-iii, B-iv, C-i, D-ii
37. The incorrect statement(s) about O3 is/are 2) A-ii, B-iii, C-i, D-iv
1) O−O bond lengths are equal 3) A-iii, B-i, C-ii, D-iv
2) Thermal decomposition of O3 is 4) A-iv, B-iii, C-ii, D-i
endothermic 44. Find the incorrect statement.
3) O3 is diamagnetic in nature 1) Magnetic moment of Mn2+ ion is 35
4) O3 has a bent structure 2) Ti4+ has purple colour.
38. A gas that cannot be collected over water is 3) 1 Bohr magneton (BM) = 9.27 × 10−24
1) N2 2) O2 J/Tesla
4) Zn, Cd do not show variable oxidation
3) SO2 4) PH3
states, Hg can show +1, +2 states
5 Test ID : 831[A]
OH
3) 6 4) 16
1) 2) 84. The percentage of phenotypic recombinant
progeny formed during F2 generation in
Mendels dihybrid cross is
3) 4)
1) 37.50 2) 62.50
79. The example of homogeneous catalysis is 3) 56.25 4) 31.25
9 Test ID : 831[A]
85. Mendel’s law of segregation is occurs in 1) Both (A) and (R) are correct but (R) is not
which phase of meiosis the correct explanation of (A).
1) Anaphase 2) Anaphase I 2) Both (A) and (R) are correct and (R) is the
3) Metaphase I 4) Zygotene correct explanation of (A)
86. Identify the ploidy of given cells / structures
3) (A) is not correct but (R) is correct
respectively in angiosperms
4) (A) is correct but (R) is not correct
Polar nuclei, Endosperm, Secondary nucleus
92. The spermatogenous cell of male gametophyte
of embryosac, synergid, generative cell of
male gametophyte in angiosperms is
1) Both the statements are correct produced by one meiosis in a pollen mother
2) Both the statements are incorrect cell?
3) Statement – I is correct, statement – II is 1) 1 2) 4
incorrect 3) 8 4) 2
4) Statement – I is incorrect, statement – II is 158. A flower on a dioecious plant would be
correct 1) Bisexual 2) Asexual
152. The approximate length of DNA in a typical 3) Complete 4) Unisexual
mammalian cell is 159. Endosperm is completely consumed by
1) 0.34 x 109 metre 2) 2.2 metre developing embryo in the seed of
9
3) 3.4 x 10 metre 4) 2.2 nm 1) coconut 2) pea
153. The packaging of DNA helix occurs in a
3) castor 4) maize
typical eukaryotic cell with the help of
160. Assertion (A) : Synergids are present at the
1) Histone proteins
micropylar end of embryosac.
2) Dietary proteins Reason (R) : Synergids are vegetative cells of
3) Non-histone chromosomal proteins embryosac and involved in triple fusion.
4) Both (1) and (3) 1) Both (A) and (R) are correct but (R) is not
154. Statement – I : RNA is chemically active and the correct explanation of (A).
better suitable for storage of genetic
2) Both (A) and (R) are correct and (R) is the
information.
correct explanation of (A)
Statement – II : RNA can directly code for
the synthesis of proteins thus DNA is 3) (A) is not correct but (R) is correct
dependent on RNA for the synthesis of 4) (A) is correct but (R) is not correct
proteins
15 Test ID : 831[A]
161. Termination of transcription in prokaryotes is 166. Monocarpic, perennial monocot is
done by 1) Paddy 2) Bamboo
1) ρ factor 2) σ factor 3) Mango 4) Raphanus
3) RNA Repressor 4) RNA Inducer 167. Assertion (A) : Dioecious animals contains
162. In eukaryotes, mostly a single mRNA is
male and female sex organs in the same body.
synthesised from
Reason (R) : Cross fertilization occurs in
1) A single structural gene
many hermaphrodite animals
2) Many structural genes
1) Both (A) and (R) are correct but (R) is not
3) A cluster of structural genes
the correct explanation of (A).
4) Two structural genes
163. Semi-conservative replication of DNA was
2) Both (A) and (R) are correct and (R) is the
first studied in correct explanation of (A)
1) Diplococus pneumonia 3) (A) is not correct but (R) is correct
2) Drosophila melanogaster 4) (A) is correct but (R) is not correct
3) Escherichia coli 168. The ratio of egg cell and synergids in a typical
4) Neurospora crassa embryosac is
164. Match the following 1) 1 : 2 2) 2 : 1
List – I List – II 3) 1 : 1 4) 2 : 3
A) CCU I) Histidine 169. A few statements with regard to sexual
B) CAU II) Aspartic acid reproduction are given below
C) GAU III) Proline I) Sexual reproduction does not always
D) GUC IV) Valine require two individuals
A B C D II) Sexual reproduction generally involves
1) III I II IV gamete fusion
2) IV II III I III) Meiosis never occurs during sexual
3) I III II IV reproduction in angiosperms
4) II IV III I IV) External fertilization is a rule during
165. Identify the B, S and N in the below given
sexual reproduction.
diagram
Choose the correct statements from the given
list
1) II and III 2) I and IV