Final JEE - Main Exam Januar y, 2020/07-01-2020/Morning Session

FINAL JEE–MAIN EXAMINATION – JANUARY, 2020

(Held On Tuesday 07th JANUARY, 2020) TIME : 9 : 30 AM to 12 : 30 PM
CHEMISTRY TEST PAPER WITH ANSWER & SOLUTION
1. A solution of m-chloroaniline, m-chlorophenol 2. 1-methyl ethylene oxide when treated with an
and m-chlorobenzoic acid in ethyl acetate was excess of HBr produces :
Br Br
extracted initially with a saturated solution of (1) (2)
CH3 Br
NaHCO 3 to give fraction A. The left over
Br
organic phase was extracted with dilute NaOH CH3
Br
(3) Br (4)
solution to give fraction B. The final organic CH3
layer was labelled as fraction C. Fractions A, NTA Ans. (4)
B and C, contain respectively : ALLEN Ans. (4)
(1) m-chlorobenzoic acid, m-chloroaniline and Sol. CH3 – CH – CH 2 ¾¾ ¾
HBr
® CH3 – CH – CH2
m-chlorophenol O O +
(2) m-chloroaniline, m-chlorobenzoic acid and H
m-chlorophenol Br
(3) m-chlorobenzoic acid, m-chlorophenol and
m-chloroaniline
(4) m-chlorophenol, m-chlorobenzoic acid and
m-chloroaniline
EN 3.
¾¾¾
(1) Br–

(2) HBr
® CH3 – CH – CH2
Br
Amongst the following statements, that which
was not proposed by Dalton was :
NTA Ans. (3) (1) all the atoms of a given element have
ALLEN Ans. (3) identical properties including identical mass.
Sol. Atoms of different elements differ in mass.
NH2 OH COOH (2) chemical reactions involve reorganisation
LL
of atoms. These are neither created nor
destroyed in a chemical reaction.
Cl Cl Cl (3) when gases combine or reproduced in a
chemical reaction they do so in a simple
O = C – OH O = C – O – Na+ ratio by volume provided all gases are at the
NaHCO3
+ H2CO3 ® H2O + CO2 same T & P.
A

(4) matter consists of indivisible atoms.

Cl Cl
NTA Ans. (3)
Fraction-A ALLEN Ans. (3)
Sol. Option(3) is according to Gaylussac's law of
OH O –Na+
volume combination.
NaOH 4. What is the product of following reaction ?
Cl Cl (i) NaBH4
Hex-3-ynal (ii) PBr ?
3
(iii) Mg/ether
Fraction-B +
(iv) CO2/H3O
NH2 (1) COOH

(2) COOH
Cl (3) COOH
Fraction-C
(4) COOH
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Final JEE - Main Exam Januar y, 2020/07-01-2020/Morning Session

NTA Ans. (3) NTA Ans. (3)

ALLEN Ans. (3) ALLEN Ans. (3)
Sol. Sol. Atomic radius of Ag and Au is nearly same due
to lanthanide contraction.
O
NaBH4 7. The dipole moments of CCl4, CHCl3 and CH4
CH3 – CH2 – C º C – CH2 – C are in the order :
H
(1) CH4 = CCl4 < CHCl3
CH3 – CH2 – C º C – CH 2 – CH2 – OH (2) CH4 < CCl4 < CHCl3
PBr3 (3) CCl4 < CH4 < CHCl3
(4) CHCl3 < CH4 = CCl4
Mg/ether NTA Ans. (1)
CH3 – CH 2 – C º C – CH 2 – CH 2 – Br
ALLEN Ans. (1)

(1) CO2 H Cl
CH3 – CH2 – C º C – CH2 – CH2 – MgBr
(2) H 3O +
C C
O Sol. H µnet = 0 Cl µnet = 0
H Cl
CH3 – CH2 – C º C – CH2 – CH2 – C – OH H Cl

5. The increasing order of pKb for the following

compounds will be :
NH2 – CH = NH,
EN H
C
Cl µnet ¹ 0
(A) Cl
Cl
N 8. Given that the standard potentials (E°) of
Cu2+/Cu and Cu+/Cu are 0.34 V and 0.522 V
LL
N NH,
respectively, the E° of Cu2+/Cu+ is :
(1) +0.158 V (2) 0.182 V
(B) (3) –0.182 V (4) –0.158 V
CH3NHCH3 NTA Ans. (1)
(C) ALLEN Ans. (1)
(1) (A) < (B) < (C) (2) (C) < (A) < (B) Sol. E0 DG0
A

