Naveen's Academy

Basic of Chem + Basics of Org Chem

11th Standard
11th StandardICSE
CBSE
Chemistry
"All The Best"
Time : 01:15:00 Hrs

Total Marks : 50
Section -ï Aï
1) 5.6 litres of oxygen at NTP is equivalent to 1

(a) 1 mole (b) 

mole (c) 
mole (d) 
mole
2) How many grams are contained in 1 gram atom of Na? 1

(a) 13 g (b) 1 g (c) 23 g (d) 

ïg
3) 12 g of Mg will react completely with an acid to give: 1

(a) 1 mole of O2 (b) 

mole of H2 (c) 1ïmole of H2 (d) 2ïmole of H2
4) Which of the following has the highest mass? 1
23
(a) 1 g atom of C (b) 
mole of CH4 (c) 10 mL of water (d) 3.011 x 10 atoms of oxygen
5) Which of the following carbocation is most stable? 1
   
(a)     (b)    (c)    (d)    
Section -ï B
6) If 2 L of N2ïis mixed with 2 L of H2at a constant temperature and pressure,then what will be the volume of 1

NH3ïformed?
7) What is the diyerence between 5.0 g and 5.00 g ? 1

u  
8) Ifï
  ïmolecules of N2ïreact completely with H2ïaccording to the equationï 1

     

ïthen calculate the number of molecules of NH3 formed.
9) In DNA and RNA, nitrogen atom is present in the ring system.Can Kjeldahl's method used for the estimation of 1

nitrogen present in these?Give reason

10) Will CCI4ïgive precipitate of AgCI on heating it with silver nitrate?Give reason for your answer. CCl4ïis a covalent 1

compound and does not give CI-ïions.

Section -ï C
11) Which one of the following will have the largest number of atoms? (i) ï 1g Au ( s ) (ii) ï1g Na ( s )ï (iii) 1g Liï( s ) (iv) 1g of 2

Cl2 ( g )
12) Calculate the atomic mass (average) of chlorine using the following data: 2

ï % Natural Abundance Molar Mass

35
CI75.77 34.9689
37
Cl24.23 36.9659
13) Write bond-line formulas for: Isopropyl alcohol, 2,3-Dimethylbutanal, Heptan-4-one. 2

14) Draw the resonance structures for the following compounds. Show the electron shiz using curved-arrow 2

notation.CH3CH=CHCH2
15) Which type of compounds are purified by steam distillation? 2

Section -ï D

u  
16) What volume of 0.250 M HCl (aq) is required to react completely with 22.6 g of sodium carbonate according to the 3

reaction ?         

   
17) Calculate the percentage by mass of chromium in the following oxide. 'CrO3' 3

18) Give a brief description of the principles of the following techniques taking an example in each case: 3

Chromatography.
19) (a) What do you understand by Homolytic fission? (b) What are carbanions? Give an example. 3
20) Discuss the chemistry of Lassaigne's test. 3

Section -ï E

u
21) Calcium carbonate reacts with aqueous HCI to give CaCI2ïand CO2ïaccording to the reation, CaCo3(s) + 2HCI(aq)ï 5

ïCaCl2(aq) + CO2ï(g) + H2O (l) What mass of CaCo3 is required to react completely with 25 mL of 0.75 M HCI?
22) (a) Wfult is the basic principle involved in the estimation of nitrogen by Dumas method. (b) In a Dumas nitrogen 5
3
estimation method, 0.30 g of an organic compound gave 50 cm of N2 collected at 300 K and 715 mm Hg pressure.
Calculate the percentage composition of nitrogen in the compound. (Vapour pressure of water at 300 K is 15 mm Hg)
23) Hoe does the inductive eyect of an alkyl group ayect the stability of these three intermediates? 5

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