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YAKEEN 2.0 2023 (Vidyapeeth Stars)

Amines and Diazonium salts DPP-03

1. The final product C, obtained in this reaction would 4. Predict the product
be NHCH3
NH2 +NaNO2+HCl  Product

Ac 2O Br2 H2O OH
A B + C
CH3COOH H
N — CH3
(1)
CH3
NH2 COCH3 CH3
COCH3 Br N—N = O
(2)
(1) (2)
CH3
CH3 CH3 N—NO 2
NH2 NHCOCH3 (3)
Br Br
(3) (4) NHCH3 NHCH3

NO
CH3 CH3 (4) +

2. Which of the following amine does not react with

Hinsberg reagent NO
(1) Neopentyl amine
(2) Isopropyl amine 5. In the chemical reactions
NH2
(3) Triethyl amine
(4) Ethyl methyl amine NaNO 2 CuCN
A B
HCl, 278 K D
3. Aniline in a set of reactions yielded a end product D
The compounds A and B respectively are
(1) Fluorobenzene and phenol
(2) Benzene diazonium chloride and benzonitrile
(3) Nitrobenzene and chlorobenzene
The structure of the product D would be (4) Phenol and bromobenzene
(1) C6H5CH2OH 6. Which of the following forms a stable diazonium
(2) C6H5CH2NH2 salt at 273 to 278 K.
(3) C6H5NHOH (1) Ethylamine
(4) C6H5NHCH2CH3 (2) Aniline
(3) Dimethylamine
(4) Benzylamine
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7. Benzene diazonium chloride on reaction with water 11. In the given reaction product [C] is
gives NH2
(1) Benzylamine (2) Benzaldehyde
(3) Aniline (4) Phenol

NaNO 2 /HCl
(A) 
H 3 PO 4
H2O
 (B)
8. The end product (z) of the following reaction is
+ –
N2 Cl

+

CuCN
 (x) 
H /H 2 O
 (y) 
NaOH/CaO
D
 (z) OH

(1) An arene
(2) An amine (1)
(3) A cyanide
(4) A Carboxylic acid
(2) NH OH
9. When benzene diazonium salt react with
Hypophosphorous acid, then product formed will be
(1) Aniline (2) Benzene (3) N=N OH
(3) Nitrobenzene (4) Benzoic acid

10. In the following reaction (A) is (4) HO N=N NH2

NO2 NO2
[A]
Br Br
+ N2 Cl–
(1) Cu2Cl2 (2) H+/H2O
(3) H3PO2/H2O (4) HgSO4/H2SO4
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.

Answer Key
1. (3)
2. (3)
3. (1)
4. (2)
5. (2)
6. (2)
7. (4)
8. (1)
9. (2)
10. (3)
11. (3)

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