(3) (B) < (A) < (C) (4) (B) < (C) < (A)
Cu 2 Å + 2e Å ¾¾
® Cu 0.34 = – 2F (0.34)
NTA Ans. (3)
ALLEN Ans. (3) Cu Å + e Å ¾¾
® Cu 0.522 = –F (0.522)
Sol. Base strength order
Cu 2Å + eÅ ¾¾
® Cu +
N
DG0 = –2F (0.34) – (– F(0.522) = –F (0.68 –
> NH 2 – CH = NH > CH 3 – NH – CH 3
N NH (+R) 0.522) = – F (0.158)
(+R) (+R)

(B) (A) (C) - F ( 0.158 )

E0 = = 0.158V
–F
increasing order of pkb order (B < A < C)
6. The atomic radius of Ag is closest to :
(1) Cu (2) Hg (3) Au (4) Ni

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 Final JEE - Main Exam Januar y, 2020/07-01-2020/Morning Session
9. In comparison to the zeolite process for the Which of these reaction(s) will not produce
removal of permanent hardness, the synthetic Saytzeff product ?
resins method is : (1) (c) only (2) (a), (c) and (d)
(1) less efficient as it exchanges only anions (3) (d) only (4) (b) and (d)
(2) more efficient as it can exchange only NTA Ans. (1)
cations ALLEN Ans. (1)
(3) less efficient as the resins cannot be Sol.
regenerated
(4) more efficient as it can exchange both
cations as well as anions CH3 CH3
H+
NTA Ans. (4) (a) CH 3 – C – CH – CH3 CH3 – C – CH – CH3
–H2O +
ALLEN Ans. (4) CH3 OH CH3
2+
Sol. (a) Zeolite method removes only cations (Ca
2+
and Mg ion) present in hard water
2+ +
CH3
2NaZ + M (aq) ® MZ2(s) + 2Na (aq) CH 3 – C – CH – CH3
–H+ +
(M®Mg, Ca) CH3
(b) Synthetic resin method removes cations (Saytzeff
(Ca
2+

HCO3 , SO4
and Mg
–

(Cation exchange
2–
2+

etc.)
ion) and anions (like Cl ,

2+
(i) 2RNa(s) + M (aq) ® R2M(s) + 2Na (aq)
(M®Mg, Ca)
EN +
– major)

(b) CH3 – CH – CH – CH3 ¾¾¾

CH3 Br
® CH3 – C = CH – CH 3
alc.KOH
D
CH3
resin) (Saytzeff
+ – – + – major)
(ii) RNH 3 OH (s) + X (aq) ® RNH3 X (s) +
–
LL
OH (aq) O– K + / D
a b
– – – 2–
(Anion exchange (X =Cl ,HCO3 ,SO4 (c) CH3 – CH – CH – CH3
resin) etc) CH3 Br (Hoffmann
10. The relative strength of interionic/ major)
intermolecular forces in decreasing order is :
(1) ion-dipole > ion-ion > dipole-dipole OH O CH3 O
(2) dipole-dipole > ion-dipole > ion-ion (d) CH3 – C – CH2 – C – H ¾D
®
A

CH – C – H
(3) ion-dipole > dipole-dipole > ion-ion CH3 CH3 (Saytzeff
(4) ion-ion > ion-dipole > dipole-dipole major)
NTA Ans. (4)
ALLEN Ans. (4) (CH 3 ) 3 O – K + is incorrect representation of
potassium tert-butoxide [(CH3)3CO–K+].
Sol. Order is
So it is possible that it can be given as Bonus
ion – ion > ion – dipole > dipole – dipole
12. The purest form of commercial iron is
11. Consider the following reactions :
conc.H 2SO 4
(1) scrap iron and pig iron
(a) (CH3 )3 CCH(OH)CH 3 ¾¾¾¾¾ ®
(2) wrought iron
alc.KOH
(b) (CH3 ) 2 CHCH(Br)CH 3 ¾¾¾¾
® (3) cast iron
given by NTA (CH3 )3 OQKÅ
(c) (CH3 )2 CHCH(Br)CH3 ¾¾¾¾¾¾¾¾¾
It should be (CH ) CO K
®
3 3
Q Å (4) pig iron
D NTA Ans. (2)
(d) (CH 3)2C–CH 2–CHO
ALLEN Ans. (2)
OH

