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  • C.C-9 Q.P 2023

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    This document appears to be a chemistry exam paper containing 6 sections with a total of 60 marks. It includes multiple choice and long answer questions testing knowledge of organic chemistry reactions, mechanisms, and structures. Some of the key topics covered are the Gabriel phthalimide synthesis, carbylamine reaction, anthracene substitution, furfural reactions, isoprene rule, terpenoids, alkaloids, nitrobenzene reduction, effects of substituents on amine basicity, structures of napthalene and pyridine, and detecting functional groups in alkaloids.

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    This document appears to be a chemistry exam paper containing 6 sections with a total of 60 marks. It includes multiple choice and long answer questions testing knowledge of organic chemistry reactions, mechanisms, and structures. Some of the key topics covered are the Gabriel phthalimide synthesis, carbylamine reaction, anthracene substitution, furfural reactions, isoprene rule, terpenoids, alkaloids, nitrobenzene reduction, effects of substituents on amine basicity, structures of napthalene and pyridine, and detecting functional groups in alkaloids.

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    5 views4 pages

    C.C-9 Q.P 2023

    Uploaded by

    Poyu Rt
    This document appears to be a chemistry exam paper containing 6 sections with a total of 60 marks. It includes multiple choice and long answer questions testing knowledge of organic chemistry reactions, mechanisms, and structures. Some of the key topics covered are the Gabriel phthalimide synthesis, carbylamine reaction, anthracene substitution, furfural reactions, isoprene rule, terpenoids, alkaloids, nitrobenzene reduction, effects of substituents on amine basicity, structures of napthalene and pyridine, and detecting functional groups in alkaloids.

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    of 4

    Total Pages:6

    IV-CC-Chem-iX

    2023

    CHEMISTRY

    Paper-C-DX
    Full Marks : 60

    Time:3 hours

    Answer all questions.


    The figures in the right-hand margin
    indicate marks.

    GROUP-A
    Answer all questions: 1x 8

    1. (a) Gabriel phthalimide synthesis is used


    forthe preparation of
    (b) Which amine will respond carbyla
    mine reaction ?

    (c) An aqueous solution benzene diazo


    nium chloride on heating gives
    (Turn Over )
    (2 ) (3 )
    (d) Furan reacts with meta-bromno
    Convert Nitrobenzene to
    sence of alumina ammonia
    in pre
    at 400 °C gives chlorobenzenethrough benzene diazo
    internediate.
    nium chloride as an
    (e) Anthracene undergoes electrophillic when.a-Terpineol is
    (e) What happen
    substitution reaction preferably at
    position.
    treated with cone HI,SO,?
    anthracene
    ) How can you synthesis
    acts as a reservoir for protein from Benzene?
    synthesis. furoic
    furfural to
    (g) How can you convert
    (g) Pyridine is basic than pyrrole. acid ?

    n) Write the structure of Nicotine. (h) What is diazonium coupling reaction?


    Give an example.
    GROUP B monocyclic
    Answer any eight: 1.5 x 8 i) What do you mean by
    terpenoids ?
    2. (a) Convert Benzene toAniline. major
    (i) What are alkaloids ? Write their
    Sources.
    (b) Explain why trimethyl amine weaker
    base than methyl amine ? GROUP-C
    Answer anyeight: 2x 8
    (c) What happens when Aniline reacts
    with Bromine in aqueous medium ?
    Give equation.
    (Turn Over )
    IV-CC-Chem-IX IV-CC-Chem-IX
    (Continued )
    (4 ) (5 )

    3. (a) Explain Nucleophillic substitution in (i) What is Isoprene rule ? Explain with
    2,4-dinitrochlorobenzene is easier suitable example.
    than chlorobenzene.
    ) Explain the cause of stability of Bio
    (6) Write a note on Hoffmann bromamide cyclic mono terpenoids.
    reaction.
    GROUP-D 6x4
    (c) What do you known about cope elimi
    nation reaction ?
    4. Discuss the reduction of Nitrobenzene in
    (d) How do you convert benzene diazo (a) Acidic, (b) Alkaline, (c) Neutral
    nium chloride to lodobenzene? medium. 2+2+2

    Or
    (e) What happens when furfural is sub
    jected to Cannizarro's reaction ? Write Discuss the effect of substituent and
    equation. solvent on basicity of amines.
    () How can youestimate methoxy group 5. Elucidate the structure of Napthalene. 6
    inan alkaloid ?
    Or
    (g) What is Fischer-Indole synthesis ?
    Write equation. Discuss the mechanism of diazotisation
    reaction. How do you synthesis phenol
    (h) What happens when Pyridine under from benzene diazonium chloride.
    J goes reduction with HI ?

    IV-CC-Chem-1X ( Continued) IV-CC-Chem-lX (Turn Over )


    (6 )

    6. Elucidate the structure of Pyridine and


    onfirm it by synthesis. 6

    Or

    Describe the chemical properties of


    furan.

    7. Elucidate the structure of Hygrine.


    Or

    How will you detect the followings in


    an alkaloid ? 3+3

    () Presence of unsaturation

    (ii) Presence of phenolic group

    IV-CC-Chem-IX NA-1,200

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