2. Inareaction of aniline, a colored product Cwas obtained.

CH,

NH, CH,
NaNO,
HCI
Cold

The structure of C would be

(1) CH,
N

CHs
(2)

CH,
(3) CH, CH,
-N=N

(4) CH,
N
 1
ORGANIcCOMPOUNDS CONTAINING NITROGEN 771

16. Method by which aniline cannot be prepared is NO

(2 CN

(1) reduction of nitrobenzene with H,/Pd in ethanol.

(2) potassium salt of phthalimide treated with
chlorobenzene followed by hydrolysis with aqueous (3 (4)
NaOH solution. CONH, NH,
(3) hydrolysis of phenyl isocyanide with acidic solution.
(4) degradation of benzamide with bromine in alkaline
solution.
(NEET II 2016)
(RE AIPMT 2015)
19. The correct increasing order of basic strength for the fol
17. The correct statement regarding the basicity of lowing compound is
arylamines is NH
NH, NH,
(1) arylamines are generally less basic than alkylamines
because the nitrogen lone-pair electrons are delo
calized by interaction with thc aromatic ring zclcc
tron system.
(2) arylamines are generally more basic than alky NO H,
lamines because the nitrogen lone-pair electrons (II) (II)
are not delocalized by interaction with the aromatic
ring zelectron system. (1) II <I<lII (2) II <Il <I
(3) arylamines are generally more basic than alky (3) II <I< II (4) II< II <I

lamines because of aryl group.

(NEET 2017)
(4) arylamines are generally more basic than alky
lamines, because the nitrogen atom in arylamines 20. Which of the following reactions is appropriate for
is sp-hybridized. converting acetamide to methanamine?

A given
WW. (NEET I2016) (1) Hofmann hypobromamide reaction
(2) Stephens reaction
18.
nitrogen-containing aromatic an
reacts with Sn/HCI, followed by HNO, to givecompoud
A (3) Gabriels phthalimide synthesis
(4) Carbylamine reaction
compound B. B, on treatment with phenol, forms a (NEET 2017)
beautiful colored compound C with the molecular for
mula CH,N,0. The structure of compound Ais

Answer Key
Level I

1. (2) 2. (1) 3. (4) 4, (2) 5. (3) 6, (2) 7. (1)

8. (3) 9. (4) 10. (4) I1. (1) 12. (2) 13. (2) 14. (1)
15. (3) 16. (3) 17. (1) 18. (1) 19. (3) 20. (4) 21. (3)
22. (3) 23. (3) 24. (4) 25. (1) 26. (2) 27. (2) 28. (1)
29. (2) 30. (3) 31. (3) 32. (1) 33. (4) 34 (1) 35. (4)
36. (2) 37. (2)

Level I|

1. (1) 2. (2) 3. (3) 4, (1) 5. (1) 6. (2) 7. (1)

8. (4) 9. (4) 10. (4) 11. (3) 12. (4) 13. (3) 14. (3)
15. (4) 16. (2) 17. (2) 18. (4) 19. (4) 20. (4) 21. (4)
22. (4) 23. (4) 24. (4)

10

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