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Final JEE - Main Exam Januar y, 2020/07-01-2020/Morning Session

Sol. Wrought iron is purest from of commercial 15. The number of orbitals associated with quantum
iron. 1
13. At 35°C, the vapour pressure of CS2 is 512 mm numbers n = 5, ms = + is :
2
Hg and that of acetone is 344 mm Hg. A
(1) 11 (2) 25 (3) 15 (4) 50
solution of CS 2 in acetone has a total vapour
pressure of 600 mm Hg. The false statement NTA Ans. (2)
amongst the following is : ALLEN Ans. (2)
2 2
(1) heat must be absorbed in order to produce Sol. No. of orbitals = n = 5 = 25
the solution at 35°C For n = 5, no. of orbi tal s = n2 = 25
(2) Raoult's law is not obeyed by this system Total number of orbitals is equal to no. of
(3) a mixture of 100 mL CS 2 and 100 mL 1
acetone has a volume < 200 mL electrons having ms =
2
(4) CS 2 and acetone are less attracted to each
16. Match the following :
other than to themselves
(i) Riboflavin (a) Beriberi
NTA Ans. (3)
(ii) Thiamine (b) Scurvy
ALLEN Ans. (3)
EN
Sol. The vapour pressure of mixture ( = 600 mm Hg)
is greater than the individual vapour pressure
of its constituents (Vapour pressure of CS 2 =
(iii)Pyridoxine
(iv)Ascorbic acid
(c) Cheilosis
(d) Convulsions
(1) (i)-(c), (ii)-(a), (iii)-(d), (iv)-(b)
(2) (i)-(c), (ii)-(d), (iii)-(a), (iv)-(b)
512 mm Hg, acetone = 344 mm Hg). Hence,
(3) (i)-(d), (ii)-(b), (iii)-(a), (iv)-(c)
the solution formed shows positive deviation
(4) (i)-(a), (ii)-(d), (iii)-(c), (iv)-(b)
from Raoult's law.
NTA Ans. (1)
LL
Þ (1) DSol H > 0 , (2) Raoult's law is not ALLEN Ans. (1)

obeyed Sol. (i) Riboflavin ¾¾

® (c) Cheilosis
(3) Dsol. Volume > 0 (ii) Thiamine ¾¾
® (a) Beriberi
(4) CS2 and Acetone are less attracted to each
ether than to themselves. (iii) Pyridoxine ¾¾
® (d) Convulsions
A

14. The electron gain enthalpy (in kJ/mol) of

(iv) Ascorbic acid ¾¾
® (b) Scurvy
fluorine, chlorine, bromine and iodine,
respectively are : 17. The theory that can completely/properly
(1) – 333, – 349, – 325 and – 296 explain the nature of bonding in [Ni(CO) 4 ]
(2) –296, – 325, – 333 and – 349 is :
(3) – 333, – 325, – 349 and – 296 (1) Werner's theory
(4) –349, – 333, – 325 and – 296 (2) Crystal field theory
NTA Ans. (1) (3) Valence bond theory
ALLEN Ans. (1) (4) Molecular orbital theory
Sol. Order of electron gain enthalpy (magnitude) is NTA Ans. (4)
ALLEN Ans. (4)
Cl > F > Br > I

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 Final JEE - Main Exam Januar y, 2020/07-01-2020/Morning Session

