Naveen's Academy

Hydro Carbons
11th Standard CBSE
Chemistry
"All The Best"

1) The peroxide e ect in anti-Markovnikov addition involves 1

( a ) The heterolytic fission of the double bond ( b ) The homolytic fission of the double bond
( c ) a free radical mechanism ( d ) an ionic mechanism
2) Baeyer's reagent is 1

( a ) aqueous KMnO4 ( b ) neutral KMnO4 ( c ) alkaline KMnO4 ( d ) aqueous bromine water

3) Benzene reacts with acetyl chloride in the presence of AlCl3 to give 1

( a ) acetophenone ( b ) toluene ( c ) benzophenone ( d ) ethyl benzene

4) An aqueous solution of compound A gives ethane on electrolysis, the compound A is 1

( a ) Ethyl acetate ( b ) Sodium acetate ( c ) Sodium propionate ( d ) Sodium ethoxide

5) Which of the following is less reactive than benzene towards electrophilic substitution reactions? 1

( a ) Nitrobenzene ( b ) Aniline ( c ) Bromobenzene ( d ) Chlorobenzene

6) What happen when iodoethane is reduced with hydroiodic acid and red phosphorus? 1
Answer :  
7) State Huckel's rule for determining whether a molecule is aromatic or not. 1

Answer :  
8) Which of the following are meta-direction? -No2,-SO3H,-Cl,-OH,-NH2-CHO 1

Answer :  
9) Can ethene show conformations?Why? 1

Answer :  
10) Write chemical equation for combustion reaction of toluene. 1

Answer : C7 H8 (g) + 9O2 (g) Δ 7C O2 + 4H2 O(g)

→

11) What is decarboxylation? Give an example. 2

Answer : The process by which carbon dioxide is removed from sodium acetate (or any sodium salt of acid) with the
help of sodalirne is called decarboxylation. CH COONa+NaOH⟶  CH  + Na  CO
heat

3 4 2 3
C ao

12) What is Lindlar's catalyst? Give its use. 2

Answer : Pd/BaSO4 is known as Lindlar's catalyst. It is used in the conversion of alkynes to alkenes with the help of H2.
13) What happens when benzene is treated with excess of Cl2 in presence of sunlight? Give chemical reaction. 2

Answer :

14) Arrange the following: HCl, HBr, HI, HF in order of decreasing reactivity towards alkenes. 2

Answer : HI > HBr > HCl > HF

15) Which is more acidic: ethene or ethyne and why? 2
Answer : Ethyne is more acidic than ethene because it has 'sp' hybridised 'C' which is more electronegative.
16) 3
Write IUPAC names of the following compounds: (a) CH3CH = C(CH3)2 (b) CH2 = CH-C≡C-CH3 (c)   (d) 

(e) 

C H3 (C H2 ) CH (C H2 )3 C H3 (g) 
|

C H2 −C H (C H3)
2

C H3 − C H = C H − C H2 − C H = C H − C H − C H2 − C H = C H2
|

C2 H5

Answer :

17) An alkene 'A' on ozonolysis gives a mixture of ethanal and pentan-3-one. Write the structure and IUPAC name of 3

'A'.
Answer : Step 1. Write the structure of the products side by side with their oxygen atoms pointing towards each other.
Remove the oxygen atoms and join the two ends by a

Step 2.

double bond, the structure of the alkene 'A' is

18) Why is benzene extra-ordinarily stable though it contains three double bonds? 3

The six electrons of the p-orbitals cover all the six carbon

Answer :

atoms, and are said to be delocalized. As a result of delocalization there formed a stronger π -bond and a more stable
molecule.
19) What is polymerization? Give an example. 3

Answer : The process by which simple molecules join together to form large molecules is known as polymerization.
Simple alkenes polymerize to form long chain addition polymers. For example, ethylene gives polyethylene.
20) Write the structure and IUPAC names of di erent structural isomers of alkenes corresponding to C5H10. 3

Answer : CH2 = CH-CH2-CH2-CH3                   Pent-1-ene CH3-CH=CH-CH2-CH3                   Pent-2-ene

C H3 − C = C H − C H3 2-Methylbut-2-ene C H 3 − C H − C H = C H2 3-Methylbut-1-ene
| |

C H3 C H3

C H2 = C − C H2 − C H3 2-Methylbut-1-ene
|

C H3

21) (a) What type of isomerism is shown by methoxymethane and ethanol? (b) How will you bring out the following 5

conversions. (i) Acetylene to ethane (ii) Benzene to Toluene (iii) Ethanol to ethene?
Answer : (a) Functional isomerism. (b) (i) C H ≡ C H + 2H             Acetylene                               Ethane
Ni

2 ⟶  C H3 − C H3
573 K

(iii) CH CH OH  CH  = CH  + H O
C onc.H2 SO 4

3 2 ⟶   2 2 2
heat