Sol. In complex [Ni(CO)4 ] decrease in Ni–C bond 20. Oxidation number of potassium in K2O, K2O2
length and increase in C–O bond length as well and KO2 , respectively, is :
as it's magnetic property is explained by MOT. (1) +1, +4 and +2
18. Consider the following reaction : (2) +1, +2 and +4
(3) +1, +1 and +1
CH3 Å ! Å ! OH–
N +Na SO3 N2Cl 'X'
CH3 1
(4) +2 , +1 and +
The product 'X' is used :
2
(1) in acid base titration as an indicator NTA Ans. (3)
(2) in protein estimation as an alternative to ALLEN Ans. (3)
ninhydrin
Sol. Potasisum has an oxidation of +1 (only) in
(3) in laboratory test for phenols
(4) as food grade colourant combined state.
NTA Ans. (1) 21. For the reaction ;
ALLEN Ans. (1) A(l) ® 2B(g)
Sol. DU = 2.1 kcal , DS = 20 cal K–1 at 300 K

H3 C

H3C
N + Cl
–
NºN
EN –
SO3 Na+
Hence DG in kcal is_________ .
NTA Ans. (–2.70)
ALLEN Ans. (–2.70)

Sol. A ( l ) ¾¾
® 2B ( g )
Me
–
N N=N SO3 Na+
DU = 2.1 Kcal , DS= 20 cal K–1 at 300 K
LL
Me
(Methyl orange) DH = DU + DngRT

It is an acid base indicator DG = DH - TDS

19. The IUPAC name of the complex
[Pt(NH3)2Cl(NH2CH3)]Cl is : DG = DU + Dn g RT - TDS
(1) Diammine (methanamine) chlorido
A

platinum (II) chloride 2 ´ 2 ´ 300 300 ´ 20

= 2.1 + -
(2) Bisammine (methanamine) chlorido 1000 1000
platinum (II) chloride
(R = 2 cal K–1 mol–1)
(3) Diamminechlorido (aminomethane)
= 2.1 + 1.2 – 6 = – 2.70 Kcal/mol
platinum(II) chloride
(4) Diamminechlorido (methanamine) platinum
(II) chloride
NTA Ans. (4)
ALLEN Ans. (4)

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Final JEE - Main Exam Januar y, 2020/07-01-2020/Morning Session
22. During the nuclear explosion, one of the
products is 90Sr with half life of 6.93 years. if
1 mg of 90Sr was absorbed in the bones of a
newly born baby in place of Ca, how much
time, in years , is required to reduce it by 90%
if it is not lost metabolically______ .
NTA Ans. (23 to 23.03)
ALLEN Ans. (23.03)
Sol. All nuclear decays follow first order kinetics
1 [A0 ]
t = ln
k [A]
( t1/2 ) ´ 2.303
= log10 10 = 10 × 2.303 × 1
0.693
Sol. 4 gm of NaOH in 100 L sol. Þ 10–3 M sol.
9.8 gm of H2SO4 in 100 L sol. Þ 10–3 M sol.
Mixture : 40L of 10–3 M NaOH and 10 L of
10–3 M H2SO4 sol.
Final Conc. of OH–
10 –3 ( 40 ´ 1 – 10 ´ 1 ´ 2 )
= = 6 ´ 10 -4 M
40 + 10
pOH = – log (6 ×10–4)
= 4 – log 6 = 4 – 0.60 = 3.40
pH = 14 – 3.40 = 10.60
25. Chlorine reacts with hot and concentrated
NaOH and produces compounds (X) and (Y).
Compound (X) gives white precipitate with
silver nitrate solution. The average bond order
between Cl and O atoms in (Y) is ______.

23.
= 23.03 years
The number of chiral carbons
chloramphenicol is _______ .

NTA Ans. (2)

EN in NTA Ans. (1.66 to 1.67)
ALLEN Ans. (1.66 or 1.67)
Sol. 3Cl 2 + 6NaOH ® 5NaCl + NaClO3 + 3H2 O
ALLEN Ans. (2.00) (X) (X)
NaCl + AgNO3 ® AgCl ¯ + NaNO3
LL
OH OH (X)
*
* Cl
O ClO3– Cl
N NH CH
Sol. – O
O C Cl O O
O
2 5
A

Bond order of Cl–O Bond = 1 + =

Chloramphenicol 3 3
24. Two solutions A and B, each of 100 L was
= 1.66 or 1.67
made by dissolving 4g of NaOH and 9.8 g of
H2SO 4 in water, respectively. The pH of the
resultant solution obtained from mixing 40 L
of solution A and 10 L of solution B
is_______.
NTA Ans. (10.60 to 10.60)

ALLEN Ans. (10.60)